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Silt
Terms modified by Silt Selected AbstractsPaleosols in Central Illinois as Potential Sources of Ammonium in GroundwaterGROUND WATER MONITORING & REMEDIATION, Issue 4 2009Justin J. G. Glessner Glacially buried paleosols of pre-Holocene age were evaluated as potential sources for anomalously large concentrations of ammonium in groundwater in East Central Illinois. Ammonium has been detected at concentrations that are problematic to water treatment facilities (greater than 2.0 mg/L) in this region. Paleosols characterized for this study were of Quaternary age, specifically Robein Silt samples. Paleosol samples displayed significant capacity to both store and release ammonium through experiments measuring processes of sorption, ion exchange, and weathering. Bacteria and fungi within paleosols may significantly facilitate the leaching of ammonium into groundwater by the processes of assimilation and mineralization. Bacterial genetic material (DNA) was successfully extracted from the Robein Silt, purified, and amplified by polymerase chain reaction to produce 16S rRNA terminal restriction fragment length polymorphism (TRFLP) community analyses. The Robein Silt was found to have established diverse and viable bacterial communities. 16S rRNA TRFLP comparisons to well-known bacterial species yielded possible matches with facultative chemolithotrophs, cellulose consumers, nitrate reducers, and actinomycetes. It was concluded that the Robein Silt is both a source and reservoir for groundwater ammonium. Therefore, the occurrence of relatively large concentrations of ammonium in groundwater monitoring data may not necessarily be an indication of only anthropogenic contamination. The results of this study, however, need to be placed in a hydrological context to better understand whether paleosols can be a significant source of ammonium to drinking water supplies. [source] A Case Study of Soil-Gas Sampling in Silt and Clay-Rich (Low-Permeability) SoilsGROUND WATER MONITORING & REMEDIATION, Issue 1 2009Todd A. McAlary Soil-gas sampling and analysis is a common tool used in vapor intrusion assessments; however, sample collection becomes more difficult in fine-grained, low-permeability soils because of limitations on the flow rate that can be sustained during purging and sampling. This affects the time required to extract sufficient volume to satisfy purging and sampling requirements. The soil-gas probe tubing or pipe and sandpack around the probe screen should generally be purged prior to sampling. After purging, additional soil gas must be extracted for chemical analysis, which may include field screening, laboratory analysis, occasional duplicate samples, or analysis for more than one analytical method (e.g., volatile organic compounds and semivolatile organic compounds). At present, most regulatory guidance documents do not distinguish between soil-gas sampling methods that are appropriate for high- or low-permeability soils. This paper discusses permeability influences on soil-gas sample collection and reports data from a case study involving soil-gas sampling from silt and clay-rich soils with moderate to extremely low gas permeability to identify a sampling approach that yields reproducible samples with data quality appropriate for vapor intrusion investigations for a wide range of gas-permeability conditions. [source] An electromagnetic modelling tool for the detection of hydrocarbons in the subsoilGEOPHYSICAL PROSPECTING, Issue 2 2000Carcione Electromagnetic geophysical methods, such as ground-penetrating radar (GPR), have proved to be optimal tools for detecting and mapping near-surface contaminants. GPR has the capability of mapping the location of hydrocarbon pools on the basis of contrasts in the effective permittivity and conductivity of the subsoil. At radar frequencies (50 MHz to 1 GHz), hydrocarbons have a relative permittivity ranging from 2 to 30, compared with a permittivity for water of 80. Moreover, their conductivity ranges from zero to 10 mS/m, against values of 200 mS/m and more for salt water. These differences indicate that water/hydrocarbon interfaces in a porous medium are electromagnetically ,visible'. In order to quantify the hydrocarbon saturation we developed a model for the electromagnetic properties of a subsoil composed of sand and clay/silt, and partially saturated with air, water and hydrocarbon. A self-similar theory is used for the sandy component and a transversely isotropic constitutive equation for the shaly component, which is assumed to possess a laminated structure. The model is first verified with experimental data and then used to obtain the properties of soils partially saturated with methanol and aviation gasoline. Finally, a GPR forward-modelling method computes the radargrams of a typical hydrocarbon spill, illustrating the sensitivity of the technique to the type of pore-fluid. The model and the simulation algorithm provide an interpretation methodology to distinguish different pore-fluids and to quantify their degree of saturation. [source] Late Quaternary depositional history of the Reuss delta, Switzerland: constraints from high-resolution seismic reflection and georadar surveysJOURNAL OF QUATERNARY SCIENCE, Issue 2 2002Frank O. Nitsche Abstract Glacial erosion has caused overdeepening of many alpine valleys. After retreat of the ice, they were filled with heterogeneous deposits of glacial, lacustrine and fluvial sediments. A typical example of such a valley segment and its infill is the Reuss delta on the southern shore of Lake Lucerne in Switzerland. To obtain a detailed three-dimensional image of this valley segment, the ETH Institute of Geophysics has acquired several two-dimensional, high-resolution seismic and georadar profiles, and conducted a three-dimensional georadar survey. Interpretations of these geophysical data were constrained by a geological core extracted from a borehole 300 m deep near the investigation site. The seismic profiles imaged ca. 600 m of sediment infill above bedrock. Based on their reflection characteristics, five different deposition units were distinguished. These units were interpreted as a succession of clay/silt at the base, followed by different sand units with variable but generally increasing amounts of gravel. This succession represented a prograding delta that filled the southern part of Lake Lucerne. The latest fluvial development of the region is best represented by the georadar data. In particular, the three-dimensional georadar data set provides a detailed view of an ancient braided river channel Copyright © 2002 John Wiley & Sons, Ltd. [source] Microbiotic crusts as biomarkers for surface stability and wetness duration in the Negev DesertEARTH SURFACE PROCESSES AND LANDFORMS, Issue 12 2009Giora J. Kidron Abstract Microbiotic crusts play an important role in arid and semi-arid regions. Yet, very little information exists regarding the factors that impact their development. In an attempt to assess the main factors that may