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Subsurface Water (subsurface + water)
Selected AbstractsThe effect of cleaning and disinfecting the sampling well on the microbial communities of deep subsurface water samplesENVIRONMENTAL MICROBIOLOGY, Issue 1 2005Odile Basso Summary Our knowledge of the microbial characteristics of deep subsurface waters is currently very limited, mainly because of the methods used to collect representative microbial samples from such environments. In order to improve this procedure, a protocol designed to remove the unspecific, contaminant biofilm present on the walls of an approximately 800 m deep well is proposed. This procedure included extensive purges of the well, a mechanical cleaning of its wall, and three successive chlorine injections to disinfect the whole line before sampling. Total bacterial counts in water samples decreased from 2.5 × 105 to 1.0 × 104 per millilitre during the cleaning procedure. Culture experiments showed that the first samples were dominated by sulfate-reducers and heterotrophs, whereas the final sample was dominated by oligotrophic and hydrogenotrophic bacteria. Community structures established on the diversity of the 16S rRNA genes and data analysis revealed that the water sample collected, after a purge without removal of the biofilm, was characterized by numerous phyla which are not representative of the deep subsurface water. On the other hand, several bacterial phyla were only detected after the full cleaning of the well, and were considered as important components of the subsurface ecosystem which would have been missed in the absence of well cleaning. [source] Exoenzyme activities as indicators of dissolved organic matter composition in the hyporheic zone of a floodplain riverFRESHWATER BIOLOGY, Issue 8 2010SANDRA M. CLINTON Summary 1. We measured the hyporheic microbial exoenzyme activities in a floodplain river to determine whether dissolved organic matter (DOM) bioavailability varied with overlying riparian vegetation patch structure or position along flowpaths. 2. Particulate organic matter (POM), dissolved organic carbon (DOC), dissolved oxygen (DO), electrical conductivity and temperature were sampled from wells in a riparian terrace on the Queets River, Washington, U.S.A. on 25 March, 15 May, 20 July and 09 October 1999. Dissolved nitrate, ammonium and soluble reactive phosphorus were also collected on 20 July and 09 October 1999. Wells were characterised by their associated overlying vegetation: bare cobble/young alder, mid-aged alder (8,20 years) and old alder/old-growth conifer (25 to >100 years). POM was analysed for the ash-free dry mass and the activities of eight exoenzymes (,-glucosidase, ,-glucosidase, , -N-acetylglucosaminidase, xylosidase, phosphatase, leucine aminopeptidase, esterase and endopeptidase) using fluorogenic substrates. 3. Exoenzyme activities in the Queets River hyporheic zone indicated the presence of an active microbial community metabolising a diverse array of organic molecules. Individual exoenzyme activity (mean ± standard error) ranged from 0.507 ± 0.1547 to 22.8 ± 5.69 ,mol MUF (g AFDM),1 h,1, was highly variable among wells and varied seasonally, with the lowest rates occurring in March. Exoenzyme activities were weakly correlated with DO, DOC and inorganic nutrient concentrations. 4. Ratios of leucine aminopeptidase : ,-glucosidase were low in March, May and October and high in July, potentially indicating a switch from polysaccharides to proteins as the dominant component of microbial metabolism. 5. Principal components analysis indicated that there were patch effects and that these effects were strongest in the summer. 6. DOM degradation patterns did not change systematically along hyporheic flowpaths but varied with overlying forest patch type in the Queets River hyporheic zone, suggesting that additional carbon inputs exist. We hypothesise that the most likely input is the downward movement of DOM from overlying riparian soils. Understanding this movement of DOM from soils to subsurface water is essential for understanding both the hyporheic metabolism and the carbon budget of streams and rivers. [source] Hyporheic Exchange in Mountain Rivers I: Mechanics and Environmental EffectsGEOGRAPHY COMPASS (ELECTRONIC), Issue 3 2009Daniele Tonina Hyporheic exchange is the mixing of surface and shallow subsurface water through porous sediment surrounding a river and is driven by spatial and temporal variations in channel characteristics (streambed pressure, bed mobility, alluvial volume and hydraulic conductivity). The significance of hyporheic exchange in linking fluvial geomorphology, groundwater, and riverine habitat for aquatic and terrestrial organisms has emerged in recent decades as an important component of conserving, managing, and restoring riverine ecosystems. Here, we review the causes and environmental effects of hyporheic exchange, and provide a simple mathematical framework for examining the mechanics of exchange. A companion paper explores