DIVERSITY AND DISTRIBUTIONS, Issue 2 2010
Francisca Alba-Sánchez
Abstract Aim, Quaternary palaeopalynological records collected throughout the Iberian Peninsula and species distribution models (SDMs) were integrated to gain a better understanding of the historical biogeography of the Iberian Abies species (i.e. Abies pinsapo and Abies alba). We hypothesize that SDMs and Abies palaeorecords are closely correlated, assuming a certain stasis in climatic and topographic ecological niche dimensions. In addition, the modelling results were used to assign the fossil records to A. alba or A. pinsapo, to identify environmental variables affecting their distribution, and to evaluate the ecological segregation between the two taxa. Location, The Iberian Peninsula. Methods, For the estimation of past Abies distributions, a hindcasting process was used. Abies pinsapo and A. alba were modelled individually, first calibrating the model for their current distributions in relation to the present climate, and then projecting it into the past,the last glacial maximum (LGM) and the Middle Holocene periods,in relation to palaeoclimate simulations. The resulting models were compared with Iberian-wide fossil pollen records to detect areas of overlap. Results, The overlap observed between past Abies refugia,inferred from fossil pollen records,and the SDMs helped to construct the Quaternary distribution of the Iberian Abies species. SDMs yielded two well-differentiated potential distributions: A. pinsapo throughout the Baetic mountain Range and A. alba along the Pyrenees and Cantabrian Range. These results propose that the two taxa remained isolated throughout the Quaternary, indicating a significant geographical and ecological segregation. In addition, no significant differences were detected comparing the three projections (present-day, Mid-Holocene and LGM), suggesting a relative climate stasis in the refuge areas during the Quaternary. Main conclusions, Our results confirm that SDM projections can provide a useful complement to palaeoecological studies, offering a less subjective and spatially explicit hypothesis concerning past geographic patterns of Iberian Abies species. The integration of ecological-niche characteristics from known occurrences of Abies species in conjunction with palaeoecological studies could constitute a suitable tool to define appropriate areas in which to focus proactive conservation strategies. [source]

Regional assessment of the impact of climatic change on the distribution of a tropical conifer in the lowlands of South America

DIVERSITY AND DISTRIBUTIONS, Issue 6 2007
Marie-Pierre Ledru
Abstract For decades, palynologists working in tropical South America are using the genus Podocarpus as a climate indicator although without referring to any modern data concerning its distribution and limiting factors. With the aim to characterize the modern and past distribution of the southern conifer Podocarpus in Brazil and to obtain new information on the distribution of the Atlantic rainforest during the Quaternary, we examined herbarium data to locate the populations of three Brazilian endemic Podocarpus species: P. sellowii, P. lambertii, and P. brasiliensis, and extracted DNA from fresh leaves from 26 populations. Our conclusions are drawn in the light of the combination of these three disciplines: botany, palynology, and genetics. We find that the modern distribution of endemic Podocarpus populations shows that they are widely dispersed in eastern Brazil, from north to south and reveals that the expansion of Podocarpus recorded in single Amazonian pollen records may have come from either western or eastern populations. Genetic analysis enabled us to delimit regional expansion: between 5° and 15° S grouping northern and central populations of P. sellowii expanded c. 16,000 years ago; between 15° and 23° S populations of either P. lambertii or sellowii expanded at different times since at least the last glaciation; and between 23° and 30° S, P. lambertii appeared during the recent expansion of the Araucaria forest. The combination of botany, pollen, and molecular analysis proved to be a rapid tool for inferring distribution borders for sparse populations and their regional evolution within tropical ecosystems. Today the refugia of rainforest communities we identified are crucial hotspots to allow the Atlantic forest to survive under unfavourable climatic conditions and, as such, offer the only possible opportunity for this type of forest to expand in the event of a future climate change. [source]

Upper Pleistocene-Holocene geomorphic changes dictating sedimentation rates and historical land use in the valley system of the Chifeng region, Inner Mongolia, northern China

EARTH SURFACE PROCESSES AND LANDFORMS, Issue 11 2010
Y. Avni
Abstract This study focuses on the late Quaternary landscape evolution in the Chifeng region of Inner Mongolia, China, its relations to the history of the Pleistocene-Holocene loess accumulation, erosion and redeposition, and their impact on human occupation. Based on 57 optically stimulated luminescence (OSL) ages of loess sediments, fluvial sand and floodplain deposits accumulated on the hill slopes and floodplains, we conclude that during most of the Pleistocene period the region was blanketed by a thick layer of aeolian loess, as well as by alluvial and fluvial deposits. The loess section is divided into two main units that are separated by unconformity. The OSL ages at the top of the lower reddish loess unit yielded an approximate age of 193,ka, roughly corresponding to the transition from MIS 7 to 6, though they could be older. The upper gray loess unit accumulated during the upper Pleistocene glacial phase (MIS 4,3) at a mean accumulation rate of 0·22,m/ka. Parallel to the loess accumulation on top of the hilly topography, active fans were operating during MIS 4,2 at the outlet of large gullies surrounding the major valley at a mean accumulation rate of 0·24,m/ka. This co-accumulation indicates that gullies have been a long-term geomorphic feature at the margins of the Gobi Desert since at least the middle Pleistocene. During the Holocene, the erosion of the Pleistocene loess on the hills led to the burial of the valley floors by the redeposited sediments at a rate that decreases from 3·2,m/ka near the hills to 1,0·4,m/ka1 in the central part of the Chifeng Valley. This rapid accumulation and the frequent shifts of the courses of the river prevented the construction of permanent settlements in the valley floors, a situation which changed only with improved man-made control of the local rivers from the tenth century AD. Copyright © 2010 John Wiley & Sons, Ltd. [source]

Geochemical mapping of carbonate sediments in the Makgadikgadi basin, Botswana using moderate resolution remote sensing data