determine their growth, measurements of the amount of fines (silt and clay), rain, moisture content, wetness duration and wind erosion and deposition were carried out along a 12 station transect within a partially crusted dune field in the western Negev Desert and compared to the crust cover and chlorophyll content. Surface stability was the only variable that exhibited significant relationship with crust cover while daylight wetness duration exhibited strong positive relationship (r2 = 0·92,0·99) with the crust's chlorophyll content. The data point out that microbiotic crusts may serve as a useful biomarker for surface stability. While wetness duration and wind will control crust cover and the crust chlorophyll content in semi-stable habitats (with absolute annual change in sand level of 2,3 mm), stable habitats (absolute change <1 mm) will be controlled primarily by moisture, while habitats with low surface stability (absolute change of tens and hundreds of millimeters) will be primarily controlled by wind. Furthermore, owing to the strong positive relationship between daylight wetness duration and the crust's chlorophyll content, the crust may serve as a useful biomarker for the quantification of surface wetness duration. Copyright © 2009 John Wiley & Sons, Ltd. [source] Expressing sand supply limitation using a modified Owen saltation equation ,EARTH SURFACE PROCESSES AND LANDFORMS, Issue 12 2008Dale A. Gillette Abstract An analysis of saltation data led us to modify the theory of P. R. Owen using a soil-related parameter ,A' that gave us the possibility of expressing limitation of sand grains of saltation-size in the underlying soil. The value of ,A' was set equal to the ratio of the horizontal flux of saltating particles to Owen's function of wind, times air density divided by gravitational acceleration. Values of A can be used to: (1) characterize the efficiency of the wind to move sand by saltation for different soil textures and aggregations; and (2) to make practical predictions of sand movement based on the condition of the surface soil. Values for A in a range from 1 to 10 are usually associated with supply-unlimited saltation and are usually associated with loose, sandy-textured soils. Values for A in a range from 0·25 to 1 are associated with finer soils that contain more silt and clay. The range of A values between 0 and 0·25 usually reflects finer textured soils that are packed, aggregated, or crusted. A decrease of A to a smaller value is a sign of supply limitation and usually to the soil changing from a looser state to a more aggregated state or more depleted state. Likewise, an increase of A usually corresponds to soil changing from an aggregated state to a looser state. Copyright © 2008 John Wiley & Sons, Ltd. [source] Linking upstream channel instability to downstream degradation: Grenada Lake and the Skuna and Yalobusha River Basins, MississippiECOHYDROLOGY, Issue 3 2009Sean J. Bennett Abstract Unstable fluvial systems are characterized by actively migrating knickpoints, incising channel beds, failing banks, and recruitment of large woody debris and it would appear that river corridors downstream of these processes would be adversely affected or impaired because of higher fluxes of sediment and other riverine products. In north-central Mississippi, the Yalobusha River is one such system and the characteristics of two downstream locations are examined to explore this geomorphic linkage between upstream instability and downstream degradation. For the large woody debris plug along the Yalobusha River, it is found that (1) the deposit is composed mostly of sand covered with a veneer of silt and clay, (2) agrichemicals and enriched concentrations of elements are prevalent, and (3) excessive sedimentation and wood accumulation have forced river flow entirely out-of-bank. For Grenada Lake, it is found that (1) the impounded sediment is predominantly clay, (2) agrichemicals and elements observed throughout the reservoir show no spatial variation, (3) little difference exists in the amount and quality between the sediments deposited in Skuna and Yalobusha River arms, and (4) only a small fraction of the reservoir's storage capacity has been lost because of sedimentation. While excessive sedimentation and large woody debris recruitment have had a marked affect on stream corridor function in the area of the debris plug, the high sediment loads associated with the unstable portions of the Yalobusha River and their associated products have not been communicated to Grenada Lake. The fish consumption advisories within Grenada Lake and its tributaries due to bioaccumulated trace elements and agrichemicals, appear to be independent of the pervasive river channel instability occurring upstream. Copyright © 2009 John Wiley & Sons, Ltd. [source] The effects of continuous and pulsed exposures of suspended clay on the survival, growth, and reproduction of Daphnia magnaENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 1 2010Sarah E. Robinson Abstract Suspended sediments are a natural component of aquatic ecosystems, but anthropogenic activity such as land development can result in significant increases, especially after rain events. Continuous exposures of suspended clay and silt have been shown to affect growth and reproduction of Cladocera, leading to a decrease in population growth rate. The mechanism of clay toxicity in these filter-feeding organisms is clogging of the gut tract, resulting in decreased food uptake and assimilation. When placed in clean water, daphnids can purge clay from their gut and recover. In many surface waters, aquatic organisms experience episodic exposures of high concentrations of suspended solids driven by rain events. However, little is known about the consequences of pulsed exposures on individuals and populations. The objective of the present study was to characterize the effects of continuous and pulsed exposures of natural and defined clays on survival, growth, and reproduction of Daphnia magna. Two defined clays, montmorillonite and kaolinite, as well as clay isolated from the Piedmont region of South Carolina, USA, were used. Continuous exposures of clays elicited a dose dependent decrease in survival. Toxicity varied depending on clay source with montmorillonite,>,natural clay,>,kaolinite. Pulsed exposures caused a decrease in survival in a 24 h exposure of 734 mg/L kaolinite. Exposure to 73.9 mg/L also caused an increase in the time to gravidity, although there was not a corresponding decrease in neonate production over 21 d. No significant effects resulted from 12 h exposures even at 730 mg/L, almost 10 times the 24-h reproductive effects concentration. This suggests that exposure duration impacted toxicity more than exposure concentration in these pulsed exposures. Environ. Toxicol. Chem. 2010;29:168,175. © 2009 SETAC [source] Investigation of an onsite wastewater treatment system in sandy soil: Site characterization and fate of anionic and nonionic surfactantsENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 12 