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Shape Memory Effect (shape + memory_effect)
Selected AbstractsShape Memory Effect of Bacterial Poly[(3-hydroxybutyrate)- co -(3-hydroxyvalerate)],MACROMOLECULAR RAPID COMMUNICATIONS, Issue 13 2005Young Baek Kim Abstract Summary: A bacterial poly[(3-hydroxybutyrate)- co -(3-hydroxyvalerate)] biosynthesized by Pseudomonas sp. HJ-2 was found to be a shape memory polymer. Permanent shapes were set by annealing at room temperature the samples that had been pre-treated above 95,°C in specified shapes. The temporary shapes were set by stretching and holding the elongated samples. Thermal shrinkage began at 45,°C and stopped at 75,°C to recover to their permanent shapes. Apparently, the orientation induced the formation of hard segments that were responsible for setting the temporary shapes. The shape memory effect of this polymer was explained based on the DSC and XRD results at different phases. The recovery of a coil shape upon heating a strip of HJ-2 PHB35V, demonstrating the polymers shape memory effect. [source] Shape memory effect of poly(methylene-1,3-cyclopentane) and its copolymer with polyethylenePOLYMER INTERNATIONAL, Issue 4 2002Han Mo Jeong Abstract Poly(methylene-1,3-cyclopentane) (PMCP) cyclopolymerized from 1,5-hexadiene by metallocene catalyst, rac -(ethylenebis(1-indenyl))Zr(N(CH3)2)2 is partially crystalline and has a value of elongation at break of more than 400% in the temperature range 25,85,°C. The shape memory effect of PMCP with moderate molecular weight is enhanced by sequentially polymerized polyethylene segments, the crystalline phase of which seems to strengthen the fixed structure which memorizes the original shape. The glass transition temperature or melting temperature of PMCP can be selectively used as shape recovery temperature when an appropriate deformation temperature is chosen. © 2002 Society of Chemical Industry [source] Phase transformation behaviour and bending properties of hybrid nickel,titanium rotary endodontic instrumentsINTERNATIONAL ENDODONTIC JOURNAL, Issue 4 2007Y. Hayashi Abstract Aim, To investigate the bending properties of hybrid rotary nickel,titanium endodontic instruments in relation to their transformation behaviour. Methodology, Four types of nickel,titanium rotary endodontic instruments with different cross-sectional shapes (triangular-based and rectangular-based) and different heat treatment conditions (super-elastic type and hybrid type with shape memory effect) were selected to investigate bending properties and phase transformation behaviour. Bending load of the instruments was measured in a cantilever-bending test at 37 °C with the maximum deflection of 3.0 mm. A commercial rotary instrument, ProFile (PF; Dentsply Maillefer, Ballaigues, Switzerland) was used as a reference for the bending test. Phase transformation temperatures were calculated from the diagrams obtained from differential scanning calorimetry. Data were analysed by anova and Scheffe's test. Results, The bending load values of the hybrid type that had undergone additional heat treatment at the tip were significantly lower (P < 0.05) than those of the super-elastic type with no additional heat treatment. The bending load values of rectangular-based cross-sectional shaped instruments were significantly lower (P < 0.05) than those of triangular-based cross-sectional shaped instruments. Phase transformation temperatures (Ms and Af points) of the hybrid type were significantly higher (P < 0.05) than the super-elastic type. The Mf and As points of the tip part were significantly higher (P < 0.05) than those of the whole part of the hybrid instrument. Conclusions, Additional heat treatment of hybrid nickel,titanium instruments may be effective in increasing the flexibility of nickel,titanium rotary instruments. [source] Improvements and algorithmical considerations on a recent three-dimensional model describing stress-induced solid phase transformationsINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN ENGINEERING, Issue 11 2002Ferdinando Auricchio Abstract During mechanical loading,unloading cycles shape-memory alloys (SMA) are able to undergo large deformations without showing residual strains (pseudoelasticity) or recovering them through thermal cycles (shape memory effect). Motivated by stress-induced solid phase transformations, these unique behaviours induce the SMA exploitation in innovative and commercially valuable applications, stimulating, consequently, the interest in the development of constitutive models. Also if many models are now available in the literature, effective three-dimensional proposals are still few and limited in several aspects. In this paper, a three-dimensional thermomechanical model recently proposed by Souza et al. (European Journal of Mechanics,A/Solids, 1998; 17: 789,806.) is taken into consideration; such a model is of particular interest for its effectiveness and flexibility, but it also shows some limitations and missing links in the algorithmical counterparts. This work discusses some improvements to the original model as well as the