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Reduction Procedures (reduction + procedure)

Distribution by Scientific Domains

Medical Sciences	28%
Life Sciences	28%
Chemistry	28%
Mathematics and Statistics	14%

Selected Abstracts

A Facile Reduction Procedure for N,N,-Bis[5-substituted salicylidene]m/p-phenylenediamines with Sodium Borohydride,Silica Gel System.

CHEMINFORM, Issue 32 2004
V. Sridharan
No abstract is available for this article. [source]

Ventricular Volume Reduction Procedures

JOURNAL OF CARDIAC SURGERY, Issue 2003
Akira T. Kawaguchi M.D.
Other volume reduction procedures have become popular with renewed interest in ventricular reshaping to improve function. Although recent refined selection criteria have improved survival with PLV, earlier unpredictable results prompted less invasive procedures based on the same physiologic concept of reducing radius or wall tension by wrapping, piercing, or clasping. These new techniques are not only less invasive but also reversible and adjustable and appear safer for less symptomatic patients at risk of progressive heart failure. Nonetheless, mechanisms of action and degrees of volume reduction and/or restriction need to be delineated before widespread clinical application. (J CARD SURG 2003;18 (Suppl 2):S69-S75) [source]

A Convergent Approach to Biocompatible Polyglycerol "Click" Dendrons for the Synthesis of Modular Core,Shell Architectures and Their Transport Behavior

CHEMISTRY - A EUROPEAN JOURNAL, Issue 30 2008
Monika Wyszogrodzka Dipl.-Ing.
Abstract Dendrimers are an important class of polymeric materials for a broad range of applications in which monodispersity and multivalency are of interest. Here we report on a highly efficient synthetic route towards bifunctional polyglycerol dendrons on a multigram scale. Commercially available triglycerol (1), which is highly biocompatible, was used as starting material. By applying Williamson ether synthesis followed by an ozonolysis/reduction procedure, glycerol-based dendrons up to the fourth generation were prepared. The obtained products have a reactive core, which was further functionalized to the corresponding monoazido derivatives. By applying copper(I)-catalyzed 1,3-dipolar cycloaddition, so-called "click" coupling, a library of core,shell architectures was prepared. After removal of the 1,2-diol protecting groups, water-soluble core,shell architectures 24,27 of different generations were obtained in high yields. In the structure,transport relationship with Nile red we observe a clear dependence on core size and generation of the polyglycerol dendrons. [source]

Portosystemic pressure gradient during transjugular intrahepatic portosystemic shunt with Viatorr stent graft: What is the critical low threshold to avoid medically uncontrolled low pressure gradient related complications?

JOURNAL OF GASTROENTEROLOGY AND HEPATOLOGY, Issue 1 2008
Hwan-Hoon Chung
Abstract Background:, Inappropriately decreased portosystemic pressure gradient (PSG) during transjugular intrahepatic portosystemic shunt (TIPS) can cause fatal complications but the critical low threshold of PSG is still not clear. The aim of the present study was to evaluate the critical low threshold of PSG during TIPS. Methods:, Sixty-six patients with cirrhosis who successfully underwent de novo TIPS with Viatorr stent grafts were studied. Medically uncontrolled low pressure gradient (LPR) complication was defined as when a patient died, or when acute transplantation or a TIPS reduction procedure was performed due to refractory encephalopathy or the deterioration of hepatic function within 3 months after the procedure. For the determination of the risk group for medically uncontrolled LPR complications, the Child-Pugh score and the model of end-stage liver disease (MELD) score showing a 100% negative predictive value was decided on as a threshold for each score. The risk group was defined when either of both scores was higher than its threshold. For the determination of a critical low post-TIPS PSG, a value of post-TIPS PSG showing the highest discrimination power on the receiver operating characteristic (ROC) curve in the risk group was decided on as a critical low threshold of PSG. The medically uncontrolled LPR complication rates of the patients with the determined threshold or lower were evaluated for the risk group. Results:, Medically uncontrolled LPR complications developed in nine patients (13.6%). Five patients died and four patients had TIPS reduction procedures. Patients with more than 10 on the Child-Pugh score or more than 14 on the MELD score were determined to be the risk group and 34 patients were included. The critical lower threshold of the post-TIPS PSG showing the highest discrimination power on the ROC curve was 5 mmHg (sensitivity 100%, specificity 72%), and the medically uncontrolled LPR complication rates of the patients with 5 mmHg or lower on the post-TIPS PSG were 56.3% (9/16) in the risk group. Conclusions:, The critical threshold of the post-TIPS PSG to avoid the medically uncontrolled LPR complications of TIPS was >5 mmHg. The PSG should not be reduced below this level in the risk group. [source]

