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Smaller Particles (smaller + particle)
Terms modified by Smaller Particles Selected AbstractsThe production of high polymer to surfactant microlatexesJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 1 2010Raul P. Moraes Abstract Starved-feed microemulsion polymerization of styrene was investigated. The influence of the type (SDS or Dowfax 2A1) and concentration of anionic surfactant on the final particle size of latex made by the polymerization of microemulsions of styrene was studied. In addition, the influence of 1-pentanol and acrylic acid as cosurfactants was examined. Latexes with 20% solids content and polymer to surfactant ratio of 22 were produced, with a particle diameter of 42 nm and very low polydispersity indexes. Smaller particles are produced using SDS than Dowfax 2A1 for the same weight fraction of surfactant; however, similar particle sizes were obtained with the same molar concentrations of SDS and Dowfax 2A1. Further shot additions of monomer increased solids level as high as 40% and polymer to surfactant ratios greater than 40, with particles remaining monodisperse with average diameter smaller than 60 nm. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 48,54, 2010 [source] Improvement and validation of a snow saltation model using wind tunnel measurementsEARTH SURFACE PROCESSES AND LANDFORMS, Issue 14 2008Andrew Clifton Abstract A Lagrangian snow saltation model has been extended for application to a wide variety of snow surfaces. Important factors of the saltation process, namely number of entrained particles, ejection angle and speed, have been parameterized from data in the literature. The model can now be run using simple descriptors of weather and snow conditions, such as wind, ambient pressure and temperature, snow particle sizes and surface density. Sensitivity of the total mass flux to the new parameterizations is small. However, the model refinements also allow concentration and mass flux profiles to be calculated, for comparison with measurements. Sensitivity of the profiles to the new parameterizations is considerable. Model results have then been compared with a complete set of drifting snow data from our cold wind tunnel. Simulation mass flux results agree with wind tunnel data to within the bounds of measurement uncertainty. Simulated particle sizes at 50 mm above the surface are generally larger than seen in the tunnel, probably as the model only describes particles in saltation, while additional smaller particles may be present in the wind tunnel at this height because of suspension. However, the smaller particles carry little mass, and so the impact on the mass flux is low. The use of simple input data, and parameterization of the saltation process, allows the model to be used predictively. This could include applications from avalanche warning to glacier mass balance. Copyright © 2008 John Wiley & Sons, Ltd. [source] Adhesion and Percolation Parameters in Two Dimensional Pd,LSCM Composites for SOFC Anode Current CollectionADVANCED FUNCTIONAL MATERIALS, Issue 5 2010Samir Boulfrad Abstract This paper is concerned with palladium,(La0.75Sr0.25)0.97Cr0.5Mn0.5O3 (LSCM) composite current collectors for solid oxide fuel cells (SOFCs); the composites, which are in a 2D configuration (thickness of about 8,10,µm), are deposited upon an LSCM electrode layer on top of an yttria zirconia electrolyte substrate. The influence of the LSCM particle size on the adhesion between palladium and LSCM are reported and discussed. Compositions using four different LSCM particle sizes (0.21, 0.49, 0.64, and 0.81,µm) with sintered Pd particle sizes approaching 10,µm are investigated. The best bonding is obtained when smaller particles are used. The electrical dc conductivity of the composite is reported as a function of the palladium volume fraction for all used LSCM particle sizes. The measured experimental values present typical insulating,conductive percolation. However, the transition occurs at ,33% of the conductive phase, that is, a lower percentage than for 2D ideal systems and a higher percentage than for 3D ideal systems. This is consistent with lower-dimension percolation for a system of large-grained conductors and small-grained insulators. The general effective media (GEM) equation is used to fit the experimental data, and the two main parameters (the