EARTH SURFACE PROCESSES AND LANDFORMS, Issue 6 2006
Kevin White
Abstract This paper maps the carbonate geochemistry of the Makgadikgadi Pans region of northern Botswana from moderate resolution (500 m pixels) remotely sensed data, to assess the impact of various geomorphological processes on surficial carbonate distribution. Previous palaeo-environmental studies have demonstrated that the pans have experienced several highstands during the Quaternary, forming calcretes around shoreline embayments. The pans are also a significant regional source of dust, and some workers have suggested that surficial carbonate distributions may be controlled, in part, by wind regime. Field studies of carbonate deposits in the region have also highlighted the importance of fluvial and groundwater processes in calcrete formation. However, due to the large area involved and problems of accessibility, the carbonate distribution across the entire Makgadikgadi basin remains poorly understood. The MODIS instrument permits mapping of carbonate distribution over large areas; comparison with estimates from Landsat Thematic Mapper data show reasonable agreement, and there is good agreement with estimates from laboratory analysis of field samples. The results suggest that palaeo-lake highstands, reconstructed here using the SRTM 3 arc-second digital elevation model, have left behind surficial carbonate deposits, which can be mapped by the MODIS instrument. Copyright © 2006 John Wiley & Sons, Ltd. [source]

Tilting neotectonics of the Guadiamar drainage basin, SW Spain

EARTH SURFACE PROCESSES AND LANDFORMS, Issue 2 2004
Josep M. SalvanyArticle first published online: 23 DEC 200
Abstract The Guadiamar river ,ows from the southern Iberian Massif to the Guadalquivir foreland basin, SW Spain. Its drainage basin displays asymmetries in the stream network, the arrangement of alluvial terraces and the con,guration of the trunk river valley. The stream network asymmetry was studied using morphometric measures of transverse topographic sym-metry, asymmetry factor and drainage basin shape. The alluvial terraces were studied through the lithologic logs of more than a hundred boreholes and ,eld mapping. The morphometric methods demonstrate a regional tectonic tilting toward the SSE, causing both the migration of the Guadiamar river toward the east and the migration of the Guadiamar tributaries toward the southwest. As a consequence of the Guadiamar river migration, an asymmetric valley developed, with a steep eastern margin caused by river dissection, and a gentle western margin where the main alluvial deposits are found. The ages obtained using the 14C analysis of samples from several alluvial deposits show that the river migration, and thus tilting, has occurred during the Holocene as well as earlier in the Quaternary. This interpretation revises the Guadiamar longitudinal fault assumed by previous studies. Copyright © 2003 John Wiley & Sons, Ltd. [source]

Amino acids in Quaternary soil horizons from southwest Poland

EUROPEAN JOURNAL OF SOIL SCIENCE, Issue 2 2003
A. Szponar
Summary Aminostratigraphy has proved to be a useful approach for dating fossils from the Quaternary. In these studies the amino acids in Quaternary soil formations were determined in an attempt to establish their stratigraphical relationships and relative ages. The sampling sites are in the southwest of Poland, in the Trzebnickie Hills. Three samples of fossil soils and two of recent soils were analysed. The absolute age of the soil samples was estimated by radiocarbon dating. We found that the total amount of amino acids decreased with the increasing age of soil. The smallest amounts of amino acids were found in the oldest fossil soil of Denekamp (Vistulian) age dated 29 600 ± 760 years bp. A sample of recent loess soil contained the most total amino acids, whereas the fossil soil of Lower Atlantic age, dated 3540 ± 230 years bp, was intermediate in respect of the total amount of amino acids, oxidation state and degree of biochemical transformation. Neutral amino acids formed a majority of all the amino acids studied. The method we describe could be useful in relative chronostratigraphical identification of fossil soils. [source]

CLIMATE PREDICTORS OF LATE QUATERNARY EXTINCTIONS

EVOLUTION, Issue 8 2010
David Nogués-Bravo
Between 50,000 and 3,000 years before present (BP) 65% of mammal genera weighing over 44 kg went extinct, together with a lower proportion of small mammals. Why species went extinct in such large numbers is hotly debated. One of the arguments proposes that climate changes underlie Late Quaternary extinctions, but global quantitative evidence for this hypothesis is still lacking. We test the potential role of global climate change on the extinction of mammals during the Late Quaternary. Our results suggest that continents with the highest climate footprint values, in other words, with climate changes of greater magnitudes during the Late Quaternary, witnessed more extinctions than continents with lower climate footprint values, with the exception of South America. Our results are consistent across species with different body masses, reinforcing the view that past climate changes contributed to global extinctions. Our model outputs, the climate change footprint dataset, provide a new research venue to test hypotheses about biodiversity dynamics during the Late Quaternary from the genetic to the species richness level. [source]

THE EVOLUTION OF FEMALE MATING PREFERENCES: DIFFERENTIATION FROM SPECIES WITH PROMISCUOUS MALES CAN PROMOTE SPECIATION

EVOLUTION, Issue 10 2006
Mark A. McPeek
Abstract Females of many species are frequently courted by promiscuous males of their own and other closely related species. Such mating interactions may impose strong selection on female mating preferences to favor trait values in conspecific males that allow females to discriminate them from their heterospecific rivals. We explore the consequences of such selection in models of the evolution of female mating preferences when females must interact with heterospecific males from which they are completely postreproductively isolated. Specifically, we allow the values of both the most preferred male trait and the tolerance of females for males that deviate from this most preferred trait to evolve. Also, we consider situations in which females base their mating decisions on multiple male traits and must interact with males of multiple species. Females will rapidly differentiate in preference when they sometimes mistake heterospecific males for suitable mates, and the differentiation of female preference will select for conspecific male traits to differentiate as well. In most circumstances, this differentiation continues indefinitely, but slows substantially once females are differentiated enough to make mistakes rare. Populations of females with broader preference functions (i.e., broader tolerance for males with trait values that deviate from females most preferred values) will evolve further to differentiate if the shape of the function cannot evolve. Also, the magnitude of separation that evolves is larger and achieved faster when conspecific males have lower relative abundance. The direction of differentiation is also very sensitive to initial conditions if females base their mate choices on multiple male traits. We discuss how these selection pressures on female mate choice may lead to speciation by generating differentiation among populations of a progenitor species that experiences different assemblages of heterospecifics. Opportunities for differentiation increase as the number of traits involved in mate choice increase and as the number of species involved increases. We suggest that this mode of speciation may have been particularly prevalent in response to the cycles of climatic change throughout the Quaternary that forced the assembly and disassembly of entire communities on a continentwide basis. [source]

