Home About us Contact
|
Home About us Contact | ||
|
|
||
Thermodynamic Properties (thermodynamic + property)
Selected AbstractsThe application of spreadsheets to the analysis and optimization of systems and processes in the teaching of hydraulic and thermal engineeringCOMPUTER APPLICATIONS IN ENGINEERING EDUCATION, Issue 4 2006A. Rivas Abstract This article shows the capability of current spreadsheets to define, analyze and optimize models of systems and processes. Specifically, the Microsoft spreadsheet Excel is used, with its built-in solver, to analyze and to optimize systems and processes of medium complexity, whose mathematical models are expressed by means of nonlinear systems of equations. Two hydraulic and thermal engineering-based application examples are presented, respectively: the analysis and optimization of vapor power cycles, and the analysis and design of piping networks. The mathematical models of these examples have been implemented in Excel and have been solved with the solver. For the power cycles, the thermodynamic properties of water have been calculated by means of the add-in TPX (Thermodynamic Properties for Excel). Performance and optimum designs are presented in cases studies, according to the optimization criteria of maximum efficiency for the power cycle and minimum cost for the piping networks. © 2006 Wiley Periodicals, Inc. Comput Appl Eng Educ 14: 256,268, 2006; Published online in Wiley InterScience (www.interscience.wiley.com); DOI 10.1002/cae.20085 [source] Chemical-Picture-Based Modeling of Thermodynamic Properties of Dense Multicharged-Ion Plasmas Using the Superconfiguration ApproachCONTRIBUTIONS TO PLASMA PHYSICS, Issue 10 2009P.A. Loboda Abstract Using the chemical-picture representation of plasmas as a mixture of various ions and free electrons, a consistent description of thermodynamics of dense multicharged-ion plasmas is being developed that involves the effects of Coulomb non-ideality and degeneracy of plasma electrons; contribution of the excited ion states (on the base of the superconfiguration approach) that may exist under an appropriate truncation of ion energy spectra due to plasma effects; hard-sphere-model representation of the finite-volume effects of plasma ions with the model parameters (effective ion sizes) corresponding to superconfigurations yielding the greatest contribution to partition functions. We present the calculated data for average ionization, Grüneisen coefficient, and specific heat of aluminum and iron plasmas at temperatures of 0.03,3 keV and densities 10,3 , 10,5 of their normal material densities. Calculated thermodynamic functions and shock Hugoniots are compared with other theoretical and experimental data (© 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Thermodynamic Properties and Plasma Phase Transition in dense HydrogenCONTRIBUTIONS TO PLASMA PHYSICS, Issue 5-6 2004V. S. Filinov Abstract The internal energy and equation of state of dense hydrogen are investigated by direct path integral Monte Carlo method simulations which are further improved in comparison to our previous results. Data for four isotherms , T = 10, 000K, 30, 000K, 50, 000K, and 100, 000K , are presented. For T = 10, 000K it is shown that the internal energy is lowered due to droplet formation for densities of the order 1023cm,3 giving direct support for the existence of a plasma phase transition in megabar hydrogen. (© 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Thermodynamic Properties and Phase Diagram for the System MoO2,TiO2JOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 2 2008K. Thomas Jacob The activity of molybdenum dioxide (MoO2) in the MoO2,TiO2 solid solutions was measured at 1600 K using a solid-state cell incorporating yttria-doped thoria as the electrolyte. For two compositions, the emf was also measured as a function of temperature. The cell was designed such that the emf is directly related to the activity of MoO2 in the solid solution. The results show monotonic variation of activity with composition, suggesting a complete range of solid solutions between the end members and the occurrence of MoO2 with a tetragonal structure at 1600 K. A large positive deviation from Raoult's law was found. Excess Gibbs energy of mixing is an asymmetric function of composition and can be represented by the subregular solution model of Hardy as follows The temperature dependence of the emf for two compositions is reasonably consistent with ideal entropy of mixing. A miscibility gap is indicated at a lower temperature with the critical point characterized by Tc (K)=1560 and. Recent studies indicate that MoO2 undergoes a transition from a monoclinic to tetragonal