threshold point ,c and the exponent t) are defined. [source] Synthesis of Nanophased Metal Oxides in Supercritical Water: Catalysts for Biomass ConversionINTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, Issue 5 2006Caroline Levy Nanoparticles of zinc oxide-based materials (ZnO, ZnAl2O4) with various morphologies were synthesized in supercritical water (SCW) with a flow-type apparatus and in sub- and supercritical water with a batch reactor. In the flow-type apparatus, smaller particles were obtained. Depending on the precursors, the morphology of crystallites is rod, hexagonal, or rectangular shaped. ZnAl2O4 was synthesized with a high specific surface area (SBET) reaching 210 m2/g and nanocrystallite sizes ,10 nm. The KOH concentration played a major role in the formation of ZnO and ZnAl2O4 phases. Then, the synthesized materials were used as catalysts for the biomass conversion by the oxidation process to produce hydrogen. [source] Polyurethane/acrylate hybrids: Effects of the acrylic content and thermal treatment on the polymer propertiesJOURNAL OF APPLIED POLYMER SCIENCE, Issue 5 2010Pablo J. Peruzzo Abstract Polyurethane (PU)/acrylate hybrids with different acrylic contents (10, 30, 50, 70, and 90 wt %) were prepared by the polymerization of acrylic monomers in the presence of preformed PU chains with polymerizable terminal vinyl groups. Films obtained by the casting of polymer dispersions before and after thermal annealing were characterized by dynamic light scattering, Fourier transform infrared spectroscopy, transmission electron microscopy (TEM), TEM electron energy-loss spectroscopy, differential scanning calorimetry, and gel fraction determination. Small-angle X-ray scattering (SAXS), wide-angle X-ray scattering, mechanical properties testing, atomic force microscopy, water contact angle testing, Buchholz hardness testing, and roughness testing of the films were also performed. The effects of the acrylic content and thermal treatment on the structure and properties were determined. TEM showed that a core,shell morphology was formed during polymerization. When the acrylic content increased, smaller particles without core,shell morphologies were observed. TEM energy-loss spectroscopy studies confirmed this observation. Systems with up to 50 wt % acrylic component were homogeneous, as determined by SAXS, before and after thermal annealing. An attempt to incorporate a higher amount of acrylic component led to phase-separated materials with a different morphology and, therefore, different properties. The relationship between the acrylic content and properties did not follow linear behavior. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 [source] The role of auxiliary monomers and emulsifiers on wet scrub resistance of various latex paints at different pigment volume concentrationsJOURNAL OF APPLIED POLYMER SCIENCE, Issue 5 2009M. Khorassani Abstract This work is an attempt to study the effect of different latex types containing various auxiliary monomers and emulsifiers on their pigmentation and their corresponding behavior on scrub resistance. The auxiliary monomers investigated were acrylic acid (AA), methacrylic acid (MAA), and itaconic acid and the emulsifiers contained sodium lauryl sulfate (SLS) and sodium dodecylbenzene sulfonate (SDBS). It was shown that a semibatch polymerization technique which led to smaller particles and sharper size distributions is preferable. The best wet scrub results were obtained by using MAA and SLS. It was also shown that the proper selection of an auxiliary monomer generally depended on the range of incorporated pigment volume concentration (PVC). At high PVCs, AA gave better performances compared with MMA. The reverse effect was shown to occur at low PVCs. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 [source] Extraction and Application of Dietary Fiber and Cellulose from Pineapple CoresJOURNAL OF FOOD SCIENCE, Issue 4 2002T. Prakongpan Pineapple core dietary fiber (PDF) was obtained by alcoholic extraction; pineapple core cellulose (PC) was a product of alkali extraction with a bleaching process. Total dietary fiber content of PDF and PC was 99.8% and 95.2% (dry basis), respectively, and their water activity was 0.25. PC contained 91.2% cellulose with a pH value of 4.0, while that of PDF was 6.2. The fiber product with large particle size gave higher values than the product with smaller particles for pH, water and oil retention capacity, settling volume and emulsifying activity. Both had rough, pitted surfaces and presented showed good functions in cake-type doughnuts, golden layer cake and beef burgers. [source] Impairment of cytoskeleton-dependent vesicle and organelle translocation in green algae: combined use of a microfocused infrared laser as microbeam and optical tweezersJOURNAL OF MICROSCOPY, Issue 2 2002A. Holzinger Summary A Nd-YAG laser at 1064 nm is used as optical tweezers to move intracellular objects and a laser microbeam to cause impairment of cytoskeleton tracks and influence intracellular motions in desmidiaceaen green algae. Naturally occurring migrations of large nuclei are inhibited in Micrasterias denticulata and Pleurenterium tumidum when the responsible microtubules are targeted with a laser microbeam generating 180 mW power in the focal plane. Impairment of the microtubule tracks appears to be irreversible, as the nucleus cannot pass the former irradiated area in Pleurenterium or remains abnormally dislocated in Micrasterias. The actin filament-dependent movement of secretory vesicles and smaller particles can be manipulated by the same IR-laser at 90 mW when functioning as optical tweezers. In Closterium lunula particles are displaced from their cytoplasmic tracks for up to 10 µm but return to their tracks immediately after removing the light pressure gained by the optical tweezers. The cytoplasmic tracks consist of actin filament cables running parallel to the longitudinal axis of Closterium cells as depicted by Alexa phalloidin staining and confocal laser scanning microscopy. Dynamics and extensibility of the cytoplasmic strands connecting particles to the tracks are also demonstrated in the area of large vacuoles which are surrounded by actin filament bundles. In Micrasterias trapping of secretory vesicles by the optical tweezers causes irreversible malformations of the cell shape. The vesicle accumulation itself dissipates within 30 s after removing the optical tweezers, also indicating reversibility of the effects induced, in the case of actin filament-mediated processes. [source] Quantifying effects of particulate properties on powder flow properties using a ring shear testerJOURNAL OF PHARMACEUTICAL SCIENCES, Issue 9 2008Hao Hou Abstract Effects of particle size, morphology, particle density, and surface silicification, on powder flow properties were investigated using a ring shear tester. Flow properties were quantified by flow function (FF), that is, unconfined yield strength, fc, as a function of major principal stress. A total of 11 powders from three series of microcrystalline cellulose (MCC): Avicel (regular MCC, elongated particles), Prosolv (silicified MCC, elongated particles), and Celphere (spherical MCC), were studied. Particle size distribution in each type of MCC was systematically different. Within each series, smaller particles always led to poorer powder flow properties. The slope of FF line was correlated to degree of powder consolidation by external stress. A key mechanism of the detrimental effect of particle size reduction on flow properties was the larger powder specific surface area. Flow properties of Celphere were significantly better than Avicel of comparable particles size, suggesting spherical morphology promoted better powder flow properties. Flow properties of powders different in densities but similar in particle size, shape, and surface properties were similar. When corrected for density effect, higher particle density corresponded to better flow behavior. Surface silicification significantly improved flow properties of finer MCC, but did not improve those of coarser. © 2008 Wiley-Liss, Inc. and the American Pharmacists Association J Pharm Sci 97:4030,4039, 2008 [source] Stabilization of alum-adjuvanted vaccine dry powder formulations: Mechanism and applicationJOURNAL OF PHARMACEUTICAL SCIENCES, Issue 2 2003Yuh-Fun Maa Abstract Studies were performed to elucidate the mechanism of alum gel coagulation upon freezing and drying and its relationship to vaccine potency loss and to develop a novel freeze-drying process for the production of stable alum-adjuvanted vaccine formulations suitable for conventional needle injection and epidermal powder immunization (EPI). The alum hydroxide-adjuvanted hepatitis-B surface antigen (Alum-HBsAg) and the