RIVER CAPTURE, RANGE EXPANSION, AND CLADOGENESIS: THE GENETIC SIGNATURE OF FRESHWATER VICARIANCE

EVOLUTION, Issue 5 2006
C. P. Burridge
Abstract River capture is potentially a key geomorphological driver of range expansion and cladogenesis in freshwater-limited taxa. While previous studies of freshwater fish, in particular, have indicated strong relationships between historical river connections and phylogeographic pattern, their analyses have been restricted to single taxa and geological hypotheses were typically constructed a posteriori. Here we assess the broader significance of river capture among taxa by testing multiple species for the genetic signature of a recent river capture event in New Zealand. During the Quaternary an upper tributary of the Clarence River system was diverted into the headwaters of the Wairau River catchment. Mitochondrial DNA (control region and cytochrome b) sequencing of two native galaxiid fishes (Galaxias vulgaris and Galaxias divergens) supports headwater exchange: populations from the Clarence and Wairau Rivers are closely related sister-groups, whereas samples from the geographically intermediate Awatere River are genetically divergent. The upland bully Gobiomorphus breviceps (Eleotridae), in contrast, lacks a genetic signature of the capture event. We hypothesize that there is an increased likelihood of observing genetic signatures from river capture events when they facilitate range expansion, as is inferred for the two galaxiid taxa studied here. When river capture merely translocates genetic lineages among established populations, by contrast, we suggest that the genetic signature of capture is less likely to be retained, as might be inferred for G. breviceps. Rates of molecular evolution calibrated against this recent event were elevated relative to traditional estimates, consistent with the contribution of polymorphisms to branch lengths at shallow phylogenetic levels prior to fixation by purifying selection and drift. [source]

Biodiversity of Belgian groundwater fauna in relation to environmental conditions

FRESHWATER BIOLOGY, Issue 4 2009
PATRICK MARTIN
Summary 1. The Pleistocene glaciations during the Quaternary appear to have resulted in an impoverished groundwater fauna in northern Europe. Re-colonisation may have occurred either through long-distance dispersal from unglaciated southern areas or from local refugia. 2. The Belgian groundwater fauna was sampled at multiple sites, and its habitats characterised, to assess whether the composition of present-day stygobiotic assemblages can be attributed to either of these mechanisms. 3. A total of 202 sampling sites were selected in four hydrogeographic units of the Meuse River catchment. Sites were equally divided among the saturated and unsaturated zones of fractured aquifers (karst) and within the hyporheic and phreatic zones of porous aquifers. Seventeen environmental parameters were determined in parallel. 4. More than 140 species were recorded, including representatives of the Amphipoda, Cladocera, Copepoda, Hydrachnidia, Isopoda, Oligochaeta, Ostracoda, Mollusca, Syncarida and Nematoda. Thirty stygobiont species were identified, of which 10 species were new to the Belgian fauna, raising the total number of stygobiotic species in Belgium to 41. 5. The frequency of occurrences of stygobiotic species was always low, with 37% of the sampled sites lacking stygobionts. A few species were exclusive to one hydrological zone, although no statistically significant differences were detected in species richness at any of the four hierarchial levels considered (Meuse catchment = region, hydrogeographic units, aquifer type and hydrological zone). 6. Overall, results suggest that the stygobiotic fauna of Belgium is species-poor and mostly comprises widely distributed species with broad ecological tolerances. This supports the view that eurytopic species re-colonised the area by long-distance dispersal from refugia in southern Europe. The virtual absence of endemic species further suggests that the scenario of an ancient fauna that survived in local refugia is of minor importance. [source]

Quaternary paleoenvironments and potential for human exploitation of the Jordan plateau desert interior

GEOARCHAEOLOGY: AN INTERNATIONAL JOURNAL, Issue 4 2005
Caroline P. Davies
The physical, chemical, numerical, and radiometric analyses of a 31-m sediment core from the Qa'el-Jafr basin provide an important record of Quaternary paleoenvironments for the Jordan Plateau and evidence for several significant changes in climate regime. Cluster and PCA analyses of the geochemical data support the designation of major sedimentation regimes identified by stratigraphic and sediment analyses. Multiple cycles of alluvial deposition, lacustrine units, and erosional unconformities characterize the deepest sediments, followed by a period(s) of intense evaporation. Radiocarbon ages of charcoal in the uppermost 7 m place the aeolian/alluvial phase between 16,030 ± 140 yr B.P. and 24,470 ± 240 yr B.P. Deflation processes may explain the lack of a Holocene sequence. Despite lacking radiometric ages for the lower sediments, the thickness and degree of calcium-carbonate cementation suggest considerable age for the basal sediments, which suggests that a very long terrestrial record of Quaternary climate changes has been preserved in the Jafr basin. This new record of paleoenvironments provides important context to the archaeological record of the Jordan Plateau during the Quaternary. Several archaeological surveys demonstrate extensive human exploitation of lakes and springs of the major wadis along the western margin of the Rift Valley. However, little is known of human exploitation of the desert interiors. Qa'el-Jafr sediments demonstrate significant lacustrine and high moisture phases sufficient for human exploitation of the eastern desert during the Pleistocene. © 2005 Wiley Periodicals, Inc. [source]

Late Quaternary landscape history and geoarchaeology of two drainages on Black Mesa, northeastern Arizona, USA

GEOARCHAEOLOGY: AN INTERNATIONAL JOURNAL, Issue 1 2005
Eric T. Karlstrom
Two approximately 5- to 6-km drainage segments on Black Mesa preserve unusually complete sequences of late Quaternary alluvium and soils. Radiocarbon- and tree-ring-dated alluvial and soil stratigraphy suggests entrenched paleoarroyos were beginning to aggrade at about >24,260, 11,070, 9660, 8800, 7060, 3500, 2140, and 1870 14C yr B.P. Using the quantity of sediment removal from post-A.D. 1900 arroyos as analogue, at least 77,200% of total valley alluvium has been removed and replaced by younger sediments during an estimated 11 late Pleistocene and Holocene erosion epicycles. Given that most (59%) of the 150 recorded prehistoric sites in the two study areas occur on valley floors where only about 3% of surface alluvium predates Lolomai phase Basketmaker II occupation (,1900,1600 yr B.P.), it may be inferred that pre-Lolomai phase Basketmaker II sites which may have been located along washes have been removed or buried by fluvial erosion. Identification of five buried hearths in alluvial sections, including White Dog and Lolomai phase Basketmaker II sites (dating about 3500 and 1870 14C yr B.P., respectively) and one possible Early Archaic site, supports this conclusion. © 2005 Wiley Periodicals, Inc. [source]

Eolian processes, ground cover, and the archaeology of coastal dunes: A taphonomic case study from San Miguel Island, California, U.S.A.

