Secondary References (secondary + reference)

Distribution by Scientific Domains


Selected Abstracts


NMR nomenclature: Nuclear spin properties and conventions for chemical shifts (IUPAC recommendations 2001),

CONCEPTS IN MAGNETIC RESONANCE, Issue 5 2002
Robin K. Harris
Abstract A unified scale is recommended for reporting the NMR chemical shifts of all nuclei relative to the 1H resonance of tetramethylsilane. The unified scale is designed to provide a precise ratio, ,, of the resonance frequency of a given nuclide to that of the primary reference, the 1H resonance of tetramethylsilane (TMS) in dilute solution (volume fraction, , < 1%) in chloroform. Referencing procedures are discussed, including matters of practical application of the unified scale. Special attention is paid to recommended reference samples and values of , for secondary references on the unified scale are listed, many of which are the results of new measurements. Some earlier recommendations relating to the reporting of chemical shifts are endorsed. The chemical shift, ,, is redefined to avoid previous ambiguities but to leave practical usage unchanged. Relations between the unified scale and recently published recommendations for referencing in aqueous solutions (for specific use in biochemical work) are discussed, as well as the special effects of working in the solid state with magic-angle spinning. In all, nine new recommendations relating to chemical shifts are made. Standardized nuclear spin data are also presented in tabular form for the stable (and some unstable) isotopes of all elements with non-zero quantum numbers. The information given includes quantum numbers, isotopic abundances, magnetic moments, magnetogyric ratios and receptivities, together with quadrupole moments and linewidth factors (where appropriate). © 2001 IUPAC. Concepts Magn Reson 14:326,346, 2002 [source]


Clinical education facilitators: a literature review

JOURNAL OF CLINICAL NURSING, Issue 6 2005
Veronica Lambert BNS
Aims and objectives., The aim of this literature review, set within an Irish context, is to present a broad overview of former and existing clinical support personnel, explore the concept of facilitation and examine what is known about the role of the clinical education facilitator. Background., The importance of providing a supportive clinical environment to enhance clinical teaching and learning is strongly portrayed in the literature. While the past two decades have borne witness to various clinical support personnel, the literature identifies conflicting demands that these personnel face. No suggestions are advanced as to how to overcome these difficulties, which inevitably influence the quality and quantity of their clinical teaching role. An identifiable gap exists over who has prime responsibility for clinical teaching. It is timely that alternative possibilities for organizing clinical teaching are investigated. A new post emerging in practice settings is that of the clinical education facilitator who is meant to be the key linchpin in clinical areas for reducing the theory,practice gap. Method., Relevant literature for this review was sourced using the computerized databases CINAHL, Medline and Synergy. Manual searching of relevant nursing journals and sourcing of secondary references extended the search. Government reports and other relevant documents were obtained through pertinent websites. Results., Papers that explicitly examined the concept of facilitation and explored the posts of clinical education facilitators were included; six research papers were accessed and reviewed. In addition seven non-empirical papers were included. Conclusions., It is clear that considerable lack of role clarity resides over what constitutes clinical facilitation and the role of the clinical facilitator. Thus, it is paramount to strengthen this support role with Irish empirical evidence. Relevance to clinical practice., A major advantage in having a ward-based clinical education facilitator is the benefit of having access to someone who can concentrate solely on clinical education and support with attempts to narrow the theory,practice divide. [source]


Pollution and Cost in the Coke-Making Supply Chain in Shanxi Province, China

JOURNAL OF INDUSTRIAL ECOLOGY, Issue 3-4 2002
Applying an Integrated System Model to Siting, Transportation Trade-Offs
Summary An integrated system trade-off model has been developed to assess costs and pollution associated with transportation in the coke-making supply chain in Shanxi Province, China. A transportation-flow, cost-minimization solver is combined with models for calculating coke-making plant costs, estimating transportation costs from a geographic information system road and rail database, and aggregating coke-making capacity among plants. Model outputs of economic cost, nitrogen oxides (NOx) emissions, and transport distributions are visualized using an Internet-based graphic user interface. Data for the model were collected on survey trips to Shanxi Province as well as from secondary references and proxies. The modularity and extensibility of the system trade-off model facilitate introduction of new data sets in order to examine various planning scenarios. Scenarios of coke-making plant aggregation, rail infrastructure improvement, and technology transfer were evaluated using the model. Costs and pollution emissions can be reduced by enlarging coke-making plants near the rail stations and closing down other plants. Preferential minimization of transportation costs gives a lower total cost than simply minimizing plant costs. Therefore, policy makers should consider transportation costs when planning the reallocation of coke-making capacity in Shanxi Province. Increasing rail-transport capacity is less effective than aggregating plant capacity. On the other hand, transfer of low-pollution truck technology results in a large emission reduction, however, reflecting the importance of truck transportation in the Shanxi Province coke-making industry. [source]


NMR nomenclature: nuclear spin properties and conventions for chemical shifts.

MAGNETIC RESONANCE IN CHEMISTRY, Issue 7 2002
Applied Chemistry., IUPAC Recommendations 2001., International Union of Pure
Abstract An Addendum has been published for this article in Magnetic Resonance in Chemistry 40(9) 2002, 622. A unified scale is recommended for reporting the NMR chemical shifts of all nuclei relative to the 1H resonance of tetramethylsilane. The unified scale is designed to provide a precise ratio, ,, of the resonance frequency of a given nuclide to that of the primary reference, the 1H resonance of tetramethylsilane (TMS) in dilute solution (volume fraction, , < 1%) in chloroform. Referencing procedures are discussed, including matters of practical application of the unified scale. Special attention is paid to recommended reference samples, and values of , for secondary references on the unified scale are listed, many of which are the results of new measurements. Some earlier recommendations relating to the reporting of chemical shifts are endorsed. The chemical shift, ,, is redefined to avoid previous ambiguities but to leave practical usage unchanged. Relations between the unified scale and recently published recommendations for referencing in aqueous solutions (for specific use in biochemical work) are discussed, as well as the special effects of working in the solid state with magic-angle spinning. In all, nine new recommendations relating to chemical shifts are made. Standardized nuclear spin data are also presented in tabular form for the stable (and some unstable) isotopes of all elements with non-zero quantum numbers. The information given includes quantum numbers, isotopic abundances, magnetic moments, magnetogyric ratios and receptivities, together with quadrupole moments and linewidth factors (where appropriate). Copyright 2001 IUPAC. Reprinted with permission from Pure Appl. Chem. 2001; 73: 1795. [source]


Drug effects on salivary glands: dry mouth

ORAL DISEASES, Issue 4 2003
C Scully CBE
Objective: To identify drugs associated with the complaint of dry mouth. Materials and Methods: MEDLINE was searched for papers 1980,2002 using keywords, oral, mouth, salivary, drugs, dry mouth and xerostomia, and relevant secondary references were hand-searched. Results: Evidence was forthcoming for a number of xerogenic drugs, especially antimuscarinic agents, some sympathomimetic agents, and agents affecting serotonin and noradrenaline uptake, as well as a miscellany of other drugs such as appetite suppressants, protease inhibitors and cytokines. Conclusion: Dry mouth has a variety of possible causes but drugs , especially those with anticholinergic activity against the M3 muscarinic receptor , are the most common cause of reduced salivation. [source]