structure at 1533 K with a transition entropy of 9.91 J·(mol·K),1. The solid solubility of TiO2 with rutile structure in MoO2 with a monoclinic structure is negligible. These features give rise to a eutectoid reaction at 1412 K. The topology of the computed phase diagram differs significantly from that suggested by Pejryd. [source] ChemInform Abstract: Thermodynamic Properties of the Gaseous Gallium Molybdates and Tungstates.CHEMINFORM, Issue 8 2010S. I. Lopatin Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source] ChemInform Abstract: Crystal Structure, Spectroscopy and Thermodynamic Properties of MIVWO6 (MI: Li, Na).CHEMINFORM, Issue 6 2010Aleksandr V. Knyazev Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source] ChemInform Abstract: Lithium Calcium Imide [Li2Ca(NH)2] for Hydrogen Storage: Structural and Thermodynamic PropertiesCHEMINFORM, Issue 47 2008S. Bhattacharya Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source] ChemInform Abstract: Lanthanide(III) Halides: Thermodynamic Properties and Their Correlation with Crystal Structure.CHEMINFORM, Issue 12 2008L. Rycerz Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source] System Ln,Fe,O (Ln: Ho, Er): Thermodynamic Properties of Ternary Oxides Using Differential Scanning Calorimetry and Solid-State Electrochemical Cells.CHEMINFORM, Issue 37 2006S. C. Parida Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF. [source] Molecular Dynamics Study of the Thermodynamic Properties of Calcium Apatites.CHEMINFORM, Issue 28 2006Part 2. Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF. [source] Thermodynamic Properties of PaCl5 and PaF5 Based on Quantum Chemical Calculations.CHEMINFORM, Issue 23 2003A. Kovacs No abstract is available for this article. [source] ChemInform Abstract: Thermodynamic Properties of Ti,Al Intermetallics.CHEMINFORM, Issue 35 2001R. G. Reddy Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source] ChemInform Abstract: Thermodynamic Properties and Phase Diagrams of the Binary Systems B2O3,Ga2O3, B2O3,Al2O3 and B2O3,In2O3.CHEMINFORM, Issue 31 2001Michael Hoch Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source] ChemInform Abstract: Conformations and Thermodynamic Properties of Sulfur Homocycles.CHEMINFORM, Issue 17 2001Part 1. Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source] Theoretical Study on the Vibrational Spectra and Thermodynamic Properties for Nitro Derivatives of Benzene and AnilinesCHINESE JOURNAL OF CHEMISTRY, Issue 8 2008Gui-Xiang WANG Abstract Nitro derivatives of benzene and anilines were optimized to obtain their molecular geometries and electronic structures at a DFT-B3LYP/6-31G, level. Their IR spectra were obtained and assigned by vibrational analysis. Comparing the calculated IR spectra with these of experiments known, all the IR data obtained in this paper were considered to be reliable. Based on the frequencies scaled by 0.96 and the principle of statistic thermodynamics, the thermodynamic properties were evaluated, which were linearly related with the number of nitro and amino groups as well as the temperature, obviously showing good group additivity. [source] A solar ejector air-conditioning system using environment-friendly working fluidsINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 13 2008E. Nehdi Abstract In this paper, the performance of the solar-driven ejector air conditioning with several environment-friendly working fluids is studied. The effect of the fluid nature and operating conditions on the ejector performance is examined. This performance is calculated using an empirical correlation. Thermodynamic properties of functioning fluids are obtained with a package REFPROP7. It appears that the refrigerant R717 offers the highest coefficient of performance (COP). For generator temperature TB,=,90°C, condenser temperature TC,=,35°C and evaporator temperature TE,=,15°C and with R717, the COP of ejector air-conditioning system is 0.408. Using a meteorological data for the city of Tunis, the system performance is computed for three collector types. The air-conditioning season and period were taken for six months from April to September. The daily period is between 8 and 17,h. For the solar air-conditioning application, the COP of the overall system varied from 0.21 to 0.28 and the exergy efficiency varied from 0.14 to 0.19 with the same working conditions and total solar radiation (351,875,Wm,2) in July. Copyright © 2008 John Wiley & Sons, Ltd. [source] Thermal Effects on Fast Skeletal Myosins from Alaska Pollock, White Croaker, and Rabbit in Relation to Gel FormationJOURNAL OF FOOD SCIENCE, Issue 5 2003H. Fukushima ABSTRACT Thermodynamic properties in differential scanning calorimetry (DSC) and changes in viscoelasticity upon heating of myosins from white croaker, Alaska pollock, and rabbit fast muscles were investigated in relation to their thermal gel formation abilities. Alaska pollock myosin unfolded in a wide temperature range of 19 to 69°C as revealed by DSC, whereas rabbit myosin unfolded in very narrow range of 32 to 56°C. Thermal unfolding of white croaker myosin occurred in an intermediate temperature range of 30 to 60°C. Viscoelastic properties determined as storage modulus, G,, and loss modulus, G,, reflected differences observed in DSC for the 3 myosins. [source] Thermodynamic properties of the Ising and Heisenberg S = 1 ferromagnet with biquadratic exchange and uniaxial anisotropyPHYSICA STATUS SOLIDI (B) BASIC SOLID STATE PHYSICS, Issue 2 2006M. Manojlovi Abstract We study the thermodynamic properties of S = 1 Ising and Heisenberg ferromagnets with both bilinear and biquadratic exchange and/or uniaxial anisotropy of both easy axis/plane character. Using the mean-field (MF) approximation we evaluated the free energy enabling us to study in detail the behavior of the order parameters and the dependence of the critical point on the anisotropy. We show that in the presence of biquadratic interaction, there is a difference in the behavior between the Ising and the Heisenberg model even in the MF approximation, which is not the case for the bilinear interaction. Combining the equations of motion for Green's functions with identities particular to S = 1, we managed to perform the random phase approximation without the decoupling of the operators at the same site, avoiding the peculiarities of the Callen,Anderson decoupling. This allowed us to improve the phase diagram for the Heisenberg model. The important result is the demonstration of the effect of anisotropy to nonvanishing of the quadrupolar order parameter at the Curie point. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] The application of spreadsheets to the analysis and optimization of systems and processes in the teaching of hydraulic and thermal engineeringCOMPUTER APPLICATIONS IN ENGINEERING EDUCATION, Issue 4 2006A. Rivas Abstract This article shows the capability of current spreadsheets to define, analyze and optimize models of systems and processes. Specifically, the Microsoft spreadsheet Excel is used, with its built-in solver, to analyze and to optimize systems and processes of medium complexity, whose mathematical models are expressed by means of nonlinear systems of equations. Two hydraulic and thermal engineering-based application examples are presented, respectively: the analysis and optimization of vapor power cycles, and the analysis and design of piping networks. The mathematical models of these examples have been implemented in Excel and have been solved with the solver. For the power cycles, the thermodynamic properties of water have been calculated by means of the add-in TPX (Thermodynamic Properties for Excel). Performance and optimum designs are presented in cases studies, according to the optimization criteria of maximum efficiency for the power cycle and minimum cost for the piping networks. © 2006 Wiley Periodicals, Inc. Comput Appl Eng Educ 14: 256,268, 2006; Published online in Wiley InterScience (www.interscience.wiley.com); DOI 10.1002/cae.20085 [source] Java applet on computation of thermodynamic properties of steam and R134a refrigerantCOMPUTER APPLICATIONS IN ENGINEERING EDUCATION, Issue 4 2003F. L. Tan Abstract This paper describes the application of Java programming on the computation of thermodynamic properties of steam and the HFC-134a, 1,1,1,2-tetrafluoroethane (R134a) refrigerant through the Java applets. The Java applets can compute thermodynamic properties of steam and R134a refrigerant, such as specific volume, internal energy, enthalpy, and entropy in the phases of saturated mixture, compressed liquid, and superheated vapor. The calculated values are accurate compared to the standard reference properties tables for steam and refrigerant. © 2004 Wiley Periodicals, Inc. Comput Appl Eng Educ 11: 211,225, 2003; Published online in Wiley InterScience (www.interscience.wiley.com); DOI 10.1002/cae.10049 [source] Thermodynamics of Hydrogen and Hydrogen-Helium Plasmas: Path Integral Monte Carlo Calculations and Chemical PictureCONTRIBUTIONS TO PLASMA PHYSICS, Issue 3-4 2005V. S. Filinov Abstract In this paper we study thermodynamic properties of hydrogen and hydrogen-helium mixtures with the help of the direct path integral Monte Carlo simulations. The results are compared with available theoretical and experimental methods based, in particular, on chemical picture. We investigate the effects of temperature ionization in low-density hydrogen plasma. We also present a number of calculated isotherms for hydrogenhelium mixture with the mass concentration of helium Y = 0.234 in the range from 104 K to 2 · 105 K. In the density region where a sharp conductivity rise have been observed experimentally the simulations give indications for one or two plasma phase transitions, in accordance with earlier theoretical predictions. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Numerical simulation of thermal interaction between polymer and argon induction thermal plasmaELECTRONICS & COMMUNICATIONS IN JAPAN, Issue 1 2009Yoshitaka Takeuchi Abstract Influence of polymer powder injection into Ar thermal plasmas was investigated by numerical approaches. Thermal plasma,polymer solid coupling phenomena such as melting and evaporation were considered to study plasma-quenching effect of polymer injection. Dominant process for decay of plasma temperature was examined by changing thermodynamic parameters such as melting, boiling temperatures and their latent heats of solid and liquid polymers. As a result, thermodynamic properties of evaporated polymer vapor directly affect plasma-quenching phenomena more markedly than the properties of liquid and solid which influence plasma quenching efficiency through the amount of evaporation. © 2009 Wiley Periodicals, Inc. Electron Comm Jpn, 92(1): 24,33, 2009; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/ecj.10226 [source] Toxicity of arsenic species to Lemna gibba L. and the influence of phosphate on arsenic bioavailabilityENVIRONMENTAL TOXICOLOGY, Issue 1 2004Martin Mkandawire Abstract The toxicity of arsenic (As) species to Lemna gibba L. and the influence of PO on As bioavailability and uptake were tested in batch culture. L. gibba were exposed to six test concentrations of NaHAsO4 · 7H2O and NaAsO3, with 0, 0.0136, 13.6, and 40 mg L,1 KH2PO4. In batch culture As toxicity to L. gibba did not relate linearly to As concentration. The growth rate, related to frond number as recommended by OECD and ISO/DIN, was significantly inhibited in fronds exposed to 20,50 ,g L,1 As(III) compared with fronds exposed to As(V). The growth rate was stimulated when plants were exposed to 50,250 ,g L,1 of both As(III) and As(V). After exposure to 300,800 ,g L,1 growth inhibition was significantly higher for As(III) than for As(V), whereas above 800 ,g L,1 As(V) was inhibited the most. The bioaccumulation of As(III) and As(V) was significantly higher for P-deficient cultures (0.98 ± 0.08 and 1.02 ± 0.19 g kg,1, respectively for 0.0136 mg L,1 PO) than for P-sufficient cultures (243 and 343 mg kg,1 for 40 mg L,1, respectively). Plants exposed to As(V) had uptake and accumulation values slightly higher than did plants exposed to As(III). No significant differences in bioaccumulation were found between plants exposed to a concentration of As(III) >1 mg L,1 and those exposed to As(V) at the same concentration. This indicates a direct relationship to P content in the culture. Toxicity may result from the uptake of As(V) instead of PO as a result of ion competition during uptake because of close thermodynamic properties, which may change the interaction among components in the media. The toxicity pattern is interpreted as a manifestation of changing speciation in the batch culture and of the oxidation of As(III) to As(V) in an oxygen-rich environment. © 2004 Wiley Periodicals, Inc. Environ Toxicol 19: 26,34, 2004. [source] Concentration dependency of biota-sediment accumulation factors for chlorinated dibenzo- p -dioxins and dibenzofurans in dungeness crab (Cancer magister) at marine pulp mill sites in British Columbia, CanadaENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 12 2000Walter J. Cretney Abstract Biota-sediment accumulation factors (BSAFs) for some chlorinated dibenzo- p -dioxin and dibenzofuran congeners (PCDD/Fs) in Dungeness crab (Cancer magister) hepatopancreas and associated sediments are concentration independent as required by equilibrium partition models. In particular 2, 3, 7, 8-tetrachlorodibenzo- p -dioxin (2, 3, 7, 8-TCDD), 2, 3, 7, 8-tetrachlorodibenzofuran, the 2, 3, 7, 8-substituted pentachlorodibenzofurans, and the non-2, 3, 7, 8-hexachlorodibenzofurans (HxCDFs) seem to fall into this group. The BSAFs for other isomers exhibit significant, nonlinear variations with sediment or crab PCDD/F concentrations. For some of these other isomers (e.g., the non-2, 3, 7, 8 TCDDs and possibility the 2, 3, 7, 8-substituted HxCDFs), association of a variable fraction of the total present with soot carbon may provide a satisfactory explanation for the concentration behavior. For the HxCDDs we propose that the