the potential effects of channel morphology on exchange processes and the hyporheic environments that may result in mountain basins (Buffington and Tonina 2009). [source] Quantifying the impact of groundwater discharge on the surface,subsurface exchangeHYDROLOGICAL PROCESSES, Issue 15 2009Fulvio Boano Abstract The exchange of oxygen and nutrients between the well-aerated stream water and the subsurface water is crucial for the biochemical conditions of the hyporheic zone. The metabolic activity of the hyporheic microorganisms controls the fate of nitrogen and phosphorus in the pore water, and influences the fate of these nutrients at the catchment scale. Unfortunately, the incomplete knowledge of the complex hydrodynamics of the coupled surface-subsurface flow field often hinders the understanding of the ecological relevance of the hyporheic processes. Here, we analyse the influence of groundwater discharge through the streambed on bedform-induced hyporheic exchange. A simple mathematical model of a coupled stream-aquifer system is developed in order to describe the essential feature of the surface-subsurface exchange. The most representative characteristics of the hyporheic exchange, e.g. the depth of the hyporheic zone - are parametrized in terms of a small number of easily measurable quantities. This information on the hyporheic flow field provides the fundamental basis for the study of the ecological function of the hyporheic zone. Copyright © 2009 John Wiley & Sons, Ltd. [source] Effects of hillslope topography on hydrological responses in a weathered granite mountain, Japan: comparison of the runoff response between the valley-head and the side slopeHYDROLOGICAL PROCESSES, Issue 14 2008Masamitsu Fujimoto Abstract To evaluate the effects of hillslope topography on storm runoff in a weathered granite mountain, discharge rate, soil pore water pressures, and water chemistry were observed on two types of hillslope: a valley-head (a concave hillslope) and a side slope (a planar hillslope). Hydrological responses on the valley-head and side slope reflected their respective topographic characteristics and varied with the rainfall magnitude. During small rainfall events (<35 mm), runoff from the side slope occurred rapidly relative to the valley-head. The valley-head showed little response in storm runoff. As rainfall amounts increased (35,60 mm), the valley-head yielded a higher flow relative to the side slope. For large rainfall events (>60 mm), runoff from both hillslopes increased with rainfall, although that from the valley-head was larger than that from the side slope. The differences in the runoff responses were caused by differences in the roles of lower-slope soils and the convergence of the hillslope. During small rainfall events, the side slope could store little water; in contrast, all rainwater could be stored in the soils at the valley-head hollow. As the amount of rainfall increased, the subsurface saturated area of the valley-head extended from the bottom to the upper portion of the slope, with the contributions of transient groundwater via lateral preferential flowpaths due to the high concentration of subsurface water. Conversely, saturated subsurface flow did not contribute to runoff responses, and the subsurface saturated area at the side slope did not extend to the upper slope for the same storm size. During large rainfall events, expansion of the subsurface saturated area was observed in both hillslopes. Thus, differences in the concentration of subsurface water, reflecting hillslope topography, may create differences in the extension of the subsurface saturated area, as well as variability in runoff responses. Copyright © 2007 John Wiley & Sons, Ltd. [source] Estimation of mean residence times of subsurface waters using seasonal variation in deuterium excess in a small headwater catchment in JapanHYDROLOGICAL PROCESSES, Issue 3 2007Naoki Kabeya Abstract We measured deuterium excess (d = ,D , 8,18O) in throughfall, groundwater, soil water, spring water, and stream water for 3 years in a small headwater catchment (Matsuzawa, 0·68 ha) in the Kiryu Experimental Watershed in Japan. The d value represents a kinetic effect produced when water evaporates. The d value of the throughfall showed a sinusoidal change (amplitude: 6·9, relative to Vienna standard mean ocean water (V-SMOW)) derived from seasonal changes in the source of water vapour. The amplitude of this sinusoidal change was attenuated to 1·3,6·9, V-SMOW in soil water, groundwater, spring water, and stream water. It is thought that these attenuations derive from hydrodynamic transport processes in the subsurface and mixing processes at an outflow point (stream or spring) or a well. The mean residence time (MRT) of water was estimated from d value variations using an exponential-piston flow model and a dispersion model. MRTs for soil water were 0,5 months and were not necessarily proportional to the depth. This may imply the existence of bypass flow in the soil. Groundwater in the hillslope zone