Transform

Distribution by Scientific Domains
Distribution within Chemistry

Kinds of Transform

  • cosine transform
  • discrete fourier transform
  • discrete wavelet transform
  • fast fourier transform
  • fourier transform
  • hankel transform
  • hilbert transform
  • huang transform
  • integral transform
  • inverse scattering transform
  • laplace transform
  • radon transform
  • scattering transform
  • wavelet transform

  • Terms modified by Transform

  • transform analysis
  • transform approach
  • transform domain
  • transform fault
  • transform infrared
  • transform infrared analysis
  • transform infrared spectrometry
  • transform infrared spectroscopy
  • transform infrared spectroscopy analysis
  • transform infrared spectrum
  • transform ion cyclotron resonance
  • transform ion cyclotron resonance mass spectrometer
  • transform ion cyclotron resonance mass spectrometry
  • transform ir
  • transform ir spectroscopy
  • transform mass spectrometry
  • transform method
  • transform raman spectroscopy
  • transform spectroscopy
  • transform technique

  • Selected Abstracts


    Near-Term Travel Speed Prediction Utilizing Hilbert,Huang Transform

    COMPUTER-AIDED CIVIL AND INFRASTRUCTURE ENGINEERING, Issue 8 2009
    Khaled Hamad
    In this study, we propose an innovative methodology for such prediction. Because of the inherently direct derivation of travel time from speed data, the study was limited to the use of speed only as a single predictor. The proposed method is a hybrid one that combines the use of the empirical mode decomposition (EMD) and a multilayer feedforward neural network with backpropagation. The EMD is the key part of the Hilbert,Huang transform, which is a newly developed method at NASA for the analysis of nonstationary, nonlinear time series. The rationale for using the EMD is that because of the highly nonlinear and nonstationary nature of link speed series, by decomposing the time series into its basic components, more accurate forecasts would be obtained. We demonstrated the effectiveness of the proposed method by applying it to real-life loop detector data obtained from I-66 in Fairfax, Virginia. The prediction performance of the proposed method was found to be superior to previous forecasting techniques. Rigorous testing of the distribution of prediction errors revealed that the model produced unbiased predictions of speeds. The superiority of the proposed model was also verified during peak periods, midday, and night. In general, the method was accurate, computationally efficient, easy to implement in a field environment, and applicable to forecasting other traffic parameters. [source]


    Feature Extraction for Traffic Incident Detection Using Wavelet Transform and Linear Discriminant Analysis

    COMPUTER-AIDED CIVIL AND INFRASTRUCTURE ENGINEERING, Issue 4 2000
    A. Samant
    To eliminate false alarms, an effective traffic incident detection algorithm must be able to extract incident-related features from the traffic patterns. A robust feature-extraction algorithm also helps reduce the dimension of the input space for a neural network model without any significant loss of related traffic information, resulting in a substantial reduction in the network size, the effect of random traffic fluctuations, the number of required training samples, and the computational resources required to train the neural network. This article presents an effective traffic feature-extraction model using discrete wavelet transform (DWT) and linear discriminant analysis (LDA). The DWT is first applied to raw traffic data, and the finest resolution coefficients representing the random fluctuations of traffic are discarded. Next, LDA is employed to the filtered signal for further feature extraction and reducing the dimensionality of the problem. The results of LDA are used as input to a neural network model for traffic incident detection. [source]


    Efficacy of laser Doppler flowmetry for the diagnosis of revascularization of reimplanted immature dog teeth

    DENTAL TRAUMATOLOGY, Issue 2 2001
    Kallaya Yanpiset
    Abstract , This study was performed to assess if laser Doppler flowmetry (LDF) is an improved method for the detection of revascularization of replanted teeth. Teeth were extracted and reimplanted under different experimental conditions. LDF readings were taken before extraction and weekly for 3 months. In control teeth, LDF baseline readings were taken and then repeated after the apical blood vessels were cut surgically. At the end of 3 months it was determined radiographically and histologically whether revascularization had occurred, i.e. vitality had returned. Results: LDF readings correctly predicted the pulp status (vital vs. non-vital) in 83.7% of the readings. 73.9% (17 of 23) were correct for the vital teeth and 95% (19 of 20) were correct for the non-vital teeth. Fisher's exact test (2-tail) indicated that there was no significant association between the efficacy of LDF and tooth type (P=0.166), although P2 was the least accurate tooth tested. Wilcoxon's matched-pair signed rank test demonstrated that in the revascularized (vital) teeth, the flux value between the baseline and week 2 dropped significantly (P=0.0001), increased significantly from week 2 to week 4 (P=0.0001) and then decreased steadily until week 12. However, at week 12 the flux was still significantly higher than at week 2 (P=0.010). In the teeth that failed to revascularize, the flux value dropped significantly by weeks 1 and 2 (P=0.004 and P=0.0001, respectively). Flux values did not increase from week 2. A Fast Fourier Transform (FFT) analysis confirmed a pulse of dominant frequency of 2 Hz in the teeth that returned to vitality and the lack thereof in those that stayed non-vital. One tooth in which the flux value evaluation indicated a non-vital tooth but the radiographic/histologic findings showed vital (false negative) possessed a pulse of dominant frequency and proved by this method to have successfully revascularized. [source]


