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Sulfonic Acid Content (sulfonic + acid_content)
Selected AbstractsSulfonated poly(ether imide) and poly(ether sulfone) blends for direct methanol fuel cells.JOURNAL OF APPLIED POLYMER SCIENCE, Issue 5 2008Abstract This investigation examines characteristics of sulfonated polyether imides (SPEI) with various ion exchange capacity values (IEC) and completes previous work to enable its blends to be adopted as polyelectrolyte in direct methanol fuel cells (DMFC). Polyether imides (PEI) were sulfonated by using chlorosulfonic acid as the sulfonating agent and chloroform as the solvent. The structure of SPEI was observed by FTIR and 1H NMR. The sulfonate or sulfonic acid content of the polymers, expressed as a number per repeat unit of the polymer, was accurately determined by elemental analysis and conductometric titration. Physical properties such as solubility, intrinsic viscosities, thermal stability, and glass transition temperature (Tg) were studied for both PEI and SPEI. TGA-FTIR verified that sulfonic groups, attached to the aromatic ring in the PEI backbone, are split at 230,350°C, but the main-chain splitting temperature of SPEI is similar to that of pure polymer. The sulfonated samples exhibited good solubilities and increased glass transition temperatures (Tg values) as degree of sulfonation (DS) increased; two Tg values were detected when IEC was sufficiently high. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 [source] Synthesis and characterization of sulfonated poly(benzoxazole ether ketone)s by direct copolymerization as novel polymers for proton-exchange membranesJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 11 2007Jinhuan Li Abstract A new series of sulfonated poly(benzoxazole ether ketone)s (SPAEKBO-X) were prepared by the aromatic nucleophilic polycondensation of 4,4,-(hexafluoroisopropylidene)-diphenol with 2,2,-bis[2-(4-fluorophenyl)benzoxazol-6-yl]hexafluoropropane and sodium 5,5,-carbonylbis-2-fluorobenzenesulfonate in various ratios. Fourier transform infrared and 1H NMR were used to characterize the structures and sulfonic acid contents of the copolymers. The copolymers were soluble in N -methyl-2-pyrrolidinone, N,N -dimethylacetamide, and N,N -dimethylformamide and could form tough and flexible membranes. The protonated membranes were thermally stable up to 320 °C in air. The water uptake, hydrolytic and oxidative stability, and mechanical properties were evaluated. At 30,90 °C and 95% relative humidity, the proton conductivities of the membranes increased with the sulfonic acid content and temperature and almost reached that of Nafion 112. At 90,130 °C, without external humidification, the conductivities increased with the temperature and benzoxazole content and reached above 10,2 S/cm. The SPAEKBO-X membranes, especially those with high benzoxazole compositions, possessed a large amount of strongly bound water (>50%). The experimental results indicate that SPAEKBO-X copolymers are promising for proton-exchange membranes in fuel cells, and their properties might be tailored by the adjustment of the copolymer composition for low temperatures and high humidity or for high temperatures and low humidity; they are especially promising for high-temperature applications. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2273,2286, 2007 [source] Structure,property correlations of sulfonated polyimides.JOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 14 2004Abstract A series of six-membered sulfonated polyimides were synthesized using 1,4,5,8-naphthalenetetracarboxylic dianhydride, 4,4,-diaminobiphenyl 2,2,-disulfonic acid as the sulfonated diamine, and various nonsulfonated diamine monomers having different bridging groups. These bulky bridging groups have the capacity to increase hydrolytic stability and proton conductivity. Polyimides with bulky bridging groups showed increased solubility but exhibited lower thermal stability. The ion exchange capacity and water uptake reduced with increase in the bulkiness of the bridging group. This was attributed to the increase in the molecular weight of the repeating unit and hence effectively reduced the sulfonic acid content. In low temperatures, the conductivity was lower than Nafion®115 and, with increase in temperature, the conductivity rapidly increased and exhibited better conductivity than Nafion®115. Polyimides with bulky bridging groups 4-amino phenyl sulfone, and 2-bis[4-(4-aminophenoxy)phenyl]hexafluoropropane showed higher conductivity than other polyimides and Nafion®115 despite low ion exchange capacity. The hydrolytic stability of the polyimides with bulky bridging groups was higher than the polyimides with less bulky atoms because of the imparted flexibility. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3612,3620, 2004 [source] Synthesis and characterization of sulfonated poly(benzoxazole ether ketone)s by direct copolymerization as novel polymers for proton-exchange membranesJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 11 2007Jinhuan Li Abstract A new series of sulfonated poly(benzoxazole ether ketone)s (SPAEKBO-X) were prepared by the aromatic nucleophilic polycondensation of 4,4,-(hexafluoroisopropylidene)-diphenol with 2,2,-bis[2-(4-fluorophenyl)benzoxazol-6-yl]hexafluoropropane and sodium 5,5,-carbonylbis-2-fluorobenzenesulfonate in various ratios. Fourier transform infrared and 1H NMR were used to characterize the structures and sulfonic acid contents of the copolymers. The copolymers were soluble in N -methyl-2-pyrrolidinone, N,N -dimethylacetamide, and N,N -dimethylformamide and could form tough and flexible membranes. The protonated membranes were thermally stable up to 320 °C in air. The water uptake, hydrolytic and oxidative stability, and mechanical properties were evaluated. At 30,90 °C and 95% relative humidity, the proton conductivities of the membranes increased with the sulfonic acid content and temperature and almost reached that of Nafion 112. At 90,130 °C, without external humidification, the conductivities increased with the temperature and benzoxazole content and reached above 10,2 S/cm. The SPAEKBO-X membranes, especially those with high benzoxazole compositions, possessed a large amount of strongly bound water (>50%). The experimental results indicate that SPAEKBO-X copolymers are promising for proton-exchange membranes in fuel cells, and their properties might be tailored by the adjustment of the copolymer composition for low temperatures and high humidity or for high temperatures and low humidity; they are especially promising for high-temperature applications. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2273,2286, 2007 [source] | ||||||||||