had short residence times, similar to those of the soil water. For groundwater in the saturated zone near the spring outflow point, the MRTs differed between shallow and deeper groundwater; shallow groundwater had a shorter residence time (5,8 months) than deeper groundwater (more than 9 months). The MRT of stream water (8,9 months) was between that of shallow groundwater near the spring and deeper groundwater near the spring. The seasonal variation in the d value of precipitation arises from changes in isotopic water vapour composition associated with seasonal activity of the Asian monsoon mechanism. The d value is probably an effective tracer for estimating the MRT of subsurface water not only in Japan, but also in other East Asian countries influenced by the Asian monsoon. Copyright © 2006 John Wiley & Sons, Ltd. [source] Hydrological influences on hyporheic water quality: implications for salmon egg survivalHYDROLOGICAL PROCESSES, Issue 9 2004I. A. Malcolm Abstract The spatial and temporal variability of groundwater,surface-water (GW,SW) interactions was investigated in an intensively utilized salmon spawning riffle. Hydrochemical tracers, were used along with high-resolution hydraulic head and temperature data to assess hyporheic dynamics. Surface and subsurface hydrochemistry were monitored at three locations where salmon spawning had been observed in previous years. Temperature and hydraulic head were monitored in three nests of three piezometers located to characterize the head, the run and the tail-out of the riffle feature. Hydrochemical gradients between surface and subsurface water indicated increasing GW influence with depth into the hyporheic zone. Surface water was characterized by high dissolved oxygen (DO) concentrations, low alkalinity and conductivity. Hyporheic water was generally characterized by high levels of alkalinity and conductivity indicative of longer residence times, and low DO, indicative of reducing conditions. Hydrochemical and temperature gradients varied spatially over the riffle in response to changes in local GW,SW interactions at the depths investigated. Groundwater inputs dominated the head and tail of the riffle. The influence of SW increased in the area of accelerating flow and decreasing water depth through the run of the riffle. Temporal GW,SW interactions also varied in response to changing hydrological conditions. Gross changes in hyporheic hydrochemistry were observed at the weekly scale in response to changing flow conditions and surface water inputs to the hyporheic zone. During low flows, caused by freezing or dry weather, hyporheic hydrochemistry was dominated by GW inputs. During higher flows hyporheic hydrochemistry indicated that SW contributions increased. In addition, high-resolution hydraulic head data indicated that rapid changes in GW,SW interactions occurred during hydrological events. The spatial, and possibly the temporal, variability of GW,SW interactions had a marked effect on the survival of salmon ova. It is concluded that hyporheic dynamics and their effect on stream ecology should be given increased consideration by fisheries and water resource managers. Copyright © 2004 John Wiley & Sons, Ltd. [source] ENSO and the South China Sea summer monsoon onsetINTERNATIONAL JOURNAL OF CLIMATOLOGY, Issue 2 2007Wen Zhou Abstract This paper investigates the relationship between the onset date of the South China Sea summer monsoon (SCSSM) and the El Niño/Southern Oscillation (ENSO). The monsoon onset date (MOD) is defined on the basis of the switch of the 850-hPa zonal winds over the South China Sea (SCS) from easterly to westerly for two consecutive pentads. The ENSO signal is represented by the ocean heat content (OHC), which is proportional to the depth of the 20 °C isotherm. It is found that, in years associated with a warm (cold) ENSO event or the year after, the monsoon tends to have a late (an early) onset and the intensity of the SCSSM also tends to be weaker (stronger). During a 2-year period prior to the onset, anomalies of OHC have an obvious eastward propagation. The 850-hPa flow east of the Philippines, specifically the strength of the subtropical high, is also found to be critical in determining the MOD. The link between these two results appears to be the propagation of cold (warm) subsurface water into the western North Pacific (WNP), which strengthens (weakens) the subtropical high, and hence a late (an early) SCSSM onset. Copyright © 2006 Royal Meteorological Society. [source] FOREST-RIVER INTERACTIONS: INFLUENCE ON HYPORHEIC DISSOLVED ORGANIC CARBON CONCENTRATIONS IN A FLOODPLAIN TERRACE,JOURNAL OF THE AMERICAN WATER RESOURCES ASSOCIATION, Issue 3 2002Sandra M. Clinton ABSTRACT: In large floodplain rivers, hyporheic (subsurface) flow-paths transfer nutrients from productive riparian terraces to oligotrophic off-channel habitats. Because dissolved organic carbon (DOC) fuels microbial processes and hyporheic microorganisms represent the first stage of retention and transformation of these