    The application of modified lapped transform domain median filter to narrow,band interference excision in DSSS systems

    EUROPEAN TRANSACTIONS ON TELECOMMUNICATIONS, Issue 4 2001
    Chongni Li Guangruihu
    A novel communication receiver which uses lapped transform (LT) incorporating modified median filter (MMF) algorithm is designed for narrow,band interference (NB1) excision. Comparing to traditional Fourier Transform, LT has longer basis vectors, less spectral leakage, thus better frequency resolution. The LT domain MMF algorithm takes full advantages of the direct sequence spread spectrum signal, as well as the characteristics of LT, performs the transform domain filtering twice. The first filtering locates the position of interference and mitigates most of them. The second filtering was performed in a small neighborhood of the located interference. So LT domain MMF algorithm can completely mitigate the interference without distorting the desired signal. Simulation results demonstrated the improved BER performance and increased robustness of our approach. [source]


    Thickness of the lithosphere east of the Dead Sea Transform

    GEOPHYSICAL JOURNAL INTERNATIONAL, Issue 2 2006
    Ayman Mohsen
    SUMMARY We use the S receiver function method to study the lithosphere at the Dead Sea Transform (DST). A temporary network of 22 seismic broad-band stations was operated on both sides of the DST from 2000 to 2001 as part of the DESERT project. We also used data from six additional permanent broad-band seismic stations at the DST and in the surrounding area, that is, in Turkey, Saudi Arabia, Egypt and Cyprus. Clear S -to- P converted phases from the crust,mantle boundary (Moho) and a deeper discontinuity, which we interpret as lithosphere,asthenosphere boundary (LAB) have been observed. The Moho depth (30,38 km) obtained from S receiver functions agrees well with the results from P receiver functions and other geophysical data. We observe thinning of the lithosphere on the eastern side of the DST from 80 km in the north of the Dead Sea to about 65 km at the Gulf of Aqaba. On the western side of the DST, the few data indicate a thin LAB of about 65 km. For comparison, we found a 90-km-thick lithosphere in eastern Turkey and a 160-km-thick lithosphere under the Arabian shield, respectively. These observations support previous suggestions, based on xenolith data, heat flow observations, regional uplift history and geodynamic modelling, that the lithosphere around DST has been significantly thinned in the Late Cenozoic, likely following rifting and spreading of the Red Sea. [source]


    Seismotectonics of the Sinai subplate , the eastern Mediterranean region

    GEOPHYSICAL JOURNAL INTERNATIONAL, Issue 1 2003
    Amos Salamon
    SUMMARY We define the Sinai subplate, from a seismotectonic perspective, as a distinct component in the plate tectonics of the eastern Mediterranean region. This is based on the tectonic characteristics of a comprehensive listing of all ML, 4 recorded seismicity in the region during the 20th century, on newly calculated and recalculated fault plane mechanisms of first P -wave arrivals and on published solutions based on waveform inversion of broad-band data. The low seismicity level and scarcity of strong events in the region required a thorough search for useful data and a careful examination of the reliability of the focal solutions. We gathered all available records of first P -wave onsets from the ISS and ISC Bulletins and the local seismic networks. Altogether, we were able to calculate 48 new focal mechanisms and 33 recalculated ones of events that occurred during the years 1940,1992. With the increasing number of teleseismic and regional broad-band stations in the later years, we added 37 solutions based on teleseismic and regional waveform inversions of events that occurred during 1977,2001. These mechanisms enabled us to examine the seismotectonic character of the Sinai subplate. The strike and rake directions of the calculated mechanisms usually reflect the geometry and the large-scale type of deformation observed along the boundaries of the Sinai subplate,the Dead Sea Transform, the Cypriot Arc convergent zone and the Suez Rift. Nevertheless, along each of these boundaries we found anomalous solutions that attest to the complexity of the deformation processes along plate margins. Earthquakes along the Dead Sea Transform exhibit mainly sinistral transtension and transpression, reflecting its leaky manner and local change in the transform geometry. The presence of other unexpected mechanisms near the transform, however, reflects the heterogeneous deformation it induces around. As expected, thrust mechanisms along the Cypriot Arc mirror its convergent nature and typical curved geometry. Transtension and transpressional solutions in the eastern segment of the arc reflect the sinistral shear motion between Anatolia and Sinai there. However, shear mechanisms found between Cyprus and the Eratosthenes Seamount pose a problem regarding its collision process. Most intriguing of all are ML, 4 thrust and shear solutions found in the Gulf of Suez. They are associated with predominantly normal mechanisms within a rift zone and therefore constitute a unique phenomenon, yet to be deciphered. [source]


    Three-dimensional elastic earthquake modelling based on integrated seismological and InSAR data: the Mw= 7.2 Nuweiba earthquake, gulf of Elat/Aqaba 1995 November

