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Theoretical Limit (theoretical + limit)
Selected AbstractsCorrelation Between Triplet,Triplet Annihilation and Electroluminescence Efficiency in Doped Fluorescent Organic Light-Emitting DevicesADVANCED FUNCTIONAL MATERIALS, Issue 8 2010Yichun Luo Abstract Triplet,triplet annihilation (TTA) is studied in a wide range of fluorescent host:guest emitter systems used in organic light-emitting devices (OLEDs). Strong TTA is observed in host:guest systems in which the dopant has a limited charge-trapping capability. On the other hand, systems in which the dopant can efficiently trap charges show insignificant TTA, an effect that is due, in part, to the efficient quenching of triplet excitons by the trapped charges. Fluorescent host:guest systems with the strongest TTA are found to give the highest OLED electroluminescence efficiency, a phenomenon attributed to the role of TTA in converting triplet excitons into additional singlet excitons, thus appreciably contributing to the light output of OLEDs. The results shed light on and give direct evidence for the phenomena behind the recently reported very high efficiencies attainable in fluorescent host:guest OLEDs with quantum efficiencies exceeding the classical 25% theoretical limit. [source] Mesoporous Hydrous Manganese Dioxide Nanowall Arrays with Large Lithium Ion Energy Storage CapacitiesADVANCED FUNCTIONAL MATERIALS, Issue 7 2009Dawei Liu Abstract Novel nanowall arrays of hydrous manganese dioxide MnO2,·,0.5H2O are deposited onto cathodic substrates by the potentiostatic method from a mixed aqueous solution of manganese acetate and sodium sulfate. The deposition is induced by a change of local pH resulting from electrolysis of H2O, and hierarchical mesoporous nanowall arrays are formed as a result of simultaneous precipitation of manganese hydroxide and release of hydrogen gas bubbles from the cathode. The morphology and lithium ion intercalation properties are found to change appreciably with the concentration of the precursor electrolyte, with a significant reduction in specific surface area with an increased precursor concentration. For example, mesoporous nanowall arrays deposited from 0.1,M solution possess a surface area of ,96,m2 g,1 and exhibit a stable high intercalation capacity of 256,mA hg,1 with a film of 0.5,µm in thickness, far exceeding the theoretical limit of 150,mA hg,1 for manganese dioxide bulk film. Such mesoporous nanowall arrays offer much greater energy storage capacity (e.g., ,230,mA hg,1 for films of ,2.5,µm) than that of anodic deposited films of the same thickness (,80,mA hg,1). Such high lithium ion intercalation capacity and excellent cyclic stability of the mesoporous nanowall arrays, especially for thicker films, are ascribed to the hierarchically structured macro- and mesoporosity of the MnO2,·,0.5H2O nanowall arrays, which offer large surface to volume ratio favoring interface Faradaic reactions, short solid-state diffusion paths, and freedom to permit volume change during lithium ion intercalation and de-intercalation. [source] A mechanistic model for roll waves for two-phase pipe flowAICHE JOURNAL, Issue 11 2009George W. Johnson Abstract A new two-phase roll wave model is compared with data from high pressure two-phase stratified pipe flow experiments. Results from 754 experiments, including mean wave speed, wave height, pressure gradient, holdup and wave length, are compared with theoretical results. The model was able to predict these physical quantities with good accuracy without introducing any new empirically determined quantities to the two-fluid model equations. This was possible by finding the unique theoretical limit for nonlinear roll amplitude and applying a new approach for determining the friction factor at the gas-liquid interface. © 2009 American Institute of Chemical Engineers AIChE J, 2009 [source] USING INCIDENT LIGHT TO MAXIMIZE RESOLUTION OF STRUCTURE ON DIATOM VALVES WITH A LIGHT MICROSCOPEJOURNAL OF PHYCOLOGY, Issue 2001Article first published online: 24 SEP 200 Siver, P. A. Botany Department, Connecticut College, New London, CT 06320 Because of their abundance in a diverse array of aquatic habitats and chemical conditions, and the fact that their species-specific siliceous outer coverings remain for millennia in sediments, diatoms have become one of the most powerful organismal groups used in the reconstruction of historical environmental conditions. Although SEM is now needed to identify some species, the bulk of the identifications and data collection is still accomplished with a light microscope. In this paper I will demonstrate the use of interference reflection contrast (incident light) for the examination of diatoms that significantly improves the resolution of structural detail. Using incident light one can routinely distinguish between structures close to the theoretical limit of resolution for visible light, and about 70 nm closer together than resolvable with standard transmitted light optics. Examples of how the incident light technique can improve data collection with light microscopy will be given. Most research light microscopes could be easily and inexpensively outfitted to use this technique. [source] Gel-free sample preparation for the nanoscale LC-MS/MS analysis and identification of low-nanogram protein samplesJOURNAL OF SEPARATION SCIENCE, JSS, Issue 14 2007Marco Gaspari Abstract Protein identification at the low nanogram level could in principle be obtained by most nanoscale LC-MS/MS systems. Nevertheless, the complex sample preparation procedures generally required in biological applications, and the consequent high risk of sample losses, very often hamper practical achievement of such low levels. In fact, the minimal amount of protein required for the identification from a gel band or spot, in general, largely exceeds the theoretical limit of identification reachable