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Zircon
Kinds of Zircon Terms modified by Zircon Selected AbstractsAccurate U-Pb Age and Trace Element Determinations of Zircon by Laser Ablation-Inductively Coupled Plasma-Mass SpectrometryGEOSTANDARDS & GEOANALYTICAL RESEARCH, Issue 3 2004Honglin Yuan LA-ICP-MS; laser excimer; zircon; géochronologie; éléments en trace Various zircons of Proterozoic to Oligocene ages (1060-31 Ma) were analysed by laser ablation-inductively coupled plasma-mass spectrometry. Calibration was performed using Harvard reference zircon 91500 or Australian National University reference zircon TEMORA 1 as external calibrant. The results agree with those obtained by SIMS within 2s error. Twenty-four trace and rare earth elements (P, Ti, Cr, Y, Nb, fourteen REE, Hf, Ta, Pb, Th and U) were analysed on four fragments of zircon 91500. NIST SRM 610 was used as the reference material and 29Si was used as internal calibrant. Based on determinations of four fragments, this zircon shows significant intra-and inter-fragment variations in the range from 10% to 85% on a scale of 120 ,m, with the variation of REE concentrations up to 38.7%, although the chondrite-normalised REE distributions are very similar. In contrast, the determined age values for zircon 91500 agree with TIMS data and are homogeneous within 8.7 Ma (2s). A two-stage ablation strategy was developed for optimising U-Pb age determinations with satisfactory trace element and REE results. The first cycle of ablation was used to collect data for age determination only, which was followed by continuous ablation on the same spot to determine REE and trace element concentrations. Based on this procedure, it was possible to measure zircon ages as low as 30.37 0.39 Ma (MSWD = 1.4; 2s). Other examples for older zircons are also given. Différents zircons d'âges variant du Protérozoïque à l'Oligocène (1060-31 Ma) ont été analysés par spectrométrie avec source à plasma induit et ablation laser. La calibration a été faite en utilisant le zircon 91500 de référence de Harvard ou le zircon TEMORA 1 de référence de l'Université Nationale Australienne comme calibrant externe. Les résultats sont en accord avec ceux obtenus par SIMS aux erreurs analytiques près (2s). Vingt-quatre éléments en trace et Terres Rares (P, Ti, Cr, Y, Nb, quatorze ETR, Hf, Ta, Pb, Th et U) ont été analysés sur quatre fragments du zircon 91500. Le standard SRM 610 de NIST a été utilisé comme matériau de référence et 29Si comme calibrant interne. À partir des déterminations faites sur ces quatre fragments, ce zircon montre des variations intra et inter fragments de l'ordre de 10%à 85%à une échelle de 120 ,m, avec des variations des concentrations de Terres Rares allant jusquà 38.7%, bien que le spectre de Terres Rares normalisé aux chondrites reste très constant. Au contraire, les âges déterminés pour le zircon 91500 sont en accord avec les résultats de TIMS et sont homogènes à 8.7 Ma près (2s). Une stratégie d'ablation en deux étapes a été développée pour optimiser les déterminations d'âges U-Pb, et avoir des résultats de Terres Rares et d'éléments en trace satisfaisants. Le premier cycle d'ablation était utilisé pour collecter les données nécessaires à la détermination de l'âge seulement et était suivi d'un cycle d'ablation continue sur le même spot, pour déterminer les concentrations en Terres Rares et en éléments en trace. Grâce à cette procédure, il a été possible de mesurer des âges sur zircons aussi récents que 30.37 0.39 Ma (MSWD = 1.4; 2s). D'autres exemples sur des zircons plus vieux sont aussi donnés. [source] Geology of the summit limestone of Mount Qomolangma (Everest) and cooling history of the Yellow Band under the Qomolangma detachmentISLAND ARC, Issue 4 2005Harutaka Sakai Abstract Newly discovered peloidal limestone from the summit of Mount Qomolangma (Mount Everest) contains skeletal fragments of trilobites, ostracods and crinoids. They are small pebble-sized debris interbedded in micritic bedded limestone of the Qomolangma Formation, and are interpreted to have been derived from a bank margin and redeposited in peri-platform environments. An exposure of the Qomolangma detachment at the base of the first step (8520 m), on the northern slope of Mount Qomolangma was also found. Non-metamorphosed, strongly fractured Ordovician limestone is separated from underlying metamorphosed Yellow Band by a sharp fault with a breccia zone. The 40Ar,39Ar ages of muscovite from the Yellow Band show two-phase metamorphic events of approximately 33.3 and 24.5 Ma. The older age represents the peak of a Barrovian-type Eo-Himalayan metamorphic event and the younger age records a decompressional high-temperature Neo-Himalayan metamorphic event. A muscovite whole-rock 87Rb,86Sr isochron of the Yellow Band yielded 40.06 ± 0.81 Ma, which suggests a Pre-Himalayan metamorphism, probably caused by tectonic stacking of the Tibetan Tethys sediments in the leading margin of the Indian subcontinent. Zircon and apatite grains, separated from the Yellow Band, gave pooled fission-track ages of 14.4 ± 0.9 and 14.4 ± 1.4 Ma, respectively. These new chronologic data indicate rapid cooling of the hanging wall of the Qomolangma detachment from approximately 350°C to 130°C during a short period (15.5,14.4 Ma). [source] Ordovician high-grade metamorphism of a newly recognised late Neoproterozoic terrane in the northern Harts Range,central AustraliaJOURNAL OF METAMORPHIC GEOLOGY, Issue 4 2001I. S. Buick Abstract Granulite facies rocks from the northernmost Harts Range Complex (Arunta Inlier, central Australia) have previously been interpreted as recording a single clockwise cycle of presumed Palaeoproterozoic metamorphism (800,875 °C and >9,10 kbar) and subsequent decompression in a kilometre-scale, E-W striking zone of noncoaxial, high-grade (c. 700,735 °C and 5.8,6.4 kbar) deformation. However, new SHRIMP U-Pb age determinations of zircon, monazite and titanite from partially melted metabasites and metapelites indicate that granulite facies metamorphism occurred not in the Proterozoic, but in the Ordovician (c. 470 Ma). The youngest metamorphic zircon overgrowths from two metabasites (probably meta-volcaniclastics) yield 206Pb/238U ages of 478±4 Ma and 471±7 Ma, whereas those from two metapelites yield ages of 463±5 Ma and 461±4 Ma. Monazite from the two metapelites gave ages equal within error to those from metamorphic zircon rims in the same rock (457±5 Ma and 462±5 Ma, respectively). Zircon, and possibly monazite ages are interpreted as dating precipitation of these minerals from crystallizing melt within leucosomes. In contrast, titanite from the two metabasites yield 206Pb/238U ages that are much younger (411±5 Ma & 417±7 Ma, respectively) than those of coexisting zircon, which might indicate that the terrane cooled slowly following final melt crystallization. One metabasite has a second titanite population with an age of 384±7 Ma, which reflects titanite growth and/or recrystallization during the 400,300 Ma Alice Springs Orogeny. The c. 380 Ma titanite age is indistinguishable from the age of magmatic zircon from a small, late and weakly deformed plug of biotite granite that intruded the granulites at 387±4 Ma. These data suggest that the