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Situ Growth (situ + growth)
Selected AbstractsIn Situ Growth of Mesoporous SnO2 on Multiwalled Carbon Nanotubes: A Novel Composite with Porous-Tube Structure as Anode for Lithium Batteries,ADVANCED FUNCTIONAL MATERIALS, Issue 15 2007Z. Wen Abstract A novel mesoporous-nanotube hybrid composite, namely mesoporous tin dioxide (SnO2) overlaying on the surface of multiwalled carbon nanotubes (MWCNTs), was prepared by a simple method that included in situ growth of mesoporous SnO2 on the surface of MWCNTs through hydrothermal method utilizing Cetyltrimethylammonium bromide (CTAB) as structure-directing agents. Nitrogen adsorption,desorption, X-ray diffraction and transmission electron microscopy analysis techniques were used to characterize the samples. It was observed that a thin layer tetragonal SnO2 with a disordered porous was embedded on the surface of MWCNTs, which resulted in the formation of a novel mesoporous-nanotube hybrid composite. On the base of TEM analysis of products from controlled experiment, a possible mechanism was proposed to explain the formation of the mesoporous-nanotube structure. The electrochemical properties of the samples as anode materials for lithium batteries were studied by cyclic voltammograms and Galvanostatic method. Results showed that the mesoporous-tube hybrid composites displayed higher capacity and better cycle performance in comparison with the mesoporous tin dioxide. It was concluded that such a large improvement of electrochemical performance within the hybrid composites may in general be related to mesoporous-tube structure that possess properties such as one-dimensional hollow structure, high-strength with flexibility, excellent electric conductivity and large surface area. [source] Crystal Growth of the Metal,Organic Framework Cu3(BTC)2 on the Surface of Pulp FibersADVANCED ENGINEERING MATERIALS, Issue 1-2 2009Pia Küsgens In situ growth of highly porous metal,organic frameworks (MOFs) in the presence of pulp fibers results in high surface area MOF/textile composites. Such a carrier concept is indispensable for any industrial application of MOFs. [source] In Situ Growth of Mesoporous SnO2 on Multiwalled Carbon Nanotubes: A Novel Composite with Porous-Tube Structure as Anode for Lithium Batteries,ADVANCED FUNCTIONAL MATERIALS, Issue 15 2007Z. Wen Abstract A novel mesoporous-nanotube hybrid composite, namely mesoporous tin dioxide (SnO2) overlaying on the surface of multiwalled carbon nanotubes (MWCNTs), was prepared by a simple method that included in situ growth of mesoporous SnO2 on the surface of MWCNTs through hydrothermal method utilizing Cetyltrimethylammonium bromide (CTAB) as structure-directing agents. Nitrogen adsorption,desorption, X-ray diffraction and transmission electron microscopy analysis techniques were used to characterize the samples. It was observed that a thin layer tetragonal SnO2 with a disordered porous was embedded on the surface of MWCNTs, which resulted in the formation of a novel mesoporous-nanotube hybrid composite. On the base of TEM analysis of products from controlled experiment, a possible mechanism was proposed to explain the formation of the mesoporous-nanotube structure. The electrochemical properties of the samples as anode materials for lithium batteries were studied by cyclic voltammograms and Galvanostatic method. Results showed that the mesoporous-tube hybrid composites displayed higher capacity and better cycle performance in comparison with the mesoporous tin dioxide. It was concluded that such a large improvement of electrochemical performance within the hybrid composites may in general be related to mesoporous-tube structure that possess properties such as one-dimensional hollow structure, high-strength with flexibility, excellent electric conductivity and large surface area. [source] Energy-Absorbing Hybrid Composites Based on Alternate Carbon-Nanotube and Inorganic LayersADVANCED MATERIALS, Issue 28 2009Qiang Zhang Hybrid materials with aligned carbon nanotubes intercalating naturally layered compounds (see upper figures) are fabricated using general metal-ion intercalation and in situ growth. As indicated by SEM images (lower figures), they exhibit periodic and hierarchical structures. The ability to control their composition resulted in some samples possessing excellent mechanical properties, such as high energy absorption during compression. [source] Hybrid ZnAl-LDH/CNTs nanocomposites: Noncovalent assembly and enhanced photodegradation performanceAICHE JOURNAL, Issue 3 2010Hui Wang Abstract In this article, we reported a facile and effective strategy for assembling hybrid ZnAl-layered double hydroxide/carbon nanotubes (ZnAl-LDH/CNTs) nanocomposites through noncovalent bonds, for the first time, in the presence of L -cysteine molecules. The materials have been characterized by powder X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM), thermogravimetry and differential scanning calorimetry (TG-DSC), X-ray photoelectron spectra (XPS) and specific surface area measurement. The results indicate that L -cysteine as bridging linker plays a key role for enhancing both adhesion and dispersion of LDH nanocrystallites onto the surface of CNTs matrix through the interfacial interaction, and effectively inhibits the in situ growth of LDH crystallites, thus resulting in remarkably reduced LDH crystallite sizes; the Eu(III) fluorescence quenching in intercalated-Eu(III)complex LDH/CNTs nanocomposite can occur because of the interaction between LDH crystallites and CNTs matrix. Furthermore, it is found that as-assembled hybrid LDH/CNTs nanocomposites exhibit excellent performance for photodegradation of methyl orange molecules under UV irradiation, which is closely related to the unique hybrid nanostructure and composition of composites. © 2009 American Institute of Chemical Engineers AIChE J, 2010 [source] Raman scattering probe of anharmonic effects in NiSiJOURNAL OF RAMAN SPECTROSCOPY, Issue 7 2004S. K. Donthu Abstract We report a systematic temperature-dependent Raman scattering study of NiSi thin films. In agreement with the basic anharmonic theory, the strong Raman peak from NiSi at about 214 cm,1 shows phonon softening and broadening with an increase in the sample temperature. Comparative study of the temperature dependence of this first-order Raman peak from NiSi powder and the film show that NiSi layers of thickness 15,90 nm are under tensile thermal stress. The results also show that the total phonon shift observed in the temperature range 80,500 K is independent of the silicide film thickness. We have also shown that Raman spectroscopy is a faster and more sensitive technique than x-ray diffraction for phase identification in NiSi nanolayers, hence Raman scattering can be used as a valuable tool for in situ growth and process monitoring of nickel silicides. Copyright © 2004 John Wiley & Sons, Ltd. [source] | |||||||||||||