nutrients, understanding DOC flux can provide information on the constraints of microbial metabolism in the hyporheic zone of rivers. We monitored hydrology, physicochemical indicators, and dissolved organic carbon (DOC) dynamics during low and high discharge periods in the hyporheic zone of a riparian terrace on the Queets River, Washington, to understand what processes control the supply of carbon to subsurface microbial communities. As discharge increased, terrace hyporheic flowpaths changed from parallel to focused, and the location of surface water inputs to the terrace shifted from the terrace edge to head. Overall, DOC concentrations decreased along hyporheic flowpaths; however, concentrations at points along the flowpaths varied with position along the head gradient and age of the overlying vegetation. We estimated that there is insufficient DOC in adverting surface water to support hyporheic microbial metabolism in this riparian terrace. These trends indicate that there are additional carbon sources to the subsurface water, and we conclude that DOC is leaching from overlying riparian soils within the forest patches. Thus, subsurface DOC concentrations reflect a balance between surface water inputs, metabolic uptake, and allochthonous inputs from forest soils. [source] Holocene paleoceanography of the northern Barents Sea and variations of the northward heat transport by the Atlantic OceanBOREAS, Issue 1 2001JEAN-CLAUDE DUPLESSY Foraminiferal assemblages were studied in northern Barents Sea core ASV 880 along with oxygen and carbon isotope measurements in planktonic (N. pachyderma sin.) and benthic (E clavatum) species. AMS C-14 measurements performed on molluscs Yoldiella spp. show that this core provides a detailed and undisturbed record of Holocene climatic changes over the last 10000 calendar years. Surface and deep waters were very cold (<0°C) at the beginning of the Holocene. C. reniforme dominated the highly diverse benthic foraminiferal assemblage. From 10 to 7.8 cal. ka BP, a warming trend culminated in a temperature optimum, which developed between 7.8 and 6.8 cal. ka BP. During this optimum, the input of Atlantic water to the Barents Sea reached its maximum. The Atlantic water mass invaded the whole Franz Victoria Trough and was present from subsurface to the bottom. No bottom water, which would form through rejection of brine during winter, was present at the core depth (388 m). The water stratification was therefore greatly reduced as compared to the present. An increase in percentage of I. helenae/norcrossi points to long seasonal ice-free conditions. The temperature optimum ended rather abruptly, with the return of cold polar waters into the trough within a few centuries. This was accompanied by a dramatic reduction of the abundance of C. reniforme. During the upper Holocene, the more opportunistic species E. clavatum became progressively dominant and the water column was more stratified. Deep water in Franz Victoria Trough contained a significant amount of cold Barents Sea bottom water as it does today, while subsurface water warmed progressively until about 3.7 cal. ka BP and reached temperatures similar to those of today. These long-term climatic changes were cut by several cold events of short duration, in particular one in the middle of the temperature optimum and another, which coincides most probably with the 8.2 ka BP cold event. Both long- and short-term climatic changes in the Barents Sea are associated with changes in the flow of Atlantic waters and the oceanic conveyor belt. [source] Abundance and activity of Chloroflexi -type SAR202 bacterioplankton in the meso- and bathypelagic waters of the (sub)tropical AtlanticENVIRONMENTAL MICROBIOLOGY, Issue 7 2008Marta M. Varela Summary The contribution of Chloroflexi -type SAR202 cells to total picoplankton and bacterial abundance and uptake of d - and l -aspartic acids (Asp) was determined in the different meso- and bathypelagic water masses of the (sub)tropical Atlantic (from 35°N to 5°S). Fluorescence in situ hybridization (FISH) revealed that the overall abundance of SAR202 was , 1 × 103 cells ml,1 in subsurface waters (100 m layer), increasing in the mesopelagic zone to 3 × 103 cells ml,1 and remaining fairly constant down to 4000 m depth. Overall, the percentage of total picoplankton identified as SAR202 increased from < 1% in subsurface waters to 10,20% in the bathypelagic waters. On average, members of the SAR202 cluster accounted for about 30% of the Bacteria in the bathypelagic waters, whereas in the mesopelagic and subsurface waters, SAR202 cells contributed < 5% to total bacterial abundance. The ratio of d -Asp : l -Asp uptake by the bulk picoplankton community increased from the subsurface layer (d -Asp : l -Asp uptake ratio , 0.03) to the deeper layers reaching a ratio of ,1 at 4000 m depth. Combining FISH with microautoradiography to determine the proportion of SAR202 cells taking up d -Asp versus l -Asp, we found that ,,30% of the SAR202 cells were taking up l -Asp throughout the water