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Sorption Behaviour (sorption + behaviour)
Selected AbstractsAn improved experimental and regression methodology for sorption isothermsJOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE, Issue 2 2005Elisabeth J Quirijns Abstract Sorption isotherms of corn and starch cylinders with immobilised catalase are experimentally determined at different temperatures for use in drying models in optimal control studies. This application of the sorption isotherm requires an accurate prediction of the sorption data at different temperatures for the low water activity range. The GAB equation is used for the prediction of the sorption isotherms. Two major problems are encountered by employing standard procedures, ie prediction of sorption at aw < 0.11 and sensitivity of the GAB parameters to the applied data range. An improved methodology is developed, consisting of extending the standard experimental procedure with additional data points in the low water activity range and changing the criterion in the regression procedure in the sum of squares, which is weighed by the variance of the experimental data. The new methodology leads to accurate, consistent and physically relevant parameters of the GAB equation, which are independent of the applied data range in the regression analysis and which result in accurate predictions of the sorption behaviour at low water activity. The sorption data at different temperatures at low water activity can be predicted in the best way with parameters obtained after direct regression based on weighed SSQ. Copyright © 2004 Society of Chemical Industry [source] Physicochemical properties and application of pullulan edible films and coatings in fruit preservationJOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE, Issue 10 2001Tony Diab Abstract The effects of water, sorbitol and a sucrose fatty acid ester (SE) on the water sorption behaviour and thermal and mechanical properties of pullulan-based edible films as well as the physiological responses of fruit coated with pullulan have been studied. Incorporation of sorbitol or SE in pullulan films resulted in lower equilibrium moisture contents at low to intermediate water activities (aw), but much higher moisture contents at aw,>,0.75; estimates of monolayer values (within 4.1,5.9,gH2O,kg,1 solids) were given by application of the Brunauer,Emmett,Teller (BET) and Guggenheim,Anderson,DeBoer (GAB) models. A single glass,rubber transition (Tg), attributed to the polysaccharide component, was detected by calorimetry and dynamic mechanical thermal analysis (DMTA) at a sorbitol level of 15,30% DM. With both tests the strong plasticising action of water and polyol was evident in the thermal curves, and the Tg vs moisture content data were successfully fitted to the Gordon,Taylor empirical model. Multifrequency DMTA measurements provided estimates for the apparent activation energy of the glass transition in the range of , 300,488,kJ,mol,1. With large-deformation mechanical testing, large decreases in Young's moduli (tensile and three-point bend tests) were observed as a result of water- and/or polyol-mediated glass-to-rubber transition of the polymeric films. In the moisture content range of 2,8%, increases in flexural modulus (E) and maximum stress (,max) with small increases in moisture content were found for films made of pullulan or pullulan mixed with 15% DM sorbitol; a strong softening effect was observed when the water content exceeded this range. Addition of sorbitol increased the water vapour transmission rate of the films, whereas addition of SE had the opposite effect. Application of a pullulan/sorbitol/SE coating on strawberries resulted in large changes in internal fruit atmosphere composition which were beneficial for extending the shelf-life of this fruit; the coated fruit showed much higher levels of CO2, a large reduction in internal O2, better firmness and colour retention and a reduced rate of weight loss. In contrast, similar studies on whole kiwifruits showed increased levels of internal ethylene, which caused acceleration of fruit ripening during storage. © 2001 Society of Chemical Industry [source] The effect of high-pressure food processing on the sorption behaviour of selected packaging materialsPACKAGING TECHNOLOGY AND SCIENCE, Issue 3 2004C. Caner Abstract The sorption behaviour and flavour-scalping potential of selected packaging films in contact with food simulant liquids (FSLs) (ethanol and acetic acid solutions) were evaluated after high-pressure processing (HPP). The films used were monolayer polypropylene (PP), a multilayer (polyethylene/nylon/ethylene vinyl alcohol/polyethylene: PE/nylon/EVOH/PE), film and a metallized (polyethylene terephthalate/ethylene,vinyl acetate/linear low-density polyethylene: metallized PET/EVA/LLDPE) material. D-limonene was used as the sorbate and was added to each of the FSLs. After HPP treatment at 800,MPa, 10,min, 60°C, the amount of D-limonene sorbed by the packaging materials and the amount remaining in the FSL was measured. Untreated controls (1,atm, 60°C and 40°C) were also prepared. Extraction of the D-limonene from the films was performed using a purge/trap method. D-limonene was quantified in both the films and the FSL, using gas chromatography (GC). The results showed that D-limonene concentration, in both the films and the food simulants, was not significantly affected by HPP, except for the metallized PET/EVA/LLDPE. Significant differences in D-limonene sorption were found in comparison with the control pouches. The results also showed that changes in temperature significantly affected the sorption behaviour of all films. Copyright © 2004 John Wiley & Sons, Ltd. [source] Preparation and characterization of biocompatible spongy cryogels of poly(vinyl alcohol),gelatin and study of water sorption behaviourPOLYMER INTERNATIONAL, Issue 9 2005Dr AK Bajpai Abstract Porous biocompatible spongy hydrogels of poly(vinyl alcohol) (PVA),gelatin were prepared by the freezing,thawing method and characterized by infrared and differential scanning calorimetry. The prepared so-called ,cryogels' were evaluated for their water-uptake potential and the influence