northern Harts Range has been subject to at least two periods of reworking (475,460 Ma & 400,300 Ma) during the Palaeozoic. Detrital zircon from the metapelites and metabasites, and inherited zircon from the granite, yield similar ranges of Proterozoic ages, with distinct age clusters at c. 1300,1000 and c. 650 Ma. These data imply that the deposition ages of the protoliths to the Harts Range Complex are late Neoproterozoic or early Palaeozoic, not Palaeoproterozoic as previously assumed. [source] Fixed partial dentures: all-ceramics, fibre-reinforced composites and experimental systemsJOURNAL OF ORAL REHABILITATION, Issue 9 2003M. Rosentritt Summary, The aim of this in vitro study was to compare the fracture strength of three-unit FPDs (fixed partial dentures) and three-unit inlay FPDs after a simulated 5-year oral wearing period. The restorations were made of a pressable all-ceramic (Empress 2) and two specially designed, experimentally fixed partial dentures combining ceramics with dental composite. Three-unit FPDs and inlay FPDs were manufactured and were adhesively luted onto human molars. After thermal cycling and mechanical loading in an artificial environment, the fracture strength was determined. Zircon-based milled ceramic (Lava) three-unit FPDs were used as a control. The zircon ceramic and the fibre-based ceramic three-unit FPDs showed median fracture values between 1000 and 1400 N. For composite veneered zircon FPDs a fracture strength of about 800 N and for all-ceramic Empress 2 of about 350 N could be determined. The results for the inlay FPDs were between 1300 N and 1400 N for FRC/ceramic, 1000 N for zircon/composite and 500 N for all-ceramic restorations. The all-ceramic showed higher fracture resistance applied as inlay FPDs. The described hybrid techniques combining ceramics and composites could represent an interesting procedure for further investigations and, eventually, clinical implication. [source] Zirconia,Silica,Carbon Coatings on Ceramic FibersJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 10 2004Emmanuel E. Boakye Precursors for zircon,carbon mixtures were made to coat fibers for ceramic-matrix composites. Precursors were characterized using XRD, TGA, and DTA. Zircon formed from vanadium- or lithium-doped precursors after heat treatments at ,900°C in air, but it did not form at 1200°,1400°C in argon when large amounts of carbon were added. Some precursors were used to coat NextelÔ 720 and Hi-NicalonÔ fibers. The coatings were characterized using SEM and TEM, and coated-fiber tensile strengths were measured. Although zircon formed in powders, only tetragonal-zirconia,silica mixed phases formed in fiber coatings at 1200°C in air. Loss of vanadium oxide flux to the fibers may have caused the lack of conversion to zircon. The strengths of the coated fibers were severely degraded after heat treatment at ,1000°C in air, but not in argon. The coated fibers were compared with zirconia,carbon-coated fibers made using similar methods. Mechanisms for fiber strength degradation are discussed. [source] New Route for the Extraction of Crude Zirconia from ZirconJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 9 2002Nicholas J. Welham A commercial grade of zircon (ZrSiO4) concentrate was mechanically milled with MgO for up to 100 h in a laboratory-scale mill. The resultant powders were subjected to thermal processing, chemical leaching, and X-ray diffraction (XRD). There was no direct evidence of reaction during the milling step, with no new phases evident from XRD. Leaching of the powder showed that a reaction had occurred, and increased solubility with milling time was attributed to the formation of a nanostructured Mg-Zr-Si oxide, which dissolved congruently. Heating the powders resulted in a number of thermal events, including the formation/crystallization of ZrO2 and Mg2SiO4. Thermal treatment of the milled powders allowed selective chemical leaching of the magnesium and silicon, leaving a powder containing ,90% ZrO2. [source] Fabrication and Characterization of Cordierite/Zircon Composites by Reaction Sintering: Formation Mechanism of ZirconJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 6 2002En-Hai Sun The formation mechanism of ZrSiO4 in the cordierite-ZrO2 system was studied in the temperature range of 1250° to 1400°C by X-ray diffraction analysis and discussed by analyzing experimental data using some reported reaction models. Nuclei growth models were found to describe the reaction well, and a satisfactory fit was obtained by applying the Avrami equation to estimate the reaction rate constant ,. Different values of the time exponent m were obtained at different temperatures: 0.32 at 1250°C, 0.34 at 1300°C, 0.39 at 1350°C, and 0.49 at 1400°C. The results indicate that there is a progressive change in reaction mechanism. [source] Detrital Zircon of 4100 Ma in Quartzite in Burang, TibetACTA GEOLOGICA SINICA (ENGLISH EDITION), Issue 6 2006DUO Ji Abstract: A detrital zircon aged 4.1 Ga is discovered by the SHRIMP U-Pb method in a quartzite in Burang County, western Tibet. This is presently the oldest single-grain detrital zircon in China. The Th-U ratios of the two testing points of the >4.0 Ga zircon are between 0.76 and 0.86, indicating their magmatic origin. This discovery has offered an important age for investigating the geological evolution of the Qinghai-Tibet Plateau. [source] U-Pb SHRIMP Dating of Zircon from Quartz Veins of the Yangshan Gold Deposit in Gansu Province and Its Geological SignificanceACTA GEOLOGICA SINICA (ENGLISH EDITION), Issue 2 2004QI Jinzhong Abstract, The Yangshan gold deposit is a super-large fine-grained disseminated gold deposit located in southern Gansu Province. Its metallogenic age has been determined by using the cathodoluminescence image and ion probe U-Pb dating techniques. It is found that zircons from quartz veinlet of the fine-grained disseminated gold ore show characters of magmatic origin with prism idiomorphism, oscillatory zoning and dominant Th/U ratios of 0.5,1.5. Three main populations of zircons are obtained, giving average 206Pb/238U ages of 197.6±1.7 Ma, 126.9±3.2 Ma and 51.2±1.3 Ma respectively. The first age corresponds to the K-Ar age of the plagiogranite dike, while the latter two ages indicate that buried Cretaceous and Tertiary intrusives exist in the orefield, suggesting that the Yangshan gold deposit was genetically related to the three magmatic hydrothermal activities. By contrast, zircons from coarse gold-bearing quartz vein in the mining area are much older than the host rock, indicating that the vein was formed earlier and was not contaminated by later magmatic fluids. It is concluded that the coupling of multiperiodic hydrothermal activities in the mining area has contributed a lot to mineralization of the Yangshan gold deposit. [source] U-Pb Age Determination for Seven Standard Zircons using Inductively Coupled Plasma,Mass Spectrometry Coupled with Frequency Quintupled Nd-YAG (, = 213 nm) Laser Ablation System: Comparison with LA-ICP-MS Zircon Analyses with a NIST Glass Reference MaterialRESOURCE GEOLOGY, Issue 2 2008Yuji Orihashi Abstract This paper evaluates the analytical precision, accuracy and long-term reliability of the U-Pb age data obtained using