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Reference Temperature (reference + temperature)
Selected AbstractsEffect of temperature on water retention phenomena in deformable soils: theoretical and experimental aspectsEUROPEAN JOURNAL OF SOIL SCIENCE, Issue 1 2010S. Salager In this paper, a theoretical and experimental investigation of the effect of temperature on water retention phenomena in deformable soils is presented. A general law expressing the change in suction with water content, temperature and void ratio is proposed theoretically. This law accounts for the influence of density and temperature on water retention. It also provides a general framework which appears to be well-adapted to describe many particular cases. The effect of temperature is studied through a predictive relationship which is established in this framework. This relationship allows us to obtain the water retention curve at any temperature from that at a reference temperature, thus reducing strongly the number of tests required to characterize the thermo-hydraulic behaviour of a soil. The relevance of this relationship was experimentally verified from new tests as well as the results previously reported in the literature. The new tests were performed on two model media, namely, a terracotta ceramic and a clayey-silty sand. The tests taken from the literature concerned two different clays. Comparison between theoretical prediction and experimental data was particularly promising and shows the capability of the model to cover a wide range of soils. [source] An optimized kinetics model for OH chemiluminescence at high temperatures and atmospheric pressuresINTERNATIONAL JOURNAL OF CHEMICAL KINETICS, Issue 12 2006Joel M. Hall Chemiluminescence from the OH(A , X) transition near 307 nm is a commonly used diagnostic in combustion applications such as flame chemistry, shock-tube experiments, and reacting-flow visualization. Although absolute measurements of OH(X) concentrations are well defined, there is no elementary relation between emission from the electronically excited state (OH*) and its absolute concentration. Thus, to enable quantitative emission measurements, a kinetics model has been assembled and optimized to predict OH* formation and quenching at combustion conditions. Shock-tube experiments were conducted in mixtures of H2/O2/Ar, CH4/O2/Ar, and CH4/H2/O2/Ar with high levels of argon dilution (>98%). Elementary reactions to model OH*, along with initial estimates of their rate coefficients, were taken from the literature. The important formation steps follow: (R0) (R1) Sensitivity analyses were performed to identify experimental conditions under which the shape of the measured OH* profiles and the magnitude of the OH* emission would be sensitive to the formation reactions. A fitting routine was developed to express the formation rate parameters as a function of a single rate, k1 at the reference temperature (1490 K). With all rates so expressed, H2/CH4 mixtures were designed to uniquely determine the value of k1 at the reference temperature, from which the remaining rate parameters were calculated. Quenching rates were fixed at their literature values. The new model predicts the experimental data over the range of conditions studied and can be used to calibrate the emission diagnostic for other applications, such as measurements in real combustion environments, containing higher order hydrocarbon fuels and lower levels of dilution in air. © 2006 Wiley Periodicals, Inc. Int J Chem Kinet 38: 714,724, 2006 [source] Modelling the respiration rate of fresh-cut Annurca apples to develop modified atmosphere packagingINTERNATIONAL JOURNAL OF FOOD SCIENCE & TECHNOLOGY, Issue 5 2009Elena Torrieri Summary In this work, the effect of temperature, oxygen, red coloration process and post-harvest storage time on the respiration rate of fresh-cut Annurca apples was studied to properly develop modified atmosphere packaging. Our results showed that the red coloration process and the post-harvest storage time did not affect the respiration rate or the respiratory quotient of fresh-cut Annurca apples in the range of temperature studied (5,20 °C). A Michaelis,Menten-type equation, with the model constants described by means of an Arrhenius-type relationship, was used for predicting respiration rate on varying the temperature and O2 concentration in the head space. The maximal respiration rate (mL kg h,1) (RRmax) and the O2% corresponding to values estimated at the reference temperature (12.5 °C), i.e. the average of the experimental temperature ranges, were, respectively, 6.77 ± 0.1 mL kg,1 h,1 and 0.68 ± 0.07% v/v, and the activation energy of the aerobic respiration rate of fresh-cut Annurca apples was estimated at 51 ± 1 kJ mol,1. The model works well to develop a modified atmosphere for fresh-cut Annurca apples. [source] Field measurements of the water content in the top soil using a new capacitance sensor with a flat sensitive volumeJOURNAL OF PLANT NUTRITION AND SOIL SCIENCE, Issue 2 2005Bernhard Ruth Abstract Water content directly near the soil surface plays an essential role for degradation of natural organic material and agrochemicals by soil microbes. Furthermore, the water losses by evaporation depend sensitively on the top-soil water content. Rain, irrigation, evaporation, and the water flow between the soil horizons together with the natural inhomogeneity of soils cause a high spatial gradient and a pronounced time dependence of the water content in the top soil. To understand processes in top soil such as redox gradients, the knowledge on ecological conditions in the top soil, which is subject to rapid changes, is essential. In order to meet the requirements for such field measurements, a capacitance sensor with a depth resolution of 1,cm and an active area of 7.5,cm × 14,cm was constructed and operated by a special electronic circuit. Field measurements using these sensors at 1,cm depth showed the high dynamics when measurements were carried out every 10,min. As simultaneous measurements of the soil temperature at 1,cm depth exhibit large temperature variations during the day, its influence on the measurements must be compensated for. As the data, measured during drying periods, allow the assessment of the temperature coefficient, the water content at a reference temperature can be calculated. The course of the water content reflects precipitation events and quantifies the drying of the soil, providing these parameters for process evaluation. Furthermore, the diurnal variation exhibits the drying during the day and the possible rewetting from deeper horizons during the night. Freilandmessungen des Wassergehalts im Oberboden mit einem neuen Kapazitätssensor mit flachem sensitiven Volumen Der Wassergehalt direkt an der Bodenoberfläche spielt für den mikrobiellen Abbau natürlicher organischer Substanz und von Agrochemikalien eine bedeutende Rolle. Darüber hinaus hängen die Wasserverluste durch Evaporation empfindlich vom Wassergehalt an der Bodenoberfläche ab. Regen, Bewässerung, Evaporation und die Wasserbewegung zwischen den Bodenhorizonten, sowie die natürliche Inhomogenität des Bodens verursachen einen großen Gradienten und eine ausgeprägte Zeitabhängigkeit des Wassergehalts und entsprechender Stofftransformationsprozesse im Oberboden. Für das Verständnis der Prozesse im Oberboden, wie z.,B. der Redox-Gradienten, ist die Kenntnis der ökologischen Bedingungen in dem sich schnell verändernden Oberboden unerlässlich. Um die Anforderungen für solche Feldmessungen zu erfüllen, wurde ein Kapazitätssensor mit einer Tiefenauflösung von 1,cm und einer aktiven Fläche von 7.5,cm × 14,cm konstruiert und mit einem speziellen elektronischen Schaltkreis betrieben. Feldmessungen in der Tiefe von 1,cm zeigen eine große Dynamik, wenn alle 10 min ein neuer Messwert erfasst wird. Da simultane Messungen der Bodentemperatur in 1,cm Tiefe hohe Variationen zeigen, muss deren Einfluss auf die Messung kompensiert werden. Da die Messungen während der Trockenperioden die Abschätzung des Temperaturkoeffizienten erlauben, kann der Wassergehalt bei einer Referenztemperatur errechnet werden. Die Messergebnisse korrespondieren mit Regenereignissen und erfassen die Austrocknung des Bodens, so dass damit Parameter für die Prozessberechnung zur Verfügung gestellt werden. Der Tagesgang zeigt Austrocknung während des Tages und die mögliche Wiederbefeuchtung aus tieferen Horizonten während der Nacht. [source] Effect of Chain Straightening on Plateau Modulus and Entanglement Molecular Weight of Ni-diimine Poly(1-hexene)sMACROMOLECULAR RAPID COMMUNICATIONS, Issue 11 2006Zhibin Ye Abstract Summary: In this communication, we report the first rheological study on the chain-straightened Ni-diimine poly(1-hexene)s and investigate the unique effect of chain straightening on plateau modulus and entanglement molecular weight of this series of polymers. Two Ni-diimine poly(1-hexene) samples having different levels of chain straightening were prepared with a chain-walking Ni-diimine catalyst, (ArNC(An)C(An)NAr)NiBr2 (An,=,acenaphthene, Ar,=,2,6-(i -Pr)2C6H3) at two different temperatures. Rheological analyses show that the chain-straightened polymers exhibit significantly enhanced plateau modulus and