2002Allen M. Nielsen Abstract This study reports on the fate of linear alkylbenzene sulfonate (LAS), alcohol ethoxylate (AE), and alcohol ether sulfate (AES) surfactants in a home septic system near Jacksonville (FL, USA) that has been used since 1976. The drainfield at this site resides in fine sand (<6% silt and clay) with an unsaturated zone that ranges from 0 to 1.3 m. During the wettest times of the year, it is likely that effluent from the septic system passes directly into the groundwater without exposure to an unsaturated zone of soil. Groundwater was collected during two sampling events, representing seasonal high and low groundwater table levels, and analyzed for the surfactants LAS, AES, and AE. During the wet season, the unsaturated zone was approximately 0.01 m beneath the drainfield. During the dry season, the unsaturated zone was about 0.4 m below the drainfield. Alcohol ethoxylate was not detected in any groundwater samples during either sampling. Alcohol ether sulfate was not found in the dry season sampling, but traces of AES had migrated downgradient about 4.7 m horizontally and 1.8 m vertically in the wet season. Linear alkylbenzene sulfonate was detected in some dry season samples and had moved downgradient some 11.7 m horizontally and 3.7 m vertically in the wet season. These observations demonstrate that these surfactants were removed to a great extent; otherwise, they would have traveled more than 260 m downgradient, which is the calculated distance that a conservative tracer like bromide would have moved downgradient over the life of the system. The most likely removal mechanisms for these surfactants were biodegradation and sorption. Therefore, this study indicates that LAS, AE, and AES are readily removed from groundwater in soils below septic system drainfields even in situations with minimal unsaturated soil zones. [source] Distribution of polycyclic aromatic hydrocarbons in particle-size separates and density fractions of typical agricultural soils in the Yangtze River Delta, east ChinaEUROPEAN JOURNAL OF SOIL SCIENCE, Issue 6 2008J. Z. Ni Summary Soil organic matter can be divided into different organic carbon (C) pools with different turnover rates. The organic pollutants in soils associated with these organic C pools may have different bioavailability and environmental risks during the decomposition of soil organic matter. We studied the distribution patterns of 15 USEPA priority polycyclic aromatic hydrocarbons (PAHs) in different particle-size separates (clay, fine silt, coarse silt, fine sand and coarse sand) and density fractions (light and heavy fractions) of nine agricultural topsoils (0,20 cm depth) from a contaminated area in the Yangtze River Delta region of east China. There was a decreasing trend in PAH concentration in particle-size separates with decreasing particle size. However, the different particle-size separates had similar PAH composition. The concentration of PAHs in the light fraction ranged from 13 037 to 107 299 ,g kg,1, far higher than in the heavy fraction, which ranged from 222 to 298 ,g kg,1. Although the light fraction accounted for only 0.4,2.3% of the soils, it was associated with 31.5,69.5% of soil PAHs. The organic matter in coarse silt had the strongest capacity for enrichment with PAHs. Combining the distributions of PAHs and the turnover rates of organic matter in different soil fractions, the environmental risks of PAH-polluted soils may be due mainly to the PAHs associated with sand and the light fraction. [source] In search of stable soil organic carbon fractions: a comparison of methods applied to soils labelled with 14C for 40 days or 40 yearsEUROPEAN JOURNAL OF SOIL SCIENCE, Issue 2 2008S. Bruun Summary A reliable method for the isolation of a stable fraction of soil organic carbon (SOC) would be very helpful for improving our understanding of the mechanisms responsible for stabilization of SOC and the dynamics of SOC turnover. We tested acid hydrolysis, physical fractionation (particle density/size), photo-oxidation, treatment with chemical oxidants (NaOCl and NaS2O8) and thermal treatment on two soils incubated with 14C-labelled barley straw for either 40 days or 40 years. Different intensities of the treatments were included. Acid hydrolysis, photo-oxidation and treatment with a chemical oxidant consistently removed more 40-year-old C than 40-day-old C, which suggests that the isolated fractions contained a large proportion of material with a relatively rapid turnover. The clay + silt associated SOC fraction contained a small proportion of 40-day-old C and a large proportion of 40-year-old C. This is consistent with a SOC fraction with medium turnover. The thermal treatment removed more 40-year-old C than 40-day-old C. At 400°C there was still a small proportion of the 40-year-old C remaining, whereas almost all the 40-day-old C was removed. This is consistent with a stable SOC fraction. However, because only 2,3% of the C remained after this treatment, the isolated SOC fraction may be of little quantitative importance. Furthermore, the thermally resistant fraction is likely to be heavily altered by the treatment, and therefore unsuitable for further studies of the chemical nature of stable SOC. [source] Soil organic carbon in density fractions of tropical soils under forest , pasture , secondary forest land use changesEUROPEAN JOURNAL OF SOIL SCIENCE, Issue 2 2008S. Paul Summary Our knowledge of effects of land use changes and soil types on the storage and stability of different soil organic carbon (SOC) fractions in the tropics is limited. We analysed the effect of land use (natural forest, pasture, secondary forest) on SOC storage (depth 0,0.1 m) in density fractions of soils developed on marine Tertiary sediments and on volcanic ashes in the humid tropics of northwest Ecuador. The origin of organic carbon stored in free light (< 1.6 g cm,3) fractions, and in two light fractions (LF) occluded within aggregates of different stability, was determined by means of ,13C natural abundance. Light occluded organic matter was isolated in a first step after aggregate disruption by shaking aggregates with glass pearls (occluded I LF) and in a subsequent step by manual destruction of the most stable microaggregates that survived the first step (occluded II LF). SOC storage in LFs was greater in volcanic ash soils (7.6 ± 0.6 Mg C ha,1) than in sedimentary soils (4.3 ± 0.3 Mg C ha,1). The contribution of the LFs to SOC storage was greater in natural forest (19.2 ± 1.2%) and secondary forest (16.6 ± 1.0%) than in pasture soils (12.8 ± 1.0%), independent of soil parent material. The amount of SOC stored in the occluded I LF material increased with increasing silt + clay content (sedimentary soils, r = 0.73; volcanic ash soils, r = 0.58) and aggregation (sedimentary soils, r = 0.52; volcanic ash soils, r = 0.45). SOC associated with occluded I LF, had the smallest proportion of new, pasture-derived carbon, indicating the stabilizing effect of aggregation. Fast turnover of the occluded II LF material, which