inductively coupled plasma,mass spectrometry (ICP-MS) with a frequency quintupled Nd-YAG (, = 213nm) laser ablation system. The U-Pb age data for seven standard zircons of various ages, from 28 Ma to 2400 Ma (FCT, SL13, 91500, AS3, FC1, QGNG and PMA7) were obtained with an ablation pit size of 30 ,m diameter. For 207Pb/206Pb ratio measurement, the mean isotopic ratio obtained on National Institute of Standards and Technology (NIST) SRM610 over 4 months was 0.9105 ± 0.0014 (n = 280, 95% confidence), which agrees well with the published value of 0.9096. The time-profile of Pb/U ratios during single spot ablation showed no significant difference in shape from NIST SRM610 and 91500 zircon standards. These results encouraged the use of the glass standard as a calibration standard for the Pb/U ratio determination for zircons with shorter wavelength (, = 213 nm) laser ablation. But 206Pb/238U and 207Pb/235U ages obtained by this method for seven zircon standards are systematically younger than the published U-Pb ages obtained by both isotope dilution,thermal ionization mass spectrometry (ID-TIMS) and sensitive high-resolution ion-microprobe (SHRIMP). Greater discrepancies (3,4% younger ages) were found for the 206Pb/238U ages for SL13, AS3 and 91500 zircons. The origin of the differences could be heterogeneity in Pb/U ratio on SRM610 between the different disks, but a matrix effect accuracy either in the ICP ion source or in the ablation-transport processes of the sample aerosols cannot be neglected. When the 206Pb/238U (= 0.2302) newly defined in the present study is used, the measured 206Pb/238U and 207Pb/235U ages for the seven zircon standards are in good agreement with those from ID-TIMS and SHRIMP within ±2%. This suggests that SRM610 glass standard is suitable for ICP-MS with laser ablation sampling (LA-ICP-MS) zircon analysis, but it is necessary to determine the correction factor for 206Pb/238U by measuring several zircon standards in individual laboratories. [source] Miocene to Recent exhumation of the central Himalaya determined from combined detrital zircon fission-track and U/Pb analysis of Siwalik sediments, western NepalBASIN RESEARCH, Issue 4 2006Matthias Bernet ABSTRACT Fission-track (FT) analysis of detrital zircon from synorogenic sediment is a well-established tool to examine the cooling and exhumation history of convergent mountain belts, but has so far not been used to determine the long-term evolution of the central Himalaya. This study presents FT analysis of detrital zircon from 22 sandstone and modern sediment samples that were collected along three stratigraphic sections within the Miocene to Pliocene Siwalik Group, and from modern rivers, in western and central Nepal. The results provide evidence for widespread cooling in the Nepalese Himalaya at about 16.0±1.4 Ma, and continuous exhumation at a rate of about 1.4±0.2 km Myr,1 thereafter. The ,16 Ma cooling is likely related to a combination of tectonic and erosional activity, including movement on the Main Central thrust and Southern Tibetan Detachment system, as well as emplacement of the Ramgarh thrust on Lesser Himalayan sedimentary and meta-sedimentary units. The continuous exhumation signal following the ,16 Ma cooling event is seen in connection with ongoing tectonic uplift, river incision and erosion of lower Lesser Himalayan rocks exposed below the MCT and Higher Himalayan rocks in the hanging wall of the MCT, controlled by orographic precipitation and crustal extrusion. Provenance analysis, to distinguish between Higher Himalayan and Lesser Himalayan zircon sources, is based on double dating of individual zircons with the FT and U/Pb methods. Zircons with pre-Himalayan FT cooling ages may be derived from either nonmetamorphic parts of the Tethyan sedimentary succession or Higher Himalayan protolith that formerly covered the Dadeldhura and Ramgarh thrust sheets, but that have been removed by erosion. Both the Higher and Lesser Himalaya appear to be sources for the zircons that record either ,16 Ma cooling or the continuous exhumation afterwards. [source] Paleoproterozoic, High-Metamorphic, Metasedimentary Units of Siberian CratonACTA GEOLOGICA SINICA (ENGLISH EDITION), Issue 5 2009Lena URMANTSEVA Abstract: Sensitive, high-resolution ion microprobe zircon U,Pb ages of Paleoproterozoic, high-grade, metasedimentary rocks from the south-western part of the Siberian Craton are reported. Early Precambrian, high-grade complexes, including garnet,biotite, hypersthene,biotite, and cordierite-bearing gneisses compose the Irkut terrane of the Sharyzhalgay Uplift. Protoliths of studied gneisses correspond to terrigenous sediments, ranging from greywacke to shale. The paragneiss model Nd ages of 2.4,3.1 Ga indicate Archean-to-Paleoproterozoic source provinces. Zircons from gneisses show core-rim textures in cathodoluminescence (CL) image. Round or irregular shaped cores indicate detrital origin. Structureless rims with low Th/U are metamorphic in origin. The three age groups of detrital cores are: ,2.7, ,2.3, and 1.95,2 Ga. The ages of metamorphic rims range from 1.86 to 1.85 Ga; therefore, the sediments were deposited between 1.95 and 1.86 Ga and derived from Archean and Paleoproterozoic source rocks. It should be noted that Paleoproterozoic metasedimentary rocks of the Irkut Block are not unique. High-grade metaterrigenous sediments, with model Nd ages ranging from 2.3 to 2.5 Ga, are widely distributed within the Aldan and Anabar Shields of the Siberian Craton. The same situation is observed in the North China Craton, where metasedimentary rocks contain detrital igneous zircon grains with ages ranging from 3 to 2.1 Ga (Wan et al., 2006). All of these sedimentary units were subjected to Late Paleoproterozoic metamorphism. In the Siberian Craton, the Paleoproterozoic sedimentary deposits are possibly marked passive margins of the Early Precambrian crustal blocks, and their high-grade metamorphism was related to the consolidation of the Siberian Craton. [source] Petrographic and SHRIMP Studies of Zircons from the Caledonian Xiongdian Eclogite, Northwestern Dabie MountainsACTA GEOLOGICA SINICA (ENGLISH EDITION), Issue 4 2000JIAN Ping Abstract The Xiongdian eclogite occurring in the Sujiahe tectonic mélange zone at Luoshan County, Henan Province, in the western Dabie Mountains, is typical high-pressure (HP)-ultrahigh-pressure (UHP) and medium-temperature eclogite. The occurrence, internal texture and surface characteristics of zircons in eclogite were studied rather systematically petrographically combined with the cathodoluminescence (CL) and scanning electron microscope (SEM) methods. Zircons are mainly hosted in garnet and other metamorphic minerals with sharp boundaries, have a multifaceted morphology and are homogeneous or exhibit a metamorphic growth texture in the interior, thus indicating that they are the product of metamorphism. SHRIMP analyses give zircon 206Pb/238U ages of 335 to 424 Ma and show a certain degree of radiogenic Pb loss; therefore it may be inferred that the age of 424±5 Ma represents the minimum age of a HP-UHP metamorphic age. From the above analyses coupled with previous Sm-Nd, 40Ar- 39Ar, U-Pb and 207Pb/206Pb age data, it is suggested that the peak metamorphic age of