    GEOPHYSICAL JOURNAL INTERNATIONAL, Issue 3 2003
    G. Shamir
    SUMMARY The Nuweiba earthquake (1995 November 22; Mw= 7.2), the largest seismic event along the Dead Sea Transform (DST) in at least 160 yr, ruptured 45,50 km along the Aragonese segment of the left-stepping strike-slip fault system occupying the gulf of Elat/Aqaba (southern segment of the DST). The rupture initiated in a partly normal, low-slip first subevent near the southern end of the fault and propagated unilaterally north-northeastward as a high-slip, nearly pure sinistral second subevent, which was responsible for over 90 per cent of the total seismic moment. The source mechanism and slip distribution, derived from inversion of teleseismic broad-band waveforms, are used to construct a 3-D elastic model of the earthquake based on the boundary elements method, resulting in the full 3-D displacement and stress fields induced by the earthquake. In the absence of sufficient Global Positioning System data, the only other constraints on the geometry and slip distribution of the rupture are provided by interferometric synthetic aperture radar (InSAR) measurements spanning the coseismic and early post-seismic period. We calculate simulated interferograms by transforming the calculated surface displacement field into the satellite coordinate system and comparing them with the observed interferograms. The model parameters are then iteratively modified until a best-fitting model is obtained, providing a refined set of static source parameters for the mainshock. This model is then used to calculate the static Coulomb stress changes induced by the mainshock on the step-over faults, suggesting that the major (Mw, 5) aftershocks in the first eight post-seismic months were triggered by small changes (<1 bar) in the left-lateral Coulomb stress, with effective friction coefficient not higher than 0.2. Aftershock distribution and mechanisms indicate that the available Coulomb stress dropped below the frictional strength of the fault but was not complete. [source]


    Analytical solution for the electric potential in arbitrary anisotropic layered media applying the set of Hankel transforms of integer order

    GEOPHYSICAL PROSPECTING, Issue 5 2006
    E. Pervago
    ABSTRACT The analytical solution and algorithm for simulating the electric potential in an arbitrarily anisotropic multilayered medium produced by a point DC source is here proposed. The solution is presented as a combination of Hankel transforms of integer order and Fourier transforms based on the analytical recurrent equations obtained for the potential spectrum. For the conversion of the potential spectrum into the space domain, we have applied the algorithm of the Fast Fourier Transform for logarithmically spaced points. A comparison of the modelling results with the power-series solution for two-layered anisotropic structures demonstrated the high accuracy and computing-time efficiency of the method proposed. The results of the apparent-resistivity calculation for both traditional pole-pole and tensor arrays above three-layered sequence with an azimuthally anisotropic second layer are presented. The numerical simulations show that both arrays have the same sensitivity to the anisotropy parameters. This sensitivity depends significantly on the resistivity ratio between anisotropic and adjacent layers and increases for the models with a conductive second layer. [source]


    A funerary rite study of the Phoenician,Punic necropolis of Mount Sirai (Sardinia, Italy)

    INTERNATIONAL JOURNAL OF OSTEOARCHAEOLOGY, Issue 2 2010
    G. Piga
    Abstract A recent excavation in the Phoenician,Punic necropolis of Mount Sirai, located in the southwestern part of Sardinia, Italy, has brought to light a number of tombs contextually attributed to a period from the early 6th to early 5th century BC, which is simultaneous with the beginning of the Carthago influence in Sardinia. Among the interred burials recently brought to light, the skeletal remains, sometimes of two superposed bodies, are found in a primary position and with fine anatomic connection. Some of the bones were visually stained, suggesting they were possibly subjected to fire treatment. In order to ascertain more objectively whether the bodies were subjected to burning, the bones from all the tombs were investigated by powder X-ray diffraction (XRD) and Fourier Transform infra-red (FT-IR) spectroscopy techniques. After excluding the role of important diagenetic effects, from line broadening/sharpening analysis of hydroxylapatite in the bones according to the Rietveld method, it was evaluated that the bodies were probably subjected to a temperature regime from 300 to 700°C. These data were supplemented and confirmed by an analysis of the splitting factor (SF) of apatite phosphate peaks in the infra-red spectrum of the bones. Our results indicate the existence of a rite intermediate between incineration and inhumation. This sort of ,semi-combustion', perhaps limited to the period of the early 5th century BC, appears to be peculiar just to this site. Copyright © 2008 John Wiley & Sons, Ltd. [source]


    Research Article: Fingerprinting Analysis of Saposhnikovia divaricata using 1H Nuclear Magnetic Resonance Spectroscopy and High Performance Liquid Chromatography

