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Surface Tension Measurements (surface + tension_measurement)
Selected AbstractsIdentifying rotation and oscillation in surface tension measurement using an oscillating droplet methodHEAT TRANSFER - ASIAN RESEARCH (FORMERLY HEAT TRANSFER-JAPANESE RESEARCH), Issue 7 2008Shumpei Ozawa Abstract We proposed a new approach to identify the frequencies of droplet rotation and m=±2 oscillation that degrade the accuracy of surface tension measurement by an oscillating droplet method. Frequencies of droplet rotation and m=±2 oscillation can be identified by a phase unwrapping analysis of time dependence of the deflection angle for the maximum diameter of the droplet image observed from above. The present method was validated, using test data with given frequencies. © 2008 Wiley Periodicals, Inc. Heat Trans Asian Res, 37(7): 421,430, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/htj.20214 [source] Solubilities and surface activities of phthalates investigated by surface tension measurementsENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 1 2001Marianne Thomsen Abstract Aueous solutions of DEP (di-ethyl), DnBP (di- n -butyl), DnH(6)P (di- n -hexyl), and DEHP (di-[2-ethyl-hexyl])phthalates have been investigated by use of surface tension measurements at temperatures between 10 and 35°C. A tensiometric approach allows for the determination of unimeric solubilities and ,G°, which is the standard Gibbs free energy change, for the dissolution of phthalates in water. The unimeric solubility of the phthalates increase with decreasing temperature. The ,G° shows a linear increase with increasing phthalate alkyl chain length. The contribution of enthalpy (,H°) and entropy (,S°) to ,G° were calculated from the temperature-dependent solubilities. The contributions of both ,H° and ,S° are negative and increase in magnitude with increasing alkyl chain length, suggesting hydrophobic interactions between phthalates and water. The ability of different phthalates to lower the surface tension decreases with increasing alkyl chain length, whereas the relative affinity for adsorption in the air-water interface increases drastically for long-chain phthalates. Despite the low surface activity of phthalates compared with that of common surfactants, they show significant affinity for adsorption in air-water interfaces of natural surface waters. This property, combined with their low solubilities, may affect the fate of these compounds within the natural environment, because they form emulsions above unimeric saturation in aqueous media. [source] The effect of viscosity on surface tension measurements by the drop weight methodJOURNAL OF APPLIED POLYMER SCIENCE, Issue 3 2007T. Kaully Abstract Viscosity is one of the parameters affecting the measured surface tension, as fluid mechanics affects the measurement process using conventional methods. Several methods including the selected planes (SPM) and WDSM which combines the weight drop method (WDM) and SPM, are applied to surface tension measurement of high viscous liquids. Yet, none of them treats the viscosity effect separately. The current publication presents a simple, easy to apply empirical approach of satisfactory accuracy, for evaluation of surface tension of liquids having wide range of viscosities up to 10 Pa s. The proposed method is based on Tate's law and the "drop weight" method using calibration curves of known liquids having similar surface tensions but different viscosities. Drop weight of liquids having viscosity ,0.05 Pa s, was found to be significantly affected by the liquid viscosity. The shape factor, f, of high viscosity liquids was found to correlate linearly with the logarithm of viscosity, pointing the importance of viscosity correction. The experimental correlation presented in the current work can be used as a tool for the evaluation of surface tension for high viscosity liquids such as prepolymers. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 [source] Electrospinning of cellulose-based nanofibersJOURNAL OF APPLIED POLYMER SCIENCE, Issue 3 2007Audrey Frenot Abstract Cellulose derivatives of carboxymethyl cellulose sodium salt (CMC), hydroxypropyl methylcellulose (HPMC), methylcellulose (MC), and enzymatically treated cellulose have been electrospun, and the microstructure of the resulting nanofibers has been analyzed by scanning electron microscopy (SEM). Before electrospinning, the solutions were characterized by viscometry and surface tension measurements, and the results were correlated with spinnability. Four different CMC derivatives, varying in molecular weight (Mw), degree of substitution (DS), and substitution pattern, have been electrospun in mixtures with poly(ethylene oxide) (PEO), and nanofibers