Crystal temperature control in the Czochralski crystal growth process

AICHE JOURNAL, Issue 1 2001
Antonios Armaou
This work proposes a control configuration and a nonlinear multivariable model-based feedback controller for the reduction of thermal gradients inside the crystal in the Czochralski crystal growth process after the crystal radius has reached its final value. Initially, a mathematical model which describes the evolution of the temperature inside the crystal in the radial and axial directions and accounts for radiative heat exchange between the crystal and its surroundings and motion of the crystal boundary is derived from first principles. This model is numericully solved using Galerkin's method and the behaviour of the crystal temperature is studied to obtain valuable insights which lead to the precise formulation of the control problem, the design of a new control configuration for the reduction of thermal gradients inside the crystal and the derivation of a simplified 1-D in a space dynamic model. Then, a model reduction procedure for partial differential equation systems with time-dependent spatial domains (Armaou and Christofides, 1999) based on a combination of Galerkin's method with approximate inertial manifolds is used to construct a fourth-order model that describes the dominant thermal dynamics of the Czochralski process. This low-order model is employed for the synthesis of a fourth-order nonlinear multivariable controller that can be readily implemented in practice. The proposed control scheme is successfully implemented on a Czochralski process used to produce a 0.7 m long silicon crystal with a radius of 0.05 m and is shown to significantly reduce the axial and radial thermal gradients inside the crystal. The robustness of the proposed controller with respect to model uncertainty is demonstrated through simulations. [source]

Simultaneous solution of Lagrangean dual problems interleaved with preprocessing for the weight constrained shortest path problem

NETWORKS: AN INTERNATIONAL JOURNAL, Issue 4 2009
Ranga Muhandiramge
Abstract Conventional Lagrangean preprocessing for the network Weight Constrained Shortest Path Problem (WCSPP), for example Beasley and Christofides (Beasley and Christofides, Networks 19 (1989), 379,394), calculates lower bounds on the cost of using each node and edge in a feasible path using a single optimal Lagrange multiplier for the relaxation of the WCSPP. These lower bounds are used in conjunction with an upper bound to eliminate nodes and edges. However, for each node and edge, a Lagrangean dual problem exists whose solution may differ from the relaxation of the full problem. Thus, using one Lagrange multiplier does not offer the best possible network reduction. Furthermore, eliminating nodes and edges from the network may change the Lagrangean dual solutions in the remaining reduced network, warranting an iterative solution and reduction procedure. We develop a method for solving the related Lagrangean dual problems for each edge simultaneously which is iterated with eliminating nodes and edges. We demonstrate the effectiveness of our method computationally: we test it against several others and show that it both reduces solve time and the number of intractable problems encountered. We use a modified version of Carlyle and Wood's (38th Annual ORSNZ Conference, Hamilton, New Zealand, November, 2003) enumeration algorithm in the gap closing stage. We also make improvements to this algorithm and test them computationally. © 2009 Wiley Periodicals, Inc. NETWORKS, 2009 [source]

Correction of mass spectrometric isotope ratio measurements for isobaric isotopologues of O2, CO, CO2, N2O and SO2