    JOURNAL OF INTEGRATIVE PLANT BIOLOGY, Issue 9 2010
    Yue-Yang Xin
    The 1H nuclear magnetic resonance (1H NMR) fingerprints of fractionated non-polar and polar extracts (control substance for plant drug [CSPD] A and B) from the roots of 12 specimens of Saposhnikovia divaricata (Turcz.) Schischk were achieved with Fourier Transform (FT)-NMR spectrometer and assigned by comparison to each other and to the 1H NMR spectra of the isolated individual compounds. These fingerprints were found to be uniform in terms of the specificity for the implication of all 12 specimens being systematically of the same origin. The uniformity was further affirmed by high performance liquid chromatography (HPLC), which also revealed exactly identical specificity for the identified S. divaricata species with the 1H NMR appearances of corresponding CSPD on the part of the composition of characteristic constituents when comparing to corresponding individual compounds. This investigation unambiguously shows that the specific signals from the chemotaxonomically significant compounds of chromones and coumarins in S. divaricata are exhibited distinctively in the composite features of both 1H NMR fingerprints and HPLC profiles. The 1H NMR and HPLC profiles established can successfully be used as reference for the authentication of the origin of S. divaricata species as well as for chemotaxonomic studies. [source]


    Fingerprinting Analysis of Rhizoma Chuanxiong of Commercial Types using 1H Nuclear Magnetic Resonance Spectroscopy and High Performance Liquid Chromatography Method

    JOURNAL OF INTEGRATIVE PLANT BIOLOGY, Issue 6 2009
    Hai-Lin Qin
    Abstract The 1H nuclear magnetic resonance (1H NMR) fingerprints of fractionated non-polar extracts (control substance for a plant drug (CSPD) A) from Rhizoma chuanxiong, the rhizomes of Ligusticum chuanxiong Hort., of seven specimens from different sources were measured on Fourier Transform (FT)-NMR spectrometer and assigned by comparing them with the 1H NMR spectra of the isolated pure compounds. The 1H NMR fingerprints showed exclusively characteristic resonance signals of the major special constituents of the plant. Although the differences in the relative intensity of the 1H NMR signals due to a discrepancy in the ratio of the major constituents among these samples could be confirmed by high performance liquid chromatography analysis, the general features of the 1H NMR fingerprint established for an authentic sample of the rhizomes of L. chuanxiong exhibited exclusive data from those special compounds and can be used for authenticating L. Chuanxiong species. [source]


    Ground truth hardware phantoms for validation of diffusion-weighted MRI applications

    JOURNAL OF MAGNETIC RESONANCE IMAGING, Issue 2 2010
    Pim Pullens MSc
    Abstract Purpose: To quantitatively validate diffusion-weighted MRI (DW-MRI) applications, a hardware phantom containing crossing fibers at a sub-voxel level is presented. It is suitable for validation of a large spectrum of DW-MRI applications from acquisition to fiber tracking, which is an important recurrent issue in the field. Materials and Methods: Phantom properties were optimized to resemble properties of human white matter in terms of anisotropy, fractional anisotropy, and T2. Sub-voxel crossings were constructed at angles of 30, 50, and 65 degrees, by wrapping polyester fibers, with a diameter close to axon diameter, into heat shrink tubes. We show our phantoms are suitable for the acquisition of DW-MRI data using a clinical protocol. Results: The phantoms can be used to succesfully estimate both the diffusion tensor and non-Gaussian diffusion models, and perform streamline fiber tracking. DOT (Diffusion Orientation Transform) and q-ball reconstruction of the diffusion profiles acquired at b = 3000 s/mm2 and 132 diffusion directions reveal multimodal diffusion profiles in voxels containing crossing yarn strands. Conclusion: The highly purpose adaptable phantoms provide a DW-MRI validation platform: applications include optimisation of acquisition schemes, validation of non-Gaussian diffusion models, comparison and validation of fiber tracking algorithms, and quality control in multi-center DWI studies. J. Magn. Reson. Imaging 2010;32:482,488. © 2010 Wiley-Liss, Inc. [source]


    Novel experiments and a mechanistic model for macroinstabilities in stirred tanks

    AICHE JOURNAL, Issue 2 2006
    A. Paglianti
    Abstract In this work a new experimental technique and a simple model for the identification and the analysis of macro-instabilities (MIs) in stirred tanks are presented. A pressure transducer is proposed for detecting the MIs that can take place inside a stirred vessel; its main advantages are the non-intrusivity, cheapness, and simplicity of installation and operation. Moreover, it can be used for both laboratory and industrial scale stirred tanks. The experimental technique and the time series analysis method, based on Fast Fourier Transform (FFT), are shown to provide reliable information on the frequency of MIs, through the comparison of the present data with those, from literature, obtained in similar systems. Its applicability to solid-liquid systems is also assessed. Afterwards, the data collected in several conditions differing by geometric characteristics of the stirred tanks and by the physical properties of the systems are presented. Finally, a new simplified model, based on the theory of impinging jets,1 is suggested for predicting the MI frequency. © 2005 American Institute of Chemical Engineers AIChE J, 2006 [source]


    Analysis of low content drug tablets by transmission near infrared spectroscopy: Selection of calibration ranges according to multivariate detection and quantitation limits of PLS models