the Xiongdian eclogite should be between 424 and 480 Ma. This study further validate the view of the existence of a Caledonian HP-UHP metamorphic event in the western Dabie Mountains. [source] Structure, reactivity and spectroscopic properties of minerals from lateritic soils: insights from ab initio calculationsEUROPEAN JOURNAL OF SOIL SCIENCE, Issue 4 2007E. Balan Summary We review here some recent applications of ab initio calculations to the modelling of spectroscopic and energetic properties of minerals, which are key components of lateritic soils or govern their geochemical properties. Quantum mechanical ab initio calculations are based on density functional theory and density functional perturbation theory. Among the minerals investigated, zircon is a typical resistant primary mineral. Its resistance to weathering is at the origin of the peculiar geochemical behaviour of Zr, an element often used in mass balance calculations of continental weathering. Numerical modelling gives a unique picture of the origin of the chemical durability and radiation-induced amorphization of zircon. We also present several applications of ab initio calculations to the description of properties of secondary minerals, such as kaolinite-group minerals and gibbsite. Special attention is given to the calculation of infrared and Raman spectra. Surface properties and particle shape are major properties of finely-divided materials such as clay minerals. We show how theoretical modelling of infrared spectroscopic data provides information on natural samples at both the microscopic (atomic structure) and macroscopic (particle shape) length-scale. The systematic comparison of experimental and theoretical data significantly improves our understanding of mineral transformations during soil formation and evolution in lateritic environments. [source] Petrography and provenance of Laecanius Amphorae from Istria, northern Adriatic region, CroatiaGEOARCHAEOLOGY: AN INTERNATIONAL JOURNAL, Issue 5 2006Maria A. Mange Amphorae sherds from the Laecanius workshop of Roman Istria (10,5 B.C. and 78 A.D.), Croatia, were studied by integrating archaeological and geological techniques including fabric analysis, thin-section petrography, X-ray diffractometry (XRD), and heavy mineral analysis. The fabric of the sherds showed distinctive characteristics, permitting their classification and allocation into nine fabric groupss. Petrography revealed that quartz is the dominant clastic component, whereas carbonate is common as temper; XRD provided information on firing temperatures that ranged between 750 and 900°C. The sherds contain diverse heavy mineral suites with generally high epidote and garnet proportions; zircon is occasionally important. Garnet/epidote ratios and the presence of diagnostic species (pyroxene, hornblende) showed systematic variations that coincided with similar variations in fabric characteristics. Heavy mineral signatures of amphorae produced in other workshops proved essential in differentiating them from Laecanius sherds. A comparative heavy mineral analysis of terra rossa samples from the vicinity of the workshop indicated that terra rossa was the major source for the paste. Differences observed in the heavy mineral composition of the sherds and terra rossa were interpreted by the spatial heterogeneity of the latter and the mixing of the paste with sandy temper. Fresh Adriatic sponge spicules in the majority of Laecanius sherds and the temper-derived, generally immature heavy mineral assemblages suggest that sandy deposits from the Adriatic were used for the clastic temper. © 2006 Wiley Periodicals, Inc. [source] The syn-collisional Danac,obas, biotite leucogranite derived from the crustal thickening in central Anatolia (K,r,kkale), TurkeyGEOLOGICAL JOURNAL, Issue 5 2005bel Tatar Abstract The Behrekda, composite batholith, which crops out as a huge N,S-trending plutonic body in central Anatolia, Turkey, consists of five mappable granitoid units of Late Cretaceous age. They are (1) the S-type, peraluminous Danac,obas, biotite leucogranite, (2) the I-type, hybrid, metaluminous Konur K-feldspar megacrystic quartz monzonite, (3) the mafic A-type, alkaline Kizdede monzogabbro, (4) the felsic A-type, alkaline Hasandede quartz syenite/monzonite, and (5) the M-type, low-K tholeiitic Yeniköy tonalite. The S-type Danac,obas, biotite leucogranite constitutes the oldest intrusive unit in the mapped area. It has coarse- to medium-crystalline texture and consists of quartz, orthoclase and plagioclase, with variable amounts of biotite and accessory minerals, including apatite, zircon and opaque phases. K-Ar age dating of biotite separates, yields cooling ages of 69.1,±,1.42 and 71.5,±,1.45,Ma for the Danac,obas, biotite leucogranite. Major-element, trace-element, and rare-earth element geochemical data suggest an exclusively peraluminous, S-type, high-K calc-alkaline, upper crustal genesis for the Danac,obas, biotite leucogranite. This petrogenetic interpretation is also supported by oxygen-isotope data from quartz separates, with a mean value of 10.58,±,0.11 , of ,18OVSMOW value. The magma source of the Danac,obas, biotite leucogranite is proposed to have been a syn-collisional leucogranitic melt derived by anatexis of high-grade metasediments of the Central Anatolian Crystalline Complex during peak conditions of regional metamorphism. This metamorphic event was induced by crustal thickening which was a result of Late Cretaceous collision between the Eurasia and Tauride,Anatolide Platform along the ,zmir,Ankara,Erzincan Suture Zone in central Anatolia. Copyright © 2005 John Wiley & Sons, Ltd. [source] A precisely dated Proterozoic palaeomagnetic pole from the North China craton, and its relevance to palaeocontinental reconstructionGEOPHYSICAL JOURNAL INTERNATIONAL, Issue 1 2000Henry C. Halls A palaeomagnetic pole position, derived from a precisely dated primary remanence, with minimal uncertainties due to secular variation and structural correction, has been obtained for China's largest dyke swarm, which trends for about 1000 km in a NNW direction across the North China craton. Positive palaeomagnetic contact tests on two dykes signify that the remanent magnetization is primary and formed during initial cooling of the intrusions. The age of one of these dykes, based on U,Pb dating of primary zircon, is 1769.1 ± 2.5 Ma. The mean palaeomagnetic direction for 19 dykes, after structural correction, is D = 36°, I = , 5°, k = 63, ,95 = 4°, yielding a palaeomagnetic pole at Plat=36°N, Plong=247°E, dp = 2°, dm = 4° and a palaeolatitude of 2.6°S. Comparison of this pole position with others of similar age from the Canadian Shield allows a continental reconstruction that is compatible with a more or less unchanged configuration of Laurentia, Siberia and the North China craton since about 1800 Ma [source] Accurate U-Pb Age and Trace Element Determinations of Zircon by Laser Ablation-Inductively Coupled Plasma-Mass SpectrometryGEOSTANDARDS & GEOANALYTICAL RESEARCH, Issue 3 2004Honglin Yuan LA-ICP-MS; laser excimer; zircon; géochronologie; éléments en trace Various zircons of Proterozoic to Oligocene ages (1060-31 Ma) were analysed by laser ablation-inductively coupled plasma-mass spectrometry. Calibration