alum phosphate-adjuvanted diphtheria and tetanus toxoids (Alum-DT) were dehydrated by freeze drying (FD), spray drying (SD), air drying (AD), or spray freeze drying (SFD). After drying by FD, SD, or AD, alum gels coagulated when examined by optical microscopy and particle size analysis. In addition, desorption of antigen molecules from the coagulated when examined by optical microscopy and particle size analysis. In addition, desorption of antigen molecules from the coagulated alum gel upon reconstitution appeared to be difficult, as indicated by attenuated band intensity on SDS-PAGE. In contrast, SFD alum gels turned a homogenous suspension upon reconstitution, suggesting minimal alum coagulation. In the mouse model, the in vivo immunogenicity of SFD Alum-HBsAg was preserved, whereas the FD Alum-HBsAg suffered significant immunogenicity loss. Grinding of coagulated FD Alum-HBsAg into smaller particles could partially recover the immunogenicity. In a guinea pig study using EPI, the SD Alum-DT formulation was not immunogenic, but the SFD Alum-DT formulations had a vaccine potency comparable to that of the untreated DT administered by I.M. injection. Overall, the relationship of coagulation of alum gel upon reconstitution and the loss of vaccine potency was established in this study. Alum gels became highly coagulated after dehydration by spray drying and traditional freeze-drying processes. However, freezing rate played a critical role in preserving the adjuvant effect of alum and fast freezing decreased the tendency of alum coagulation. Spraying the alum gel into liquid nitrogen represents the fastest freezing rate achievable and resulted in no discernible alum coagulation. Therefore, SFD presents a novel and effective drying process for alum-adjuvanted vaccine formulations and is particularly valuable for dry powder applications such as EPI. © 2003 Wiley-Liss, Inc. and the American Pharmaceutical Association J Pharm Sci 92:319,332, 2003 [source] Gastrointestinal persorption and tissue distribution of differently sized colloidal gold nanoparticlesJOURNAL OF PHARMACEUTICAL SCIENCES, Issue 12 2001Julián F. Hillyer Abstract The gastrointestinal uptake of micro- and nanoparticles has been the subject of recent efforts to develop effective carriers that enhance the oral uptake of drugs and vaccines. Here, we used correlative instrumental neutron activation analysis and electron microscopy to quantitatively and qualitatively study the gastrointestinal uptake and subsequent tissue/organ distribution of 4, 10, 28, and 58 nm diameter metallic colloidal gold particles following oral administration to mice. In our quantitative studies we found that colloidal gold uptake is dependent on particle size: smaller particles cross the gastrointestinal tract more readily. Electron microscopic studies showed that particle uptake occurred in the small intestine by persorption through single, degrading enterocytes in the process of being extruded from a villus. To our knowledge this is the first report, at the ultrastructural level, of gastrointestinal uptake of particulates by persorption through holes created by extruding enterocytes. © 2001 Wiley-Liss, Inc. and the American Pharmaceutical Association J Pharm Sci 90:1927,1936, 2001 [source] Transition from microemulsion to emulsion polymerization: Mechanism and final propertiesJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 20 2004Kevin D. Hermanson Abstract Microemulsion and emulsion polymerization can have some similarities in starting conditions and polymerization mechanisms, but the resulting latices are unalike in particle size and molecular weight. Here we show that polymerizations can be formulated that display the characteristics often separately associated with microemulsion or emulsion polymerization. Kinetic modeling and particle size measurements show that emulsion polymerizations with initial concentrations close to the microemulsion,emulsion phase boundary demonstrate relatively fast consumption of monomer droplets and produce smaller particles. Because of their high surfactant concentrations, none of the emulsion polymerizations examined demonstrate the classical Smith,Ewart kinetics usually associated with emulsion polymerization. Instead these emulsion polymerizations have a long period of particle nucleation that subsides only after the disappearance of monomer droplets. