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Solid Loading (solid + loading)
Kinds of Solid Loading Selected AbstractsThermal Decomposition of Energetic Materials 85: Cryogels of Nanoscale Hydrazinium Diperchlorate in Resorcinol-FormaldehydePROPELLANTS, EXPLOSIVES, PYROTECHNICS, Issue 2 2003Bryce Abstract The objective of this work was to try to desensitize an energetic material by using sol-gel processing and freeze drying to incorporate the energetic material into the fuel matrix on the nano (or at least submicron) particle size scale. Hydrazinium diperchlorate ([N2H6][ClO4]2 or HP2) and resorcinol-formaldehyde (RF) were chosen as the oxidizer and fuel, respectively. Solid loading up to 88% HP2 was achieved by using the sol gel-to-cryogel method. Various weight percentages of HP2 in RF were characterized by elemental analysis, scanning electron (SEM) and optical microscopy, T-jump/FTIR spectroscopy, DSC, and drop-weight impact. SEM indicated that 20,50,nm diameter HP2 plates aggregated into porous 400,800,nm size clusters. Below 80% HP2 the cryogels are less sensitive to impact than physical mixtures having the same ratios of HP2 and RF. The decomposition temperatures of the cryogels are higher than that of pure HP2, which is consistent with their lower impact sensitivity. The heat of decomposition as measured at a low heating rate increases with increasing percentage of HP2. The cryogels and physical mixtures release similar amounts of energy, but the cryogels exhibit mainly a single exotherm by DSC whereas the physical mixtures showed a two-step energy release. Flash pyrolysis revealed gaseous product ratios suggestive of more energy being released from the cryogels than the physical mixtures. Cryogels also burn faster by visual observation. [source] Fabrication of Gradient Pore TiO2 Sheets by a Novel Freeze,Tape-Casting ProcessJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 9 2007Linlin Ren Gradient pore structure TiO2 sheets were fabricated by a novel freeze,tape-casting process. Aqueous TiO2 ceramic slurries were prepared by the traditional tape-casting processing and were then cast onto an aluminum foil carrier. The slurries were immediately frozen on the substrate, whose temperature was about ,18°C. After freezing completely, the green sheets were then dried in a lyophilizer. Freeze,tape casting led to formation of a gradient pore microstructure of the TiO2 sheet. The results showed that the solid loading of slurry considerably affected the pore microstructure, pore morphology, and the porosity. Solid loadings of 10, 20, 30, 40, and 50 wt% slurries were used, respectively, and the gradient pore structure TiO2 sheets with different porosities of 75%,88% were obtained. [source] Effects of Solids Loading, pH, and Polyelectrolyte Addition on the Stabilization of Concentrated Aqueous BaTiO3 SuspensionsJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 2 2000Jau-Ho Jean Colloidal stability of concentrated aqueous BaTiO3 suspensions with ammonium salts of poly(acrylic acid) (PAA-NH4) and poly(methacrylic acid) (PMAA-NH4) as a function of pH and solids loading is investigated. For suspensions with solids loading less than 40 vol%, the required polyelectrolyte concentration to stabilize aqueous BaTiO3 suspensions decreases with increasing pH, but remains relatively unchanged with increasing solids loading. As the solids loading continuously increases (e.g., >50 vol%), the required amount of polyelectrolyte increases, but exhibits a minimum at pH , 9.2. The critical amount of polyelectrolyte needed to achieve colloidal stability of aqueous BaTiO3 suspensions as a function of pH and solids loading is summarized in a three-dimensional stability map. [source] EFFECT OF INSOLUBLE PARTICLES UPON SOLID INCLUSION LEVELS IN ICE FORMED ON A SUBCOOLED STAINLESS STEEL SURFACEJOURNAL OF FOOD PROCESS ENGINEERING, Issue 2 2000PING CHEN ABSTRACT This study employed an insoluble solid particle, i.e. a potato starch used as an example, to investigate the impact of the concentration of such particles suspended in water (with solid loading of 5, 10, 20 and 30 wt%) upon the solid inclusion levels in ice layers formed on a sub-cooled smooth stainless steel plate surface. The effects of ice growth rate, bulk concentration and suspension velocity on insoluble solid inclusion, i.e. potato