was performed using Harvard reference zircon 91500 or Australian National University reference zircon TEMORA 1 as external calibrant. The results agree with those obtained by SIMS within 2s error. Twenty-four trace and rare earth elements (P, Ti, Cr, Y, Nb, fourteen REE, Hf, Ta, Pb, Th and U) were analysed on four fragments of zircon 91500. NIST SRM 610 was used as the reference material and 29Si was used as internal calibrant. Based on determinations of four fragments, this zircon shows significant intra-and inter-fragment variations in the range from 10% to 85% on a scale of 120 ,m, with the variation of REE concentrations up to 38.7%, although the chondrite-normalised REE distributions are very similar. In contrast, the determined age values for zircon 91500 agree with TIMS data and are homogeneous within 8.7 Ma (2s). A two-stage ablation strategy was developed for optimising U-Pb age determinations with satisfactory trace element and REE results. The first cycle of ablation was used to collect data for age determination only, which was followed by continuous ablation on the same spot to determine REE and trace element concentrations. Based on this procedure, it was possible to measure zircon ages as low as 30.37 0.39 Ma (MSWD = 1.4; 2s). Other examples for older zircons are also given. Différents zircons d'âges variant du Protérozoïque à l'Oligocène (1060-31 Ma) ont été analysés par spectrométrie avec source à plasma induit et ablation laser. La calibration a été faite en utilisant le zircon 91500 de référence de Harvard ou le zircon TEMORA 1 de référence de l'Université Nationale Australienne comme calibrant externe. Les résultats sont en accord avec ceux obtenus par SIMS aux erreurs analytiques près (2s). Vingt-quatre éléments en trace et Terres Rares (P, Ti, Cr, Y, Nb, quatorze ETR, Hf, Ta, Pb, Th et U) ont été analysés sur quatre fragments du zircon 91500. Le standard SRM 610 de NIST a été utilisé comme matériau de référence et 29Si comme calibrant interne. À partir des déterminations faites sur ces quatre fragments, ce zircon montre des variations intra et inter fragments de l'ordre de 10%à 85%à une échelle de 120 ,m, avec des variations des concentrations de Terres Rares allant jusquà 38.7%, bien que le spectre de Terres Rares normalisé aux chondrites reste très constant. Au contraire, les âges déterminés pour le zircon 91500 sont en accord avec les résultats de TIMS et sont homogènes à 8.7 Ma près (2s). Une stratégie d'ablation en deux étapes a été développée pour optimiser les déterminations d'âges U-Pb, et avoir des résultats de Terres Rares et d'éléments en trace satisfaisants. Le premier cycle d'ablation était utilisé pour collecter les données nécessaires à la détermination de l'âge seulement et était suivi d'un cycle d'ablation continue sur le même spot, pour déterminer les concentrations en Terres Rares et en éléments en trace. Grâce à cette procédure, il a été possible de mesurer des âges sur zircons aussi récents que 30.37 0.39 Ma (MSWD = 1.4; 2s). D'autres exemples sur des zircons plus vieux sont aussi donnés. [source] Further Characterisation of the 91500 Zircon CrystalGEOSTANDARDS & GEOANALYTICAL RESEARCH, Issue 1 2004Michael Wiedenbeck zircon 91500; matériau de référence; intercomparaison entre techniques; valeurs de travail This paper reports the results from a second characterisation of the 91500 zircon, including data from electron probe microanalysis, laser ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS), secondary ion mass spectrometry (SIMS) and laser fluorination analyses. The focus of this initiative was to establish the suitability of this large single zircon crystal for calibrating in situ analyses of the rare earth elements and oxygen isotopes, as well as to provide working values for key geochemical systems. In addition to extensive testing of the chemical and structural homogeneity of this sample, the occurrence of banding in 91500 in both backscattered electron and cathodoluminescence images is described in detail. Blind intercomparison data reported by both LA-ICP-MS and SIMS laboratories indicate that only small systematic differences exist between the data sets provided by these two techniques. Furthermore, the use of NIST SRM 610 glass as the calibrant for SIMS analyses was found to introduce little or no systematic error into the results for zircon. Based on both laser fluorination and SIMS data, zircon 91500 seems to be very well suited for calibrating in situ oxygen isotopic analyses. Cet article présente les résultats d'une nouvelle caractérisation du zircon 91500, dont des données de microanalyse par sonde électronique, d'analyse par ablation laser en couplage à un ICP-MS, d'analyse par sonde ionique (SIMS) et d'analyse par fluorination laser. Le but de cette étude etait de démontrer que ce large monocristal de zircon pouvait être utilisé pour la calibration d'analyses in situ de Terres Rares et des isotopes de I'Oxygène, et en même temps de fournir des valeurs "de travail" pour un certain nombre de systémes géochimiques cruciaux. En complément des tests systématiques d'homogénéité de I'échantillon, tant chimiquement que structurellement, /'ex/sfence, dans le zircon 91500, de zonages visibles en électrons retro diffusés et en cathodoluminescence, est décrite en détail, line comparaison en aveugle des résultats obtenus par LA-ICP-MS et par SIMS, dans des laboratoires différents, montre que les différences systématiques entre les ensembles de données obtenues par ces deux techniques sont très faibles. De plus, I'utilisation du verre NIST SRM 610 comme calibrant lors de I'analyse par SIMS n'introduit qu'une erreur systématique très faible si ce n'est inexistante sur les résultats du zircon. Sur la base des analyses par fluorination laser et par SIMS, le zircon 91500 semble être parfaitement adapte a son utilisation pour la calibration d'analyses isotopiques in situ d'oxygène. [source] SHRIMP U,Pb zircon chronology of ultrahigh-temperature spinel,orthopyroxene,garnet granulite from South Altay orogenic belt, northwestern ChinaISLAND ARC, Issue 3 2010Zilong Li Abstract Diagnostic mineral assemblages, mineral compositions and zircon SHRIMP U,Pb ages are reported from an ultrahigh-temperature (UHT) spinel,orthopyroxene,garnet granulite (UHT rock) from the South Altay orogenic belt of northwestern China. This Altay orogenic belt defines an accretionary belt between the Siberian and Kazakhstan,Junggar Plates that formed during the Paleozoic. The UHT rock examined in this study preserves both peak and retrograde metamorphic assemblages and microstructures including equilibrium spinel + quartz, and intergrowth of orthopyroxene, spinel, sillimanite, and cordierite formed during decompression. Mineral chemistry shows that the spinel coexisting with quartz has low ZnO contents, and the orthopyroxene is of high alumina type with Al2O3 contents up to 9.3 wt%. The peak temperatures of metamorphism were >950°C, consistent with UHT conditions, and the rocks were exhumed along a clockwise P,T path. The zircons in this UHT rock display a zonal structure with a relict core and metamorphic rim. The cores yield bimodal ages of 499 ± 8 Ma (7 spots), and 855 Ma (2 spots), with the rounded clastic zircons having ages with 490,500 