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5253,5261, 2004 [source] Polycarbonate particles and dye-labeled particles by miniemulsion polymerizationJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 8 2004Frédéric Tronc Abstract We describe the synthesis of several different polycarbonate particles by miniemulsion polymerization. The monomers were allylmethyl carbonate (AlMeC), di(ethylene glycol) bisallylcarbonate (DBAC), and 4-vinyl-1,3-dioxan-2-one [vinyl ethylene carbonate (VEC)]. For these polymerizations, higher monomer conversions were obtained with oil-soluble initiators (azobisisobutyronitrile and benzoyl peroxide) than with a water-soluble initiator (potassium persulfate). Benzoyl peroxide was particularly effective in yielding particles with a narrow size distribution. Although increasing amounts of a surfactant (sodium dodecyl sulfate) led to smaller particles, the choice of the monomer was the major determinant. For example, in polymerization reactions carried out at 85 °C with benzoyl peroxide as the initiator and with otherwise identical recipes, we obtained particle sizes of 181 nm with AlMeC, 296 nm with VEC, and 203 nm with DBAC. Fluorescent particles were synthesized with comonomers based on the benzothioxanthene nucleus. Because the dyes had poor solubility in the monomers, it was necessary to include typically 20 wt % bromobenzene or dichlorobenzene based on the monomer in the miniemulsion reaction mixture. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1999,2009, 2004 [source] Surface-enhanced Raman scattering from analytes adsorbed on gold nanoparticles inside polymer beadsJOURNAL OF RAMAN SPECTROSCOPY, Issue 10 2004Mina Larsson Abstract Porous polymer beads with a large inner area were used as a stabilizing matrix for SERS-active gold particles. A commercially available ion exchanger (SOURCETM) was used together with HAuCl4. Absorbance measurements and an x-ray diffraction study confirmed that nanocrystalline gold was obtained in the polymer beads. Transmission electron microscope measurements were performed and showed that larger nanoparticles, 20,100 nm, were obtained on the surface, whereas in the interior smaller particles, approximately 2,10 nm, could be found. Three analytes, mercaptoethanesulfonate, mercaptopropionic acid and thiocyanate, were adsorbed on the gold particles inside the polymer beads. From all analytes enhanced Raman spectra could be obtained. The distribution of analytes adsorbed on gold nanoparticles was investigated by confocal Raman spectroscopy. SERS spectra from the analytes could be observed throughout the polymer bead, indicating a fairly uniform distribution of analytes adsorbed on gold nanoparticles. Copyright © 2004 John Wiley & Sons, Ltd. [source] Study of the Dehydroxylation,Rehydroxylation of PyrophylliteJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 8 2010Jose L. Perez-Rodriguez Pyrophyllite is a raw material of significant interest due to its large number of applications. Most of these applications require a thermal transformation of pyrophyllite; this thermal transformation implies the release of structural OH groups and the formation of new phases. In this paper, we report on the dehydroxylation of pyrophyllite and the reversibility of the process. A value of 224±16 kJ/mol for the dehydroxylation of pyrophyllite was obtained. In addition, it was observed that the partially or totally dehydroxylated pyrophyllite suffered a partial reversible rehydroxylation when cooled to room temperature. This rehydroxylation was substantiated by thermogravimetric measurements, while infrared spectroscopic studies showed that, during the rehydroxylation, the intensity of the OH band at 3675 cm,1 increased as two new bands at 3690 and 3702 cm,1 appeared. This rehydroxylation process was heavily influenced by the particle size of the pyrophyllite. Thus, smaller particles (<1 ,m) showed a larger rehydroxylation percentage (about 12%), while the larger ones (20,40 ,m) showed a smaller percentage (about 1.6%). The extent of rehydroxylation also depended on the dehydroxylation temperature and reached a maximum value at 750°C. [source] High-performance liquid chromatography-bioassay profiles of endocrine disrupters discharged from point and non-point pollution sources in Lake Biwa basinLAKES & RESERVOIRS: RESEARCH AND MANAGEMENT, Issue 4 2002Saburo Matsui Abstract Toxic pollution