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Situ Chemical Reduction (situ + chemical_reduction)

Distribution by Scientific Domains

Polymers and Materials Science	40%

Selected Abstracts

Structural Evolution and Copper-Ion Release Behavior of Cu-pHEMA Hybrids Synthesized In Situ,

ADVANCED ENGINEERING MATERIALS, Issue 11 2009
Yen-Yu Liu
Abstract A novel Cu-pHEMA hybrid was successfully prepared by in situ photopolymerization of 2-hydroxyethyl methacrylate (HEMA) monomer in the presence of Cu(II) copper ions, following an in situ chemical reduction. Experimental observations indicate that intermolecular interactions such as the coupling force and hydrogen bonding between the Cu and the hydroxyl groups further stabilize the hybrid structure to a considerable extent. Localization of the metallic copper particles within the pHEMA network structure as a result of those intermolecular interactions gives rise to the formation of discretely distributed nanocrystallites with particle sizes ranging from 5 to 25,nm in diameter. A crystallographic change of the Cu nanophase from an amorphous-like to a crystalline structure is observed as the H2O:HEMA molar ratio increases, upon synthesis, accompanied with an increase in the particle size. A relatively slow and sustained release of the Cu (in the form of cupric ions) from the hybrids was measured for a time period of about 10 days, which also illustrates a Cu(II)-induced proliferation of the endothelial cells over a relatively small range of release rate of the Cu from the hybrids. Such a new type of Cu-loaded hybrid hydrogel is expected to be compatible and may be considered as a candidate biomaterial for biomedical/therapeutic uses. [source]

A Transparent, Flexible, Low-Temperature, and Solution-Processible Graphene Composite Electrode

ADVANCED FUNCTIONAL MATERIALS, Issue 17 2010
Haixin Chang
Abstract The synthesis and preparation of a new type of graphene composite material suitable for spin-coating into conductive, transparent, and flexible thin film electrodes in ambient conditions is reported here for the first time. Solution-processible graphene with diameter up to 50 ,m is synthesized by surfactant-assisted exfoliation of graphite oxide and in situ chemical reduction in a large quantity. Spin-coating the mixing solution of surfactant-functionalized graphene and PEDOT:PSS yields the graphene composite electrode (GCE) without the need for high temperature annealing, chemical vapor deposition, or any additional transfer-printing process. The conductivity and transparency of GCE are at the same level as those of an indium tin oxide (ITO) electrode. Importantly, it exhibits high stability (both mechanical and electrical) in bending tests of at least 1000 cycles. The performance of organic light-emitting diodes based on a GCE anode is comparable, if not superior, to that of OLEDs made with an ITO anode. [source]

In situ remediation of PCE at a site with clayey lithology and a significant smear zone

REMEDIATION, Issue 3 2010
Josephine Molin
Groundwater at the former Serry's Dry Cleaning site in Corvallis, Oregon, was impacted by chlorinated volatile organic compounds (CVOCs). The primary CVOCs impacting the site include tetrachloroethene, trichloroethene, dichloroethene, and vinyl chloride, which were detected at concentrations up to 22,000, 1,700, 3,100, and 7 ,g/L, respectively, prior to treatment. Large seasonal fluctuations in groundwater CVOC concentrations indicated that a significant fraction of the CVOC mass was present in the smear zone. Field-scale pilot tests were performed for the Oregon Department of Environmental Quality's Dry Cleaner Program to evaluate the performance of EHC® in situ chemical reduction (ISCR) technology. The pilot study involved evaluating field performance and physical distribution into low-permeability soil using basic Geoprobe® injection tooling. The testing results confirmed that bioremediation enhanced by ISCR supported long-term treatment at the site. This article describes the implementation and results of the tests. Performance data are available from a three-year period following the injections, allowing for a discussion about sustained performance and reagent longevity. © 2010 Wiley Periodicals, Inc. [source]

Successful ISCR-enhanced bioremediation of a TCE DNAPL source utilizing EHC® and KB-1®

REMEDIATION, Issue 3 2010
James G. D. Peale
Remediation of chlorinated solvent DNAPL sites often meets with mixed results. This can be attributed to the diametrically opposed nature of the impacts, where the disparate dissolved-phase plume is more manageable than the localized, high-concentration source area. A wide range of technologies are available for downgradient plume management, but the relative mass of contaminants in a DNAPL source area generally requires treatment for such technologies to be effective over the long term. In many cases, the characteristics of DNAPL source zones (e.g., depth, soil heterogeneity, structural limitations) limit the available options. The following describes the successful full-scale implementation of in situ chemical reduction (ISCR) enhanced bioremediation of a TCE DNAPL source zone. In this demonstration, concentrations of TCE were rapidly reduced to below the maximum contaminant level (MCL) in less than six months following implementation. The results described herein suggest that ISCR-enhanced bioremediation is a viable remedial alternative for chlorinated solvent source zones. © 2010 Wiley Periodicals, Inc. [source]

TCE plume remediation via ISCR-enhanced bioremediation utilizing EHC® and KB-1®

REMEDIATION, Issue 4 2008
James G. D. Peale
Groundwater below an operating manufacturing facility in Portland, Oregon, was impacted by chlorinated volatile organic compounds (CVOCs), with concentrations indicative of a dense, nonaqueous-phase liquid (DNAPL) release. The downgradient plume stretched under the adjacent Willamette River, intersecting zones of legacy impacts from a former manufactured gas plant (MGP). An evaluation of source-area and downgradient plume treatment remedies identified in situ bioremediation as most likely to be effective for the CVOC plume, while leaving the legacy impacts for other responsible parties. With multiple commercially available products to choose from, the team developed and implemented a bench test to identify the most appropriate technology, which was further evaluated in a field pilot study. The results of the testing demonstrated conclusively that bioremediation enhanced by in situ chemical reduction (ISCR) using EHC® and KB-1® was most appropriate for this site, providing outstanding results. The following describes the implementation and results of the tests. © 2008 Wiley Periodicals, Inc. [source]