Ma. Since the granulite was metamorphosed at temperatures >900°C, exceeding the closure temperature of U,Pb system in zircon, a possible interpretation is that the 499 ± 8 Ma age obtained from the largest population of zircons in the rock marks the timing of formation of the protolith of the rock, with the zircons sourced from a ,500 Ma magmatic provenance, in a continental margin setting. We correlate the UHT metamorphism with the northward subduction of the Paleo-Asian Ocean and associated accretion-collision tectonics of the Siberian and Kazakhstan,Junggar Plates followed by rapid exhumation leading to decompression. [source] Late Cretaceous-Cenozoic exhumation of the Yanji area, northeast China: Constraints from fission-track thermochronologyISLAND ARC, Issue 1 2010Xiaoming Li Abstract The Yanji area, located at the border of China, Russia, and Korea, where the Phanerozoic granitoids have been widely exposed, was considered part of the orogenic collage between the North China Block in the south and the Jiamusi,Khanka Massifs in the northeast. In this study, the cooling and inferred uplift and denudation history since the late Mesozoic are intensively studied by carrying out apatite and zircon fission-track analyses, together with electron microprobe analyses (EMPA) of chemical compositions of apatite from the granitoid samples in the Yanji area. The results show that: (i) zircon and apatite fission-track ages range 91.7,99.6 Ma and 76.5,85.4 Ma, respectively; (ii) all apatite fission-track length distributions are unimodal and yield mean lengths of 12,13.2 µm, and the apatites are attributed to chlorine-bearing fluorapatite as revealed by EMPA results; and (iii) the thermal history modeling results based on apatite fission-track grain ages and length distributions indicate that the time,temperature paths display similar patterns and the cooling has been accelerated for each sample since ca 15 Ma. Thus, we conclude that sequential cooling, involving two rapid (95,80 Ma and ca 15,0 Ma) and one slow (80,15 Ma) cooling, has taken place through the exhumation of the Yanji area since the late Cretaceous. The maximum exhumation is more than 5 km under a steady-state geothermal gradient of 35°C/km. Combined with the tectonic setting, this exhumation is possibly related to the subduction of the Pacific Plate beneath the Eurasian Plate since the late Cretaceous. [source] Metamorphic and cooling history of the Shimanto accretionary complex, Kyushu, Southwest Japan: Implications for the timing of out-of-sequence thrustingISLAND ARC, Issue 4 2008Hidetoshi Hara Abstract Illite crystallinity, K,Ar dating of illite, and fission-track dating of zircon are analyzed in the hanging wall (Sampodake unit) and footwall (Mikado unit) of a seismogenic out-of-sequence thrust (Nobeoka thrust) within the Shimanto accretionary complex of central Kyushu, southwest Japan. The obtained metamorphic temperatures, and timing of metamorphism and cooling, reveal the tectono-metamorphic evolution of the complex, and related development of the Nobeoka thrust. Illite crystallinity data indicate that the Late Cretaceous Sampodake unit was metamorphosed at temperatures of around 300 to 310°C, while the Middle Eocene Mikado unit was metamorphosed at 260 to 300°C. Illite K,Ar ages and zircon fission-track ages constrain the timing of metamorphism of the Sampodake unit to the early Middle Eocene (46 to 50 Ma, mean = 48 Ma). Metamorphism of the Mikado unit occurred no earlier than 40 Ma, which is the youngest depositional age of the unit. The Nobeoka thrust is inferred to have been active during about 40 to 48 Ma, as the Sampodake unit started its post metamorphic cooling after 48 Ma and was thrust over the Mikado unit at about 40 Ma along the Nobeoka thrust. These results indicate that the Nobeoka thrust was active for more than 10 million years. [source] SHRIMP zircon and EPMA monazite dating of granitic rocks from the Maizuru terrane, southwest Japan: Correlation with East Asian Paleozoic terranes and geological implicationsISLAND ARC, Issue 3 2008Masahiro Fujii Abstract The Maizuru terrane, distributed in the Inner Zone of southwest Japan, is divided into three subzones (Northern, Central and Southern), each with distinct lithological associations. In clear contrast with the Southern zone consisting of the Yakuno ophiolite, the Northern zone is subdivided into the western and eastern bodies by a high-angle fault, recognized mainly by the presence of deformed granitic rocks and pelitic gneiss. This association suggests an affinity with a mature continental block; this is supported by the mode of occurrence, and petrological and isotopic data. Newly obtained sensitive high mass-resolution ion microprobe (SHRIMP) zircon U,Pb ages reveal the intrusion ages of 424 ± 16 and 405 ± 18 Ma (Siluro,Devonian) for the granites from the western body, and 249 ± 10 and 243 ± 19 Ma (Permo,Triassic) for the granodiorites from the eastern body. The granites in the western body also show inherited zircon ages of around 580 and 765 Ma. In addition, electron probe microanalysis (EPMA) monazite U,Th,total Pb dating gives around 475,460 Ma. The age of intrusion, inherited ages, mode of occurrence, and geological setting of the Siluro,Devonian granites of the Northern zone all show similarities with those of the Khanka Massif, southern Primoye, Russia, and the Hikami granitic rocks of the South Kitakami terrane, Northeast Japan. We propose that both the Siluro,Devonian and Permo,Triassic granitic rocks of the Northern zone are likely to have been juxtaposed through the Triassic,Late Jurassic dextral strike-slip movement, and to have originated from the Khanka Massif and the Hida terrane, respectively. This study strongly supports the importance of the strike-slip movement as a mechanism causing the structural rearrangement of the Paleozoic,Mesozoic terranes in the Japanese Islands, as well as in East Asia. [source] Cooling and inferred exhumation history of the Ryoke metamorphic belt in the Yanai district, south-west Japan: Constraints from Rb,Sr and fission-track ages of gneissose granitoid and numerical modelingISLAND ARC, Issue 2 2001Takamoto Okudaira Abstract The Ryoke metamorphic belt in south-west Japan consists mainly of I-type granitoids and associated low-pressure/high-temperature metamorphic rocks. In the Yanai district, it has been divided into three structural units: northern, central and southern units. In this study, we measured the Rb,Sr whole-rock,mineral isochron ages and fission-track ages of the gneissose granodiorite in the central structural unit. Four Rb,Sr ages fall in a range of ca 89,87 Ma. The fission-track ages of zircon and apatite are 68.9 ± 2.6 Ma and 57.4 ± 2.5 Ma (1, error), respectively. Combining the newly obtained ages with previously reported (Th,)U,Pb ages from the same unit, thermochronologic study revealed two distinctive cooling stages; 1) a rapid cooling (> 40°C/Myr) for a period (~7 Myr) soon after the peak metamorphism (~ 95 Ma) and 2) the subsequent slow cooling stage (~ 5°C/Myr) after ca 88 Ma. The first rapid cooling stage corresponds to thermal relaxation of the intruded granodiorite magma and its associated metamorphic rocks, and to the uplift by a displacement along