starch mass fraction, in ice layer were studied. The experiments, where potato starch is added into aqueous sucrose solutions or the reverse where sucrose is added into starch suspension, were also carried out to investigated effect of the starch particles on sucrose inclusion in ice and effect of solute (sucrose) on starch particle inclusion in ice. It has been found that solid inclusion in ice increases with increasing bulk concentration and average ice growth rate, at constant solution and coolant velocities, and increasing suspension velocity can help pure ice formation. The average distribution coefficient of sucrose in ice layer formed from sucrose solution does not appear to be affected by the addition of potato starch. However, the average distribution coefficient of potato starch in ice layer formed from suspension is influenced by sucrose concentration quite significantly. [source] Effects of chemical structure on the properties of carboxylate-type copolymer dispersant for coal-water slurryAICHE JOURNAL, Issue 9 2009Renfu Xu Abstract In this study, a series of carboxylate-type copolymer dispersants were prepared. The effects of chemical structures of the copolymer dispersants, including the molecular weight, kind, quantity and ratio of hydrophilic/hydrophobic groups, and side chain length, on the solid loading, apparent viscosity, zeta potential, rheological behavior, and stability of coal-water slurry (CWS) prepared from Dongtan, Yima, and Datong coals were systematically investigated. The dispersion performance of the copolymer can be improved by adjusting its chemical structures, and the dispersion mechanism was discussed. In addition, a high solid loading CWS with excellent stability toward settling can be achieved by means of the copolymer dispersant and carboxymethyl cellulose sodium salt (CMC-Na). Experiments have proved that the copolymer has the potential to be developed as a new high-effective dispersant for CWS. © 2009 American Institute of Chemical Engineers AIChE J, 2009 [source] Fabrication and Characterization of Anode-Supported Tubular Solid-Oxide Fuel Cells by Slip Casting and Dip Coating TechniquesJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 2 2009Lan Zhang High-performance anode-supported tubular solid-oxide fuel cells (SOFCs) have been successfully developed and fabricated using slip casting, dip coating, and impregnation techniques. The effect of a dispersant and solid loading on the viscosity of the NiO/Y2O3,ZrO2 (NiO/YSZ) slurry is investigated in detail. The viscosity of the slurry was found to be minimum when the dispersant content was 0.6 wt% of NiO/YSZ. The effect of sintering temperature on the shrinkage and porosity of the anode tubes, densification of the electrolyte, and performance of the cell at different solid loadings is also investigated. A Ni/YSZ anode-supported tubular cell fabricated from the NiO/YSZ slurry with 65 wt% solid loading and sintered at 1380°C produced a peak power output of ,491 and ,376 mW/cm2 at 800°C in wet H2 and CH4, respectively. With the impregnation of Ce0.8Gd0.2O2 (GDC) nanoparticles, the peak power density increased to ,1104 and ,770 mW/cm2 at 800°C in wet H2 and CH4, respectively. GDC impregnation considerably enhances the electrochemical performance of the cell and significantly reduces the ohmic and polarization resistances of thin solid electrolyte cells. [source] Sodium Bismuth Titanate-Based Lead-Free Piezoceramics Prepared by Aqueous GelcastingJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 9 2008Dongxiang Zhou Aqueous gelcasting for 0.94Bi0.5Na0.5TiO3,0.06BaTiO3 (BNBT6) lead-free piezoceramics was investigated in this paper. A stable BNBT6 suspension with 50 vol% of solid loading and <1Pa·s of viscosity was successfully prepared when 0.5 wt% of PMAA-NH4 was added with the pH value controlled in the range 8,10. Dehydration and desiccation of the gelled parts could be controlled easily through dipping pretreatment with a 5 wt% ammonium persulfate solution for 24 h or with a 10 wt% ammonium persulfate solution for 12 h. Scanning electron microscopy micrographs show that the BNBT6 ceramic prepared by the gelcasting route exhibits a homogeneous microstructure and a high density. Optimal piezoelectric and dielectric properties were obtained: d33=132pC/N, , tg ,=0.019, and