    JOURNAL OF PHARMACEUTICAL SCIENCES, Issue 12 2008
    Manel Alcalà
    Abstract The content uniformity of low dose products is a major concern in the development of pharmaceutical formulations. Near infrared spectroscopy may be used to support the design and optimization of potent drug manufacturing processes through the analysis of blends and tablets in a relatively short time. A strategy for the selection of concentration ranges in the development of multivariate calibration is presented, evaluating the detection and quantitation limits of the obtained multivariate models. The strategy has been applied to the determination of an active principle in pharmaceutical tablets of low concentration (0,5%, w/w), using Fourier Transform Near Infrared (FT-NIR) transmission spectroscopy. The quantitation and detection limits decreased as the upper concentration level of the calibration models was reduced. The results obtained show that the selection of concentration ranges is a critical aspect during model design. The selection of wide concentration ranges with high levels is not recommended for the determination of analytes at minor levels (<1%, w/w), even when the concentration of interest is within the range of the model. © 2008 Wiley-Liss, Inc. and the American Pharmacists Association J Pharm Sci 97:5318,5327, 2008 [source]


    A neural network-based approach to determine FDTD eigenfunctions in quantum devices

    MICROWAVE AND OPTICAL TECHNOLOGY LETTERS, Issue 9 2009
    Antonio Soriano
    Abstract This article combines a Neural Network (NN) algorithm with the Finite Difference Time Domain (FDTD) technique to estimate the eigenfunctions in quantum devices. A NN based on the Least Mean Squares (LMS) algorithm is combined with the FDTD technique to provide a first approach to the confined states in quantum wires. The proposed technique is in good agreement with analytical results and is more efficient than FDTD combined with the Fourier Transform. This technique is used to calculate a numerical approximation to the eigenfunctions associated to quantum wire potentials. The performance and convergence of the proposed technique are also presented in this article. © 2009 Wiley Periodicals, Inc. Microwave Opt Technol Lett 51: 2017,2022, 2009; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/mop.24562 [source]


    Numerical analysis of interferograms for evaluation of tear film build-up time

    OPHTHALMIC AND PHYSIOLOGICAL OPTICS, Issue 3 2009
    Dorota H. Szczesna
    Abstract The lateral shearing interferometer was applied to the in vivo dynamic investigation of the external surface of the pre-corneal tear film after an eye blink. Sequences of interferograms were recorded at a sampling frequency of 25 Hz. Immediately after every eye blink, a bright pattern was observed under the interference fringes. This disappeared after a short time interval (around 0.5,2 s): smooth interference fringes were then observed, corresponding to the creation of a smooth anterior optical surface over the cornea. The purpose of this study is to describe in detail the kinetics of pre-corneal tear film stability and to propose quantitative measures of the stabilisation process in healthy eyes during the 3 s period after a blink. Two methods of quantitative assessment of the tear film build-up time are presented. The first is based upon the evaluation of the inhomogeneity of the background of the interferogram; the second evaluates the orientation of the structure of the background by the analysis of the zero order of the Fast Fourier Transform (FFT) spectrum. The quasi-vertically oriented bright line patterns observed in interferograms immediately after a blink and the mirror-symmetry of their tilts for right and left eyes indicate that the pattern is related to the wiping movements of the upper eyelids during the eye blink. [source]


    Carbon nanotube probe resolution: a quantitative analysis using Fourier Transform

    PHYSICA STATUS SOLIDI (A) APPLICATIONS AND MATERIALS SCIENCE, Issue 5 2004
    H. R. Gutiérrez
    Abstract A method to quantify the resolution of atomic force microscopy (AFM) probes using Fourier analysis of the AFM images is proposed. The maximum detectable spatial frequency obtained from the power spectrum was used to estimate the lateral resolution. Carbon nanotube tips were successfully used to study very dense arrays of semiconductor nanostructures. In particular, accurate measurements of shallow facet angles were obtained, which are in perfect agreement with results obtained by two complementary techniques , High Resolution Transmission Electron Microscopy and Reflection High-Energy Electron Diffraction. (© 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


    Semi-classical calculation of resonant states of a charged particle interacting with a metallic surface

    PHYSICA STATUS SOLIDI (B) BASIC SOLID STATE PHYSICS, Issue 10 2005
    John Jairo Zuluaga
    Abstract We assess the applicability of the semi-classical approach of Herman,Kluk with filter diagonalization to determine resonant states of either the electron-surface system or the ion-surface system. An effective potential model of the interaction of an electron with a ruthenium metallic surface is used. The evolution of the wave-function and the resonant states of this system are calculated. Analogous results for the interaction of the system formed by the H, and the ruthenium surface are presented. For the calculation of the resonances, the semi-classical wave-function is found, and the autocorrelation function between the initial and final wave-functions is calculated, from which the position and width of the resonances are extracted by using the harmonic inversion by filter diagonalization. The results are compared with results available in the literature for similar models obtained by quantum calculations using fast Fourier Transform. The positions of the lower-lying resonances found with the semi-classical and quantum approaches match closely, while the values of the widths of the resonances show larger discrepancies. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


    Effects of coupling agents on the oxidation and darkening of cellulosic materials used as reinforcements for thermoplastic matrices in composites