low-angle faults which initiated soon after the intrusion of the magma. Uplift by the later stage deformation having formed large-scale upright folds resulted in progress of the exhumation during the first stage. The average exhumation velocity of the stage is , 2 mm/yr. During the second stage, the rocks were not accompanied by ductile deformation and were exhumed with the rate of 0.1,0.2 mm/yr. The difference in the exhumation velocity between the first and second cooling stages resulted from the difference in the thickness of the crust and in the activity of ductile deformation between the early and later stages of the orogenesis. [source] Geology of the Kokchetav UHP-HP metamorphic belt, Northern KazakhstanISLAND ARC, Issue 3 2000Y. Kaneko Abstract Ultrahigh-pressure metamorphic (UHPM) rocks of the Kokchetav Massif of Kazakhstan contain metamorphic microdiamond and coesite inclusions inside rigid capsules such as garnet and zircon. Precambrian protoliths of the UHPM rocks were metamorphosed at around 530 Ma, at pressures of about 7 GPa, which suggests that crustal protoliths were subducted to depths of over 200 km. Primary UHPM minerals are poorly preserved due to partial obliteration by subsequent Barrovian overprint during exhumation and later collision events in Caledonian times. We report the results of detailed mapping of the Kokchetav Massif and use structural data to propose intrusion and exhumation mechanisms for the UHPM rocks. Detailed mapping revealed that many subvertical structures in the ultrahigh-pressure,high-pressure (UHP,HP) units were formed due to later folding. The primary structure appears to be subhorizontal and the total thickness of the UHP rocks is estimated at around 2 km. The first order structure is sandwich-like; that is, the UHP,HP units are separated from underlying low-P metamorphic rocks of the Daulet Series and from feebly metamorphosed to unmetamorphosed sedimentary strata on the top by subhorizontal faults. Kinematic indicators show top-to-the-south sense of shear along the top, and top-to-the-north displacement along the bottom boundaries. These shear senses, together with the observed metamorphic gradients, suggest that the thin UHPM sheet was extruded toward the north. We consider wedge extrusion to have been the most effective mechanism for the exhumation of the UHPM rocks. [source] Overview of the geology, petrology and tectonic framework of the high-pressure,ultrahigh-pressure metamorphic belt of the Kokchetav Massif, KazakhstanISLAND ARC, Issue 3 2000S. Maruyama Abstract High- to ultrahigh-pressure metamorphic (HP,UHPM) rocks crop out over 150 km along an east,west axis in the Kokchetav Massif of northern Kazakhstan. They are disposed within the Massif as a 2 km thick, subhorizontal pile of sheet-like nappes, predominantly composed of interlayered pelitic and psammitic schists and gneisses, amphibolite and orthogneiss, with discontinuous boudins and lenses of eclogite, dolomitic marble, whiteschist and garnet pyroxenite. On the basis of predominating lithologies, we subdivided the nappe group into four north-dipping, fault-bounded orogen-parallel units (I,IV, from base to top). Constituent metabasic rocks exhibit a systematic progression of metamorphic grades, from high-pressure amphibolite through quartz,eclogite and coesite,eclogite to diamond,eclogite facies. Coesite, diamond and other mineral inclusions within zircon offer the best means by which to clarify the regional extent of UHPM, as they are effectively sequestered from the effects of fluids during retrogression. Inclusion distribution and conventional geothermobarometric determinations demonstrate that the highest grade metamorphic rocks (Unit II: T = 780,1000°C, P = 37,60 kbar) are restricted to a medial position within the nappe group, and metamorphic grade decreases towards both the top (Unit III: T = 730,750°C, P = 11,14 kbar; Unit IV: T = 530°C, P = 7.5,9 kbar) and bottom (Unit I: T = 570,680°C; P = 7,13.5 kbar). Metamorphic zonal boundaries and internal structural fabrics are subhorizontal, and the latter exhibit opposing senses of shear at the bottom (top-to-the-north) and top (top-to-the-south) of the pile. The orogen-scale architecture of the massif is sandwich-like, with the HP,UHPM nappe group juxtaposed across large-scale subhorizontal faults, against underlying low P,T metapelites (Daulet Suite) at the base, and overlying feebly metamorphosed clastic and carbonate rocks (Unit V). The available structural and petrologic data strongly suggest that the HP,UHPM rocks were extruded as a sequence of thin sheets, from a root zone in the south toward the foreland in the north, and juxtaposed into the adjacent lower-grade units at shallow crustal levels of around 10 km. The nappe pile suffered considerable differential internal displacements, as the 2 km thick sequence contains rocks exhumed from depths of up to 200 km in the core, and around 30,40 km at the margins. Consequently, wedge extrusion, perhaps triggered by slab-breakoff, is the most likely tectonic mechanism to exhume the Kokchetav HP,UHPM rocks. [source] Provenance of sandstones from the Wakino Subgroup of the Lower Cretaceous Kanmon Group, northern Kyushu, JapanISLAND ARC, Issue 1 2000Daniel K. Asiedu Abstract The Wakino Subgroup is a lower stratigraphic unit of the Lower Cretaceous Kanmon Group. Previous studies on provenance of Wakino sediments have mainly concentrated on either petrography of major framework grains or bulk rock geochemistry of shales. This study addresses the provenance of the Wakino sandstones by integrating the petrographic, bulk rock geochemistry, and mineral chemistry approaches. The proportions of framework grains of the Wakino sandstones suggest derivation from either a single geologically heterogeneous source terrane or multiple source areas. Major source lithologies are granitic rocks and high-grade metamorphic rocks but notable amounts of detritus were also derived from felsic, intermediate and mafic volcanic rocks, older sedimentary rocks, and ophiolitic rocks. The heavy mineral assemblage include, in order of decreasing abundance: opaque minerals (ilmenite and magnetite with minor rutile), zircon, garnet, chromian spinel, aluminum silicate mineral (probably andalusite), rutile, epidote, tourmaline and pyroxene. Zircon morphology suggests its derivation from granitic rocks. Chemistry of chromian spinel indicates that the chromian spinel grains were derived from the ultramafic cumulate member of an ophiolite suite. Garnet and ilmenite chemistry suggests their derivation from metamorphic rocks of the epidote-amphibolite to upper amphibolite facies though other source rocks cannot be discounted entirely. Major and trace element data for the Wakino sediments suggest their derivation from igneous and/or metamorphic rocks of felsic composition. The major element compositions suggest that the type of tectonic environment was of an active continental margin. The trace element data indicate that the sediments were derived from crustal rocks with a minor contribution from mantle-derived rocks. The trace element data further suggest that recycled sedimentary rocks are not major contributors of detritus. It appears that the granitic and metamorphic rocks of the Precambrian