of various characteristics have formed. The CMC-based nanostructures, i.e., the nonwoven sheet and individual nanofibers, proved to be independent of Mw and DS but largely dependent on the substitution pattern. The nonwoven sheets varied in homogeneity, and beads appeared on the individual fibers. Depending on the chemical nature of the CMC, the extraction of PEO resulted in pure CMC nanostructures of varying appearance, indicating that the distribution of PEO and CMC in the nanofibers also varied. Two different HPMC derivatives, varying in DS, were electrospun into nanofibers. Homogeneous nonwoven sheets based on nanofibers of similar appearance are formed, independent of the substitution content of the HPMC sample. Preliminary fibers were obtained from enzymatically treated cellulose in a solvent system based on lithium chloride dissolved in dimethyl acetamide (LiCl: DMAc). © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 1473,1482, 2007 [source] The Dynamic Interaction of Water with Four Dental Impression Materials During CureJOURNAL OF PROSTHODONTICS, Issue 4 2009Dariush Hosseinpour PhD Abstract Purpose: The purpose of this work was to investigate the interaction of water with four different dental impression materials: Aquasil (Ultra XLV Type 3), Take 1 (Wash Regular Set), Genie (Light Body, Standard Set), and Impregum Garant (Soft Light Bodied Consistency). Materials and Methods: Apparent contact angles of de-ionized water made against thin horizontal sample films of the different materials under different conditions were measured from analysis of profile images of symmetrical sessile drops of water placed on the sample films using a Model FTÅ200 dynamic drop shape analysis system, which included a JAI M30 high speed CCD camera combined with a zoom microscope. Data were taken for specimens of dry ages (times following mixing) from a minimum of 20 seconds up to 1220 seconds. Imaging was started before the initial water/impression material contact, and lasted for at least 420 seconds in each case. The interval at the beginning of each run was 0.033 second, and then increased by a factor of 1.012 to the end. During the initial 3 seconds following the drop deposition, the drop's shape oscillated due to inertial effects, so apparent contact angle data during this period were neglected in all cases. All measurements were made at room temperature. The drops were enclosed in a humidified chamber that suppressed evaporation. All data were repeated at least five times, and results were analyzed where appropriate using one-way ANOVA. Microscopic images of the water/impression material interactions for fresh (uncured) materials were acquired to reveal the destructive interactions that resulted from such contact. Finally, surface tension measurements were made of water that had been contacted with material of varying dry age using the pendant drop method capability of the drop shape analysis system. These helped to assess the origin of hydrophilicity development for the different materials. Results: For short curing times (dry ages), water showed a destructive effect on the integrity of all of the impression materials, as evidenced by the formation of a crater beneath the water drop and a scum of material at its surface. These effects diminished with dry age until a critical curing time was reached, beyond which such destructive interactions were no longer detectable. These critical curing times were determined to be 80, 140, 110, and 185 seconds for Aquasil, Take 1, Genie, and Impregum, respectively. The initial contact angle following the respective critical curing time was lowest for Impregum, at 66°; while values for Aquasil, Genie, and Take 1 were 93°, 104°, and 110°, respectively. Beyond the critical curing times for the different materials, different degrees of hydrophilicity were observed. Aquasil showed the lowest final contact angle (<10°), with Impregum, Take 1, and Genie showing 31°, 34°, and 40°, respectively. Measurements of the surface tension of water after contact with the different materials suggested that for Aquasil, hydrophilicity appears to be developed through the leaching of surfactant from the material, whereas for Impregum, Take 1, and Genie, hydrophilicity is developed at least in part through a change in surface structure in contact with water. Impregum and Aquasil materials of dry ages well beyond the critical curing time exhibited a stick-slip behavior in their interline movement or contact angle evolution. This was believed to be due to the slowness in the leaching of surfactant (in the case of Aquasil) or the re-orientation of unleachable surface groups (in the case of the other materials) in comparison to the inherent kinetics of water drop spreading. Conclusions: All materials