nonlinear concentration behavior may arise from the thermodynamic properties of fluids confined in hydrophobic voids within particulate and colloidal material produced by the pulp mills. The nonlinear relationship between BSAFs and PCDD/F concentrations greatly complicates prediction of the potential for dioxin and furan bioaccumulation in crabs and the formulation of sediment quality criteria. We provide a nonlinear equation relating toxic equivalency and sediment concentrations. [source] Binding of ligands originates small perturbations on the microscopic thermodynamic properties of a multicentre redox proteinFEBS JOURNAL, Issue 9 2005Carlos A. Salgueiro NMR and visible spectroscopy coupled to redox measurements were used to determine the equilibrium thermodynamic properties of the four haems in cytochrome c3 under conditions in which the protein was bound to ligands, the small anion phosphate and the protein rubredoxin with the iron in the active site replaced by zinc. Comparison of these results with data for the isolated cytochrome shows that binding of ligands causes only small changes in the reduction potentials of the haems and their pairwise interactions, and also that the redox-sensitive acid,base centre responsible for the redox,Bohr effect is essentially unaffected. Although neither of the ligands tested is a physiological partner of cytochrome c3, the small changes observed for the thermodynamic properties of cytochrome c3 bound to these ligands vs. the unbound state, indicate that the thermodynamic properties measured for the isolated protein are relevant for a physiological interpretation of the role of this cytochrome in the bioenergetic metabolism of Desulfovibrio. [source] Thermodynamic and kinetic analysis of the isolated FAD domain of rat neuronal nitric oxide synthase altered in the region of the FAD shielding residue Phe1395FEBS JOURNAL, Issue 12 2004Adrian J. Dunford In rat neuronal nitric oxide synthase, Phe1395 is positioned over the FAD isoalloxazine ring. This is replaced by Trp676 in human cytochrome P450 reductase, a tryptophan in related diflavin reductases (e.g. methionine synthase reductase and novel reductase 1), and tyrosine in plant ferredoxin-NADP+ reductase. Trp676 in human cytochrome P450 reductase is conformationally mobile, and plays a key role in enzyme reduction. Mutagenesis of Trp676 to alanine results in a functional NADH-dependent reductase. Herein, we describe studies of rat neuronal nitric oxide synthase FAD domains, in which the aromatic shielding residue Phe1395 is replaced by tryptophan, alanine and serine. In steady-state assays the F1395A and F1395S domains have a greater preference for NADH compared with F1395W and wild-type. Stopped-flow studies indicate flavin reduction by NADH is significantly faster with F1395S and F1395A domains, suggesting that this contributes to altered preference in coenzyme specificity. Unlike cytochrome P450 reductase, the switch in coenzyme specificity is not attributed to differential binding of NADPH and NADH, but probably results from improved geometry for hydride transfer in the F1395S, and F1395A,NADH complexes. Potentiometry indicates that the substitutions do not significantly perturb thermodynamic properties of the FAD, although considerable changes in electronic absorption properties are observed in oxidized F1395A and F1395S, consistent with changes in hydrophobicity of the flavin environment. In wild-type and F1395W FAD domains, prolonged incubation with NADPH results in development of the neutral blue semiquinone FAD species. This reaction is suppressed in the mutant FAD domains lacking the shielding aromatic residue. [source] Discrete Bose-Einstein systems in a box with low adiabatic invariantFORTSCHRITTE DER PHYSIK/PROGRESS OF PHYSICS, Issue 4-5 2003V.I. Vlad The Bose-Einstein energy spectrum of an ideal quantum gas confined in a box is discrete and strongly dependent on the box geometry and temperature, for low product of the atomic mass number, Aat and the adiabatic invariant, TV2/3, i.e. on , = Aat TV2/3. Even within the approximation of non-interacting particles in the gas, the calculation of the thermodynamic properties of Bose-Einstein systems turns out to be a difficult mathematical problem. The present study compares the total number of particles, the total energy and the specific heat obtained by sums over the discrete states to the results of the approximate integrals (for defined values of ,) and shows the noticeable errors of the last ones at low adiabatic invariant (around condensation). Then, more rigorous and precise analytical approximations of sums are found in the case of finite number of atoms (correlated with the