loading from both point and non-point sources in Lake Biwa should be further reduced. In order to tackle toxicity problems, it is necessary to analyse characteristics of toxic pollution. We have developed a new profiling technique to display toxic distributions of endocrine disrupters in complex mixtures of environmental samples, using high-performance liquid chromatography in combination with yeast bioassays. We have applied this technique to the major point and non-point pollution sources in the Lake Biwa basin, that is, to municipal sewage-treatment water (point) and road dust (non-point). The dominant oestrogenic chemical in sewage-treatment water was 17 ,-estradiol. The extracts from screened road dust showed arylhydrocarbon-receptor binding activity (AhR,ligand activity), with much of this located in smaller particles of sifted dust. There were at least seven major AhR,ligand peaks in the road-dust sample. [source] RAFT Miniemulsion Polymerization Kinetics, 2 , Molecular Weight Distribution,MACROMOLECULAR THEORY AND SIMULATIONS, Issue 2 2009Hidetaka Tobita Abstract The molecular weight distribution formed in a RAFT polymerization conducted inside submicron particles (Dp,<,300 nm) is considered. For small particles, the MWD at low to middle conversion might be rather broad because of the large differences in MWDs formed in different polymer particles. Such a broad MWD can be made narrower by increasing the radical entry frequency. On the other hand, larger frequencies of radical entry result in a broader MWD at the final conversion levels. The number of dead polymer chains increases with time, and the dead polymer peak could be observed in the MWD at a prolonged aging time. According to this theoretical investigation, smaller particles are advantageous in implementing a faster polymerization rate, a narrower MWD, and a smaller number of dead polymer molecules. [source] Spinodal Decomposition in Ternary Systems with Significantly Different Component DiffusivitiesMACROMOLECULAR THEORY AND SIMULATIONS, Issue 6 2007Abdulrahman A. Alfarraj Abstract A numerical method for simulating spinodal decomposition in ternary systems with order-of-magnitude differences in diffusion coefficients is presented. The method has been partially verified by molecular dynamic simulations and gives results equivalent to the standard technique when the diffusivities are equal. A two-dimensional simulation of an asymmetric polymer/polymer/polymer system reproduces an experimentally observed bimodal distribution of dispersed-phase particle sizes. The ripening exponent for the larger particles is near the expected value of 0.33, but that for the smaller particles is only about 0.1. The method was also used for a polymer/polymer/solvent system. [source] Layer Inversion and Bed Contraction in Down-Flow Binary-Solid Liquid-Fluidized BedsTHE CANADIAN JOURNAL OF CHEMICAL ENGINEERING, Issue 1 2007R. Escudié Abstract Experiments were carried out on downward-flow water-fluidized binary mixture of spheres selected for possible layer inversion. With the two binaries tested (relatively high-density large particles mixed with lower-density smaller particles), only one of the five possible steps of the layer inversion progression was clearly identified for the higher liquid velocities, a mixed layer being observed at the top of the column close to the distributor. This layer manifested a bed contraction so large that its bulk density was lower than those of its constituent mono-components at the same liquid velocity, which determined its location within the column. The voidage of the mixed layer could be predicted with good accuracy (<0.7%) by regression of the Westman packed bed equation with one adjustable parameter. Des expériences ont été menées sur un mélange binaire fluidisé par de l'eau et à écoulement descendant, comprenant des sphères sélectionnées pour une inversion possible des couches. Avec les deux binaires testées (de grosses particules de masse volumique relativement élevée mélangées à de petites particules de faible masse volumique), seulement une des cinq étapes possibles menant à l'inversion des couches est clairement identifiée pour les vitesses de liquide les plus élevées, une couche mixte étant observée dans la partie supérieure de la colonne près du distributeur. Cette couche montre une contraction du lit si grande que sa masse volumique globale est