GEOARCHAEOLOGY: AN INTERNATIONAL JOURNAL, Issue 8 2002
Torben C. Rick
Geomorphological evidence and historical wind records indicate that eolian processes have heavily influenced San Miguel Island environments for much of the Late Quaternary. The island is almost constantly bombarded by prevailing northwesterly winds, with peak velocities exceeding 75 km/h and wind gusts reaching over 100 km/h. These strong winds played an important role in the location, formation, and preservation of the island's more than 600 archaeological sites. Excavation and surface collection at a stratified Middle and Late Holocene archaeological site on the island's north coast suggest that wind related disturbances result in significant displacement of light fish bones, produce concentrations of shellfish and heavy mammal bones, and cause significant abrasion, etching, and polishing of bones, shells, and artifacts. These data illustrate that wind not only alters surface materials but can significantly disturb subsurface deposits to a depth of at least 20 cm. Working in concert with a variety of taphonomic processes, wind can play a fundamental role in the preservation of archaeological sites and careful scrutiny during excavation and laboratory analysis is required to delineate its effects. © 2002 Wiley Periodicals, Inc. [source]

Tectonic and environmental evolution of Quaternary intramontane basins in Southern Apennines (Italy): insights from palaeomagnetic and rock magnetic investigations

GEOPHYSICAL JOURNAL INTERNATIONAL, Issue 2 2010
M. Porreca
SUMMARY Southern Apennines is characterized by active extensional tectonics with NE,SW stretching direction. The seismicity of the region is very well understood and continuously monitored. In contrast, the onset of extensional tectonics is chronologically poorly constrained. The aim of this study is that to give important constraints on the development of extensional regime and the onset of the continental deposition during Quaternary in Southern Apennines. We report the results of palaeomagnetic and rock magnetic analyses from four Quaternary small intramontane basins in the Picentini Mountains (Southern Apennines). The sedimentary sequences are located at different altitudes, from 600 to 1200 m a.s.l., and were deposited in fluvial-lacustrine environments. We sampled 29 sites in clays and lacustrine limestones from Tizzano, Piano del Gaudo and Acerno basins and in red palaeosoils and matrix-supported conglomerates from the Iumaiano basins. In the clay and limestones samples magnetite, titano-magnetite, hematite and iron-sulphide have been recognized as the main magnetic carriers, whereas magnetite and hematite characterize the Iumaiano conglomerates and red soils. Palaeomagnetic results have been integrated with published radiometric data in order to constrain the age of each sedimentary basins. Sites from the Iumaiano basin, which represents the substrate of the Tizzano and Piano del Gaudo basins, show a reverse polarity and therefore have been attributed to the lower Matuyama chron. In contrast, palaeomagnetic data from Tizzano basin show a transition from reversed to normal polarity along the exposed section, which has been interpreted as the Matuyama/Brunhes transition. Sites from Acerno and Piano del Gaudo basins show a normal polarity, which, according to radiometric and pollen data, have been correlated to the Brunhes epoch. On the base of such results we discuss the tectono-stratigraphic evolution of the basins and the role of extensional tectonics in this portion of the Southern Apennine during the Quaternary. [source]

Reconstructing the demise of Tethyan plants: climate-driven range dynamics of Laurus since the Pliocene

GLOBAL ECOLOGY, Issue 6 2008
Francisco Rodríguez-Sánchez
ABSTRACT Aim Climate changes are thought to be responsible for the retreat and eventual extinction of subtropical lauroid species that covered much of Europe and North Africa during the Palaeogene and early Neogene; little is known, however, of the spatial and temporal patterns of this demise. Herein we calibrate ecological niche models to assess the climatic requirements of Laurus L. (Lauraceae), an emblematic relic from the Tethyan subtropical flora, subsequently using these models to infer how the range dynamics of Laurus were affected by Plio-Pleistocene climate changes. We also provide predictions of likely range changes resulting from future climatic scenarios. Location The Mediterranean Basin and Macaronesian islands (Canaries, Madeira, Azores). Methods We used a maximum-entropy algorithm (Maxent) to model the relationship between climate and Laurus distribution over time. The models were fitted both to the present and to the middle Pliocene, based on fossil records. We employed climatic reconstructions for the mid-Pliocene (3 Ma), the Last Glacial Maximum (21 ka) and a CO2 -doubling future scenario to project putative species distribution in each period. We validated the model projections with Laurus fossil and present occurrences. Results Laurus preferentially occupied warm and moist areas with low seasonality, showing a marked stasis of its climatic niche. Models fitted to Pliocene conditions successfully predicted the current species distribution. Large suitable areas existed during the Pliocene, which were strongly reduced during the Pleistocene, but humid refugia within the Mediterranean Basin and Macaronesian islands enabled long-term persistence. Future climate conditions are likely to re-open areas suitable for colonization north of the current range. Main conclusions The climatic requirements of Laurus remained virtually unchanged over the last 3 Myr. This marked niche conservatism imposed largely deterministic range dynamics driven by climate conditions. This species's relatively high drought tolerance might account for the survival of Laurus in continental Europe throughout the Quaternary whilst other Lauraceae became extinct. Climatic scenarios for the end of this century would favour an expansion of the species's range towards northern latitudes, while severely limiting southern populations due to increased water stress. [source]

Organocatalytic Asymmetric Michael Addition of Pyrazolin-5-ones to Nitroolefins with Bifunctional Thiourea: Stereocontrolled Construction of Contiguous Quaternary and Tertiary Stereocenters

ADVANCED SYNTHESIS & CATALYSIS (PREVIOUSLY: JOURNAL FUER PRAKTISCHE CHEMIE), Issue 5 2010
Yu-Hua Liao
Abstract The first organocatalytic diastereo- and enantioselective Michael addition reaction of 4-substituted-pyrazolin-5-ones to nitroolefins has been developed with a chiral bifunctional thiourea as organocatalyst. A wide variety of desired multi-substituted pyrazolin-5-one derivatives with contiguous quaternary and tertiary stereocenters are smoothly obtained in very good yields (up to 98%) with excellent enantioselectivities (up to>99% ee) and acceptable diastereoselectivities (up to 80:20). This experimentally simple process facilitates the access to various enantioenriched, multiply substituted pyrazolin-5-one derivatives, potential biologically active molecules, starting from readily available starting materials. [source]

Highly Efficient Synthesis of Quaternary ,-Hydroxy Phosphonates via Lewis Acid-Catalyzed Hydrophosphonylation of Ketones