existence of a zero energy level) and the finite volume of the gas. The corrected thermodynamic functions depend on , (for fixed fugacity). The condensation temperature is corrected also in order to describe more accurately the discrete Bose-Einstein systems. Under these circumstances, the analysis of the specific heat leads to the conclusion that it shows no discontinuity, for the entire range of , values. [source] Direct computation of thermodynamic properties of chemically reacting air with consideration to CFDINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS, Issue 4 2003Joe IannelliArticle first published online: 2 SEP 200 Abstract This paper details a two-equation procedure to calculate exactly mass and mole fractions, pressure, temperature, specific heats, speed of sound and the thermodynamic and jacobian partial derivatives of pressure and temperature for a five-species chemically reacting equilibrium air. The procedure generates these thermodynamic properties using as independent variables either pressure and temperature or density and internal energy, for CFD applications. An original element in this procedure consists in the exact physically meaningful solution of the mass-fraction and mass-action equations. Air-equivalent molecular masses for oxygen and nitrogen are then developed to account, within a mixture of only oxygen and nitrogen, for the presence of carbon dioxide, argon and the other noble gases within atmospheric air. The mathematical formulation also introduces a versatile system non-dimensionalization that makes the procedure uniformly applicable to flows ranging from shock-tube flows with zero initial velocity to aerothermodynamic flows with supersonic/hypersonic free-stream Mach numbers. Over a temperature range of more than 10000 K and pressure and density ranges corresponding to an increase in altitude in standard atmosphere of 30000 m above sea level, the predicted distributions of mole fractions, constant-volume specific heat, and speed of sound for the model five species agree with independently published results, and all the calculated thermodynamic properties, including their partial derivatives, remain continuous, smooth, and physically meaningful. Copyright © 2003 John Wiley & Sons, Ltd. [source] Adiabatic capillary tube flow of carbon dioxide in a transcritical heat pump cycleINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 11 2007Neeraj Agrawal Abstract Flow characteristics of an adiabatic capillary tube in a transcritical CO2 heat pump system have been investigated employing the homogeneous model. The model is based on fundamental equations of mass, energy and momentum which are solved simultaneously. Two friction factor empirical correlations (Churchill, Lin et al., Int. J. Multiphase Flow 1991; 17(1):95,102) and four viscosity models (Mcadams, Cicchitti, Dukler and Lin) are comparatively used to investigate the flow characteristics. Choked condition at the outlet is also investigated for maximum mass flow rate. Subcritical and supercritical thermodynamic and transport properties of CO2 are calculated employing a precision property code. Choice of viscosity model causes minor variation in results unlike in chlorofluorocarbons (CFCs) refrigerants. Relationships between cooling capacity with capillary tube diameter, length and maximum mass flow rate are presented. A lower evaporating temperature yields a larger cooling capacity due to the unique thermodynamic properties of CO2. It is also observed that an optimum cooling capacity exists for a specified capillary tube. Copyright © 2006 John Wiley & Sons, Ltd. [source] Performance characteristics and modelling of a micro gas turbine for their integration with thermally activated cooling technologiesINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 2 2007Adrián Vidal Abstract We have developed a simple model of a micro gas turbine system operating at high ambient temperatures and characterized its performance with a view to integrating this system with thermally activated cooling technologies. To develop and validate this model, we used experimental data from the micro gas turbine test facility of the CREVER research centre. The microturbine components were modelled and the thermodynamic properties of air and combustion gases were estimated using a commercial process simulator. Important information such as net output power, microturbine fuel consumption and exhaust gas mass flow rate can be obtained with the empirical correlations we have developed in this study. This information can be useful for design exhaust gas fired absorption chillers. Copyright © 2006 John Wiley & Sons, Ltd. [source] | |||||||||||||||||||||||||||||||||||||