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ZnO Nanorods (zno + nanorod)
Selected AbstractsTemplate Deformation-Tailored ZnO Nanorod/Nanowire Arrays: Full Growth Control and Optimization of Field-EmissionADVANCED FUNCTIONAL MATERIALS, Issue 19 2009Haibo Zeng Abstract Here, a facile and effective route toward full control of vertical ZnO nanorod (NR)/nanowire (NW) arrays in centimeter-scale areas and considerable improvement of field-emission (FE) performance is reported. Controlled deformation of colloidal crystal monolayer templates is introduced by heating near glass-transition temperature. The NR/NW density, uniformity, and tapering were all adjusted through selection of template size and deformation, and electrolyte composition. In line with the adjustments, the field-emission performance of the arrays is significantly improved. A low turn-on electric field of 1.8,V µm,1, a field-enhancement factor of up to 5,750, and an emitting current density of up to 2.5,mA cm,2 were obtained. These improved parameters would benefit their potential application in cold-cathode-based electronics. [source] Mechanically Powered Transparent Flexible Charge-Generating Nanodevices with Piezoelectric ZnO NanorodsADVANCED MATERIALS, Issue 21 2009Min-Yeol Choi Transparent flexible charge-generating piezoelectric nanodevices are developed. The resulting integrated nanodevice generates a noticeable current when it is pushed by application of an external load. Piezoelectric ZnO nanorod-based nanodevices with embossed PdAu top electrodes produce the highest output current density of approximately 10 ,A cm,2 at a load of 0.9 kgf. [source] FIB fabrication of ZnO nanotetrapod and cross-sensorPHYSICA STATUS SOLIDI (B) BASIC SOLID STATE PHYSICS, Issue 7 2010Lee Chow Abstract This article presents the fabrication of zinc oxide (ZnO) nanotetrapod and cross-nanorods-based sensors. This low-dimensional device is made in a focused ion beam set-up by using nanodeposition for metal electrodes. The gas response of the sensor based on an individual zinc oxide nanotetrapod and on crossed ZnO nanorod for detection of ultraviolet (UV) light and hydrogen at room temperature is presented. It is shown that ZnO tetrapod has potential application as UV and as chemical sensor with multi-terminal construction. The chemisorbed gas molecules on the ZnO surface can extract or donate electrons to ZnO and this effect was used to monitor the electrical resistance values change of the tetrapod sensor. ZnO tetrapod sensor demonstrates sensitivity and selectivity in resistance upon exposure to UV light, H2, O2, NH3, CO, CO2, and LPG gas. The resistivity change is different for UV and for H2 gas sensing. The presented ZnO sensor proves to be promising for application in various processes. [source] Sonochemical synthesis and characterization of ZnO nanorod/Ag nanoparticle compositesCRYSTAL RESEARCH AND TECHNOLOGY, Issue 11 2009Fei Li Abstract A simple sonochemical route for the synthesis of Ag nanoparticles on ZnO nanorods is reported. Ultrasonic irradiation of a mixture of ZnO nanorods, Ag(NH3)2+, and formaldehyde in an aqueous medium yields ZnO nanorod/Ag nanoparticle composites. The powder X-ray diffraction of the ZnO/Ag composites shows additional diffraction peaks corresponding to the face-center-cubic structured Ag crystalline, apart from the signals from the ZnO nanorods. Scanning electron microscopy and transmission electron microscopy images of the ZnO/Ag composites reveal that the ZnO nanorods are coated with Ag nanoparticles with a mean size of several tens nanometer. The absorption band of ZnO/Ag composites is distinctly broadened and red-shifted, indicating the strong interfacial interaction between ZnO nanorods and Ag nanoparticles. This sonochemical method is simple, mild and readily scaled up, affording a simple way for synthesis of other composites. (© 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Low temperature hydrothermal growth and optical properties of ZnO nanorodsCRYSTAL RESEARCH AND TECHNOLOGY, Issue 1 2009J. H. Yang Abstract Well-faceted hexagonal ZnO nanorods have been synthesized by a simple hydrothermal method at relative low temperature (90°C) without any catalysts or templates. Zinc oxide (ZnO) nanorods were grown in an aqueous solution that contained Zinc chloride (ZnCl2, Aldrich, purity 98%) and ammonia (25%). Most of the ZnO nanorods show the perfect hexagonal cross section and well-faceted top and side surfaces. The diameter of ZnO nanorods decreased with the reaction time prolonging. The samples have been characterized by X-ray powder diffraction (XRD) and scanning electron microscopy (SEM) measurement. XRD pattern confirmed that the as-prepared ZnO was the single-phase wurtzite structure formation. SEM results showed that the samples were rod textures. The surface-related optical properties have been investigated by photoluminescence (PL) spectrum and Raman spectrum. Photoluminescence measurements showed each spectrum consists of a weak band ultraviolet (UV) band and a relatively broad visible light emission peak for the samples grown at different time. It has been found that the green emission in Raman measurement may be related to surface states. (© 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Hydrothermal Growth: Polymer-Templated Hydrothermal Growth of Vertically Aligned Single-Crystal ZnO Nanorods and Morphological Transformations Using Structural Polarity (Adv. Funct.ADVANCED FUNCTIONAL