plus faible que celle de ses composants individuels constitutifs à la même vitesse de liquide, ce qui détermine sa position dans la colonne. Le degré de vide de la couche mixte a pu être prédit avec une bonne précision (<0,7%) en effectuant une régression sur l'équation de lit garni de Westman avec un paramètre ajustable. [source] Measurement of Solid Circulation Patterns in Liquid,Solid and Gas,Liquid,Solid Fluidized BedsTHE CANADIAN JOURNAL OF CHEMICAL ENGINEERING, Issue 1 2003Shahzad Barghi Abstract Solid circulation patterns were determined by measuring collisions between tracer particles and cylindrical probes in liquid,solid and gas,liquid,solid fluidized beds. Special probes were used to obtain two- and three-dimensional views of particle motion. Circulation patterns for 3 and 5 mm glass beads were studied. Mixing cells, which had been formed at low liquid velocities, grew in size and eventually merged as the liquid velocity increased. The flow patterns of smaller particles having the same density as bed particles and particles lighter than bed particles (graphite particles) with the same size were also measured. On a déterminé des profils de circulation des solides en mesurant les collisions entre des traceurs particulaires et des sondes cylindriques dans des lits fluidisés liquide, solide et gaz,liquide,solide. Des sondes spéciales ont été employées pour obtenir des images bidimensionnelle et tridimensionnelle du déplacement des particules. Les profils de circulation pour des billes de verre de 3 mm et 5 mm ont été étudiés. Les cellules de mélange, qui se forment à de faibles vitesses de liquide, augmentent en taille et finissent par fusionner à mesure que la vitesse du liquide augmente. On a également mesuré les profils d'écoulement des particules plus petites ayant la même masse volumique que les particules de lit et des particules plus légères que les particules de lit (particules de graphite) ayant la même taille. [source] Superparamagnetic iron oxide particles: contrast media for magnetic resonance imaging,APPLIED ORGANOMETALLIC CHEMISTRY, Issue 10 2004Rüdiger Lawaczeck Abstract The mainstream magnetic iron oxide particles used as contrast media for magnetic resonance (MR) imaging are composed of a magnetic iron oxide core surrounded by a dextran or carboxydextran coat. The core size ranges from 2 nm to less than 10 nm, and the hydrodynamic diameter ranges from 20 nm to about 120 nm. The coat prevents aggregation and sedimentation of the particles in aqueous solutions, achieves high biological tolerance, and prevents toxic side effects. Two kinds of particles are considered: (i) large particles (>30 nm), called superparamagnetic iron oxide particles (SPIOs) for liver imaging; (ii) smaller particles (<30 nm hydrodynamic diameter), called ultrasmall SPIOs (USPIOs), e.g. for MR angiography. To characterize the particles, Mössbauer spectra are presented for the two particle ensembles. These spectra allow insight into the magnetic coupling, the valency of the iron ions and a rough estimate of the core size to be deduced. On the basis of the concentration dependence of the MR signal intensities, two applications are discussed together with two representative clinical examples. Future indications for MR diagnostics, e.g. the labeling and tracking of stem cells during stem-cell therapy control, are outlined. Copyright © 2004 John Wiley & Sons, Ltd. [source] Particle Size Control of Nanocrystalline Anatase TiO2 Synthesized by Hydrolysis of Titanyl Organic CompoundsCHEMICAL ENGINEERING & TECHNOLOGY (CET), Issue 12 2008X.-Q. Chen Abstract The global nanocrystalline anatase TiO2 particle can be obtained by hydrolysis of titanyl organic compounds. Its particle size is mostly influenced by the titanyl organic compounds' concentration, nitric acid (HNO3) concentration, reaction time and temperature, and especially the HNO3 concentration. The formation of nanocrystalline TiO2 with bigger size can be accelerated by a higher temperature, thick solution of reactant (titanyl organic compounds), and HNO3. Vice versa, in order to gain smaller particles, such as 6 nm, the reaction conditions should be set at a thin reactant solution, low temperature, and low HNO3 concentration. The reason lies in the hydrolyzing mechanism of titanyl organic compounds, which is strongly influenced by the temperature and pH. [source] | ||||||||||||||||||||||||||||