was separated from highly stable microaggregates, strongly suggested that this fraction is important in the initial process of aggregate formation. No pasture-derived carbon could be detected in any density fractions of volcanic ash soils under secondary forest, indicating fast turnover of these fractions in tropical volcanic ash soils. [source] Composition of organic matter in a subtropical Acrisol as influenced by land use, cropping and N fertilization, assessed by CPMAS 13C NMR spectroscopyEUROPEAN JOURNAL OF SOIL SCIENCE, Issue 6 2005J. Dieckow Summary We know much about the influence of management on stocks of organic matter in subtropical soils, yet little about the influence on the chemical composition. We therefore studied by CPMAS 13C NMR spectroscopy the composition of the above-ground plant tissue, of the organic matter of the whole soil and of silt- and clay-size fractions of the topsoil and subsoil of a subtropical Acrisol under grass and arable crops. Soil samples were collected from three no-till cropping systems (bare soil; oats,maize; pigeon pea + maize), each receiving 0 and 180 kg N ha,1 year,1, in a long-term field experiment. Soil under the original native grass was also sampled. The kind of arable crops and grass affected the composition of the particulate organic matter. There were no differences in the composition of the organic matter in silt- and clay-size fractions, or of the whole soil, among the arable systems. Changes were observed between land use: the soil of the grassland had larger alkyl and smaller aromatic C contents than did the arable soil. The small size fractions contain microbial products, and we think that the compositional difference in silt- and clay-size fractions between grassland and the arable land was induced by changes in the soil's microbial community and therefore in the quality of its biochemical products. The application of N did not affect the composition of the above-ground plant tissue nor of the particulate organic matter and silt-size fractions, but it did increase the alkyl C content in the clay-size fraction. In the subsoil, the silt-size fraction of all treatments contained large contents of aromatic C. Microscopic investigation confirmed that this derived from particles of charred material. The composition of organic matter in this soil is affected by land use, but not by variations in the arable crops grown. [source] The concentrations of fatty acids in organo-mineral particle-size fractions of a ChernozemEUROPEAN JOURNAL OF SOIL SCIENCE, Issue 3 2004G. Jandl Summary Fatty acids, the most abundant class of soil lipids, indicate pedogenetic processes and soil management. However, their quantitative distribution in organo-mineral particle-size fractions is unknown. The concentrations of n -C10:0 to n -C34:0 fatty acids both in whole soil samples and in the organo-mineral particle-size fractions of the Ap horizon of a Chernozem were determined (i) to evaluate the effects of long-term fertilization and (ii) to investigate their influence on the aggregation of organo-mineral primary particles. Quantification by gas chromatography/mass spectrometry (GC/MS) showed that long-term fertilization with nitrogen, phosphorus and potassium (NPK) and farmyard manure (FYM) led to larger concentrations (25.8 µg g,1) of fatty acids than in the unfertilized sample (22.0 µg g,1). For particle-size fractions of the unfertilized soil, the fatty acid concentrations increased from the coarse silt to the clay fractions (except for fine silt). Fertilization with NPK and FYM resulted in absolute enrichments of n -C21:0 to n -C34:0 fatty acids with a maximum at n -C28:0 in clay (×2.2), medium silt (×2.0), coarse silt (×1.8) and sand (×2.9) compared with the unfertilized treatment (the factors of enrichment are given in parentheses). New evidence for the aggregate stabilizing function of n -C21:0 to n -C34:0 fatty acids was shown by the characteristic pattern in size-fractionated, disaggregated and aggregated samples. Highly significant correlations of fatty acid concentrations with organic C concentrations and specific surface areas are interpreted as indicators of (i) trapping of fatty acids in organic matter macromolecules and (ii) direct bonding to mineral surfaces. This interpretation was supported by the thermal volatilization and determination of fatty acids by pyrolysis-field ionization mass spectrometry (Py-FIMS). [source] Quantifying the effects of aggregation, particle size and components on the colour of Mediterranean soilsEUROPEAN JOURNAL OF SOIL SCIENCE, Issue 3 2004M. SĮnchez-Marańón Summary Aggregation, particle size, and chemical composition affect the colour of the soil. We have attempted to quantify and understand these effects in 12 Mediterranean soils. We measured the CIELAB colour variables hab, L*, and C*ab in aggregated and dispersed soil samples, and also in coarse sand, fine sand, silt, and clay samples before and after sequential removal of organic matter, carbonates, and Fe oxides. Grassmann's colour-mixing equations adjusted by regression analysis described the colour of the dispersed soil from its particle-size fractions with an error of 1% for hab, 4% for L*, and 9% for C*ab. This suggests that the contribution of each fraction to the colour of the dispersed soil can be accurately calculated by its colorimetric data weighted by its content and a regression coefficient, which was greatest for clay. We inferred the influence of a component within each fraction by measuring the colour changes after its removal. Iron oxides reduced hab of the silicated substrate by 19%, reduced L* by 12%, and increased C*ab by 64% in all particle-size fractions. Carbonates and organic matter had little influence: the former because they impart little colour to the silicates and the latter because there was little of it. The CIELAB colour-difference between dispersed and aggregated soil (mean ,E*ab = 15.3) was due mainly to ,L* (,14.7). Aggregation contributed to diminishing L* of dispersed soil by 34%. Scanning electron microscopy showed that Fe oxides and organic coatings cover the surface of aggregates thereby influencing soil colour. [source] Fate of microbial residues in sandy soils of the South African Highveld as influenced by prolonged arable croppingEUROPEAN JOURNAL OF SOIL SCIENCE, Issue 1 2002W. Amelung Summary Long-term cultivation of former grassland soils results in a significant decline of both living and dead microbial biomass. We evaluated the effect of duration of cropping on the preservation of fungal and bacterial residues in the coarse-textured soils of the South African Highveld. Composite samples were taken from the top 20 cm of soils (Plinthustalfs) that have been cropped for periods varying from 0 to 98 years in each of three different agro-ecosystems in the Free State Province. Amino sugars were determined as markers for the microbial residues in bulk soil and its particle-size fractions. Long-term cultivation reduced N in the soil by 55% and the contents of amino sugars by 60%. Loss rates