    POLYMER ENGINEERING & SCIENCE, Issue 2 2000
    J. Martínez Urreaga
    Oxidation and darkening occur during the processing of composites made from thermoplastic matrices and cellulosic reinforcements. We have studied the effects of several coupling agents on both the oxidation and darkening of cellulosic materials at temperatures close to those used in the processing of cellulose-reinforced thermoplastics. A maleated polypropylene wax (Epolene E-43TM) and two silanes (N-2-aminoethyl-3-aminopropyltrimethoxy silane and methyltrimethoxysilane) were used as coupling agents. Oxidation was measured by Diffuse Reflectance Infrared Fourier Transform (DRIFT) spectroscopy. Standard colorimetry was used to measure darkening. Coupling agent effects depend on the nature and extent of cellulose modification achieved by treatments and the nature of the coupling agent. Epolene wax E-43 produced scarce effects on both the oxidation and darkening of cellulosic materials at 200°C. Only for longer oxidation times was an increase in oxidation and darkening observed in E-43-treated samples. Silane coupling agents inhibited the formation of carbonyl and carboxyl groups for shorter oxidation times. The diaminosilane produced a stronger darkening, probably due to a chemical reaction that generated new chromophores containing CN bonds. [source]


    A simple method for computer quantification of stage REM eye movement potentials

    PSYCHOPHYSIOLOGY, Issue 3 2001
    Xin Tan
    We describe a simple method for computer quantification of eye movement (EM) potentials during REM sleep. This method can be applied by investigators using either period-amplitude (PA) or Fast Fourier Transform (FFT) spectral EEG analysis without special hardware or computer programming. It provides good correlations with visual ratings of EM in baseline sleep and after administration of GABAergic hypnotics. We present baseline data for both PA and FFT measures for 16 normal subjects, studied for 5 consecutive nights. Both visually rated and computer-measured EM density (EMD) showed high night-to-night correlations across baseline and drug nights and the computer measures detected the EMD suppression that is produced by GABAergic drugs. Measurement of EM in addition to stage REM provides biologically significant information and application of this simple computer method, which does not require pattern recognition algorithms or special hardware, could provide reliable data that can be compared across laboratories. [source]


    z -Transform and adaptive signal processing in analysis of tracer data

    THE CANADIAN JOURNAL OF CHEMICAL ENGINEERING, Issue 3 2002
    Leszek Furman
    Abstract In the field of data processing, the common practice is to interpret tracer-determined residence time distributions (RTDs) of particles through different arrangements of elementary flow models. However, such analysis needs an a priori chosen arrangement of these models, and some information carried by the RTD curve may be lost. This paper presents a competitive method based on adaptive filtering in a z -transform domain, and it may give better insight into flow patterns in a steady-state flow system. A physical interpretation of the transfer function was developed. The application of this modelling to the interpretation of radiotracer data from recent studies in different industry sectors is presented. Dans le domaine du traitement des données, la pratique courante consiste à interpréter les distributions de temps de séjour (DTS) déterminées par traceur de particules à travers différents arrangements de modèles d'écoulements élémentaires. Toutefois, une telle analyse implique de choisir a priori l'arrangement de ces modèles. Ainsi, certaines informations données par la courbe de DTS peuvent se perdre. On présente dans cet article une méthode compétitive basée sur le filtrage adaptatif dans le domaine de la transformée en z, qui peut permettre une meilleure compréhension des schémas d'écoulement pour un système en écoulement permanent. Une interprétation physique de la fonction de transfert a été développée. On présente l'application de cette modélisation de l'interprétation des données de traceurs radioactifs provenant d'études récentes dans différents secteurs industriels. [source]


    Intermediate-term variations in solar radius during solar cycle 23

    ASTRONOMISCHE NACHRICHTEN, Issue 4 2009
    H. Kiliç
    Abstract In this study, we look for the mid-term variations in the daily average data of solar radius measurements made at the Solar Astrolabe Station of TUBITAK National Observatory (TUG) during solar cycle 23 for a time interval from 2000 February 26 to 2006 November 15. Due to the weather conditions and seasonal effect dependent on the latitude, the data series has the temporal gaps. For spectral analysis of the data series, thus, we use the Date Compensated Discrete Fourier Transform (DCDFT) and the CLEANest algorithm, which are powerful methods for irregularly spaced data. The CLEANest spectra of the solar radius data exhibit several significant mid-term periodicities at 393.2, 338.9, 206.5, 195.2, 172.3 and 125.4 days which are consistent with periods detected in several solar time series by several authors during different solar cycles. The knowledge relating to the origin of solar radius variations is not yet present. To see whether these variations will repeat in next cycles and to understand how the amplitudes of such variations change with different phases of the solar cycles, we need more systematic efforts and the long-term homogeneous data. Since most of the periodicities detected in the present study are frequently seen in solar activity indicators, it is thought that the physical mechanisms driving the periodicities of solar activity may also be effective in solar radius variations (© 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


    Vibrational spectroscopic studies to acquire a quality control method of Eucalyptus essential oils,