development and the implementation of a robust integration algorithm to be adopted in a numerical scheme, such as a finite-element framework. Copyright © 2002 John Wiley & Sons, Ltd. [source] Celite-mediated linking of polyurethane block copolymers and the impact on the shape memory effectJOURNAL OF APPLIED POLYMER SCIENCE, Issue 6 2010Yong-Chan Chung Abstract Celite, a porous inorganic material with enormous surface area and hydroxyl groups on the surface, was used as a cross-linker of polyurethane (PU) copolymer chains to improve its shape memory and mechanical properties. PU copolymers with different Celite contents were prepared and characterized by IR, DSC, and universal testing machine. The glass transition temperature of PU copolymers was maintained around 20°C independent of Celite content. The shape memory and mechanical properties were dependent on when Celite was added during the polymerization reaction. The reaction in which Celite was added at the middle stage of polymerization showed the best shape memory and mechanical properties. The best shape recovery of PU was found at 0.3 wt % Celite and increased to 97% even after the third cycle. Likewise, the shape retention also maintained a remarkable 86% after three cycles. The reasons underlining the high shape recovery and shape retention by adopting Celite as a cross-linker are discussed in this article. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 [source] Effect of glucose crosslinking on thermomechanical properties and shape memory effect of PET-PEG copolymersJOURNAL OF APPLIED POLYMER SCIENCE, Issue 6 2008Yong-Chan Chung Abstract Poly(ethylene terephthalate) (PET) and poly (ethylene glycol) (PEG) copolymers crosslinked with glucose as a crosslinker are prepared to improve their mechanical and shape memory properties compared to the one without crosslinking. Composition of PEG and glucose is varied to search for the one with the best mechanical and shape memory properties. The highest shape recovery rate is found in the copolymer composed of 25 mol % PEG-200 and 2.0 mol % glucose. The result that crosslinking by glucose improves the shape recovery rate and supports the high shape recovery rate under the repetitive cyclic test conditions, compared to the one without crosslinking, will be discussed in the points of the structure and shape memory mechanism. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 [source] Magnetic-Field Induced Strains in Ferromagnetic Shape Memory Alloy Ni55Mn23Ga22 Deposited by RF-Magnetron SputteringPLASMA PROCESSES AND POLYMERS, Issue S1 2009Florent Bernard Abstract 1.5,µm,Ni55Mn23Ga22 ferromagnetic thin films were deposited onto silicon substrates and silicon single beam cantilever using radio-frequency magnetron sputtering. As-deposited sample and heat-treated thin films were studied on their silicon substrates and peeled off to determine the influence of the stress. Post-heat treatment process allows at the films to achieve the shape memory effect (SME). Vibrating sample magnetometer (VSM) and deflection measurement of the sample annealed at 873,K during 36,ks exhibit ferromagnetic martensitic structure with a typical SME response to the magnetic field induced strains which match the values of the bulk material. [source] Numerical Simulation of the Application of NiTi Alloys in Medical TechnologiesPROCEEDINGS IN APPLIED MATHEMATICS & MECHANICS, Issue 1 2005Daniel Christ Shape memory alloys are nowadays already established as a material which is able to solve exceptional tasks in practical applications. Particularly, its utilization in the field of medical technologies increases steadily. For example micro tools (staple, catheters) and implants (coronary stents) are made out of Nickel-Titanium well known as a basic shape memory alloy. Apart from the advantages like the avoidance of auxiliary components and joints in the system and to utilize the high volume specific work of shape memory alloys, NiTi alloys exhibit a good biocompatibility. This property is necessary with regard to either permanent or temporary implants. To optimize the use of NiTi alloys in the scope of medical technologies, the support of the development of applicable tools by numerical simulations is highly recommended. However the complex material behaviour containing a profoundly thermomechanical coupling poses indeed a big challenge to the material modeling and its implementation into a finite element code. Particularly, the material model proposed by Helm [1] proves to be a firm model containing the most common properties of shape memory alloys, as the pseudoelasticity, the shape memory effect and the two-way effect. In the present contribution the FE modelling of a medical staple used in foot surgery is presented by considering the model of Helm which was investigated by the authors to improve its performance in the finite element method [2]. The foot staple, produced by a group of members of the SFB 459 which is funded by the DFG, avails the shape memory effect to excite the desired clamping effect [3]. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] | |||||||||||||