ADVANCED SYNTHESIS & CATALYSIS (PREVIOUSLY: JOURNAL FUER PRAKTISCHE CHEMIE), Issue 16 2009
Xin Zhou
Abstract A Lewis acid catalyst has been first applied to the hydrophosphonylation of ketones, giving the corresponding quaternary ,-hydroxy phosphonates in high yields (up to 98%). The present method was highly tolerable for functionalized ketones. Moreover, the first catalytic enantioselective hydrophosphonylation of an unactivated ketone was also realized by using a tridentate Schiff base-titanium complex. [source]

Sediment sequences and paleosols in the Kyichu Valley, southern Tibet (China), indicating Late Quaternary environmental changes

ISLAND ARC, Issue 3 2009
Knut Kaiser
Abstract The Tibetan Plateau is highly sensitive to environmental changes and affects the settings of a far larger territory in Central Asia and beyond. Thus, knowledge on past environmental changes in that area is essential. Even though the Kyichu (Lhasa River) Valley and its tributaries is an easily accessible area, the Late Quaternary landscape evolution of southern Tibet is in general scarcely known. Therefore, 12 sedimentary sections in the middle and lower catchment were subjected to multidisciplinary analyses (sedimentology, paleopedology, AMS 14C and luminescence dating, and charcoal determination) aiming at results on regional paleoenvironmental changes. At the altitude studied (3600,4000 m above sealevel), no glacial relics could be detected, indicating that the valley positions have been unglaciated since the Last Interglacial. The lack of fluvial,lacustrine structures above the floodplain is due to the aggradational character of this tectonically (sub-)active valley, which caused an alluvial burying of older valley bottoms. During the Late Pleistocene the mouth area of the Kyichu was occupied by a lake which was part of a larger dam-lake in the superordinate Yarlung Zhangbo Valley. On the valley flanks, loesses were predominantly deposited before the Last Glacial Maximum (LGM), whereas eolian sands were predominantly deposited around and after the LGM. Paleosols of Last Interglacial, Last Glacial and Holocene ages regularly occur at terrestrial sites representing temperate to cool and humid to semiarid conditions during soil formation. Ages of colluvial sediments indicate that the widespread barren valley slopes were primarily formed by Late Pleistocene erosion followed by a secondary Holocene erosion phase. Charcoal spectra indicate a Late Holocene change from a forest environment to a pastoral environment with sparse grasses, herbs and dwarf shrubs. It is assumed that the Late Holocene environmental changes, such as loss of forests/woodlands and erosion, have at least been reinforced by humans, enhancing a regional climatic aridification and cooling trend. [source]

Thrust geometries in unconsolidated Quaternary sediments and evolution of the Eupchon Fault, southeast Korea

ISLAND ARC, Issue 3 2004
Young-Seog Kim
Abstract The Korean peninsula is widely regarded as being located at the relatively stable eastern margin of the Asian continent. However, more than 10 Quaternary faults have recently been discovered in and reported from the southeastern part of the Korean Peninsula. One of these, the Eupchon Fault, was discovered during the construction of a primary school, and it is located close to a nuclear power plant. To understand the nature and characteristics of the Quaternary Eupchon Fault, we carried out two trench surveys near the discovery site. The fault system includes one main reverse fault (N20°E/40°SE) with approximately 4 m displacement, and a series of branch faults, cutting unconsolidated Quaternary sediments. Structures in the fault system include synthetic and antithetic faults, hanging-wall anticlines, drag folds, back thrusts, pop-up structures, flat-ramp geometries and duplexes, which are very similar to those seen in thrust systems in consolidated rocks. In the upper part of the fault system, several tip damage zones are observed, indicating that the fault system propagates upward and terminates in the upper part of the section. Pebbles along the main fault plane show a preferred orientation of long axes, indicating the fault trace. The unconformity surface between the Quaternary deposits and the underlying Tertiary andesites or Cretaceous sedimentary rocks is displaced by this fault with a reverse movement sense. The stratigraphic relationship shows normal slip sense at the lower part of the section, indicating that the fault had a normal slip movement and was reversely reactivated during the Quaternary. The inferred length of the Quaternary thrust fault, based on the relationship between fault length and displacement, is 200,2000 m. The current maximum horizontal compressive stress direction in this area is generally east-northeast,west-southwest, which would be expected to produce oblique slip on the Eupchon Fault, with reverse and right-lateral strike-slip components. [source]

Long-term changes in distribution and chemistry of middle Miocene to Quaternary volcanism in the Chokai-Kurikoma area across the Northeast Japan Arc

ISLAND ARC, Issue 1 2004
Hirofumi Kondo
Abstract To understand the characteristics of long-term spatial and temporal variation in volcanism within a volcanic arc undergoing constant subduction since the cessation of back-arc opening, a detailed investigation of middle Miocene to Quaternary volcanism was carried out within the Chokai-Kurikoma area of the Northeast Japan Arc. This study involved a survey of available literature, with new K,Ar and fission track dating, and chemical analyses. Since 14 Ma, volcanism has occurred within the Chokai-Kurikoma area in specific areas with a ,branch-like' pattern, showing an east,west trend. This is in marked contrast to the widespread distribution of volcanism with a north,south trend in the 20,14 Ma period. The east,west- trending ,branches' are characterized by regular intervals (50,100 km) of magmatism along the arc. These branches since 14 Ma are remarkably discrepant to the general northwest,southeast or north-northeast,south-southwest direction of the crustal structures that have controlled Neogene to Quaternary tectonic movements in northeast Japan. In addition, evidence indicating clustering and focusing of volcanism into smaller regions since 14 Ma was verified. Comparison of the distribution and chemistry of volcanic rocks for three principal volcanic stages (11,8, 6,3 and 2,0 Ma) revealed that widely but sparsely distributed volcanic rocks had almost the same level of alkali and incompatible element concentrations throughout the area (with the exception of Zr) in the 11,8 Ma stage. However, through the 6,3 Ma stage to the 2,0 Ma stage, the concentration level in the back-arc cluster increased, while that in the volcanic front cluster remained almost constant. Therefore, the degree of partial melting has decreased, most likely with a simultaneous increase in the depth of magma segregation within the back-arc zone, whereas within the volcanic front zone, the conditions of magma generation have changed little over the three stages. In conclusion, the evolution of the thermal structure within the mantle wedge across the arc since 14 Ma has reduced the extent of ascending mantle diapirs into smaller fields. This has resulted in the tendency for the distribution of volcanism to become localized and concentrated into more specific areas in the form of clusters from the late Miocene to Quaternary. [source]