reduced entanglement molecular weight compared to regular poly(1-hexene)s by metallocene catalysis. Such an effect becomes more pronounced with an increase in the level of chain straightening. Loss moduli G,(,) versus reduced angular frequency in a linear, natural logarithm plot for the three polymers at the reference temperature of 100,°C. [source] Temperature responses are a window to the physiology of dark respiration: differences between CO2 release and O2 reduction shed light on energy conservationPLANT CELL & ENVIRONMENT, Issue 7 2008JÖRG KRUSE ABSTRACT We showed that temperature responses of dark respiration for foliage of Pinus radiata could be approximated by Arrhenius kinetics, whereby E0 determines shape of the exponential response and denotes overall activation energy of respiratory metabolism. Reproducible and predictable deviation from strict Arrhenius kinetics depended on foliage age, and differed between RCO2 and RO2. Inhibition of oxygen reduction (RO2) by cyanide (inhibiting COX) or SHAM (inhibiting AOX) resulted in reproducible changes of the temperature sensitivity for RO2, but did not affect RCO2. Enthalpic growth , preservation of electrons in anabolic products , could be approximated with knowledge of four variables: activation energies (E0) for both RCO2 and RO2, and basal rates of respiration at a low reference temperature (RREF). Rates of enthalpic growth by P. radiata needles were large in spring due to differences between RREF of oxidative decarboxylation and that of oxygen reduction, while overall activation energies for the two processes were similar. Later during needle development, enthalpic growth was dependent on differences between E0 for RCO2 as compared with RO2, and increased E0(RO2) indicated greater contributions of cytochrome oxidase to accompany the switch from carbohydrate sink to source. Temperature-dependent increments in stored energy can be calculated as the difference between RCO2,HCO2 and RO2,HO2. [source] Modelling sources and sinks of CO2, H2O and heat within a Siberian pine forest using three inverse methodsTHE QUARTERLY JOURNAL OF THE ROYAL METEOROLOGICAL SOCIETY, Issue 590 2003M. Siqueira Abstract Source/sink distributions of heat, CO2 and water vapour in a Siberian Scots pine forest were estimated from measured concentration and temperature profiles using three inverse analysis methods. These methods include: a Eulerian second-order closure model (EUL); a localized near-field Lagrangian dispersion model (LNF); and a hybrid model (HEL) which uses the Eulerian second-order turbulence model to calculate the flow statistics combined with the regression analysis used with the Lagrangian model. Model predictions were compared to heat flux profiles measured at five levels in the canopy, and to CO2 and water-vapour fluxes measured close to the ground and above the forest. Predictions of sensible-heat flux profiles by the LNF and HEL schemes were systematically better than results from the EUL analysis. This improvement was attributed to the redundancy in the measured profile (scalar concentration and temperature) data for LNF and HEL and to the imposed smoothness condition used in the regression analyses, whereas the EUL approach calculates a source for each level without any redundancy. The LNF and HEL schemes were also better than EUL in predicting source distributions for CO2 and water vapour, although errors were larger than for sensible heat. The main novelty in our study is the use of EUL to decompose the vertical variability in scalar (or heat) sources into variability produced by the inhomogeneity in flow statistics and variability inferred from the measured mean scalar concentration (or temperature) profile. Hence, it is possible with this analysis to assess how much ,new information' about the source variability is attributed to vertical variation in the measured mean scalar concentration (or temperature) profiles. The analysis shows that measured water vapour concentration profiles provide little information on the inferred source distribution, whereas the CO2 profiles contain more information. Monte Carlo simulations show that computed sources from all three inverse methods have similar sensitivities to errors in measured temperatures. Errors are reduced when the reference temperature above the canopy is held fixed, implying that errors in this temperature propagate throughout the entire domain. When information content and error estimations are combined, a valuable tool to assess the quality of source prediction by inverse methods can be generated. Copyright © 2003 Royal Meteorological Society [source] | |||||||||||||