of amino sugars followed bi-exponential functions, suggesting that they comprised both labile and stable fractions. With increased duration of cropping the amino sugars attached to silt dissipated faster than those associated with the clay. This dissipation was in part because silt was preferentially lost through erosion, while clay particles (and their associated microbial residues) remained. Erosion was not solely responsible for the reduction in amino sugar concentrations, however. Bacterial amino sugars were lost in preference to fungal ones as a result of cultivation, and this effect was evident in both silt- and clay-sized separates. This shift from fungal to bacterial residues was most pronounced within the first 20 years after converting the native grassland to arable cropland, but continued after 98 years of cultivation. [source] Loss of phosphorus from soil in semi-arid northern Tanzania as a result of cropping: evidence from sequential extraction and 31P-NMR spectroscopyEUROPEAN JOURNAL OF SOIL SCIENCE, Issue 4 2000D. Solomon Summary In semi-arid northern Tanzania, the native woodland is being rapidly cleared and replaced by low input agriculture. This has resulted in pronounced environmental degradation, and in particular loss of phosphorus (P) from the soil. We have used sequential extraction and 31P-NMR to investigate the effects of land use changes, i.e. native woodland, degraded woodland, cultivation for 3 and 15 years and homestead fields where manure was applied, on the amount and structural composition of P in this soil. Clearing and continuous cultivation reduced both organic and inorganic P in the soil. The difference in the amount of organic P from the bulk soil of the fields cultivated for 3 and 15 years was not statistically significant (P <,0.05), suggesting that most of the depletion in organic P occurred during the first 3 years of cultivation. By contrast, in the homesteads, there was much organic and inorganic P in the soil. The 31P-NMR revealed that cultivation resulted in a 53% depletion of orthophosphate diester P, whereas only a 30% and 39% reduction of orthophosphate monoester P was found in the bulk soil after 3 and 15 years of cultivation, respectively. These results concur with the suggestion that diester P constitutes more easily mineralizable forms of organic P in soil than does monoester P. Our 31P-NMR also showed that 70% of the inorganic orthophosphate P was depleted from the coarse and fine sand separates as a result of cultivation. The influence of clearing and subsequent cropping on the amount and forms of P was more pronounced in the coarse and fine sand than in the silt and clay, stressing the importance of particle size and chemical properties such as organic matter and oxides in the availability of P in this soil. Our results show that the current low input agricultural practice is not sustainable, and that practices must be developed to combat the ongoing degradation of the soil. A combined use of available organic materials such as animal manure with the judicious use of inorganic fertilizers can replenish the soil's fertility. [source] Determination of moisture content in a deformable soil using time-domain reflectometry (TDR)EUROPEAN JOURNAL OF SOIL SCIENCE, Issue 1 2000D. J. Kim Summary Time-domain reflectometry (TDR) is being used increasingly for measuring the moisture content of porous media. However, successful application for measuring water in soil has been limited to non-deformable soils, and it would be a valuable extension of the technique if it could be used for soils that shrink on drying. We have recently investigated its application to soils rich in clay and organic matter and peats. Here we propose a method for determining moisture content in deformable soils based on the relation between the dielectric constant, K, and the volumetric moisture content, ,, measured by TDR. Parallel TDR probes with a length of 15 cm and a spacing of 2 cm were placed horizontally in soil cores with a diameter of 20 cm and height of 10 cm taken from a forest. The soil is very porous with large proportions of both silt and clay. The sample weight and travel time of the electromagnetic wave guided by parallel TDR probes were simultaneously measured as a function of time, from saturation to oven-dryness during which the core samples shrank considerably. Vertical and horizontal components of shrinkage were also measured to take the air-exposed region of TDR probe into account in the determination of K. The effect of deformation on volumetric moisture content was formulated for two different expressions, namely actual volumetric moisture content (AVMC) and fictitious (uncorrected) volumetric moisture content (FVMC). The effects of air-exposure and expressions of volumetric moisture content on the relation between K and, were examined by fitting the observations with a third-order polynomial. Neglecting the travel time in the air-exposed part or use of the FVMC underestimated the , for a given K. The difference was more pronounced between AVMC and FVMC than between two different dielectric constants, i.e. accounting for air-exposure, Kac, and not accounting for air-exposure, Kau. When the existing empirical models were compared with the fitted results, most underestimated the relation based on the AVMC. This indicates that published empirical models do not reflect the effect of deformation on the determination of , in our forest soil. Correct use of the , expression has more impact on determining moisture content of a deformable soil than the accommodation of travel time through the air-exposed region of TDR probe. [source] An application of canonical correspondence analysis for developing ecological quality assessment metrics for river macrophytesFRESHWATER BIOLOGY, Issue 5 2005IAN DODKINS Summary 1. Aquatic macrophyte composition and abundance is required by the European Union's Water Framework Directive for determining ecological status. Five metrics were produced that can be combined to determine the deviation of aquatic macrophytes from reference conditions in Northern Ireland's rivers. 2. Species optima and niche breadths along silt, nitrate, pH, conductivity and dissolved oxygen gradients were generated from aquatic macrophyte and water quality surveys conducted at 273 sites throughout Northern Ireland using Canonical Correspondence Analysis (CCA). Five metric scores based on these environmental gradients were determined at new monitoring sites using the mean optima of the species occurring at the site, weighted by percentage cover and niche breadth of each species. 3. A preliminary reference network of 32 sites of high physico-chemical and hydromorphological quality, and representative of the range of river types in Northern Ireland, enabled reference metric scores to be produced for each river type. Five unimpacted and twenty impacted sites were used for testing the performance of the metrics. By subtracting reference metric scores from metric scores at a monitoring site measures of ecological impact could be determined along five different impact gradients. Metrics were also combined to give a measure of total ecological change. 