Global carbonate accumulation rates from Cretaceous to Present and their implications for the carbon cycle model

ISLAND ARC, Issue 1 2001
T. Nakamori
Abstract Global carbonate accumulation rates on the surface of the earth, including not only platforms but also continental margin slopes and deep-sea from the Cretaceous to Present, are estimated by compiling previous geologic studies. These rates are revised, taking account of the erosional effect of the sediments on the platform and deep-sea. Long-term model carbonate fluxes from the ocean to the crust are calculated on the basis of the carbon cycle model (GEOCARB of Berner 1991). The rates based on the actual geologic data indicate much lower values than model fluxes, excluding the Pliocene and Quaternary. The discrepancy could be attributed to the two misunderstandings, namely an overestimate of carbonate accumulation rate for the Quaternary and an incorrect use of the higher Quaternary rate for a boundary condition of the model. The carbonate accumulation rate for the Pliocene to Quaternary is lowered from 29.8 × 1018 mol/Ma (modified from Opdyke & Wilkinson 1988) to 14.8 × 1018 mol/Ma in the present study, assuming that the rate from Quaternary to Pliocene is almost the same as the Miocene value. New model fluxes are recalculated with the new boundary condition in the Quaternary (14.8 × 1018 mol/Ma). Revised model fluxes show general trends of high rates in 120 Ma or 130 Ma, and a low rate in 0 Ma, and are in agreement with the accumulation rate pattern. [source]

The Azores diversity enigma: why are there so few Azorean endemic flowering plants and why are they so widespread?

JOURNAL OF BIOGEOGRAPHY, Issue 1 2010
Mark A. Carine
Abstract Aim, Endemism in the flora of the Azores is high (33%) but in other respects, notably the paucity of evolutionary radiations and the widespread distribution of most endemics, the flora differs markedly from the floras of the other Macaronesian archipelagos. We evaluate hypotheses to explain the distinctive patterns observed in the Azorean endemic flora, focusing particularly on comparisons with the Canary Islands. Location, Azores archipelago. Methods, Data on the distribution and ecology of Azorean endemic flowering plants are reviewed to ascertain the incidence of inter-island allopatric speciation and adaptive, ecological speciation. These are contrasted with patterns for the Canary Islands. Patterns of endemism in the Azores and Canaries are further investigated in a phylogenetic context in relation to island age. beast was used to analyse a published molecular dataset for Pericallis (Asteraceae) and to investigate the relative ages of Azorean and Canarian lineages. Results, There are few examples of inter-island allopatric speciation in the Azorean flora, despite the considerable distances between islands and sub-archipelagos. In contrast, inter-island allopatric speciation has been an important process in the evolution of the Canary Islands flora. Phylogenetic data suggest that Azorean endemic lineages are not necessarily recent in origin. Furthermore, in Pericallis the divergence of the Azorean endemic lineage from its closest relative pre-dates the radiation of a Canarian herbaceous clade by inter-island allopatric speciation. Main conclusions, The data presented do not support suggestions that hypotheses pertaining to island age, age of endemic lineages and ecological diversity considered individually explain the lack of radiations and the widespread distribution of Azorean endemics. We suggest that palaeoclimatic variation, a factor rarely considered in macroecological studies of island diversity patterns, may be an important factor. Palaeoclimatic data suggest frequent and abrupt transitions between humid and arid conditions in the Canaries during the late Quaternary, and such an unstable climate may have driven the recent diversification of the flora by inter-island allopatric speciation, a process largely absent from the climatically more stable Azores. Further phylogenetic/phylogeographic analyses are necessary to determine the relative importance of palaeoclimate and other factors in generating the patterns observed. [source]

Fossil evidence and phylogeography of temperate species: ,glacial refugia' and post-glacial recolonization

JOURNAL OF BIOGEOGRAPHY, Issue 11 2009
Robert S. Sommer
Abstract We present a short synthesis of the Pleistocene distribution dynamics and phylogeographic recolonization hypotheses for two temperate European mammal species, the red deer (Cervus elaphus) and the roe deer (Capreolus capreolus), for which high-resolution patterns of fossil evidence and genetic data sets are available. Such data are critical to an understanding of the role of hypothesized glacial refugia. Both species show a similar pattern: a relatively wide distribution in the southern part of Central Europe 60,000,25,000 years ago, and a strong restriction to areas in southern Europe for nearly 10,000 years during the Last Glacial Maximum (LGM) and the early Late Glacial (25,000,14,700 years ago). With the beginning of Greenland Interstadial 1 (Bølling/Allerød warming, c. 14,700,11,600 years ago) a sudden range expansion into Central Europe is visible, but the colonization of most of Central Europe, including the northern European Lowlands, only began in the early Holocene. In a European context, regions where the species were distributed during the LGM and early Late Glacial are most relevant as potential origins of recolonization processes, because during these c. 10,000 years distribution ranges were smaller than at any other time in the Late Quaternary. As far as the present distribution of temperate species and their genetic lineages is concerned, so-called ,cryptic refugia' are important only if the species are actually confirmed there during the LGM, as otherwise they could not possibly have contributed to the recolonization that eventually resulted in the present distribution ranges. [source]

Phylogenetic relationships, diversification and biogeography in Neotropical Brotogeris parakeets

JOURNAL OF BIOGEOGRAPHY, Issue 9 2009
Camila C. Ribas
Abstract Aim, We present a molecular phylogenetic analysis of Brotogeris (Psittacidae) using several distinct and complementary approaches: we test the monophyly of the genus, delineate the basal taxa within it, uncover their phylogenetic relationships, and finally, based on these results, we perform temporal and spatial comparative analyses to help elucidate the historical biogeography of the Neotropical region. Location, Neotropical lowlands, including dry and humid forests. Methods, Phylogenetic relationships within Brotogeris were investigated using the complete sequences of the mitochondrial genes cyt b and ND2, and partial sequences of the nuclear intron 7 of the gene for Beta Fibrinogen for all eight species and 12 of the 17 taxa recognized within the genus (total of 63 individuals). In order to delinetae the basal taxa within the genus we used both molecular and plumage variation, the latter being based on the examination of 597 skin specimens. Dates of divergence and confidence intervals were estimated using penalized likelihood. Spatial and temporal comparative analyses were performed including several closely related parrot genera. Results,Brotogeris was found to be a monophyletic genus, sister to Myiopsitta. The phylogenetic analyses recovered eight well-supported clades representing the recognized biological species. Although some described subspecies are diagnosably distinct based on morphology, there was generally little intraspecific mtDNA variation. The Amazonian species had different phylogenetic affinities and did not group in a monophyletic clade. Brotogeris diversification took place during the last 6 Myr, the same time-frame as previously found for Pionus and Pyrilia. Main conclusions, The biogeographical history of Brotogeris implies a dynamic history for South American biomes since the Pliocene. It corroborates the idea that the geological evolution of Amazonia has been important in shaping its biodiversity, argues against the idea that the region has been environmentally stable during the Quaternary, and suggests dynamic interactions between wet and dry forest habitats in South America, with representatives of the Amazonian biota having several independent close relationships with taxa endemic to other biomes. [source]

