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Substrate Electrode (substrate + electrode)

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Chemistry100%

Selected Abstracts

A Dual-Electrode Approach for Highly Selective Detection of Glucose Based on Diffusion Layer Theory: Experiments and Simulation

CHEMISTRY - A EUROPEAN JOURNAL, Issue 4 2005
Kang Wang Dr.
Abstract A dual-electrode configuration for the highly selective detection of glucose in the diffusion layer of the substrate electrode is presented. In this approach, a glassy carbon electrode (GCE, substrate) modified with a conductive layer of glucose oxidase/Nafion/graphite (GNG) was used to create an interference-free region in its diffusion layer by electrochemical depletion of interfering electroactive species. A Pt microelectrode (tip, 5 ,m in radius) was located in the diffusion layer of the GNG-modified GCE (GNG-G) with the help of scanning electrochemical microscopy. Consequently, the tip of the electrode could sense glucose selectively by detecting the amount of hydrogen peroxide (H2O2) formed from the oxidization of glucose on the glucose oxidase layer. The influences of parameters, including tip,substrate distance, substrate potential, and electrolyzing time, on the interference-removing efficiency of this dual-electrode approach have been investigated systematically. When the electrolyzing time was 30 s, the tip,substrate distance was 1.8,a (9.0 ,m) (where a is the radius of the tip electrode), the potentials of the tip and substrate electrodes were 0.7 V and 0.4 V, respectively, and a mixture of ascorbic acid (0.3,mM), uric acid (0.3,mM), and 4-acetaminophen (0.3,mM) had no influence on the glucose detection. In addition, the current,time responses of the tip electrode at different tip,substrate distances in a solution containing interfering species were numerically simulated. The results from the simulation are in good agreement with the experimental data. This research provides a concept of detection in the diffusion layer of a substrate electrode, as an interference-free region, for developing novel microelectrochemical devices. [source]

Evaluation of the Chemical Reactions from Two Electrogenerated Species in Picoliter Volumes by Scanning Electrochemical Microscopy

CHEMPHYSCHEM, Issue 13 2010
Qian Wang
Abstract The volume created by the positioning of two scanning electrochemical microscope (SECM) probes (tip and substrate) at a micrometric distance defines a "picoliter beaker" where homogeneous electron-transfer reactions are studied. The SECM is used to concurrently electrogenerate in situ two reactive species and to evaluate the possibility of detecting their reactivity. Two reaction cases are studied: the first, called the "reversible case", occurs when the electrochemically generated species at the substrate electrode can also react at the tip to yield the same product as the reaction in the gap. The second case, named the "irreversible case", occurs when the electrochemically generated species at the substrate are not able to react at the tip. Digital simulations are performed and compared to experimental studies. These show that an unusual compensation between collection and feedback effects render the analysis inapplicable in the "reversible case". The "irreversible case" is shown experimentally. [source]

A New Type of Bismuth Electrode for Electrochemical Stripping Analysis Based on the Ammonium Tetrafluorobismuthate Bulk-Modified Carbon Paste

ELECTROANALYSIS, Issue 13 2010
Hanna Sopha
Abstract A carbon paste electrode bulk-modified with ammonium tetrafluorobismuthate (BiF4 -CPE) was developed and examined in the anodic stripping voltammetric mode for measurement of selected trace heavy metals. The BiF4 -CPE has revealed a favorable performance in more acidic solutions (pH,0.5,2.5) in the presence of dissolved oxygen for Cd(II) and Pb(II) as model metal ions at the low ,g L,1 concentration level. In comparison with the bismuth-oxide bulk-modified carbon paste electrode and the other two bismuth film-plated carbonaceous substrate electrodes examined, the BiF4 -CPE proved to be another attractive variant of the environmentally friendly bismuth-based electrodes, particularly convenient for analysis of acidified water samples. [source]

A Dual-Electrode Approach for Highly Selective Detection of Glucose Based on Diffusion Layer Theory: Experiments and Simulation

CHEMISTRY - A EUROPEAN JOURNAL, Issue 4 2005
Kang Wang Dr.
Abstract A dual-electrode configuration for the highly selective detection of glucose in the diffusion layer of the substrate electrode is presented. In this approach, a glassy carbon electrode (GCE, substrate) modified with a conductive layer of glucose oxidase/Nafion/graphite (GNG) was used to create an interference-free region in its diffusion layer by electrochemical depletion of interfering electroactive species. A Pt microelectrode (tip, 5 ,m in radius) was located in the diffusion layer of the GNG-modified GCE (GNG-G) with the help of scanning electrochemical microscopy. Consequently, the tip of the electrode could sense glucose selectively by detecting the amount of hydrogen peroxide (H2O2) formed from the oxidization of glucose on the glucose oxidase layer. The influences of parameters, including tip,substrate distance, substrate potential, and electrolyzing time, on the interference-removing efficiency of this dual-electrode approach have been investigated systematically. When the electrolyzing time was 30 s, the tip,substrate distance was 1.8,a (9.0 ,m) (where a is the radius of the tip electrode), the potentials of the tip and substrate electrodes were 0.7 V and 0.4 V, respectively, and a mixture of ascorbic acid (0.3,mM), uric acid (0.3,mM), and 4-acetaminophen (0.3,mM) had no influence on the glucose detection. In addition, the current,time responses of the tip electrode at different tip,substrate distances in a solution containing interfering species were numerically simulated. The results from the simulation are in good agreement with the experimental data. This research provides a concept of detection in the diffusion layer of a substrate electrode, as an interference-free region, for developing novel microelectrochemical devices. [source]