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Thicker Films (thicker + film)

Distribution by Scientific Domains

Polymers and Materials Science	50%

Selected Abstracts

Interfacial characteristics of film insert molded polycarbonate film/polycarbonate-acrylonitrile-butadiene-styrene substrate, part 1: Influence of substrate molecular weight and film thickness

POLYMER ENGINEERING & SCIENCE, Issue 12 2006
Y.W. Leong
Adhesion properties between a polycarbonate (PC)/acrylonitrile-butadiene-styrene blend substrate and PC films of various thicknesses, bonded through film insert molding, were investigated. The use of various molecular weights of PC and incorporation of PC-oligomer in the blend substrate has been found to severely affect the adhesion strength and alter the delamination characteristics at the film,substrate interface. Thicker films were able to increase film,substrate adhesion, apart from providing added impact resistance to a brittle substrate. Polym. Eng. Sci. 46:1674,1683, 2006. © 2006 Society of Plastics Engineers [source]

Pore-Filling of Spiro-OMeTAD in Solid-State Dye Sensitized Solar Cells: Quantification, Mechanism, and Consequences for Device Performance

ADVANCED FUNCTIONAL MATERIALS, Issue 15 2009
I-Kang Ding
Abstract In this paper, the pore filling of spiro-OMeTAD (2,2,,7,7,-tetrakis-(N,N -di- p -methoxyphenylamine)9,9,-spirobifluorene) in mesoporous TiO2 films is quantified for the first time using XPS depth profiling and UV,Vis absorption spectroscopy. It is shown that spiro-OMeTAD can penetrate the entire depth of the film, and its concentration is constant throughout the film. We determine that in a 2.5-µm-thick film, the volume of the pores is 60,65% filled. The pores become less filled when thicker films are used. Such filling fraction is much higher than the solution concentration because the excess solution on top of the film can act as a reservoir during the spin coating process. Lastly, we demonstrate that by using a lower spin coating speed and higher spiro-OMeTAD solution concentration, we can increase the filling fraction and consequently the efficiency of the device. [source]

A comprehensive investigation of the structural properties of ferroelectric PbZr0.2Ti0.8O3 thin films grown by PLD

PHYSICA STATUS SOLIDI (A) APPLICATIONS AND MATERIALS SCIENCE, Issue 8 2009
David Walker
Abstract X-Ray diffraction investigations were made of high-quality epitaxial thin films of the ferroelectric material lead zirconate titanate, PbZr0.2Ti0.8O3 (PZT), grown by pulsed laser deposition (PLD). Layers from 7 to 200,nm in thickness were studied, deposited on a 30,nm SrRuO3 (SRO) electrode on a [001] oriented SrTiO3 (STO) substrate. The out-of-plane lattice parameters of the PZT films were measured by high-resolution X-ray diffraction using CuK,1 radiation. A significant enhancement of the c lattice parameter with film thickness was observed, the maximum value of 4.25,Å reached in the 30,50,nm thick films. For film thicknesses greater than 100,nm, the c lattice parameter is relaxed, towards the bulk value of 4.13,Å at this composition. The in-plane lattice parameters were studied by Grazing incidence X-ray scattering (GIXS), using 15,keV synchrotron radiation at I16, Diamond. The a lattice parameter of domains with [001] oriented normal to the sample surface was effectively lattice matched to the SRO layer in the 7,nm ultra-thin film, but relaxed compared to the SRO in thicker films. The tetragonality of the [001] oriented domains decreases with increasing film thickness, approaching the bulk value of 1.05 in the thickest films. Evidence for the presence of [100] oriented a -domains was found in PZT films as thin as 30,nm, the proportion of which increased with increasing film thickness, suggesting they grow in order to relieve stresses that would prevent the epitaxial growth of thicker PZT films. The a -domains in the thicker films were found to be located nearer to the PZT/SRO interface than to the top surface of the PZT. [source]

Optimization of Electrochemical and Peroxide-Driven Oxidation of Styrene with Ultrathin Polyion Films Containing Cytochrome P450cam and Myoglobin

CHEMBIOCHEM, Issue 1 2003
Bernard Munge
Abstract The catalytic and electrochemical properties of myoglobin and cytochrome P450camin films constructed with alternate polyion layers were optimized with respect to film thickness, polyion type, and pH. Electrochemical and hydrogen peroxide driven epoxidation of styrene catalyzed by the proteins was used as the test reaction. Ionic synthetic organic polymers such as poly(styrene sulfonate), as opposed to SiO2nanoparticles or DNA, supported the best catalytic and electrochemical performance. Charge transport involving the iron heme proteins was achieved over 40,320 nm depending on the polyion material and is likely to involve electron hopping facilitated by extensive interlayer mixing. However, very thin films (ca. 12,25 nm) gave the largest turnover rates for the catalytic epoxidation of styrene, and thicker films were subject to reactant transport limitations. Classical bell-shaped activity/pH profiles and turnover rates similar to those obtained in solution suggest that films grown layer-by-layer are applicable to turnover rate studies of enzymes for organic oxidations. Major advantages include enhanced enzyme stability and the tiny amount of protein required. [source]