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Primary Amides (primary + amide)

Distribution by Scientific Domains
Chemistry100%

Selected Abstracts

A Novel Direct Conversion of Primary Amides to Their Corresponding Methyl Esters

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, Issue 6 2007
Liang-Chun Li
Abstract A novel method was used to directly convert aliphatic and aromatic primary amides into their corresponding methyl esters in high yields (up to 99,%) under mild reaction conditions. Possible mechanisms were studied at the B3LYP/6-31++G(d,p) level of theory. Formation of the ester proceeded through a rearrangement of the ,OMe and ,NH2 groups in the RC(O)NHS(O)OMe intermediate in a H+ -catalyzed six-membered ring transition state structure. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007) [source]

ChemInform Abstract: Sequential Synthesis of (E)-,,,-Unsaturated Primary Amides with Complete Stereoselectivity.

CHEMINFORM, Issue 38 2010
Jose M. Concellon
No abstract is available for this article. [source]

ChemInform Abstract: Direct Preparation of Primary Amides by Reaction of Carboxylic Acids and Ammonia in Alcohols Using DMT-MM.

CHEMINFORM, Issue 18 2009
Tsukasa Mizuhara
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]

The Synthesis of Amines by the Homogeneous Hydrogenation of Secondary and Primary Amides.

CHEMINFORM, Issue 50 2007
Angel A. Nunez Magro
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF. [source]

A Domino Copper-Catalyzed C,N and C,O Cross-Coupling for the Conversion of Primary Amides into Oxazoles.

CHEMINFORM, Issue 48 2007
Kerstin Schuh
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF. [source]

Rapid Method of Converting Primary Amides to Nitriles and Nitriles to Primary Amides by ZnCl2 Using Microwaves under Different Reaction Conditions.

CHEMINFORM, Issue 41 2007
Krishnappa Manjula
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF. [source]

Rhenium(VII) Oxo Complexes as Extremely Active Catalysts in the Dehydration of Primary Amides and Aldoximes to Nitriles.

CHEMINFORM, Issue 51 2002
Kazuaki Ishihara
No abstract is available for this article. [source]

A Rapid and Facile Conversion of Primary Amides and Aldoximes to Nitriles and Ketoximes to Amides with Triphenylphosphine and N-Chlorosuccinimide.

CHEMINFORM, Issue 47 2002
N. Iranpoor
Abstract For Abstract see ChemInform Abstract in Full Text. [source]

ChemInform Abstract: Phenyl Chloroformate: A Convenient Reagent for the Preparation of Nitriles from Primary Amides.

CHEMINFORM, Issue 49 2001
D. Subhas Bose
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]

ChemInform Abstract: Use of PyBOP as a Convenient Activator for the Synthesis of Nitriles from Primary Amides.

CHEMINFORM, Issue 28 2001
D. Subhas Bose
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]

A Novel Direct Conversion of Primary Amides to Their Corresponding Methyl Esters

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, Issue 6 2007
Liang-Chun Li
Abstract A novel method was used to directly convert aliphatic and aromatic primary amides into their corresponding methyl esters in high yields (up to 99,%) under mild reaction conditions. Possible mechanisms were studied at the B3LYP/6-31++G(d,p) level of theory. Formation of the ester proceeded through a rearrangement of the ,OMe and ,NH2 groups in the RC(O)NHS(O)OMe intermediate in a H+ -catalyzed six-membered ring transition state structure. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007) [source]

Palladium-Catalyzed One-Pot Conversion of Aldehydes to Amides

ADVANCED SYNTHESIS & CATALYSIS (PREVIOUSLY: JOURNAL FUER PRAKTISCHE CHEMIE), Issue 2-3 2010
Md Ashif Ali
Abstract The palladium-catalyzed one-pot conversion of aldehydes into primary amides in the presence of hydroxylamine hydrochloride in aqueous dimethyl sulfoxide (DMSO) at moderate temperature is described. The process is selective and free from the addition of an external chelating ligand. [source]

Electronic Properties of Propylamine-Functionalized Single-Walled Carbon Nanotubes

CHEMPHYSCHEM, Issue 11 2010
Matthias Müller
Abstract We present resonant Raman measurements on single-walled carbon nanotubes (SWCNT) functionalized with propylamine groups at different degrees. Direct nucleophilic addition based on in situ generated primary amides is used for attaching n -propylamine to the sidewalls of SWCNTs. The influence of the amino functionalities on the electronic structure of the nanotubes is investigated. From the Raman resonance profiles of the radial breathing modes (RBMs), the chiral indices of the corresponding tubes are assigned. We observe significant redshifts of the transition energies and a broadening of the resonance windows due to chemical modification of SWCNTs. Similar redshifts are derived from the analysis of the NIR/Vis transmission spectrum. The relative Raman intensities of the functionalized samples and the evaluation of their transmission spectra indicate a diameter dependence of the reactivity as it has been observed for other moieties. By analyzing the defect induced D mode we observe a considerable degree of functionalization accompanied by an almost unharmed tube structure, which ensures that the observed effects are mainly driven by changes of the electronic structure. [source]