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Yttria-Stabilized Zirconia (Yttria-Stabilize + zirconia)
Selected AbstractsLow-Temperature Superionic Conductivity in Strained Yttria-Stabilized ZirconiaADVANCED FUNCTIONAL MATERIALS, Issue 13 2010Michael Sillassen Abstract Very high lateral ionic conductivities in epitaxial cubic yttria-stabilized zirconia (YSZ) synthesized on single-crystal SrTiO3 and MgO substrates by reactive direct current magnetron sputtering are reported. Superionic conductivities (i.e., ionic conductivities of the order ,1 ,,1cm,1) are observed at 500,°C for 58-nm-thick films on MgO. The results indicate a superposition of two parallel contributions , one due to bulk conductivity and one attributable to conduction along the film,substrate interface. Interfacial effects dominate the conductivity at low temperatures (<350,°C), showing more than three orders of magnitude enhancement compared to bulk YSZ. At higher temperatures, a more bulk-like conductivity is observed. The films have a negligible grain-boundary network, thus ruling out grain boundaries as a pathway for ionic conduction. The observed enhancement in lateral ionic conductivity is caused by a combination of misfit dislocation density and elastic strain in the interface. These very high ionic conductivities in the temperature range 150,500,°C are of great fundamental importance but may also be technologically relevant for low-temperature applications. [source] Microstructure Control of Sintered Porous Yttria-Stabilized Zirconia as a Durable Thermal Shielding MaterialINTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, Issue 3 2009Kazuya Sasaki The microstructure of a thermal shielding material affects its thermal conductivity and mechanical property. In this study, the effects of the sintering temperature and the polymethyl methacrylate powder as a pore-former on the microstructure of a sintered porous yttria-stabilized zirconia (YSZ), which is used as a durable thermal shielding material, were investigated. It became clear that the microstructure of the sintered YSZ could be controlled by the particle size and the amount of the pore-former and the sintering temperature. The effect of the yttria amount in the YSZ on the microstructure was also clarified. [source] Temperature-Dependent Optical Reflectivity of Tetragonal-Prime Yttria-Stabilized ZirconiaJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 3 2006John A. Nychka The optical reflectance of dense, metastable, tetragonal-prime zirconia plates, made by densifying electron beam physical vapor-deposited powder, is reported as a function of temperature up to 1673 K (1400°C) over the range of 400,1500 cm,1 (6.67,25 ,m). Curve fitting of the reflectance as a function of temperature was performed using two different damped oscillator models, each with three infrared (IR)-active modes. Oscillator parameters were then used to calculate the values of the indices of refraction and absorption as a function of temperature using the classical dispersion theory. The reflectance data of tetragonal-prime yttria-stabilized zirconia at room temperature are qualitatively similar to that reported for the equilibrium tetragonal phase in that it can be fit with three IR-active modes. [source] Oxygen Diffusion in Yttria-Stabilized Zirconia: A New Simulation ModelJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 10 2004R. Krishnamurthy We present a multiscale modeling approach to study oxygen diffusion in cubic yttria-stabilized zirconia. In this approach, we employ density functional theory methods to calculate activation energies for oxygen migration in different cation environments. These are used in a kinetic Monte Carlo framework to calculate long-time oxygen diffusivities. Simulation results show that the oxygen diffusivity attains a maximum value at around 0.1 mole fraction yttria. This variation in the oxygen diffusivity with yttria mole fraction and the calculated values for the diffusivity agree well with experiment. The competing effects of increased oxygen vacancy concentration and increasing activation energy and correlation effects for oxygen diffusion with increasing yttria mole fraction are responsible for the observed dopant content dependence of the oxygen diffusivity. We provide a detailed analysis of cation-dopant-induced correlation effects in support of the above explanation. [source] Synthesis of Highly Porous Yttria-Stabilized Zirconia by Tape-Casting MethodsJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 3 2003Martha Boaro Porous ceramics of Y2O3 -stabilized ZrO2 (YSZ) were prepared by tape-casting methods using both pyrolyzable pore formers and NiO followed by acid leaching. The porosity of YSZ wafers increased in a regular manner with the mass of graphite or polymethyl methacrylate (PMMA) to between 60% and 75% porosity. SEM indicated that the shape of the pores in the final ceramic was related to the shape of the pore formers, so that the pore size and microstructure of YSZ wafers could be controlled by the choice of pore former. Dilatometry measurements showed that measurable shrinkage started at 1300 K, and a total shrinkage of 26% was observed, independent of the amount or type of pore former used. Temperature-programmed oxidation (TPO) measurements on the green tapes demonstrated that the binders and dispersants were combusted between 550 and 750 K, that PMMA decomposed to methyl methacrylate between 500 and 700 K, and that graphite combusted above 900 K. The porosity of YSZ ceramics prepared by acid leaching of nickel from NiO,YSZ, with 50 wt% NiO, was studied as a function of NiO and YSZ particle size. Significant changes in pore dimension were found when NiO particle size was changed. [source] Mechanism of Thermal Transport in Zirconia and Yttria-Stabilized Zirconia by Molecular-Dynamics SimulationJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 12 2001Patrick K. Schelling We present results of molecular-dynamics simulations of the thermal conductivity, ,, of ZrO2 and Y2O3 -stabilized ZrO2 (YSZ). For both pure ZrO2 and YSZ with low concentrations of Y2O3, we find that the high-temperature , is typical of a crystalline solid, with the dominant mechanism being phonon-phonon scattering. With increasing Y2O3 concentration, however, the mechanism changes to one more typical of an amorphous system. In particular, phononlike vibrational modes with well-defined wave vectors appear only at very low frequencies. As in amorphous materials, the vast majority of vibrational modes, while delocalized, do not propagate like ordinary phonon modes but transport energy in a diffusive manner. We also find that the few highest frequency modes are localized and do not contribute to ,. [source] Fluorite-Type Solid Solutions in the System Y,Ta,O,N: A Nitrogen-Rich Analogue to Yttria-Stabilized Zirconia (YSZ).CHEMINFORM, Issue 35 2006H. Schilling Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. 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