kp=0.25. [source] Tailoring Texture of ,-Y2Si2O7 by Strong Magnetic Field Alignment and Two-Step SinteringJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 8 2008Z. Q. Sun In this study, a well-dispersed ,-Y2Si2O7 ethanol-based suspension with 30 vol% solid loading was prepared by adding 1 dwb% polyethylene imine dispersant, which allows feeble magnetic ,-Y2Si2O7 particles with anisotropic magnetic susceptibility to rotate in a 12 T strong magnetic field during slip casting, resulting in the development of a strongtexture in green bodies. Pressureless sintering gives rise to more pronounced grain growth in the textured sample than in the untextured sample prepared without the magnetic field due to the rapid migration of the grain boundaries of the well-oriented grains, which was revealed by constant-heating-rate sintering kinetics. It was found that the use of two-step sintering is very efficient not only for inhibiting the grain growth but also for enhancing thetexture. This implies that controlled grain growth is crucial for enhancing texture development in ,-Y2Si2O7. [source] Dispersion Behavior of ZrB2 Powder in Aqueous SolutionJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 11 2007Sea-Hoon Lee Dispersion conditions of ZrB2 powder in water were investigated using poly(ethyleneimine) (PEI) as a dispersant. Pulverization of ZrB2 powder to submicrometer size was difficult and a substantial amount of large particles remained after an intensive planatery milling for 72 h. The isoelectric point (IEP) of ZrB2 powder was measured to be pH 5.8 by electrophoresis, which shifted to pH 6.2 after milling. The application of PEI changed the IEP of the boride slurry to ,pH 11. Well-dispersed aqueous ZrB2 slurries with a high solid loading (up to 45 vol%) were fabricated at pH 6.5,7.5 by the application of 1.5 wt% PEI. [source] Surface Treatment of Templates for Fabrication of Reticulated Porous CeramicsJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 9 2007Xi-peng Pu Before impregnation of the organic templates with an aqueous ceramic slurry, the templates were treated using silica sol. The surface morphology, elasticity of the templates, and the solid loading were studied. After the treatment, the coherence between the template and the slurry was significantly optimized, and the surfaces of the templates were uniformly covered by slurry. The elasticity of the templates was also increased. Consequently, the loading content increased considerably. [source] Fabrication of Gradient Pore TiO2 Sheets by a Novel Freeze,Tape-Casting ProcessJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 9 2007Linlin Ren Gradient pore structure TiO2 sheets were fabricated by a novel freeze,tape-casting process. Aqueous TiO2 ceramic slurries were prepared by the traditional tape-casting processing and were then cast onto an aluminum foil carrier. The slurries were immediately frozen on the substrate, whose temperature was about ,18°C. After freezing completely, the green sheets were then dried in a lyophilizer. Freeze,tape casting led to formation of a gradient pore microstructure of the TiO2 sheet. The results showed that the solid loading of slurry considerably affected the pore microstructure, pore morphology, and the porosity. Solid loadings of 10, 20, 30, 40, and 50 wt% slurries were used, respectively, and the gradient pore structure TiO2 sheets with different porosities of 75%,88% were obtained. [source] Improvement of the Dispersion of Al2O3 Slurries Using EDTA-4NaJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 4 2006Jingxian Zhang Polyacrylic acid (PAA) is known to be an effective dispersant for Al2O3 powder in aqueous media. However, at high solid loading (>55 vol%), the dispersion of the Al2O3 suspensions became difficult with only PAA as a dispersant. In this paper, ethylenediaminetetraacetic acid, tetrasodium salt, dihydrate (EDTA-4Na) was introduced to improve the dispersion of the Al2O3 suspensions. With the aid of EDTA-4Na, the adsorption amount of sodium polyacrylic acid (PAA-Na) increased, while the apparent viscosity of 60 vol% Al2O3 slurries decreased significantly. Particle size measurements showed that EDTA-4Na could help to reduce larger agglomerates, possibly by modifying the adsorbed layer thickness. The interactions between EDTA-4Na and PAA-Na were studied using