MATERIALS, Issue 18 2010Mater. Abstract Position-configurable, vertical, single-crystalline ZnO nanorod arrays are fabricated via a polymer-templated hydrothermal growth method at a low temperature of 93 °C. A sol-gel processed dense c -oriented ZnO seed layer film is employed to grow nanorods along the c -axis direction [0001] regardless of any substrate crystal mismatches. Here, one-beam laser-interference lithography is utilized to fabricate nanoscale holes over an entire 2-in. wafer during the preparation of the polymer template. As such, vertically aligned ZnO nanorods can be grown from the seed layer exposed at the bottom of each hole. Furthermore, morphological transformations of the ZnO nanorods into pencil-like, needle-like, tubular, tree-like, and spherical shapes are obtained by controlling the growth conditions and utilizing the structural polarity of the ZnO nanorods. [source] Polymer-Templated Hydrothermal Growth of Vertically Aligned Single-Crystal ZnO Nanorods and Morphological Transformations Using Structural PolarityADVANCED FUNCTIONAL MATERIALS, Issue 18 2010Ki Seok Kim Abstract Position-configurable, vertical, single-crystalline ZnO nanorod arrays are fabricated via a polymer-templated hydrothermal growth method at a low temperature of 93 °C. A sol-gel processed dense c -oriented ZnO seed layer film is employed to grow nanorods along the c -axis direction [0001] regardless of any substrate crystal mismatches. Here, one-beam laser-interference lithography is utilized to fabricate nanoscale holes over an entire 2-in. wafer during the preparation of the polymer template. As such, vertically aligned ZnO nanorods can be grown from the seed layer exposed at the bottom of each hole. Furthermore, morphological transformations of the ZnO nanorods into pencil-like, needle-like, tubular, tree-like, and spherical shapes are obtained by controlling the growth conditions and utilizing the structural polarity of the ZnO nanorods. [source] Defect-Related Emissions and Magnetization Properties of ZnO NanorodsADVANCED FUNCTIONAL MATERIALS, Issue 7 2010Bharati Panigrahy Abstract A clear correlation between defect-related emissions and the magnetization of ZnO nanorods synthesized by a one-step aqueous chemical method is demonstrated. The relative contribution of the emission bands arising from various types of defects is determined and found to be linked with the size of the nanorods and annealing conditions. When the size of the nanorods and the annealing temperature are increased, the magnetization of pure ZnO nanorods decreases with the reduction of a defect-related band originating from singly charged oxygen vacancies (). With a sufficient increase of annealing temperature (at 900,°C), the nanorods show diamagnetic behavior. Combining with the electron paramagnetic resonance results, a direct link between the magnetization and the relative occupancy of the singly charged oxygen vacancies present on the surface of ZnO nanorods is established. [source] A "Nanoprism" Probe for Nano-optical ApplicationsADVANCED MATERIALS, Issue 12 2009Taekyeong Kim "Nanoprism" probes are fabricated for nano-optical applications. The fabrication process is scalable for mass-production, and can be used to prepare nanoprobes terminated with virtually any nanostructure, such as nanoprisms, ZnO nanorods, and nanoparticles. ANSOM imaging was performed on a nanoparticle using Au-nanoprism probes, revealing field localization at the vertices of the nanoprism. [source] Site-specific deposition of Ag nanoparticles on ZnO nanorod arrays via galvanic reduction and their SERS applicationsJOURNAL OF RAMAN SPECTROSCOPY, Issue 9 2010Wei Song Abstract A controllable heterostructure consisting of ZnO nanorod arrays with attached Ag nanoparticles at only one end has been synthesized via a facile and convenient galvanic reduction method. Scanning electron microscopic images of these nanostructures showed good selectivity of Ag deposition on the tip of ZnO nanorod arrays. The formation of these regular AgZnO heterogeneous nanorod arrays can be explained by a localization of the electrons at the ends of the ZnO nanorods after the electron transfer step. By tuning the reaction time and the concentration of silver nitrate, the density of Ag nanoparticles on the tip of ZnO nanorods can be well controlled. Owing to the introduction of Ag nanoparticles with different densities, the resulting AgZnO heterogeneous nanorod arrays have been proved to be a versatile substrate for surface-enhanced Raman scattering not only for common organic molecules but also for label-free protein detection. Copyright © 2009 John Wiley & Sons, Ltd. [source] Orientation and Dynamics of ZnO Nanorod Liquid Crystals in Electric FieldsMACROMOLECULAR RAPID COMMUNICATIONS, Issue 12 2010Matthias Zorn Abstract ZnO nanorod polymer hybrids (i.e., ZnO nanorods coated with a block copolymer with a short anchor block (dopamine) and a longer solubilizing block of polystyrene (PS)) form liquid crystalline (LC) phases if they are dispersed at high concentration e.g., in a PS oligomer matrix. Due to the high mobility of the low Tg -matrix the nanorod polymer hybrids show a switching behavior under an applied AC electric field. Hence, the orientation of the nanorod mesogens can be changed from planar (parallel to the substrate) to homeotropic (perpendicular) in full analogy to the switching of low molecular liquid crystals in an electric field. Dielectric measurements