investigated in the fresh, uncured state showed qualitative decomposition when put in contact with water through the formation of a crater beneath the water drop and a scum of material at its surface. These effects diminished with curing time until beyond a critical value, no such effects were evident. The initial hydrophilicity of the materials as determined by the contact angles obtained at their respective critical dry ages was greatest for Impregum. Beyond the critical curing time, different degrees of hydrophilicity were observed, with Aquasil showing the lowest final contact angle. [source] Surface activity,thermodynamic properties and light scattering studies for some novel aliphatic polyester surfactantsPOLYMERS FOR ADVANCED TECHNOLOGIES, Issue 5 2004R. A. El-Ghazawy Abstract The preparation of 12 new polyester surfactants based on aliphatic amines and different ethylene oxide content is described. These surfactants were characterized by determining their molecular weights and polydispersity by gel permeation chromatography (GPC) and nitrogen content. Drop volume tensiometry (DVT) was used to measure the surface tension at 25, 35, 45 and 55°C. The surface tension isotherms were used to determine critical micelle concentration (CMC), maximum Gibb's adsorption (,max), minimum area per molecule (Amin), the effectiveness of surface tension reduction (,cmc) and the efficiency (pC20). The thermodynamic parameters of micellization (,Gmic, ,Hmic, ,Smic) and of adsorption (,Gad, ,Had, ,Sad) were calculated and the data showed that these surfactants favor micellization to adsorption. The static scattered light intensity measurements provide the calculation of the molecular weight of micelle and the aggregation number (N°), while the dynamic light scattering provide the hydrodynamic radius of micelle (RH) and the diffusion coefficient at different surfactant concentrations. The hydrodynamic radius of micelle (RH) at different surfactant concentrations could be used also to determine the CMC giving results that are comparable to those obtained by surface tension measurements. All the data are discussed regarding the chemical structure of the polymeric surfactants. Copyright © 2004 John Wiley & Sons, Ltd. [source] Exploring the interactions of gliadins with model membranes: Effect of confined geometry and interfacesBIOPOLYMERS, Issue 8 2009Amélie Banc Abstract Mechanisms leading to the assembly of wheat storage proteins into proteins bodies within the endoplasmic reticulum (ER) of endosperm cells are unresolved today. In this work, physical chemistry parameters which could be involved in these processes were explored. To model the confined environment of proteins within the ER, the dynamic behavior of ,-gliadins inserted inside lyotropic lamellar phases was studied using FRAP experiments. The evolution of the diffusion coefficient as a function of the lamellar periodicity enabled to propose the hypothesis of an interaction between ,-gliadins and membranes. This interaction was further studied with the help of phospholipid Langmuir monolayers. ,- and ,-gliadins were injected under DMPC and DMPG monolayers and the two-dimensional (2D) systems were studied by Brewster angle microscopy (BAM), polarization modulation infrared reflection-absorption spectroscopy (PM-IRRAS), and surface tension measurements. Results showed that both gliadins adsorbed under phospholipid monolayers, considered as biological membrane models, and formed micrometer-sized domains at equilibrium. However, their thicknesses, probed by reflectance measurements, were different: ,-gliadins aggregates displayed a constant thickness, consistent with a monolayer, while the thickness of ,-gliadins aggregates increased with the quantity of protein injected. These different behaviors could find some explanations in the difference of aminoacid sequence distribution: an alternate repeated - unrepeated domain within ,-gliadin sequence, while one unique repeated domain was present within ,-gliadin sequence. All these findings enabled to propose a model of gliadins self-assembly via a membrane interface and to highlight the predominant role of wheat prolamin repeated domain in the membrane interaction. In the biological context, these results would mean that the repeated domain could be considered as an anchor for the interaction with the ER membrane and a nucleus point for the formation and growth of protein bodies within endosperm cells. © 2009 Wiley Periodicals, Inc. Biopolymers 91: 610,622, 2009. This article was originally published online as an accepted preprint. The "Published Online" date corresponds to the preprint version. You can request a copy of the preprint by emailing the Biopolymers editorial office at biopolymers@wiley.com [source] | ||||||||||