RAPID COMMUNICATIONS IN MASS SPECTROMETRY, Issue 24 2008
Jan Kaiser
Gas isotope ratio mass spectrometers usually measure ion current ratios of molecules, not atoms. Often several isotopologues contribute to an ion current at a particular mass-to-charge ratio (m/z). Therefore, corrections have to be applied to derive the desired isotope ratios. These corrections are usually formulated in terms of isotope ratios (R), but this does not reflect the practice of measuring the ion current ratios of the sample relative to those of a reference material. Correspondingly, the relative ion current ratio differences (expressed as , values) are first converted into isotopologue ratios, then into isotope ratios and finally back into elemental , values. Here, we present a reformulation of this data reduction procedure entirely in terms of , values and the ,absolute' isotope ratios of the reference material. This also shows that not the absolute isotope ratios of the reference material themselves, but only product and ratio combinations of them, are required for the data reduction. These combinations can be and, for carbon and oxygen have been, measured by conventional isotope ratio mass spectrometers. The frequently implied use of absolute isotope ratios measured by specially calibrated instruments is actually unnecessary. Following related work on CO2, we here derive data reduction equations for the species O2, CO, N2O and SO2. We also suggest experiments to measure the required absolute ratio combinations for N2O, SO2 and O2. As a prelude, we summarise historic and recent measurements of absolute isotope ratios in international isotope reference materials. Copyright © 2008 John Wiley & Sons, Ltd. [source]

Reduction of a set of elementary modes using yield analysis

BIOTECHNOLOGY & BIOENGINEERING, Issue 2 2009
Hyun-Seob Song
Abstract This article proposes a new concept termed "yield analysis" (YA) as a method of extracting a subset of elementary modes (EMs) essential for describing metabolic behaviors. YA can be defined as the analysis of metabolic pathways in yield space where the solution space is a bounded convex hull. Two important issues arising in the analysis and modeling of a metabolic network are handled. First, from a practical sense, the minimal generating set spanning the yield space is recalculated. This refined generating set excludes all the trivial modes with negligible contribution to convex hull in yield space. Second, we revisit the problem of decomposing the measured fluxes among the EMs. A consistent way of choosing the unique, minimal active modes among a number of possible candidates is discussed and compared with two other existing methods, that is, those of Schwartz and Kanehisa (Schwartz and Kanehisa, 2005. Bioinformatics 21: 204,205) and of Provost et al. (Provost et al., 2007. Proceedings of the 10th IFAC Symposium on Computer Application in Biotechnology, 321,326). The proposed idea is tested in a case study of a metabolic network of recombinant yeasts fermenting both glucose and xylose. Due to the nature of the network with multiple substrates, the flux space is split into three independent yield spaces to each of which the two-staged reduction procedure is applied. Through a priori reduction without any experimental input, the 369 EMs in total was reduced to 35 modes, which correspond to about 91% reduction. Then, three and four modes were finally chosen among the reduced set as the smallest active sets for the cases with a single substrate of glucose and xylose, respectively. It should be noted that the refined minimal generating set obtained from a priori reduction still provides a practically complete description of all possible states in the subspace of yields, while the active set covers only a specific set of experimental data. Biotechnol. Bioeng. 2009;102: 554,568. © 2008 Wiley Periodicals, Inc. [source]