show that such a switching is mainly due to the cooperative LC behavior, because the rods themselves exhibit only a very small effective dipole moment. The process can be investigated by polarizing microscopy. SEM images show the orientations of the individual nanorods, which correspond to the Fredericks transition well known for liquid crystals aligned in an electric field. This was the first time such a transition could be visualized by electron microscopy due to the large nanorod mesogens. The observation is interesting to orient nanorods perpendicular to an electrode and can help to improve optoelectronic devices. [source] Solvothermal fabrication of ZnO nanorods using ethanolic quantum dot precursorsPHYSICA STATUS SOLIDI (A) APPLICATIONS AND MATERIALS SCIENCE, Issue 4 2009Yukihiro Hara Abstract ZnO nanorods were obtained by solvothermal reaction using quantum dot precursors suspended in ethanol. The ZnO suspensions were prepared from ethanolic zinc acetate solutions in the presence of lithium hydroxide, and treated by solvothermal synthesis under different reaction temperatures and duration times. Parameters of processing of these nanorods were investigated, including the concentration of precursors and solvothermal temperature. The ZnO nanorod powders were characterized by XRD, SEM, TEM, FT-IR, thermal analysis, and isothermal N2(g) adsorption analyses. Commercially available ZnO nanopowders were studied for comparison. Resulting ZnO nanorod powders were pure ZnO and showed higher surfaces area than commercial ZnO nanopowders. Length and diameter of ZnO nanorods depended on the concentration of precursors and the annealing temperature employed. (© 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Modeling of ZnO nanorods for evanescent field optical sensorsPHYSICA STATUS SOLIDI (A) APPLICATIONS AND MATERIALS SCIENCE, Issue 10 2007Sandra Börner Abstract The optical wave guiding properties of ZnO nanorods are simulated and studied in detail using a block-iterative frequency-domain method and the results of a finite difference method as reference data. The simulations are performed for different wavelengths in the infrared spectral region that are related to specific gas absorption lines. Here both single ZnO nanorods and nanorod arrays with varying period lengths are investigated. The evanescent field distributions and penetration depths into the surrounding media are analyzed and compared as a function of wavelength and rod diameter. Our results give a general overview on the size range where ZnO nanorods may be used for evanescent field interaction based sensors for the detection of gas molecules like CO, CO2 or O2. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Growth and characterization study of multidimensional hierarchical ZnO nanostructuresPHYSICA STATUS SOLIDI (B) BASIC SOLID STATE PHYSICS, Issue 5 2007Dong Jun Park Abstract ZnO multidimensional hierarchical structure was successfully fabricated with the sequence of ZnO top layers/ZnO nanorods/ZnO buffer/Si(111) substrate by continuous controlling growth condition in metal organic chemical vapor deposition (MOCVD) system. Transmission electron microscopy (TEM) showed that ZnO nanorods in hierarchical structure had a single crystal hexagonal wurtzite structure with ,0001,ZnO growth direction. Only near band edge (NBE) emissions with very weak deep level emission are observed around 3.28 eV. This indicates that ZnO hierarchical structure grown by MOCVD shows a good optical quality and less interior defects. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Improvement of chemical stability of aqueous solution grown ZnO nanorods by aminosilane modificationPHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 6 2010Ken-ichi Ogata Abstract Aiming at stable biosensing operation, aqueous-grown ZnO nanorods on sapphire substrates were examined their chemical stability against the immersion in HCl solution. Density and diameter of the ZnO nanorods were remained but their height was shortened when immersed with aminosilane modification while bare ZnO nanorods were completely disappeared after 5 min immersion, indicating that the aminosilane modification is useful to improve the chemical stability of ZnO nanolods even though the membrane by the silanezation process is not fully stable to HCl solution. (© 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Fabrication of porous ZnO nanostructures and morphology controlPHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 5 2007Sang Hyun Lee Abstract Porous ZnO nanostructures were easily fabricated by annealing and etching of as-grown ZnO nanorods using an aqueous solution method at low temperature. The density of ZnO nanorods was changed by repetition of coating and drying of zinc acetate hydrate in ethanol. The annealing process is a very critical step to make porous ZnO nanorods because nano-sized pore are formed at this step. Without annealing, pores could not be observed at the surface of ZnO nanorods. Furthermore, pore the size gets larger in etching steps following the annealing. The structural and optical properties for porous ZnO nanostructures were investigated using TEM and PL. Porous ZnO nanostructures were grown along the c-axis and pores were distributed in the whole body. PL intensity was increased by annealing and etching. This is ascribed to the improved crystallinity and large surface area. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] | |||||||||||||