column while d -Asp was essentially not taken up by SAR202. This d -Asp : l -Asp uptake pattern of SAR202 cells is in contrast to that of the bulk bacterial and crenarchaeal community in the bathypelagic ocean, both sustaining a higher fraction of d -Asp-positive cells than l -Asp-positive cells. Thus, although the Chloroflexi -type SAR202 constitutes a major bathypelagic bacterial cluster, it does not contribute to the large fraction of d -Asp utilizing prokaryotic community in the meso- and bathypelagic waters of the North Atlantic, but rather utilizes preferentially l -amino acids. [source] The effect of cleaning and disinfecting the sampling well on the microbial communities of deep subsurface water samplesENVIRONMENTAL MICROBIOLOGY, Issue 1 2005Odile Basso Summary Our knowledge of the microbial characteristics of deep subsurface waters is currently very limited, mainly because of the methods used to collect representative microbial samples from such environments. In order to improve this procedure, a protocol designed to remove the unspecific, contaminant biofilm present on the walls of an approximately 800 m deep well is proposed. This procedure included extensive purges of the well, a mechanical cleaning of its wall, and three successive chlorine injections to disinfect the whole line before sampling. Total bacterial counts in water samples decreased from 2.5 × 105 to 1.0 × 104 per millilitre during the cleaning procedure. Culture experiments showed that the first samples were dominated by sulfate-reducers and heterotrophs, whereas the final sample was dominated by oligotrophic and hydrogenotrophic bacteria. Community structures established on the diversity of the 16S rRNA genes and data analysis revealed that the water sample collected, after a purge without removal of the biofilm, was characterized by numerous phyla which are not representative of the deep subsurface water. On the other hand, several bacterial phyla were only detected after the full cleaning of the well, and were considered as important components of the subsurface ecosystem which would have been missed in the absence of well cleaning. [source] Interactions between fauna and sediment control the breakdown of plant matter in river sedimentsFRESHWATER BIOLOGY, Issue 4 2010SIMON NAVEL Summary 1. A substantial portion of particulate organic matter (POM) is stored in the sediment of rivers and streams. Leaf litter breakdown as an ecosystem process mediated by microorganisms and invertebrates is well documented in surface waters. In contrast, this process and especially the implication for invertebrates in subsurface environments remain poorly studied. 2. In the hyporheic zone, sediment grain size distribution exerts a strong influence on hydrodynamics and habitability for invertebrates. We expected that the influence of shredders on organic matter breakdown in river sediments would be influenced strongly by the physical structure of the interstitial habitat. 3. To test this hypothesis, the influence of gammarids (shredders commonly encountered in the hyporheos) on degradation of buried leaf litter was measured in experimental systems (slow filtration columns). We manipulated the structure of the sedimentary habitat by addition of sand to a gravel-based sediment column to reproduce three conditions of accessible pore volume. Ten gammarids were introduced in columns together with litter bags containing alder leaves at a depth of 8 cm in sediment. Leaves were collected after 28 days to determine leaf mass loss and associated microbial activity (fungal biomass, bacterial abundance and glucosidase, xylosidase and aminopeptidase activities). 4. As predicted, the consumption of buried leaf litter by shredders was strongly influenced by the sediment structure. Effective porosity of 35% and 25% allowed the access to buried leaf litter for gammarids, whereas a lower porosity (12%) did not. As a consequence, leaf litter breakdown rates in columns with 35% and 25% effective porosity were twice as high as in the 12% condition. Microbial activity was poorly stimulated by gammarids, suggesting a low microbial contribution to leaf mass loss and a direct effect of gammarids through feeding activity. 5. Our results show that breakdown of POM in subsurface waters depends on the accessibility of food patches to shredders. [source] The influence of poorly interconnected fault zone flow paths on spring geochemistryGEOFLUIDS (ELECTRONIC), Issue 2 2008J. C. ROWLAND Abstract Thermal springs commonly occur along faults because of the enhanced vertical permeability afforded by fracture zones. Field and laboratory studies of fault zone materials document substantial heterogeneities in fracture permeabilities. Modeling and field studies of springs suggest that spatial variations in permeability strongly influence spring locations, discharge rates and temperatures. The impact of heterogeneous permeability on spring geochemistry, however, is poorly documented. We present stable isotope and water chemistry data from a series of