Fourier-transform infrared spectroscopy analysis. Results showed that it was possible to introduce EDTA-4Na as the second dispersant to improve the dispersion of high solid content Al2O3 slurries. [source] Mullite Suspensions for Reticulate Ceramic PreparationJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 12 2000Edoardo Roncari The dispersing behavior of MgO-doped mullite suspension suitable for the production of reticulate ceramics by sponge impregnation was studied. Three deflocculants were tested and the optimum dispersing conditions for the mullite suspension were found. Electrokinetic studies of magnesia in water evidence that it undergoes pronounced solubilization that strongly affects the performance of the mullite suspension when added at the 1 wt% concentration, in terms of solid loading and aging effects. The optimum composition of the slurry was found, reticulate mullite samples were produced, and the green and sintered bodies were characterized. [source] Gas,liquid mass transfer in three-phase inverse fluidized bed reactor with Newtonian and non-Newtonian fluidsASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, Issue 2 2010V. Sivasubramanian Abstract Liquid-phase volumetric mass transfer coefficients, kLa were determined in three-phase inverse fluidized beds of low-density polyethylene (LDPE) and polypropylene (PP) spheres fluidized by a countercurrent flow of air and Newtonian (water and glycerol solutions) or non-Newtonian liquids [carboxy methyl cellulose (CMC) solutions]. The effects of liquid and gas velocities, particle size, solid loading and addition of organic additives (glycerol and CMC) on the volumetric mass transfer coefficient, kLa were determined. The superficial liquid velocity had a weak effect on the mass transfer whereas the gas flow rate affected the mass transfer positively. kLa increased with increase in particle diameter and decreased with increase in initial bed height (solid loading). kLa decreased as the concentration of glycerol (viscosity) and CMC increased. Empirical correlations are presented to predict the gas,liquid volumetric mass transfer coefficient in terms of operating variables. Copyright © 2009 Curtin University of Technology and John Wiley & Sons, Ltd. [source] Alkali-based AFEX pretreatment for the conversion of sugarcane bagasse and cane leaf residues to ethanolBIOTECHNOLOGY & BIOENGINEERING, Issue 3 2010Chandraraj Krishnan Abstract Sugarcane is one of the major agricultural crops cultivated in tropical climate regions of the world. Each tonne of raw cane production is associated with the generation of 130,kg dry weight of bagasse after juice extraction and 250,kg dry weight of cane leaf residue postharvest. The annual world production of sugarcane is ,1.6 billion tones, generating 279 MMT tones of biomass residues (bagasse and cane leaf matter) that would be available for cellulosic ethanol production. Here, we investigated the production of cellulosic ethanol from sugar cane bagasse and sugar cane leaf residue using an alkaline pretreatment: ammonia fiber expansion (AFEX). The AFEX pretreatment improved the accessibility of cellulose and hemicelluloses to enzymes during hydrolysis by breaking down the ester linkages and other lignin carbohydrate complex (LCC) bonds and the sugar produced by this process is found to be highly fermentable. The maximum glucan conversion of AFEX pretreated bagasse and cane leaf residue by cellulases was ,85%. Supplementation with hemicellulases during enzymatic hydrolysis improved the xylan conversion up to 95,98%. Xylanase supplementation also contributed to a marginal improvement in the glucan conversion. AFEX-treated cane leaf residue was found to have a greater enzymatic digestibility compared to AFEX-treated bagasse. Co-fermentation of glucose and xylose, produced from high solid loading (6% glucan) hydrolysis of AFEX-treated bagasse and cane leaf residue, using the recombinant Saccharomyces cerevisiae (424A LNH-ST) produced 34,36,g/L of ethanol with 92% theoretical yield. These results demonstrate that AFEX pretreatment is a viable process for conversion of bagasse and cane leaf residue into cellulosic ethanol. Biotechnol. Bioeng. 