Ryongnam Massif in South Korea were the major contributors of detritus to the Wakino basin. A minor but significant amount of detritus was derived from the basement rocks of the Akiyoshi and Sangun Terrane. The chromian spinel appears to have been derived from a missing terrane though the ultramafic rocks in the Ogcheon Belt cannot be discounted. [source] Outcomes of the International Union of Crystallography Commission on Powder Diffraction Round Robin on Quantitative Phase Analysis: samples 2, 3, 4, synthetic bauxite, natural granodiorite and pharmaceuticalsJOURNAL OF APPLIED CRYSTALLOGRAPHY, Issue 4 2002Nicola V. Y. Scarlett The International Union of Crystallography (IUCr) Commission on Powder Diffraction (CPD) has sponsored a round robin on the determination of quantitative phase abundance from diffraction data. The aims of the round robin have been detailed by Madsen et al. [J. Appl. Cryst. (2001), 34, 409,426]. In summary, they were (i) to document the methods and strategies commonly employed in quantitative phases analysis (QPA), especially those involving powder diffraction, (ii) to assess levels of accuracy, precision and lower limits of detection, (iii) to identify specific problem areas and develop practical solutions, (iv) to formulate recommended procedures for QPA using diffraction data, and (v) to create a standard set of samples for future reference. The first paper (Madsen et al., 2001) covered the results of sample 1 (a simple three-phase mixture of corundum, fluorite and zincite). The remaining samples used in the round robin covered a wide range of analytical complexity, and presented a series of different problems to the analysts. These problems included preferred orientation (sample 2), the analysis of amorphous content (sample 3), microabsorption (sample 4), complex synthetic and natural mineral suites, along with pharmaceutical mixtures with and without an amorphous component. This paper forms the second part of the round-robin study and reports the results of samples 2 (corundum, fluorite, zincite, brucite), 3 (corundum, fluorite, zincite, silica flour) and 4 (corundum, magnetite, zircon), synthetic bauxite, natural granodiorite and the synthetic pharmaceutical mixtures (mannitol, nizatidine, valine, sucrose, starch). The outcomes of this second part of the round robin support the findings of the initial study. The presence of increased analytical problems within these samples has only served to exacerbate the difficulties experienced by many operators with the sample 1 suite. The major difficulties are caused by lack of operator expertise, which becomes more apparent with these more complex samples. Some of these samples also introduced the requirement for skill and judgement in sample preparation techniques. This second part of the round robin concluded that the greatest physical obstacle to accurate QPA for X-ray based methods is the presence of absorption contrast between phases (microabsorption), which may prove to be insurmountable in some circumstances. [source] Three metamorphic events recorded in a single garnet: Integrated phase modelling, in situ LA-ICPMS and SIMS geochronology from the Moine Supergroup, NW ScotlandJOURNAL OF METAMORPHIC GEOLOGY, Issue 3 2010K. A. CUTTS Abstract In situ LA-ICP-MS monazite geochronology from a garnet-bearing diatexite within the Moine Supergroup (Glenfinnan Group) NW Scotland records three temporally distinct metamorphic events within a single garnet porphyroblast. The initial growth of garnet occurred in the interval c. 825,780 Ma, as recorded by monazite inclusions located in the garnet core. Modelled P,T conditions based on the preserved garnet core composition indicate an initially comparatively high geothermal gradient regime and peak conditions of ,650 °C and 7 kbar. Monazite within a compositionally distinct second shell of garnet has an age of 724 ± 6 Ma. This is indistinguishable from a SIMS age of 725 ± 4 Ma obtained from metamorphic zircon in the sample, which is interpreted to record the timing of migmatization. This second stage of garnet growth occurred on a P,T path from ,6 kbar and 650 °C rising to ,9 kbar and 700 °C, with the peak conditions associated with partial melting. A third garnet zone which forms the rim contains monazite with an age of 464 ± 3 Ma. Monazite in the surrounding matrix has an age of 462 ± 2 Ma. This corresponds well with a U,Pb SIMS zircon age of 463 ± 4 Ma obtained from a deformed pegmatite that was emplaced during widespread folding and reworking of the migmatite fabric. The P,T conditions associated with the final phase of garnet growth were ,7 kbar and 650 °C. The monazite ages coupled with the phase relations modelled from this multistage garnet indicate that it records two Neoproterozoic tectonothermal events as well as the widespread Ordovician Grampian event associated with Caledonian orogenesis. Thus, this single garnet records much of the Neoproterozoic to Ordovician thermal history in NW Scotland, and highlights the long history of porphyroblast growth that can be revealed by in situ isotopic dating and associated P,T modelling. This approach has the potential to reveal much of the thermal architecture of Neoproterozoic events within the Moine Supergroup, despite intense Caledonian reworking, if suitable textural and mineralogical relationships can be indentified elsewhere. [source] Geochronological and petrological constraints on Palaeoproterozoic granulite facies metamorphism in southeastern margin of the North China CratonJOURNAL OF METAMORPHIC GEOLOGY, Issue 2 2009Y.-C. LIU Abstract In the southeastern margin of the North China Craton, high-pressure (HP) granulite facies meta-basic rocks exposed as bands or lenses in the Precambrian metamorphic basement (e.g. Bengbu) and as xenoliths in Mesozoic intrusions (e.g. Jiagou) are characterized by the assemblage garnet + clinopyroxene + plagioclase + quartz + rutile ± Ti-rich hornblende. Cathodoluminescence imaging and mineral inclusions reveal that most zircon from the three dated samples displays distinct core-mantle-rim structures. The cores show typical igneous zircon characteristics and give ages of 2.5,2.4 Ga, thus dating the protolith of the metabasites. The mantles formed at granulite facies conditions as evidenced by inclusions of the HP granulite mineral assemblage garnet + clinopyroxene + rutile + plagioclase + quartz ± hornblende and Ti-rich biotite and yield ages of 1839 ± 31, 1811 ± 19 and 1800 ± 15 Ma. An inclusion-free rim yields an age of 176 ± 2 Ma with the lower Th/U ratio of 0.02. The geochronological and preliminary petrological data of this study suggest that the lower crust beneath the southeastern margin of the North China Craton formed at 2.5,2.4 Ga and underwent HP granulite facies metamorphism at c. 1.8 Ga. This HT-HP metamorphic event may be ascribed to large-scale crustal heating and thickening related to mantle-derived magma underplating at the base of the lower crust, as evidenced by widespread extension, rifting and related mafic magma emplacement in the North China Craton during this period. The age of 176 ± 2 Ma most likely records the late amphibolite facies retrogression occurring during exhumation. 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