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Reaction Heat (reaction + heat)

Distribution by Scientific Domains

Polymers and Materials Science	57%

Selected Abstracts

Combined Effects of Hot Curing Conditions and Reaction Heat on Rubber Vulcanization Efficiency and Vulcanizate Uniformity

MACROMOLECULAR THEORY AND SIMULATIONS, Issue 4-5 2009
Xiaoxia Wang
Abstract A mathematical model of the chemical kinetics of silicone rubber vulcanization is developed, with the thermal effects being computed using the increment method, and the hot vulcanization process estimated with the finite element method. The results show that the reaction heat of rubber vulcanization is important for energy saving, and that a proper curing medium temperature is important when considering both vulcanization efficiency and vulcanizate uniformity. The results also indicate that increases in the forced convective heat transfer coefficient have no significant effect above a certain level. The validity of the numerical model is indirectly proven by comparison with existing data. [source]

Semi-adaptive control of convexly parametrized systems with application to temperature regulation of chemical reactors

INTERNATIONAL JOURNAL OF ADAPTIVE CONTROL AND SIGNAL PROCESSING, Issue 4 2001
Alexander Fradkov
In this paper, we are interested in the problem of adaptive control of non-linearly parametrized systems. We investigate the viability of defining a stabilizing parameter update law for the case when the plant model is convex on the uncertain parameters. We show that, when the only prior knowledge is convexity, there does not exist an adaptation law,derivable from the standard separable Lyapunov function technique of Parks,applicable for all the state space. Therefore, we propose a semi-adaptive state feedback controller where adaptation takes place only in the region of the state space where convexity can be used to reduce parameter uncertainty. In the remaining part of the state space we freeze the adaptation and switch to a robust controller. This scheme ensures semi-global stability for convexly parametrized non-linear systems with matched uncertainty. The proposed controller is then applied to the problem of temperature regulation of continuous stirred exothermic chemical reactors where reaction heat is convex in the uncertain parameters. Copyright © 2001 John Wiley & Sons, Ltd. [source]

Numerical analysis of thermal and electrochemical phenomena for anode supported microtubular SOFC

AICHE JOURNAL, Issue 3 2009
Daan Cui
Abstract A 2D model considering momentum, heat/species transport and electrochemical phenomena, has been proposed for tubular solid oxide fuel cell. The model was validated using experimental polarization curves and the good agreement with the experimental data was attained. The temperature distributions show that temperature varies severely at the tube inlet than at the tube outlet. The heat generation and transfer mechanisms in electrodes, electrolyte and electrochemical reaction interface were investigated. The results show that the overall electrochemical reaction heat is produced at cathode/electrolyte interface, and a small portion of the heat is consumed at anode/electrolyte interface. The heat produced at cathode/electrolyte interface is about five times as much as that consumed at anode/electrolyte interface. Overwhelming part of the heat transfer between cell and outside occurs at cathode external surface. Most current flow goes into anode from a very small area where the current collectors locates. © 2009 American Institute of Chemical Engineers AIChE J, 2009 [source]

Dryout phenomena in a three-phase fixed-bed reactor

AICHE JOURNAL, Issue 1 2003
Zhen-Min Cheng
Understanding the mechanism of liquid-phase evaporation in a three-phase fixed-bed reactor is of practical importance, because the reaction heat is usually 7,10 times the vaporization heat of the liquid components. Evaporation, especially the liquid dryout, can largely influence the reactor performance and even safety. To predict the vanishing condition of the liquid phase, Raoult's law was applied as a preliminary approach, with the liquid vanishing temperature defined based on a liquid flow rate of zero. While providing correct trends, Raoult's law exhibits some limitation in explaining the temperature profile in the reactor. To comprehensively understand the whole process of liquid evaporation, a set of experiments on inlet temperature, catalyst activity, liquid flow rate, gas flow rate, and operation pressure were carried out. A liquid-region length-predicting equation is suggested based on these experiments and the principle of heat balance. [source]

Application of Modified Natural Oils as Reactive Diluents for Epoxy Resins

MACROMOLECULAR SYMPOSIA, Issue 1 2006
Piotr Czub
Abstract Bisphenol A based low-molecular-weight epoxy resin was modified with epoxidized soybean oil, which exhibit viscosity reducing ability comparable to commercial grade active diluents. The studied compositions showed a non-Newtonian rheological behavior, typical for Bingham liquids. The values of the flow index (n) and the consistency index (k) for the compositions tested in the temperature range 25,65,°C were calculated from the Ostwald-de Waele rheological model and were used to calculate the flow-activation energy (Ea) using the Arhenius equation. Studies of co-crosslinking of mixed oil-resin compositions using isophorone diamine showed essential decrease of the reaction heat and peak maximum temperature. Mechanical properties, thermal stability, water absorption and chemical resistance of the epoxy resin modified with natural oil, were also investigated. Compositions of epoxy resin Ruetapox 0162, modified with the oil diluent, preserved very good mechanical properties of the epoxy resins and demonstrated relatively low water absorption as well as high chemical resistance. The compositions displayed even higher impact strength than pure epoxy resin due to plasticizing effect of the built-in oil. Compositions with the high contents (up to 60 weight %) of the oil were flexible materials with fast elastic recovery. [source]

Combined Effects of Hot Curing Conditions and Reaction Heat on Rubber Vulcanization Efficiency and Vulcanizate Uniformity

Radiation and postirradiation crosslinking and structure of two unsaturated polyester resins

POLYMER ENGINEERING & SCIENCE, Issue 9 2008
Irina Puci
Radiation and postirradiation crosslinking of two unsaturated polyester (UP) resins were monitored, and substantial differences in the reaction course and extents were observed. DSC thermograms of one of the resins showed double peaks and significantly lower residual reaction heats. Extraction revealed that gelation dose of the resin with double peak was twice the gelation dose of the other resin that had single peak in DSC thermograms. Although other components of the polyesters were identical, NMR spectra of the resin with a single peak revealed isophthalic units while in the polyester of the resin having double DSC peaks orthophthalic units were detected. Orthophthalate reduced the compatibility of polyester and styrene and caused the reaction-induced phase separation, influencing gel structure that was visible in scanning electron microscope micrographs. Previously, the double peaks in crosslinking thermograms of UP resins were usually attributed to initiator effects, but here no initiator was used, and, in the literature, we found that the double peaks are almost exclusively present in the thermograms of UP resins containing orthophthalates, whereas in resins with isophthalates double peaks almost never appear. Crosslinking extents were significantly higher in the resin-containing isophthalate and in both cases enhanced by postirradiation reaction that is often neglected. POLYM. ENG. SCI., 2008. © 2008 Society of Plastics Engineers [source]