2010;107: 441,450. © 2010 Wiley Periodicals, Inc. [source] Fabrication and Characterization of Anode-Supported Tubular Solid-Oxide Fuel Cells by Slip Casting and Dip Coating TechniquesJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 2 2009Lan Zhang High-performance anode-supported tubular solid-oxide fuel cells (SOFCs) have been successfully developed and fabricated using slip casting, dip coating, and impregnation techniques. The effect of a dispersant and solid loading on the viscosity of the NiO/Y2O3,ZrO2 (NiO/YSZ) slurry is investigated in detail. The viscosity of the slurry was found to be minimum when the dispersant content was 0.6 wt% of NiO/YSZ. The effect of sintering temperature on the shrinkage and porosity of the anode tubes, densification of the electrolyte, and performance of the cell at different solid loadings is also investigated. A Ni/YSZ anode-supported tubular cell fabricated from the NiO/YSZ slurry with 65 wt% solid loading and sintered at 1380°C produced a peak power output of ,491 and ,376 mW/cm2 at 800°C in wet H2 and CH4, respectively. With the impregnation of Ce0.8Gd0.2O2 (GDC) nanoparticles, the peak power density increased to ,1104 and ,770 mW/cm2 at 800°C in wet H2 and CH4, respectively. GDC impregnation considerably enhances the electrochemical performance of the cell and significantly reduces the ohmic and polarization resistances of thin solid electrolyte cells. [source] Lead Zirconate Titanate Particle Dispersion in Thick-Film Ink FormulationsJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 6 2000Erik S. Thiele Diverse device applications for lead zirconate titanate (PZT) ceramics in thick-film form are currently in active development. In the present study, the particle dispersion properties of thick-film ink formulations containing PZT powder have been determined using rheological measurements. Although all of the eight commercially available dispersants tested are more effective than the terpineol solvent alone in decreasing attractive interparticle forces in suspensions, the best dispersant identified for hard and soft PZT powders is a phosphate ester oligomer. This dispersant is extremely efficient, and its use in thick-film ink formulations results in viscosity decreases of 50% at low shear rates (10 s,1) and 30% at high shear rates (100 s,1) compared with current ink formulations containing no dispersant. The effects upon rheology of the order of addition of components in the processing of inks have been studied, with the most effective processing route using a fugitive solvent that probably facilitates uniform coverage of the particle surfaces by the dispersant molecules. Modeling of the rheological profiles of inks indicates that the use of a dispersant decreases the depth of the primary minimum in the interparticle potential by a factor of 3. Demonstrated advantages of the use of a dispersant in PZT thick-film inks include improved microstructural homogeneity in the green body and the ability to formulate printable inks with higher solids loadings. No adverse effects of the dispersant upon the dielectric and piezoelectric properties of bulk PZT samples are found following burnout and sintering. [source] Particle Size of Pneumatically Conveyed Powders Measured Using Impact DurationPARTICLE & PARTICLE SYSTEMS CHARACTERIZATION, Issue 6 2007Peter J. Coghill Abstract CSIRO Minerals has developed a technique for measuring particle size in pneumatically conveyed powders [1] by measurement of the acoustic waves produced by particle impacts upon a specially designed transducer. Previous work has focused on using the peak acoustic wave amplitude to determine particle size. This produces a spectrum that is hard to determine the particle size from, as the peak amplitude is a non-linear function of particle diameter, and is strongly affected by angle of incidence and velocity of the impacting particle. In this paper impact duration measurements are used to overcome these difficulties while retaining the advantages of being able to measure in high solids loadings of up to at least 0.5,kg/m3 of powder. In laboratory tests the impact size monitor's (ISM) results have been correlated with optical diffraction measurements of the mean (by number) powder size with a correlation coefficient of 0.985 and a relative error of 5.5,%. The ISM operated successfully in the laboratory at a loading of 0.5,kg/m3 of powder and measured particles down to 50,microns in size. [source] | |||||||||||||