of various factors, such as the chemical architecture of the spongy hydrogels, pH and the temperature of the swelling bath, on the degree of water sorption by the cryogels was investigated. It was found that the water sorption capacity constantly decreased with increasing concentration of PVA while initially an increase and thereafter a decrease in swelling was obtained with increasing amounts of gelatin in the cryogel. The water sorption capacity decreased with an increase in the number of freeze,thaw cycles. The hydrogels were also swollen in salt solutions and various simulated biological fluids and a fall in swelling ratio was noticed. The effect of the drying temperature of the cryogel on its water sorption capacity was also investigated, and a decrease in swelling was obtained with increasing temperature of drying. The biocompatibility of the prepared materials was assessed by in vitro methods of blood-clot formation, platelet adhesion, and per cent haemolysis. It was noticed that with increasing concentration of PVA and gelatin the biocompatibility increased, while a reduced biocompatibility was noted with an increasing number of freeze,thaw cycles. Copyright © 2005 Society of Chemical Industry [source] Wasserdampfsorptionsverhalten ausgewählter heimischer und überseeischer HolzartenBAUPHYSIK, Issue 2 2009Rudolf Popper Dipl.-Ing. Feuchte; Versuche Abstract An 21 heimischen und 11 überseeischen Holzarten wurde die Gleichgewichtsfeuchte bei 20 °C und 35, 50, 65, 80 und 95 % relativer Luftfeuchtigkeit experimentell in der Adsorptionsphase bestimmt. Aufbauend auf den experimentell bestimmten Mittelwerten wurden mit dem Hailwood-Horrobin-Modell (HH-Modell) ausgewählte Parameter wie Fasersättigungsfeuchte, mono- und polymolekulare Sorption, spezifische Oberfläche des Sorbenten, hypothetisches Molekulargewicht des Sorbenten sowie Unzugänglichkeit des Sorbenten zum Sorbat berechnet. Zusätzlich wurden Tabellen für die Gleichgewichtsfeuchte bei 20 °C und in 2-%-Schritten abgestufter relativer Luftfeuchtigkeit berechnet. Die mittels des HH-Modells berechnete Fasersättigungsfeuchte liegt für alle geprüften Holzarten im Bereich zwischen 22 bis 36 %, im Mittel bei ca. 30 %. Es treten erhebliche Abweichungen zwischen den einzelnen Holzarten in der Fasersättigungsfeuchte auf. Die Tendenzen für die Kenngrößen der Sorptionsanalyse wurden aufgezeigt. Water vapour sorption behaviour of selected domestic and overseas wood species. At 21 domestic and 11 overseas wood species the equilibrium moisture content at 20 °C and 35, 50, 65, 80 and 95% relative humidity was experimentally determined in the adsorption phase. The experimentally determined average values were computed with help of the Hailwood Horrobin model to get selected parameters such as fiber saturation point, mono- and polymolecular sorption, specific surface, hypothetical molecular weight as well as inaccessibility of the sorbent to the sorbate. Tables for the equilibrium moisture contents at 20 °C computed in 2% steps of relative humidity are presented. The fiber saturation point computed with the Hailwood-Horrobin model lies for all examined wood in the range from 22% to 36%, on the average with approx. 30%. There are substantial deviations in the fiber saturation point between the individual wood species. The tendencies for the characteristics of the sorption analysis were pointed out. [source] Right-first-time production in batch dyeing of wool,,COLORATION TECHNOLOGY, Issue 6 2001U M Adamiak Powder dyes exhibit even more pronounced sorption behaviour than fibres. The moisture content and weight of the dyes and yarns change according to the ambient relative humidity. In this study, the variations determined in dyehouse stores caused weight changes and subsequent dyeings showed differences of ,,E* and ,,L* beyond permissible levels. The detrimental influence on the ability to reach right-first-time level of acceptance substantially diminishes the profit margin. The consequence for computer colour-matching should be the integration of the moisture content of dyes and goods in the recipe calculation. From a technological viewpoint, however, it seems preferable to avoid any fluctuation in relative humidity where dyes and goods are stored. The costs incurred for investment in humidity control will pay in the long run and the factor of moisture content may be entirely negligible. [source] Simultaneous analyses and applications of multiple fluorobenzoate and halide tracers in hydrologic studiesHYDROLOGICAL PROCESSES, Issue 14 2005Qinhong Hu Abstract An analytical method that employs ion chromatography has been developed to exploit the use of fluorobenzoic acids (FBAs) and halides more fully as hydrologic tracers. In a single run, this reliable, sensitive, and robust method can simultaneously separate and quantify halides (fluoride, chloride, bromide, and iodide) and up to seven FBAs from other common groundwater constituents (e.g. nitrate and sulphate). The usefulness of this analytical method is demonstrated in both field and laboratory tracer experiments. The field study examines the hydrologic response of fractures and the matrix to different flow rates and the contribution of matrix diffusion in chemical transport. Laboratory tracer experiments with eight geologic media from across the USA,mostly from Department of Energy facilities where groundwater contamination is prevalent and where subsurface characterization employing tracers has been ongoing or is in need,reveal several insights about tracer transport behaviour: (1) bromide and FBAs are not always transported conservatively; (2) the delayed transport of these anionic tracers is likely related to geologic media characteristics, such as organic matter, pH, iron oxide content, and clay mineralogy; (3) use of iodine as a hydrologic tracer should take into account the different sorption behaviours of iodide and iodate and the possible conversion of iodine's initial chemical form; (4) the transport behaviour of potential FBA and halide tracers under relevant geochemical conditions should be evaluated before beginning ambitious, large-scale field tracer experiments. Copyright © 2005 John Wiley & Sons, Ltd. [source] | |||||||||||||