by nanoscale LC-MS/MS systems. A method for the identification of low levels of purified proteins, allowing limits of identification down to 1 ng when using standard bore, 75 ,m id nanoscale LC-MS/MS systems is here reported. The method comprises an offline two-step sample cleanup, subsequent to protein digestion, which is designed to minimize sample losses, allows high flexibility in the choice of digestion conditions and delivers a highly purified peptide mixture even from "real world" digestion conditions, thus allowing the subsequent nanoscale LC-MS/MS analysis to be performed in automated, unattended operation for long series. The method can be applied to the characterization of low levels of affinity purified proteins. [source] An amino acid "transmembrane tendency" scale that approaches the theoretical limit to accuracy for prediction of transmembrane helices: Relationship to biological hydrophobicityPROTEIN SCIENCE, Issue 8 2006Gang Zhao Abstract Hydrophobicity analyses applied to databases of soluble and transmembrane (TM) proteins of known structure were used to resolve total genomic hydrophobicity profiles into (helical) TM sequences and mainly "subhydrophobic" soluble components. This information was used to define a refined "hydrophobicity"-type TM sequence prediction scale that should approach the theoretical limit of accuracy. The refinement procedure involved adjusting scale values to eliminate differences between the average amino acid composition of populations TM and soluble sequences of equal hydrophobicity, a required property of a scale having maximum accuracy. Application of this procedure to different hydrophobicity scales caused them to collapse to essentially a single TM tendency scale. As expected, when different scales were compared, the TM tendency scale was the most accurate at predicting TM sequences. It was especially highly correlated (r = 0.95) to the biological hydrophobicity scale, derived experimentally from the percent TM conformation formed by artificial sequences passing though the translocon. It was also found that resolution of total genomic sequence data into TM and soluble components could be used to define the percent probability that a sequence with a specific hydrophobicity value forms a TM segment. Application of the TM tendency scale to whole genomic data revealed an overlap of TM and soluble sequences in the "semihydrophobic" range. This raises the possibility that a significant number of proteins have sequences that can switch between TM and non-TM states. Such proteins may exist in moonlighting forms having properties very different from those of the predominant conformation. [source] GSn: A new service type for integrated services on the internet,EUROPEAN TRANSACTIONS ON TELECOMMUNICATIONS, Issue 1 2001Enrico Gregori Network services with deterministic guarantees are based on a worst,case description of user,generated traffic. When designing a policing and scheduling algorithm for guaranteed services on the Internet, accuracy of description of the traffic profile has to be traded with simplicity of implementation. The result of this trade off is often expressed as the number of token buckets required by the service along with the choice of their parameters. The GS type of service proposed by the IETF uses two token buckets both for characterizing the traffic and for policing it. The choice of using only two token buckets is primarily driven by policing costs. In this paper we propose a method that allows the number of token buckets used for characterizing the traffic to be greater than what is actually needed to police it. This means we can obtain an accurate profile of the traffic while keeping policing simple. The method consists of computing a profile of the traffic which involves a number of token buckets of the order of ten, and then doing the policing using only the first token bucket, plus another one which is chosen depending on the delay requirements of the receivers. This paper shows that with this simple enhancement we obtain a guaranteed service whose performance closely approaches the theoretical limits of services with deterministic guarantees. [source] Development of a Segmented Model for a Continuous Electrophoretic Moving Bed Enantiomer SeparationBIOTECHNOLOGY PROGRESS, Issue 6 2003Brian M. Thome With the recent demonstration of a continuous electrophoretic "moving bed" enantiomer separation at mg/h throughputs, interest has now turned to scaling up the process for use as a benchtop pharmaceutical production tool. To scale the method, a steady-state mathematical model was developed that predicts the process response to changes in input feed rate and counterflow or "moving bed" velocities. The vortex-stabilized apparatus used for the separation was modeled using four regions based on the different hydrodynamic flows in each section. Concentration profiles were then derived on the basis of the properties of the Piperoxan-sulfated ,-cyclodextrin system being studied. The effects of different regional flow rates on the concentration profiles were evaluated and used to predict the maximum processing rate and the hydrodynamic profiles required for a separation. Although the model was able to qualitatively predict the shapes of the concentration profiles and show where the theoretical limits of operation existed, it was not able to quantitatively match the data from actual enantiomer separations to better than 50% accuracy. This is believed to be due to the simplifying assumptions involved, namely, the neglect of electric field variations and the lack of a competitive binding isotherm in the analysis. Although the model cannot accurately predict concentrations from a separation, it provides a good theoretical framework for analyzing how the process responds to changes in counterflow rate, feed rate, and the properties of the molecules being separated. [source] | |||||||||||||