closely spaced thermal springs associated with the Hayward Fault, California. We suggest that substantial spatial variations observed in ,18O and chloride values reflect subsurface fluid transport through a poorly connected fracture network in which mixing of subsurface waters remains limited. Our measurements provide insight into the effect of fracture zone heterogeneities on spring geochemistry, offer an additional tool to intuit the nature of tectonically induced changes in fault zone plumbing, and highlight the need to consider local variations when characterizing fracture zone fluid geochemistry from spring systems with multiple discharge sites. [source] Estimation of mean residence times of subsurface waters using seasonal variation in deuterium excess in a small headwater catchment in JapanHYDROLOGICAL PROCESSES, Issue 3 2007Naoki Kabeya Abstract We measured deuterium excess (d = ,D , 8,18O) in throughfall, groundwater, soil water, spring water, and stream water for 3 years in a small headwater catchment (Matsuzawa, 0·68 ha) in the Kiryu Experimental Watershed in Japan. The d value represents a kinetic effect produced when water evaporates. The d value of the throughfall showed a sinusoidal change (amplitude: 6·9, relative to Vienna standard mean ocean water (V-SMOW)) derived from seasonal changes in the source of water vapour. The amplitude of this sinusoidal change was attenuated to 1·3,6·9, V-SMOW in soil water, groundwater, spring water, and stream water. It is thought that these attenuations derive from hydrodynamic transport processes in the subsurface and mixing processes at an outflow point (stream or spring) or a well. The mean residence time (MRT) of water was estimated from d value variations using an exponential-piston flow model and a dispersion model. MRTs for soil water were 0,5 months and were not necessarily proportional to the depth. This may imply the existence of bypass flow in the soil. Groundwater in the hillslope zone had short residence times, similar to those of the soil water. For groundwater in the saturated zone near the spring outflow point, the MRTs differed between shallow and deeper groundwater; shallow groundwater had a shorter residence time (5,8 months) than deeper groundwater (more than 9 months). The MRT of stream water (8,9 months) was between that of shallow groundwater near the spring and deeper groundwater near the spring. The seasonal variation in the d value of precipitation arises from changes in isotopic water vapour composition associated with seasonal activity of the Asian monsoon mechanism. The d value is probably an effective tracer for estimating the MRT of subsurface water not only in Japan, but also in other East Asian countries influenced by the Asian monsoon. Copyright © 2006 John Wiley & Sons, Ltd. [source] A look inside ,black box' hydrograph separation models: a study at the Hydrohill catchmentHYDROLOGICAL PROCESSES, Issue 10 2001Carol Kendall Abstract Runoff sources and dominant flowpaths are still poorly understood in most catchments; consequently, most hydrograph separations are essentially ,black box' models where only external information is used. The well-instrumented 490 m2 Hydrohill artificial grassland catchment located near Nanjing (China) was used to examine internal catchment processes. Since groundwater levels never reach the soil surface at this site, two physically distinct flowpaths can unambiguously be defined: surface and subsurface runoff. This study combines hydrometric, isotopic and geochemical approaches to investigating the relations between the chloride, silica, and oxygen isotopic compositions of subsurface waters and rainfall. During a 120 mm storm over a 24 h period in 1989, 55% of event water input infiltrated and added to soil water storage; the remainder ran off as infiltration-excess overland flow. Only about 3,5% of the pre-event water was displaced out of the catchment by in-storm rainfall. About 80% of the total flow was quickflow, and 10% of the total flow was pre-event water, mostly derived from saturated flow from deeper soils. Rain water with high ,18O values from the beginning of the storm appeared to be preferentially stored in shallow soils. Groundwater at the end of the storm shows a wide range of isotopic and chemical compositions, primarily reflecting the heterogeneous distribution of the new and mixed pore waters. High chloride and silica concentrations in quickflow runoff derived from event water indicate that these species are not suitable conservative tracers of either water sources or flowpaths in this catchment. Determining the proportion of event water alone does not constrain the possible hydrologic mechanisms sufficiently to distinguish subsurface and surface flowpaths uniquely, even in this highly controlled artificial catchment. We reconcile these findings with a perceptual model of stormflow sources and flowpaths that explicitly accounts for water, isotopic, and chemical mass balance. Copyright © 2001 John Wiley & Sons, Ltd. [source] | ||||||||||||||||