SiO2 Glass (sio2 + glass)

Distribution by Scientific Domains


Selected Abstracts


Effect of Neodymium:Yttrium Aluminum Garnet Laser Irradiation on Crystallization in Li2O,Al2O3,SiO2 Glass

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 10 2001
Yong Su Lee
A 355-nm neodymium:yttrium aluminum garnet laser, produced by a harmonic generator, was used for the nucleation process in photosensitive glass containing Ag+ and Ce3+ ions. The pulse width and frequency of the laser were 8 ns and 10 Hz, respectively. Heat treatment was conducted at 570°C for 1 h, following laser irradiation, to produce crystalline growth, after which a LiAlSi3O8 crystal phase appeared in the laser-irradiated Li2O,Al2O3,SiO2 glass. The present study compares the effect of laser-induced nucleation on glass crystallization with that of spontaneous nucleation by heat treatment. [source]


Study of Inductive Coupled Hydrogen and Argon Plasma Interaction with SiO2 Glass

PLASMA PROCESSES AND POLYMERS, Issue S1 2009
Atis Skudra
Abstract This work is devoted to the diagnostics of interaction between hydrogen and argon with the surface of SiO2 glass walls. For diagnostics of the interaction, special high-frequency electrodeless light sources were prepared, filled with pure argon of 1,Torr or argon-hydrogen of total pressure of 1,Torr (Ar/H2 mixing ratio is 9:1). Besides the mostly used spherical and cylindrical lamps, dumbbell type lamps have also been investigated. The spectroscopic and AFM measurements showed that in comparison with pure argon plasma, the argon-hydrogen plasma causes non-uniform changes of the SiO2 surface. For these modifications active OH are primarily responsible molecules, created in the reactions of hydrogen molecules with oxygen molecules, adsorbed from the walls. [source]


High-Strength Porous Silicon Carbide Ceramics by an Oxidation-Bonding Technique

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 11 2002
Jihong She
Porous silicon carbide (SiC) ceramics were fabricated by an oxidation-bonding process in which the powder compacts are heated in air so that SiC particles are bonded to each other by oxidation-derived SiO2 glass. Because of the crystallization of amorphous SiO2 glass into cristobalite during sintering, the fracture strength of oxidation-bonded SiC ceramics can be retained to a relatively high level at elevated temperatures. It has been shown that the mechanical strength is strongly affected by particle size. When 0.6 ,m SiC powders were used, a high strength of 185 MPa was achieved at a porosity of ,31%. Moreover, oxidation-bonded SiC ceramics were observed to exhibit an excellent oxidation resistance. [source]


Grain-Boundary Viscosity of Preoxidized and Nitrogen-Annealed Silicon Carbides

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 10 2001
Giuseppe Pezzotti
Internal friction experiments were conducted on a model SiC polycrystal prepared from preoxidized (high-purity) SiC powder. This material contained high-purity SiO2 glass at grain boundaries in addition to a free-carbon phase, which was completely removed upon powder preoxidation. Comparative tests were conducted on a SiC polycrystal, obtained from the as-received SiC powder with the addition of 2.5 vol% of high-purity SiO2. This latter SiC material was also investigated after annealing at 1900°C for 3 h in a nitrogen atmosphere. Electron microscopy observations revealed a glass-wetted interface structure in SiC polycrystals prepared from both as-received and preoxidized powders. However, the former material also showed a large fraction of interfaces coated by turbostratic graphite. Upon high-temperature annealing in nitrogen, partial glass dewetting occurred, and voids were systematically observed at multigrain junctions. The actual presence of nitrogen could only be detected in a limited number of wetted interfaces. A common feature in the internal friction behavior of the preoxidized, SiO2 -added and nitrogen-annealed SiC was a relaxation peak that resulted from grain-boundary sliding. Frequency-shift analysis revealed markedly different characteristics for this peak: both the magnitude of the intergranular glass viscosity and the activation energy for grain-boundary viscous flow were much higher in the nitrogen-annealed material. Results of torsional creep tests were consistent with these findings, with nitrogen-annealed SiC being the most creep resistant among the tested materials. [source]


Effect of Neodymium:Yttrium Aluminum Garnet Laser Irradiation on Crystallization in Li2O,Al2O3,SiO2 Glass

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 10 2001
Yong Su Lee
A 355-nm neodymium:yttrium aluminum garnet laser, produced by a harmonic generator, was used for the nucleation process in photosensitive glass containing Ag+ and Ce3+ ions. The pulse width and frequency of the laser were 8 ns and 10 Hz, respectively. Heat treatment was conducted at 570°C for 1 h, following laser irradiation, to produce crystalline growth, after which a LiAlSi3O8 crystal phase appeared in the laser-irradiated Li2O,Al2O3,SiO2 glass. The present study compares the effect of laser-induced nucleation on glass crystallization with that of spontaneous nucleation by heat treatment. [source]