    BIOPOLYMERS, Issue 5 2005
    M. Baranska
    Abstract This article presents a novel and original approach to analyze in situ the main components of Eucalyptus oil by means of Raman spectroscopy. The obtained two-dimensional Raman maps demonstrate a unique possibility to study the essential oil distribution in the intact plant tissue. Additionally, Fourier Transform (FT)-Raman and attenuated total reflection (ATR)-IR spectra of essential oils isolated from several Eucalyptus species by hydrodistillation are presented. Density Functional Theory (DFT) calculations were performed in order to interpret the spectra of the essential oils of the Eucalyptus species. It is shown that the main components of the essential oils can be recognized by both vibrational spectroscopic techniques using the spectral information of the pure terpenoids. Spectroscopic analysis is based on the key bands of the individual volatile substances and therefore allows one to discriminate different essential oil profiles of several Eucalyptus species. It has been found that the presented spectroscopic data correlate very well with those obtained by gas chromatography (GC) analysis. All these investigations are helpful tools to generate a fast and easy method to control the quality of the essential oils with vibrational spectroscopic techniques in combination with DFT calculations. © 2005 Wiley Periodicals, Inc. Biopolymers 78: 237,248, 2005 [source]


    4122: Exploring new strategies to record and analyse clinical electroretinograms

    ACTA OPHTHALMOLOGICA, Issue 2010
    P LACHAPELLE
    Purpose Investigate if the combination of time-frequency domain analysis and ERG dipole rotation reveals hidden features of the normal ERG that could be instrumental in the interpretation of nearly extinguished ERG responses. Methods Analyses were conducted on photopic ERGs (Photopic Hills: PH) obtained from normal subjects (n=75) and patients (n=65) affected with various retinopathies. A Discrete Wavelet Transform (DWT) was done on each ERGs and key descriptors (Holder exponent and wavelet coefficient maxima) were calculated. Dipole rotation was obtained by combining 11 gaze positions (0, 8, 16, 24, 32 and 40 degrees nasal or temporal to center) with 4 electrode locations [corneal (CE), lower lid (LL), external (EC) and internal canthi (IC)]. Results The Holder exponent follows a parabola, while some of the local wavelet maxima seem to follow a PH-like like distribution (b-wave and OPs) or a logistic growth function (a-wave). In still recordable pathological ERGs, the wavelet maxima matched that found in normal ERGs evoked at low stimulus intensities while in nearly extinguished ERGs (<10% of normal) the wavelet coefficients were significantly lower. Irrespective of the direction of gaze, there was little variation in DTL ERGs. EC ERGs were the only ones to reverse in polarity (seen 5 degrees nasal to fixation in nasal to temporal shift). Conclusion The parameters obtained with the DWT offers useful and reproducible tools to help identify subtle features of residual ERGs and therefore should allow for a more accurate quantification of low-voltage ERGs responses. Finally, our results suggest that varying the gaze and electrode positions would represent a valuable addition to the recording of clinical ERGs. Funded by NSERC. [source]


    4334: Fully automated corneal endothelial morphometry of a large set of images captured by clinical specular microscopy

    ACTA OPHTHALMOLOGICA, Issue 2010
    C BUCHT
    Purpose The endothelial cell density is the most important morphological factor of the corneal endothelium. Morphometry of the corneal endothelium is an important part of several clinical applications. Morphometry of the endothelium is presently carried out by semi automated analysis of pictures captured by Clinical Specular Microscopy (CSM). The need of operator involvement makes this process time consuming. This study presents a method for fully automated analysis of a large range of in vivo images of the corneal endothelium, captured by CSM, using Fourier analysis. Methods Software was developed in the mathematical programming language MATLAB. Pictures of the corneal endothelium, captured by CSM, were read into the analysis software. The software performed automated digital enhancement of the images. The enhanced images were Fourier transformed, using the Fast Fourier Transform. Relevant characteristics of the Fourier transformed images were identified and sampled. The data obtained from each transformed image was used to calculate the mean cell density of the original image, which in turn was compared to a semi automated method cell density estimate. The calculation was based on well known diffraction theory. Results Estimated cell densities of the corneal endothelium were obtained, using fully automated analysis software on 292 images captured by CSM. Using linear regression, a relatively large correlation between the estimates of the fully automated method and the semi automated method was found. Conclusion The results using the considerably faster fully automated method are highly encouraging for further development and implementation of the method. [source]


    Monitoring of Anti Cancer Drug Letrozole by Fast Fourier Transform Continuous Cyclic Voltammetry at Gold Microelectrode