Genetic diversity and phylogeographic analysis of Pinus leiophylla: a post-glacial range expansion

JOURNAL OF BIOGEOGRAPHY, Issue 9 2009
Abril Rodríguez-Banderas
Abstract Aim, Mexico is a centre of diversity for species of the genus Pinus, most of which have restricted geographical distributions. An exception is Pinus leiophylla Schiede and Deppe, which is widely distributed throughout most of Mexico's mountainous regions. We attempt to reconstruct the phylogeographic history of this species, in order to determine if its current broad distribution is associated with major events of environmental change that occurred during the Quaternary. Location, Coniferous forests in Sierra Madre Occidental, Eje Volcánico Transversal and Sierra Montañosa del Norte de Oaxaca, Mexico. Methods, A total of 323 individuals of both P. leiophylla var. leiophylla and P. leiophylla var. chihuahuana sampled from 22 populations were screened for variation at six paternally inherited chloroplast DNA microsatellite markers (cpSSR). In addition to haplotypic diversity estimates and neutrality tests, the following clustering methods were employed: principal components analysis (PCA), analysis of molecular variance (AMOVA), spatial analysis of molecular variance (SAMOVA), haplotype network and a technique similar to Croizat's panbiogeographical method of individual and generalized tracks. Results, The combination of mutations at the six microsatellites yielded a total of 92 different haplotypes. The percentage of shared haplotypes between varieties (P. leiophylla var. leiophylla and P. leiophylla var. chihuahuana) was only 2.2%. The average haplotypic diversity for the species was H = 0.760. PCA and SAMOVA indicate the presence of four main genetic clusters. The estimated divergence time between the two most frequent haplotypes was between 75,000 and 110,000 years. Significantly large negative Fs values suggest that most of the sampled populations are currently expanding. Individual and generalized tracks identified three potential zones that may have harboured ancestral populations of P. leiophylla and from which the expansion of this species started, as well as two secondary contact zones between the two varieties. Main conclusions, The results indicate that one of the three potential areas hypothesized to have harboured ancestral populations of P. leiophylla may be related to the origin of P. leiophylla var. chihuahuana, while the other two may be related to the origin of P. leiophylla var. leiophylla. The current broad distribution of P. leiophylla is probably associated with its strong colonization ability. [source]

Phylogeographical structure in the coastal species Senecio rodriguezii (Asteraceae), a narrowly distributed endemic Mediterranean plant

JOURNAL OF BIOGEOGRAPHY, Issue 7 2009
Arántzazu Molins
Abstract Aim, Our goals were (1) to assess the levels of chloroplast DNA variation in a narrowly distributed plant restricted to continental islands, (2) to ascertain whether a phylogeographical structure is present in plants restricted to coastal linear systems, and (3) to interpret the results in the light of the known palaeogeography of these islands. Location, The Eastern Balearic Islands (Majorca and Minorca) in the Western Mediterranean Basin. Methods, Sampling included 134 individuals from 28 populations of Senecio rodriguezii covering the entire range of the species. Sequences of the chloroplast genome (trnT,trnL spacer) were obtained and parameters of population genetic diversity and substructure were determined (hsht, Gst). The geographical structure of genetic variation was assessed by an analysis of molecular variance (AMOVA). Additionally, a spatial AMOVA (SAMOVA) was used to identify groups of populations that were geographically homogeneous and maximally differentiated from each other. Finally, a pattern of isolation by distance was assessed by testing the correlation between the matrix of pairwise ,ST values and the matrix of geographical distances between pairs of populations using a Mantel test. Results, Seven haplotypes were detected in S. rodriguezii. Only two of them were shared between islands; all of the others were restricted to Majorca (two) or Minorca (three). Overall, we found high levels of genetic diversity and significant geographical structuring of cpDNA markers. Most of the variation detected can be attributed to differences among populations (84.6%), but there was also a significant differentiation between the islands. Main conclusions, Our results support the view that the Balearic Islands constitute a reservoir of genetic diversity, not only for widespread Mediterranean taxa, but also for endemic ones. The intraspecific genetic structure found in S. rodriguezii suggests that its population history was dominated by both expansion and contraction events. This has resulted in a species that is highly structured genetically, showing very few shared haplotypes between islands, and a high number of haplotypes restricted to small geographical areas within the islands. Changes in habitat availability and dynamic processes of population fragmentation and connectivity due to repeated cycles of sea-level changes during the Quaternary are the possible underlying factors that have shaped the cpDNA pool of this endemic species on a regional scale. [source]

New approaches to understanding late Quaternary climate fluctuations and refugial dynamics in Australian wet tropical rain forests

JOURNAL OF BIOGEOGRAPHY, Issue 2 2009
Jeremy VanDerWal
Abstract Aim, We created spatially explicit models of palaeovegetation stability for the rain forests of the Australia Wet Tropics. We accounted for the climatic fluctuations of the late Quaternary, improving upon previous palaeovegetation modelling for the region in terms of data, approach and coverage of predictions. Location, Australian Wet Tropics. Methods, We generated climate-based distribution models for broad rain forest vegetation types using contemporary and reconstructed ,pre-clearing' vegetation data. Models were projected onto previously published palaeoclimate scenarios dating to c. 18 kyr bp. Vegetation stability was estimated as the average likelihood that a location was suitable for rain forest through all climate scenarios. Uncertainty associated with model projections onto novel environmental conditions was also tracked. Results, Upland rain forest was found to be the most stable of the wet forest vegetation types examined. We provide evidence that the lowland rain forests were largely extirpated from the region during the last glacial maximum, with only small, marginally suitable fragments persisting in two areas. Models generated using contemporary vegetation data underestimated the area of environmental space suitable for rain forest in historical time periods. Model uncertainty resulting from projection onto novel environmental conditions was low, but generally increased with the number of years before present being modelled. Main conclusions, Climate fluctuations of the late Quaternary probably resulted in dramatic change in the extent of rain forest in the region. Pockets of high-stability upland rain forest were identified, but extreme bottlenecks of area were predicted for lowland rain forest. These factors are expected to have had a dramatic impact on the historical dynamics of population connectivity and patterns of extinction and recolonization of dependent fauna. Finally, we found that models trained on contemporary vegetation data can be problematic for reconstructing vegetation patterns under novel environmental conditions. Climatic tolerances and the historical extent of vegetation may be underestimated when artificial vegetation boundaries imposed by land clearing are not taken into account. [source]