Ventricular Volume Reduction Procedures

A comparison of three noise reduction procedures applied to bird vocal signals

JOURNAL OF FIELD ORNITHOLOGY, Issue 3 2007
Myron C. Baker
ABSTRACT Recordings of avian vocal signals in natural habitats include ambient noise. Often this background noise corrupts across all frequencies and is of substantial amplitude. Reducing this ambient noise to prepare vocal signals for playback stimuli or to remove habitat-specific noise signatures prior to analyzing a signal's acoustic characteristics can be useful. We conducted experimental evaluations of three noise reduction procedures to determine their effectiveness. We embedded two bird vocalizations ("clean" signals) in four kinds of natural noise, resulting in eight noise-signal combinations. We then applied three noise reduction procedures (Noise Profile, Band Pass, and Noise Estimate) to each of the embedded signals and compared the recovered signals to the original (clean) signals. Noise Profile filtering was effective in reducing noise and returning fairly high-quality signals from even severe levels of masking noise. The other two noise reduction procedures did not perform as well. For the two most corrupting maskers, however, Noise Profile filtering also altered the signal properties by reducing signal amplitude at those frequencies containing high levels of noise. Apart from this loss of amplitude, the quantitative features of the filtered signals were similar to those of the original model sounds. We conclude that Noise Profile filtering produces good results for cases where noise is approximately constant over the signal duration and the signal intensity exceeds noise intensity over the frequencies of interest. SINOPSIS La grabación de sonidos de aves en hábitats naturales incluye ruidos ambientales. A menudo este ruido es de amplitud sustancial y afecta todas las frecuencias. Antes de analizar una señal vocal, podría ser útil reducir este ruido ambiental, bien para preparar vocalizaciones grabadas para provocar respuestas de aves como para remover ruidos asociados a hábitats. Llevamos a cabo una serie de experimentos con tres procedimientos de reducción de ruido para determinar su efectividad. Insertamos dos vocalizaciones de aves (señales "limpias") en cuatro tipos de ruidos naturales, obteniendo como resultado ocho combinaciones de señales con ruido. Posteriormente, aplicamos tres procedimientos de reducción de ruido ("Perfil de Ruido,""Paso de Banda" y "Estimaciones de Ruido") a cada una de las señales insertadas y comparamos las señales recuperadas con los sonidos originales (limpios). La filtración tipo "Perfil de Ruido" resultó efectiva para reducir el ruido y producir señales de razonablemente buena calidad, aún en situaciones de ruido severo. Los otros dos tratamientos no funcionaron tan bien. Para los dos tipos de ruido con mayores efectos, el "Perfil de Ruido" alteró las propiedades de la señal y redujo la amplitud de la misma, en aquellas frecuencias que contenían altos niveles de ruido. Además de la pérdida de amplitud, los elementos cuantitativos de las señales filtradas fueron similares a las de los modelos sonoros originales. Concluimos que el procedimiento de filtrado "Perfil de Ruido" produce buenos resultados para casos en donde el ruido es de duración aproximadamente constante a lo largo de la señal y cuando la intensidad de la señal excede la intensidad del ruido sobre las frecuencias de interés. [source]

Portosystemic pressure gradient during transjugular intrahepatic portosystemic shunt with Viatorr stent graft: What is the critical low threshold to avoid medically uncontrolled low pressure gradient related complications?

ASYMPTOTIC METHODS: APPLICATION TO REDUCTION OF MODELS

NATURAL RESOURCE MODELING, Issue 3 2000
LEONID V. KALACHEV
ABSTRACT. A survey of results on reduction of models related to problems of natural resource modeling using the boundary function method is presented. Detailed reduction procedures as well as conditions under which the reductions are at all possible are discussed. Particular asymptotic techniques are illustrated by simple examples taken from chemical kinetics, and a realistic example from atmospheric chemistry modeling. [source]

Path optimization for the resource-constrained searcher,

NAVAL RESEARCH LOGISTICS: AN INTERNATIONAL JOURNAL, Issue 5 2010
Hiroyuki Sato
Abstract We formulate and solve a discrete-time path-optimization problem where a single searcher, operating in a discretized three-dimensional airspace, looks for a moving target in a finite set of cells. The searcher is constrained by maximum limits on the consumption of one or more resources such as time, fuel, and risk along any path. We develop a specialized branch-and-bound algorithm for this problem that uses several network reduction procedures as well as a new bounding technique based on Lagrangian relaxation and network expansion. The resulting algorithm outperforms a state-of-the-art algorithm for solving time-constrained problems and also is the first algorithm to solve multi-constrained problems. © 2010 Wiley Periodicals, Inc. Naval Research Logistics, 2010 [source]