4. The metrics system distinguished unimpacted from impacted sites and correctly identified 77% of the known impacts. The metrics distinguished different types of impact, e.g. silt and nitrate. 5. Aquatic macrophyte occurrence and abundance has high natural variability at a site, both temporally and spatially. This method was designed to be sensitive to ecological change whilst reducing noise caused by natural variation. [source] Response of the flora and macroinvertebrate fauna of a chalk stream site to changes in managementFRESHWATER BIOLOGY, Issue 5 2003J. F. Wright SUMMARY 1. Temporal changes in a series of habitats and their macroinvertebrate assemblages were examined on a 50-m section of a chalk stream in Berkshire, England between June 1975,79 and June 1997,2001. 2. The site was part of a trout fishery in 1975,79, when river management included instream weed cutting together with control of bankside trees and riparian vegetation. Management ceased in the 1980s and by 1997,2001, the site was heavily shaded by trees and riparian vegetation. 3. The mean area of instream macrophytes decreased by 50% between the first and second sampling period. In contrast, gravel and silt increased and invading marginal vegetation formed a new habitat. 4. Changes in macroinvertebrate family richness between sampling periods were scale dependant. Although there were, on average, significantly more families in individual replicates in 1975,79 than in 1997,2001, total family richness for the site in each year did not differ significantly between sampling periods. 5. Sixty families of macroinvertebrates were recorded during the study, 50 in both sampling periods, 53 in 1975,79 and 57 in 1997,2001. This small increase in site family richness may be due to the invading marginal plants. 6. Total macroinvertebrate abundance was significantly lower in the second sampling period. A major drought in 1976 resulted in significantly higher densities of macroinvertebrates, partly through the exploitation of epiphytic diatoms by chironomid larvae. A drought in 1997 failed to elicit a similar response because of the limited macrophytes and diatoms under heavy shading by trees and marginal vegetation. 7. Significant increases in important shredders and decreases in some scrapers between the early and later sampling years largely reflected changes in available food resources. 8. Whereas macroinvertebrate family richness has been conserved under the recent ,no management' regime, the site is now less attractive as a fishery because of poor access and lower densities of some macroinvertebrates taken by brown trout. [source] Geoarchaeological study of the Phoenician cemetery of Tyre-Al Bass (Lebanon) and geomorphological evolution of a tomboloGEOARCHAEOLOGY: AN INTERNATIONAL JOURNAL, Issue 3 2008Pilar Carmona The geoarchaeological record of the Phoenician necropolis of Al Bass (Lebanon) provides information concerning the geomorphological evolution of a late Holocene tombolo. Physical and chemical analysis of sediments indicates that the cemetery (9th century B.C.) was located near a littoral lagoon, between the dunes of a cuspate spit pointing toward the island of Tyre. From the sea apex of this spit, the moles mentioned in historical chronicles were constructed. Once mainland and island were connected, at the northern coast (where the port of Sidon was located), a sediment trap was formed, which quickly filled with silt. Afterwards, an extensive field of sand dunes buried all the archaeological remains from Phoenician to Roman times. © 2008 Wiley Periodicals, Inc. [source] Geoarchaeology of the Kostenki,Borshchevo sites, Don River Valley, RussiaGEOARCHAEOLOGY: AN INTERNATIONAL JOURNAL, Issue 2 2007Vance T. Holliday The Kostenki,Borshchevo localities include 26 Upper Paleolithic sites on the first and second terraces along the west bank of the Don River, near Voronezh on the central East European Plain. Geoarchaeological research from 2001 through 2004 focused on sites Kostenki 1, 12, and 14, with additional work at Kostenki 11 and 16, and Borshchevo 5. The strata are grouped into three units (bottom up): Unit 1, > 50 ka, consists of coarse alluvium (representing upper terrace 2 deposits) and colluvium, overlain by fine-grained sediments. Unit 2 includes archaeological horizons sealed within two sets of thin lenses of silt, carbonate, chalk fragments, and organic-rich soils (termed the Lower Humic Bed and Upper Humic Bed) dating 50,30 ka. Separating the humic beds is a volcanic ash lens identified as the Campanian Ignimbrite Y5 tephra, dated elsewhere by Ar/Ar to ca. 40 ka. The humic beds appear to result from the complex interplay of soil formation, spring deposition, slope action, and other processes. Several horizons buried in the lower part of Unit 2 contain Upper Paleolithic assemblages. The springs and seeps, which are still present in the area today, emanated from the bedrock valley wall. Their presence may account for the unusually high concentration of Upper Paleolithic sites in this part of the central East European Plain. Unit 3, < 30 ka, contains redeposited loess with a buried soil (Gmelin Soil) overlain by a primary full-glacial loess with an associated Chernozem (Mollisol), forming the surface of the second terrace. © 2007 Wiley Periodicals, Inc. [source] Late Wisconsinan Port Eliza Cave deposits and their implications for human coastal migration, Vancouver Island, CanadaGEOARCHAEOLOGY: AN INTERNATIONAL JOURNAL, Issue 4 2006M. Al-Suwaidi Sediments of Port Eliza Cave provide a record of the Last Glacial Maximum (LGM) on Vancouver Island that has important implications for human migration along the debated coastal migration route. Lithofacies changes from nonglacial diamict to glacial laminated silt and clay and till, then a return to nonglacial conditions with oxidized clay, colluvial block beds, and speleothems, along with radiocarbon and U/Th dates, define glacial,nonglacial transitions. Scanning electron microscope studies and clay mineralogy confirm that the laminated fines represent glaciation. Preglacial faunal evidence shows a diverse range from small species, including birds, fish, vole, and marmot, to larger species, such as mountain goat. Pollen data from the same unit show a cold, dry tundra environment with sparse trees. Deglaciation occurred prior to an age of 12.3 ka B.P. based on dated mountain goat bone. These data support the viability of the coastal migration route for humans prior to ,16 ka B.P. and then as early as ,13 ka B.P. © 2006 Wiley Periodicals, Inc. [source] Depositional history and evolution of the Paso del Indio site, Vega Baja, Puerto RicoGEOARCHAEOLOGY: AN INTERNATIONAL JOURNAL, Issue 6 2003Jeffrey J. Clark Potshards discovered during excavation of bridge pilasters for a major expressway over the Rio Indio floodplain, a stream incised within the karsts of north-central Puerto Rico, required large-scale archaeological excavation. Five-meter-deep