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Water Absorption Properties (water + absorption_property)
Selected AbstractsWater absorption properties of phosphate glass fiber-reinforced poly-,-caprolactone composites for craniofacial bone repairJOURNAL OF APPLIED POLYMER SCIENCE, Issue 6 2008Levent Onal Abstract The moisture uptake of polymers and composites has increasing significance where these materials are specified for invasive, long-term medical applications. Here we analyze mass gain and the ensuing degradation mechanisms in phosphate glass fiber reinforced poly-,-caprolactone laminates. Specimens were manufactured using in situ polymerization of ,-caprolactone around a bed of phosphate glass fibers. The latter were sized with 3-aminopropyltriethoxysilane to control the rate of modulus degradation. Fiber content was the main variable in the study, and it was found that the moisture diffusion coefficient increased significantly with increasing fiber volume fraction. Diffusion, plasticization, and leaching of constituents appear to be the dominant aspects of the process over these short-term tests. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008 [source] Structure and properties of phase change materials based on HDPE, soft Fischer-Tropsch paraffin wax, and wood flourJOURNAL OF APPLIED POLYMER SCIENCE, Issue 3 2010M. E. Mngomezulu Abstract Phase-change materials based on high density polyethylene (HDPE), soft Fischer-Tropsch paraffin wax (M3), and alkali-treated wood flour (WF) were investigated. The blend and composite samples were prepared by melt mixing using a Brabender Plastograph, followed by melt pressing. They were characterized in terms of their morphology, as well as thermal, mechanical, thermo-mechanical, and water absorption properties. Although SEM micrographs showed some evidence of intimate contact between the WF particles and the HDPE matrix as a result of alkali treatment, poor filler dispersion, and interfacial adhesion were also observed. Partial immiscibility of the HDPE and the M3 wax was noticed, with the WF particles covered by wax. There was plasticization of the HDPE matrix by the wax, as well as partial cocrystallization, inhomogeneity and uneven wax dispersion in the polymer matrix. The HDPE/WF/M3 wax composites were more homogeneous than the blends. The presence of wax reduced the thermal stability of the blends and composites. Both the presence of M3 wax and WF influenced the viscoelastic behavior of HDPE. The HDPE/M3 wax blends showed an increase in the interfacial amorphous content as the wax content increases, which resulted in the appearance of a ,-relaxation peak. The presence of M3 wax in HDPE reduced the mechanical properties of the blends. For the composites these properties varied with WF content. An increase in wax content resulted to a decrease in water uptake by the composites, probably because the wax covered the WF particles and penetrated the pores in these particles. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 [source] Thermal, mechanical, and diffusional properties of nylon 6/ABS polymer blends: Compatibilizer effectPOLYMER ENGINEERING & SCIENCE, Issue 7 2000Seung Phil Jang The thermal, mechanical, and water absorption properties of blends of nylon 6 (PA6) and acrylonitrile-butadiene-styrene copolymer (ABS) with and without the compatibilizer maleic anhydride (MAH) were studied. Polymers were melt-blended using a twin screw extruder, and injection molded into sheets. Tensile and impact properties, hardness, heat deflection resistance, and dimensional stability were enhanced by the incorporation of MAH. Synergistic effects were observed for tensile elongation and flexural properties. The melting temperature and the thermal stability were not significantly affected by the incorporation of MAH. The mechanical property enhancement by the introduction of compatibilizer was explained by the formation of a micro-domain structure in the blends. The equilibrium water uptake increased with increasing concentration of PA6, and the diffusion coefficient was determined from the water transport kinetics at different temperatures. Activation energy was extracted from the temperature dependence of the diffusion coefficient. No compatibilizer effect was observed in the swelling behavior. [source] UV-radiation-induced preirradiation graft copolymerization of methacrylic acid and acrylic acid onto jute fibrePOLYMER INTERNATIONAL, Issue 11 2004Ferdous Khan Abstract UV-radiation-induced graft copolymerization of methacrylic acid and acrylic acid onto jute fibre was carried out using a preirradiation method with 1-hydroxycyclohexyl-phenylketone as a photoinitiator. 2-methyl-2-propene 1-sulfonic acid, sodium salt was incorporated into the grafting solution in suppressing the homopolymer/gel formation and facilitating graft copolymerization. In comparison, results showed that the type of monomer significantly influence on grafting. The results of the characterisation showed that the graft weight and the type of monomer have significant influence on the mechanical and water absorption properties in the case of grafted samples. Copyright © 2004 Society of Chemical Industry [source] | ||||||||||