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Barrier System (barrier + system)
Selected AbstractsEvaluating the transport and removal of chromate using pyrite and biotite columnsHYDROLOGICAL PROCESSES, Issue 14 2007Chul-Min Chon Abstract To remove chromate from a wastewater, a porous permeable reactive barrier system (PRBS), using pyrite and biotite, was adapted. This study included bench-scale column experiments to evaluate the efficiency of the PRBS and investigate the reaction process. The total chromium concentration of the effluent from the biotite and pyrite columns reached the influent concentration of 0·10 mM after passing through more than 150 pore volumes (PVs) and 27 PVs respectively, and remained constant thereafter. The CrVI concentration in the effluent from the biotite column became constant at about 0·08 mM, accounting for approximately 80% of the influent concentration, after passing through 200 PVs. Moreover, in the pyrite column, the CrVI concentration remained at about 0·01 mM, 10% of the input level, after passing through 116 PVs. This shows that both columns maintained their levels of chromate reduction once the CrVI breakthrough curves (BTCs) had reached the steady state, though the steady-state output concentration of total chromium had reached the influent level. The variances of the iron concentration closely followed those of the chromium. The observed data for both columns were fitted to the predicted BTCs calculated by CXTFIT, a program for estimating the solute transport parameters from experimental data. The degradation coefficient µ of the total chromium BTCs for both columns was zero, suggesting the mechanisms for the removal of chromate limit the µ of the CrVI BTCs. The CrVI degradation of the pyrite column (6·60) was much greater than that of the biotite column (0·27). In addition, the CrVI retardation coefficient R of the pyrite column (253) was also larger than that of the biotite column (125). The R values for the total chromium BTCs from both columns were smaller than those of the CrVI BTC. Whereas the total chromium BTC for the pyrite column showed little retardation (1·5), the biotite column showed considerable retardation (80). The results for the 900 °C heat-treated biotite column were analogous to those of the control column (quartz sand). This suggests that the heat-treated biotite played no role in the retardation and removal of hexavalent chromium. The parameters of the heat-treated biotite were calculated to an R of 1·2 and µ of 0·01, and these values confirmed quantitatively that the heated biotite had little effect on the transport of CrVI. These solute transport parameters, calculated by CXTFIT from the data obtained from the column tests, can provide quantitative information for the evaluation of bench- or field-scale columns as a removal technology for CrVI in wastewater or contaminated groundwater. Copyright © 2006 John Wiley & Sons, Ltd. [source] Development of a technique for modelling clay liner desiccationINTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS, Issue 6 2003Y. Zhou Abstract This paper presents a model for the analysis of clay liner desiccation in a landfill barrier system due to temperature effects. The model incorporates consideration of fully coupled heat-moisture-air flow, a non-linear constitutive relationship, the dependence of void ratio and volumetric water content on stress, capillary pressure and temperature, and the effect of mechanical deformation on all governing equations. Mass conservative numerical schemes are proposed to improve the accuracy of the finite element solution to the governing equations. The application of the model is then demonstrated by examining three test problems, including isothermal infiltration, heat conduction and non-isothermal water and heat transport. Comparisons are made with results from literature, and good agreement is observed. Copyright © 2003 John Wiley & Sons, Ltd. [source] Molecular dynamics and multiscale homogenization analysis of seepage/diffusion problem in bentonite clayINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN ENGINEERING, Issue 12 2002Y. Ichikawa Abstract A scheme combining a molecular behaviour and macro-continuum phenomenon is presented for bentonite clay, which is a key component of a barrier system for disposal and containment of hazardous wastes. On designing a disposal facility we use a macro-phenomenological model. However the existing model is not sufficiently effective. Bentonite is a microinhomogeneous material. Properties of the saturated bentonite are characterized by montmorillonite and water, called montmorillonite hydrate. Since the crystalline structure of montmorillonite determines the fundamental properties of the montmorillonite hydrate, we analyse its molecular behaviour by applying a molecular dynamics simulation to enquire into the physicochemical properties of the montmorillonite hydrate such as diffusivity of chemical species. For extending the microscopic characteristics of constituent materials to a macroscopic diffusion behaviour of the microinhomogeneous material we apply a multiscale homogenization analysis, especially in order to treat micro-level of adsorption behaviour. Copyright © 2002 John Wiley & Sons, Ltd. [source] Yttrium Silicate Powders Produced by the Sol,Gel Method, Structural and Thermal CharacterizationJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 9 2003Damien Boyer Yttrium silicate (Y2SiO5) powders of high purity have been synthesized using the sol,gel method. Alkoxide precursors were used with commercial tetraethyl orthosilicate as the silica source and yttrium propoxide synthesized from YCl3. Powders calcined from the xerogel showed submicrometer crystal sizes. These powders were sintered at temperatures <1300°C and are suitable for coating applications such as a thermal barrier system for SiC/SiC composites. [source] Polarization of electron spin in two barrier system based on semimagnetic semiconductorsPHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 4 2006S. B. Lev Abstract The spin-dependent tunneling of electrons through a two barrier semiconductor heterostructure with a semimagnetic layer was investigated. It was shown that the resonant level splitting in the semimagnetic well under an external magnetic field allows achieving a high level of spin polarization of the current flowing through the proposed spin filter. The dependence of the polarization depth on the parameters of the sample was calculated in the two component diffusion transport model. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Evaluation of a vertical frozen soil barrier at oak ridge national laboratoryREMEDIATION, Issue 3 2000Stanley W. Lynn Arctic Foundations, Inc. (AFI), of Anchorage, Alaska, has developed a freeze barrier system designed to hydraulically isolate a contaminant source area. The system can be used for long-term or temporary containment of groundwater until appropriate remediation techniques can be applied. The technology was evaluated under the United States Environmental Protection Agency's (EPA's) Superfund Innovative Technology Evaluation (SITE) program at the United States Department of Energy's (DOE's) Oak Ridge National Laboratory (ORNL) facility in Oak Ridge, Tennessee. For the demonstration, an array of freeze pipes called "thermoprobes" was installed to a depth of 30 feet below ground surface around a former waste collection pond and keyed into bedrock. The system was used to establish an impermeable frozen soil barrier to hydraulically isolate the pond. Demonstration personnel collected independent data to evaluate the technology's performance. A variety of evaluation tools were used,including a groundwater dye tracing investigation, groundwater elevation measurements, and subsurface soil temperature data,to determine the effectiveness of the freeze barrier system in preventing horizontal groundwater flow beyond the limits of the frozen soil barrier. Data collected during the demonstration provided evidence that the frozen soil barrier was effective in hydraulically isolating the pond. [source] Early Holocene drowned lagoonal deposits from the Kattegat, southern ScandinaviaBOREAS, Issue 4 2000OLE BENNIKE Shallow seismic profiling indicated the presence of a drowned lagoon,barrier system formed during the transgression of the southern Kattegat, and investigations of core material have confirmed this. Studies of plant and animal macrofossils show that the lagoonal sediments contain a mixture of marine, brackish, lacustrine, telmatic and terrestrial taxa, and analyses of foraminifers indicate brackish-water conditions. Low oxygen isotope values obtained on shells of marine molluscs also point to lowered salinity. The lagoonal sediments are situated at depths between 24 and 35 m below present sea level. They are dated to between c. 10.5 cal. ka BP and c. 9.5 cal. ka BP, and reflect a period characterized by a moderate relative sea level rise. The lagoonal sediments are underlain by lateglacial glaciomarine clay and silt, which are separated from the Holocene deposits by an unconformity. The earliest Holocene sediments consist of littoral sand with gravel, stones and shells; these sediments were formed during the transgression of the area before the barrier island,lagoon system was developed. The lagoonal sediments are overlain by mud, which contains animal remains that indicate increasing water depths. [source] Selection and Basic Properties of the Buffer Material for High-Level Radioactive Waste Repository in ChinaACTA GEOLOGICA SINICA (ENGLISH EDITION), Issue 5 2008WEN Zhijian Abstract Radioactive wastes arising from a wide range of human activities are in many different physical and chemical forms, contaminated with varying radioactivity. Their common features are the potential hazard associated with their radioactivity and the need to manage them in such a way as to protect the human environment. The geological disposal is regarded as the most reasonable and effective way to safely disposing high-level radioactive wastes in the world. The conceptual model of geological disposal in China is based on a multi-barrier system that combines an isolating geological environment with an engineered barrier system. The buffer is one of the main engineered barriers for HLW repository. It is expected to maintain its low water permeability, self-sealing property, radio nuclides adsorption and retardation properties, thermal conductivity, chemical buffering property, canister supporting property, and stress buffering property over a long period of time. Bentonite is selected as the main content of buffer material that can satisfy the above requirements. The Gaomiaozi deposit is selected as the candidate supplier for China's buffer material of high level radioactive waste repository. This paper presents the geological features of the GMZ deposit and basic properties of the GMZ Na-bentonite. It is a super-large deposit with a high content of montmorillonite (about 75%), and GMZ-1, which is Na-bentonite produced from GMZ deposit is selected as the reference material for China's buffer material study. [source] Toxicologic implications of cutaneous barriers: a molecular, cellular, and anatomical overviewJOURNAL OF APPLIED TOXICOLOGY, Issue 7 2009Abraar Karan Abstract The skin barrier is a complex system of chemical, biological and physical processes that together regulate the admission and expulsion of foreign agents in contact with the skin. The eggresive movement of the stratum corneum (SC) is often a measure of its integrity, and transepidermal water loss has typically been a gold standard. However, the skin barrier has several barrier systems, such as ion flux, O2, CO2 and pH, which can give an informative and sometimes more sensitive measure of the SC condition. Furthermore, the penetrative interactions with the barrier have focused around occlusive methods to promote drug delivery, the interactions of topically applied drugs with the barrier and the presence of environmental agents that can harm the barrier. However, the nature of penetrative barrier interactions must also be elucidated on a microscopic level. The variable nature of barrier function is demonstrated when comparing the skin properties of neonates and adults. In addition, new biochemical methods have used keratin metrics to improve diagnostic efficacy and barrier integrity analysis. This review addresses the aforementioned aspects of the skin barriers that require further study to help discern the complexity of this essential organ as it relates to dermatotoxicology and dermatopharmacology. Copyright © 2009 John Wiley & Sons, Ltd. [source] | |||||||||||||