bridge pilaster excavations in the alluvial valley provide a 4500-year history of deposition. Stratigraphic analysis of the exposed pilaster walls in combination with textural and organic carbon analyses of sediment cores obtained over a much broader area suggest a fluvial system dominated by overbank deposition. Six sequences of alternating light and dark layers of sediment were identified. The darker layers are largely composed of silts and clays, whereas the lighter layers are rich in sand-sized sediment. Archaeological evidence indicates the organic-rich dark layers, believed to be buried A horizons, coincide with pre-historic occupation by Cedrosan Saladoid, Elenan Ostionoid, and Chican Ostionoid, extending from A.D. 450 to A.D. 1500. Lighter layers below the dark soil horizons are interpreted as overbank deposits from large magnitude flood events. The floodplain aggraded discontinuously with rapid deposition of sand followed by gradual accumulation of silt, clay, and organic material. An approximately 1-m-thick layer of coarse sand and gravel halfway up the stratigraphic column represents an episode of more frequent and severe floods. Based on radiocarbon ages, this layer aggraded between A.D. 1000 and A.D. 1100, which is well within the Elenan Ostionoid era (A.D. 900,1200). Rates of sedimentation during this period were approximately 8 mm per year, ten times greater than the estimates of sedimentation rates before and after this flood sequence. The cause for the change in deposition is unknown. Nonetheless the Elenan Ostionoid would have had to endure frequent loss of habitation structures and crops during these events. © 2003 Wiley Periodicals, Inc. [source] Deltas in the Abisko area, northern Sweden: the Abiskojokka delta in lake TorneträskGEOGRAFISKA ANNALER SERIES A: PHYSICAL GEOGRAPHY, Issue 3-4 2002Hans Andrén Several small river deltas are found within the Abisko area. This study deals with the Abiskojokka delta in Lake Torneträsk. The aim is to describe the recent delta and its morphological development since the middle 1960s. In the apex of the delta, bars consist of boulders and cobbles while the mouth,bars are built by pebbles, gravel and to some extent sand. Birch vegetation is found on the sandy levées while willows and sedges dominate the interlevée basins. Mouth bars close to the lake generally lack vegetation. A comparison of the map in the present study with a map from 1965 shows comparatively small changes since 1964. Similar results are achieved when comparing aerial photographs from 1959 and 2000. Thus, the growth of the Abiskojokka delta is rather small compared to several other deltas in the Scandinavian mountains. This low growth rate is a result of upstream lakes trapping the major part of the fluvial sediments. Therefore, most of the delta sediment is redistributed old glaciofluvial material from the terraces within the Abiskojokka valley. Some material might also emanate from the Abiskojokka canyon. Formation of the main part of the delta is probably associated with the lowering of the Torneträsk ice,lakes, during and after the deglaciation of the region. Although some extreme rainstorm events have occurred in the area during recent decades, the effects of these on the delta are small. The result of such events is, however, visible as deposition of sand and silt on the levées after flooding. On the other hand, the shoreline and the mouth bars are continuously changing due to rather high wave energy especially during northerly winds. Along several mouth bars, spits are formed and reformed due to wave action. Minor changes of, and within, the two main distributaries have also been noticed, especially as bank erosion and redistribution of bars. The project will continue with a survey of the distal slope (foreset slope) of the delta as well as a study (including X,ray radiography) of the bottom sediments in Lake Torneträsk close to the delta front. The upstream deltas within this drainage basin as well as other deltas within the Torneträsk region will be studied. [source] Late-glacial remains of woolly mammoth (Mammuthus primigenius) from Shropshire, UK: stratigraphy, sedimentology and geochronology of the Condover siteGEOLOGICAL JOURNAL, Issue 4 2009J. D. Scourse Abstract In 1986 remains of an adult woolly mammoth, Mammuthus primigenius (Blumenbach), were discovered at Norton Farm Pit, Condover, south of Shrewsbury, UK. Preliminary stratigraphical investigations indicated that this individual dated to the Devensian Late-glacial Interstadial, then the first evidence for survival of mammoth in Britain following the Last Glacial Maximum. Initial radiocarbon analysis confirmed this interpretation. Subsequent excavations in 1987/1988 recovered the remains of a further three juvenile mammoth individuals. All of these remains were found in the spoil heaps of overburden (ex situ) and their true stratigraphical context had to be reconstructed from the remnants surviving in the Pit. The 1987/1988 excavations enabled stratigraphical investigation of the site and submission of samples for radiocarbon (14C) dating, including the use of ultrafiltration pretreatment for bone samples, with the aims of reconstructing the geological and palaeoenvironmental evolution of the site and the sedimentary context of the unstratified mammoth remains. These results are presented here. This investigation indicates that the woolly mammoth remains at Condover derive from a dead-ice landscape dominated by eskers, kames and kettle-hole basins, and that the sedimentary sequence in which the mammoth remains were found forms the infilling of a kettle-hole basin. The sedimentary infilling and formation of the kettle-hole basin through ice block melt-induced subsidence were syngenetic. 14C determinations indicate that basin infill was initiated prior to Greenland Interstadial 1, and probably in Greenland Stadial 2 i.e. before 14.7,ka BP and that it continued until the early Holocene, around 8,ka BP. The sedimentological and 14C data indicate that the unstratified mammoth remains can be attributed to a dark grey clayey sandy silt (Unit C1), which accumulated during the earlier part of Greenland Interstadial 1 (14 to 14.5,ka BP) within an actively subsiding slow-flowing, beaded, fluvial network characterized by channels and pools/lakes, and with relatively shallow marginal slopes. The sedimentary architecture indicates survival of the buried ice block into Greenland Interstadial 1 and final melting only towards the end of the Interstadial at ca. 12.65,ka BP. Copyright © 2009 John Wiley & Sons, Ltd. [source] Palaeoenvironmental context of the Late-glacial woolly mammoth (Mammuthus primigenius) discoveries at Condover, Shropshire, UKGEOLOGICAL JOURNAL, Issue 4 2009J. R. M. Allen Abstract In 1986/1987 the remains of several mammoths, Mammuthus primigenius (Blumenbach), were discovered on the spoil heap of an actively working gravel pit at Condover, Shropshire, England. The discovery of the remains posed two questions that could be addressed by analyses of biological