Deep genealogies and the mid-peninsular seaway of Baja California

JOURNAL OF BIOGEOGRAPHY, Issue 8 2006
Johan Lindell
Abstract Geological forces and long-term climate changes can have profound effects on species. Such effects may be manifested in the pattern and magnitude of genealogical diversity, as revealed by mitochondrial DNA (mtDNA) lineages. The relative importance of the different forces on a regional biota must be evaluated along with a good understanding of geological and climatological history. The peninsula of Baja California of north-western Mexico is one area where both geology and climate have affected the historical biogeography of the regional biota. Molecular studies based on the genealogical relationships among mtDNA lineages have contributed greatly towards elucidating the historical biogeography of Baja California. Perhaps most noticeably, numerous concordant breaks in mtDNA genealogies half-way along the peninsula suggest a vicariant history in which the mid-peninsula was temporarily submerged. This vicariant explanation has recently been criticized, as no conclusive geological evidence exists for a continuous submergence of the mid-peninsula. As an alternative, a scenario based on climatological factors has been suggested. Here we discuss the validity of the hypothesized mid-peninsular vicariance event and the climate-based alternative in explaining the concordant genealogical breaks. We argue that, despite the significant changes in climate brought about by the glacial cycles throughout the Quaternary, a vicariant history involving a mid-peninsular seaway remains the most parsimonious explanation of the observed patterns in mtDNA genealogies. [source]

A comparison of taiga flora in north-eastern Russia and Alaska/Yukon

JOURNAL OF BIOGEOGRAPHY, Issue 7 2003
David K. Swanson
Abstract Aim, To understand the similarities and differences between the taiga floras of far north-eastern Asia and north-western North America in the light of their Tertiary and Quaternary histories. Does the taiga flora follow the tundra pattern (Asian,American commonality of species as a result of continuity through the Quaternary), the temperate forest pattern (distinct species because of late Tertiary disjunction), a combination of these two patterns, or some pattern unique to the taiga? Location, The taiga regions of interior Alaska and the Yukon in North America (the ,Alaskan taiga'), and the Kolyma and eastern Indigirka River basins in Russia (the ,Kolyma taiga'). The study areas include both forested and unforested habitats below elevational treeline. The two regions have similar climate and topography and were linked via the Bering Land Bridge in the Tertiary and for several extended periods during Quaternary cold periods. Methods, Systematic comparison of the vascular floras of the two regions from published sources; and review of palaeoecological literature for the region. Results, Of the 796 species found in the study areas, 27% occur only in the Alaskan taiga, 35% occur only in the Kolyma taiga, and 38% occur in both the regions. The following subsets of species show a high proportion of species in common between the study areas (subsets are not mutually exclusive): plants that occur on the tundra and the taiga, non-flowering plants, abundant taiga understory plants, and wetland and aquatic plants. A lower proportion of shared plants was noted for warm, south-facing steppe communities. No tree species are common to both areas. Main conclusions, The Bering Strait region in the Quaternary has acted as a biogeographical filter for taiga plants. Significant divergence between northeast Asia and northwest North America has developed among the more southerly ranging fraction of the flora (e.g. trees), while the more cosmopolitan and the most cold-adapted elements of the taiga flora are common to both areas. Many plants in the former group have been disjunct between Asia and North America for millions of years, while many plants in the latter group have probably maintained continuity between the study areas via the Bering Land Bridge through much of the late Tertiary and Quaternary periods. Repeated extirpation of the less cold-adapted species from both study areas during Pleistocene cold periods has probably enhanced floristic differences between the two regions. [source]

Yellow-brown earth on Quaternary red clay in Langxi County, Anhui Province in subtropical China: Evidence for paleoclimatic change in late Quaternary period,

JOURNAL OF PLANT NUTRITION AND SOIL SCIENCE, Issue 4 2008
Xue-Feng Hu
Abstract In order to investigate the paleoclimatic changes in S China during the late Quaternary and their influence on pedogenesis and soil classification, a yellow-brown earth (YBE),red clay (RC) profile in Langxi County, Anhui Province was studied. The grain-size distribution and the major- and trace-element compositions of the profile indicate that the YBE of the profile shares the same origin with the YBE in Jiujiang and Xuancheng and the Xiashu loess in Zhenjiang, and the underlying RC also has aeolian characteristics and shares the same origin with the Xiashu loess. Grain-size characteristics, molecular ratios of SiO2/Al2O3, SiO2/(Al2O3+Fe2O3), and BA ([CaO+MgO+K2O+Na2O]/Al2O3) and other weathering indices (CaO/TiO2, MgO/TiO2, K2O/TiO2, Na2O/TiO2, and Rb/Sr) of the profile indicate that the RC is more strongly weathered than the YBE. Magnetic susceptibility (,lf) of the uniform red clay (URC) of the profile is significantly enhanced. However, that of the underlying reticulate red clay (RRC) is significantly decreased because of the paleogroundwater movement and cannot indicate its strong weathering properties. The YBE-RC profile in Langxi County recorded a great climatic change during late Quaternary: At that time, the pedogenic development of the RC was terminated and widespread dust deposition occurred. The parent material of the RC may be aeolian deposits which were accumulated before the last interglacial and were strongly weathered and rubified under the subsequent interglacial climate. It is observed that red soils, derived from the RC, and yellow-brown soils, derived from the YBE, coexist in the study area, which is contradictive to the theory of the zonal distribution of soils. Therefore, it is necessary to take into account the history of Quaternary climatic changes when studying pedogenesis. [source]