    CHINESE JOURNAL OF CHEMISTRY, Issue 7 2010
    Parviz Norouzi
    Abstract A continuous cyclic voltammetric study of letrozole at gold microelectrode was carried out. The drug in phosphate buffer (pH 2.0) is adsorbed at ,200 mV, giving rise to change in the current of well-defined oxidation peak of gold in the flow injection system. The proposed detection method has some of advantages, the greatest of which are as follows: first, it is no more necessary to remove oxygen from the analyte solution and second, this is a very fast and appropriate technique for determination of the drug compound in a wide variety of chromatographic analysis methods. Signal-to-noise ratio has significantly increased by application of discrete Fast Fourier Transform (FFT) method, background subtraction and two-dimensional integration of the electrode response over a selected potential range and time window. Also in this work some parameters such as sweep rate, eluent pH, and accumulation time and potential were optimized. The linear concentration range was of 1.0×10,7,1.0×10,10 mol/L (r=0.9975) with a limit of detection and quantitation 0.08 nmol/L and 0.15 nmol/L, respectively. The method has the requisite accuracy, sensitivity, precision and selectivity to assay letrozol in tablets. The influences of pH of eluent, accumulation potential, sweep rate, and accumulation time on the determination of the letrozol were considered. [source]


    Combined Wavelet Transform with Curve-fitting for Objective Optimization of the Parameters in Fourier Self-deconvolution

    CHINESE JOURNAL OF CHEMISTRY, Issue 10 2001
    Xiu-Qi Zhang
    Abstract Fourier self-deconvolution was the most effective technique in resolving overlapping bands, in which deconvolution function results in deconvolution and apodization smoothes the magnified noise. Yet, the choice of the original half-width of each component and breaking point for truncation is often very subjective. In this paper, the method of combined wavelet transform with curve fitting was described with the advantages of an enhancement of signal to noise ratio as well as the improved fitting condition, and was applied to objective optimization of the original half-widths of components in unresolved bands for Fourier self-deconvolution. Again, a noise was separated from a noisy signal by wavelet transform, therefore, the breaking point of apodization function can be determined directly in frequency domain. Accordingly, some artifacts in Fourier self-deconvolution were minimized significantly. [source]


    Equilibrium and kinetic studies of the cationic dye removal capability of a novel biosorbent Tamarindus indica from textile wastewater

    COLORATION TECHNOLOGY, Issue 5 2010
    Shooka Khorramfar
    In this paper, the use of tamarind hull biosorbent (Tamarindus indica) has been investigated to remove cationic dyes from textile eflluent. Basic Violet 6 and Basic Red 18 were used as cationic dye models. The surface characteristics of tamarind hull were investigated using Fourier Transform,infrared and scanning electron microscopy. The influence of process variables such as adsorbent dosage, initial dye concentration and pH were studied. The presence of fuctional groups such as hydroxy and amine groups onto the tamarind hull surface were proved by Fourier Transform,infrared analysis. Data were evaluated for compliance with the Langmuir and Freundlich isotherm models. The results indicated that the data for adsorption of Basic Violet 6 and Basic Red 18 onto tamarind hull fitted well with the Freundlich isotherm model. Also, the adsorption kinetics of Basic Violet 6 and Basic Red 18 on biosorbent was studied. The rates of sorption were found to conform to pseudo-second-order kinetics with good correlation. Results indicated that tamarind hull could be used as a biosorbent to remove cationic organics from contaminated watercourses. [source]


    Novel anti-bacterial acid dyes derived from naphthalimide: synthesis, characterisation and evaluation of their technical properties on nylon 6

    COLORATION TECHNOLOGY, Issue 2 2010
    Zinat Mohammadkhodaei
    As an attempt to combine the dyeing and functional finishing steps into one process, two novel anti-bacterial monoazo acid dyes based on N -ester-1,8-naphthalimide were synthesised. To do this, 4-amino- N -ethyl glycinate-1,8-naphthalimide was prepared, diazotised and then coupled to thiosalicylic acid or salicylic acid to produce anti-bacterial dyes. The synthesised dyes were purified and then fully characterised using Fourier Transform,infrared spectrometry, proton nuclear magnetic resonance spectroscopy and melting point analysis. Dispersion of the dyes was prepared in water and applied to nylon 6 fabrics. The novel dyes offered good build-up properties on the substrate. The anti-bacterial efficacy of the synthesised dyes was assessed, with the dyes showing activity against both Gram-positive and Gram-negative bacteria. [source]


    Synthesis, spectral properties and application of novel disazo disperse dyes derived from polyester waste

    COLORATION TECHNOLOGY, Issue 2 2010
    V S Palekar
    Terephthalic dihydrazide was obtained through aminolytic depolymerisation of polyester bottle waste by using hydrazine hydrate. It was further reacted with 4-aminobenzoic acid in the presence of polyphosphoric acid to obtain a cyclic compound, 4,4,-[5,5,-(1,4)-phenylene)bis(1,3,4-oxadiazole-5,2-diyl)dianiline, having a heterocyclic moiety. Diazotisation of this compound followed by coupling with various N,N -disubstituted anilines afford a series of novel disazo disperse dyes. The structures of these synthesised dyes were confirmed by elemental analysis and Fourier Transform,infrared, proton nuclear magnetic resonance and mass spectroscopy. Ultraviolet,visible spectra of these azo dyes in different polar solvents showed considerable variation in the wavelength of maximum absorbance (,max). Application of these dyes on polyester and nylon fabrics using high-temperature dyeing methods gave brilliant yellowish red hues with fair to moderate light fastness and very good to excellent wash fastness and sublimation fastness. [source]