proxies. First, as none of the bones was found in situ it was necessary to confirm the stratum in which the remains occurred. Second, what was the environment in which these animals lived and died? A range of biological indicators was used to address these questions, including pollen, spore and algal, plant macrofossil, invertebrate, anuran and biological mineral analyses. Multivariate statistical analyses of palynological and Pediastrum data, along with evidence from the Coleopteran assemblages, support the attribution of the mammoth bones to a unit of dark grey clayey sandy silt, although they may have lived at the time of the overlying green detritus mud. The palaeobiological data supports the correlation of these sediments to the Devensian Late-glacial. The mammoths entered this basin at the start of the Late-glacial Interstadial (Greenland Interstadial 1e) (ca. 14,830,3930 cal. year BP; 12,300,±,110 14C year BP) and became mired in soft cohesive sediments. Palaeotemperature reconstructions, based on the Coleopteran assemblages, from the time when the mammoths actually became mired, show that the climate was temperate with mean July temperatures between 15 and 19°C and mean January temperatures between ,13 and +6°C. Biological indicators from the sediments encasing the mammoths indicate that the landscape surrounding the basin was treeless and dry, contrasting with rich vegetation within the basin itself that had possibly attracted the mammoths to the site. Evidence of sedimentary disturbance suggests that the mammoths caused large-scale bioturbation of the deposits making palaeoenvironmental interpretations difficult. Fossils of terrestrial blowflies, carcass and dung beetles show that some of the decaying corpses must have lain exposed on the land surface for sufficient time for the soft parts to have rotted away and skin and bones to have become desiccated before many of them sank into the dark grey clayey sandy silt. Copyright © 2009 John Wiley & Sons, Ltd. [source] Sequestration and turnover of plant- and microbially derived sugars in a temperate grassland soil during 7 years exposed to elevated atmospheric pCO2GLOBAL CHANGE BIOLOGY, Issue 2 2007MICHAEL BOCK Abstract Temperate grasslands contribute about 20% to the global terrestrial carbon (C) budget with sugars contributing 10,50% to this soil C pool. Whether the observed increase of the atmospheric CO2 concentration (pCO2) leads to additional C sequestration into these ecosystems or enhanced mineralization of soil organic matter (SOM) is still unclear. Therefore, the aim of the presented study was to investigate the impact of elevated atmospheric pCO2 on C sequestration and turnover of plant- (arabinose and xylose) and microbially derived (fucose, rhamnose, galactose, mannose) sugars in soil, representing a labile SOM pool. The study was carried out at the Swiss Free Air Carbon Dioxide Enrichment (FACE) experiment near Zurich. For 7 years, Lolium perenne swards were exposed to ambient and elevated pCO2 (36 and 60 Pa, respectively). The additional CO2 in the FACE plots was depleted in 13C compared with ambient plots, so that ,new' (<7 years) C inputs could be determined by means of compound-specific stable isotope analysis (13C : 12C). Samples were fractionated into clay, silt, fine sand and coarse sand, which yielded relatively stable and labile SOM pools with different turnover rates. Total sugar sequestration into bulk soil after 7 years of exposure to elevated pCO2 was about 28% compared with the control plots. In both ambient and elevated plots, total sugar concentrations in particle size fractions increased in the order sand<silt A Case Study of Soil-Gas Sampling in Silt and Clay-Rich (Low-Permeability) SoilsGROUND WATER MONITORING & REMEDIATION, Issue 1 2009Todd A. McAlary Soil-gas sampling and analysis is a common tool used in vapor intrusion assessments; however, sample collection becomes more difficult in fine-grained, low-permeability soils because of limitations on the flow rate that can be sustained during purging and sampling. This affects the time required to extract sufficient volume to satisfy purging and sampling requirements. The soil-gas probe tubing or pipe and sandpack around the probe screen should generally be purged prior to sampling. After purging, additional soil gas must be extracted for chemical analysis, which may include field screening, laboratory analysis, occasional duplicate samples, or analysis for more than one analytical method (e.g., volatile organic compounds and semivolatile organic compounds). At present, most regulatory guidance documents do not distinguish between soil-gas sampling methods that are appropriate for high- or low-permeability soils. This paper discusses permeability influences on soil-gas sample collection and reports data from a case study involving soil-gas sampling from silt and clay-rich soils with moderate to extremely low gas permeability to identify a sampling approach that yields reproducible samples with data quality appropriate for vapor intrusion investigations for a wide range of gas-permeability conditions. [source] Treatment of a Chromate-Contaminated Soil Site by in situ Gaseous ReductionGROUND WATER MONITORING & REMEDIATION, Issue 1 2007E.C Thornton A proof-of-concept field test for the treatment of hexavalent chromium in the vadose zone using in situ gaseous reduction was successfully completed by the U.S. Department of Energy and U.S. Department of Defense in a joint demonstration conducted at White Sands Missile Range, New Mexico. The test involved injecting hydrogen sulfide, diluted in air, into contaminated vadose zone sediment to reduce Cr(VI) to Cr(III). The gaseous mixture was injected directly into the contaminated sediment through a central injection well and vacuum extracted through the flow field with six boreholes at the site periphery over a 76-d period. Comparison of soil samples taken before and after the test indicated 70% of the total mass of hexavalent chromium originally present at the site was reduced and immobilized. The zone of highest contamination was nearly completely treated, with average Cr(VI) concentrations decreasing in this interval from an average of 8.1 mg/kg before treatment to 1.1 mg/kg after treatment. Treatment was best in higher permeability clean gypsum sands and less effective in zones containing greater amounts of silt and clay and a slightly higher iron content. All hexavalent chromium concentrations measured in the posttest samples, however, were well below the remedial goal and regulatory limit of 30 mg/kg. In addition, the field test demonstrated that vadose zone treatment of contamination can be safely conducted using diluted hydrogen sulfide gas mixtures. Ongoing development of the technology is being directed toward addressing the limitations of gaseous treatment arising from variations in sediment permeability and iron content and assessing the relationship between hydrogen sulfide consumption and reaction kinetics. [source]
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