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Distribution by Scientific Domains


Selected Abstracts


Physicochemical factors controlling the release of dissolved organic carbon from columns of forest subsoils

EUROPEAN JOURNAL OF SOIL SCIENCE, Issue 2 2002
J.-M. Münch
Summary Retention of dissolved organic carbon in soil depends on the chemical and physical environment. We studied the release of organic carbon from three carbonate-free forest subsoil materials (Bs1, Bs2, Bg) in unsaturated column experiments as influenced by (i) variations of the flow regime and (ii) varied chemical properties of the irrigation solution. We investigated the effect of flow initiation, constant irrigation, interruptions to flow, and variation in the effective pore water velocity on the release of organic C. The influence of ionic strength and cation valence in the irrigation solution was studied by stepped pulses of NaCl and CaCl2. The release of C from all materials was characterized by an initial large output and a decline to constant concentrations under long-term irrigation. Interrupting the flow increased its release when flow was resumed. The release from the Bs1 material was not related to the duration of the interruption. The Bs2 material, in contrast, released organic carbon in a way that was successfully described by a kinetic first-order model. Increased pore water velocity decreased the concentrations of C in the effluent from it. The pH of the irrigation solution had negligible effects on the mobilization of C. Increased ionic strength reduced the release, whereas rinsing with distilled water increased the concentrations of C in the effluent. The response of dissolved C to pulses of weak solutions, however, was sensitive to the type of cation in the previous step with strong solutions. The results suggest that the release of organic matter in the soils depends on its colloidal properties. [source]


P - and S -velocity images of the lithosphere,asthenosphere system in the Central Andes from local-source tomographic inversion

GEOPHYSICAL JOURNAL INTERNATIONAL, Issue 1 2006
Ivan Koulakov
SUMMARY About 50 000 P and S arrival times and 25 000 values of t* recorded at seismic arrays operated in the Central Andes between 20°S and 25°S in the time period from 1994 to 1997 have been used for locating more than 1500 deep and crustal earthquakes and creating 3-D P, S velocity and Qp models. The study volume in the reference model is subdivided into three domains: slab, continental crust and mantle wedge. A starting velocity distribution in each domain is set from a priori information: in the crust it is based on the controlled sources seismic studies; in slab and mantle wedge it is defined using relations between P and S velocities, temperature and composition given by mineral physics. Each iteration of tomographic inversion consists of the following steps: (1) absolute location of sources in 3-D velocity model using P and S arrival times; (2) double-difference relocation of the sources and (3) simultaneous determination of P and S velocity anomalies, P and S station corrections and source parameters by inverting one matrix. Velocity parameters are computed in a mesh with the density of nodes proportional to the ray density with double-sided nodes at the domain boundaries. The next iteration is repeated with the updated velocity model and source parameters obtained at the previous step. Different tests aimed at checking the reliability of the obtained velocity models are presented. In addition, we present the results of inversion for Vp and Vp/Vs parameters, which appear to be practically equivalent to Vp and Vs inversion. A separate inversion for Qp has been performed using the ray paths and source locations in the final velocity model. The resulting Vp, Vs and Qp distributions show complicated, essentially 3-D structure in the lithosphere and asthenosphere. P and S velocities appear to be well correlated, suggesting the important role of variations of composition, temperature, water content and degree of partial melting. [source]


Mesh adaptation and transfer schemes for discrete fracture propagation in porous materials

INTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS, Issue 2 2007
Stefano Secchi
Abstract This paper presents a numerical procedure for cohesive hydraulic fracture problems in a multiphase system. The transient problem of crack nucleation and/or advancement, with the ensuing topological changes, is solved by successive remeshing and projection of the field variables required in the time marching scheme. The projection is directly applied to the nodal vector of the previous step and is performed by means of a suitable mapping operator which acts on nodal forces and fluxes. This hence ensures ,a priori' the local fulfilment of the balance equations (equilibrium and mass conservation). The resulting procedure is computationally simple; however checks have to be made on its capability of conserving strain energy of the system. The latter property together with the accuracy of the solution is heuristically assessed on the basis of numerical benchmarks. Copyright © 2007 John Wiley & Sons, Ltd. [source]


Ectoines as compatible solutes and carbon and energy sources for the halophilic bacterium Chromohalobacter salexigens

JOURNAL OF APPLIED MICROBIOLOGY, Issue 1 2006
C. Vargas
Abstract Aims:, To investigate the catabolism of ectoine and hydroxyectoine, which are the major compatible solutes synthesized by Chromohalobacter salexigens. Methods and Results:, Growth curves performed in M63 minimal medium with low (0·75 mol l,1 NaCl), optimal (1·5 mol l,1 NaCl) or high (2·5 mol l,1 NaCl) salinity revealed that betaine and ectoines were used as substrate for growth at optimal and high salt. Ectoine transport was maximal at optimal salinity, and showed 3- and 1·5-fold lower values at low and high salinity respectively. The salt-sensitive ectA mutant CHR62 showed an ectoine transport rate 6·8-fold higher than that of the wild type. Incubation of C. salexigens in a mixture of glucose and ectoine resulted in a biphasic growth pattern. However, CO2 production due to ectoine catabolism was lower, but not completely abolished, in the presence of glucose. When used as the sole carbon source, glycine betaine effectively inhibited ectoine and hydroxyectoine synthesis at any salinity. Conclusions:, The catabolic pathways for ectoine and hydroxyectoine in C. salexigens operate at optimal and high (although less efficiently) salinity. Endogenous ectoine(s) may repress its own transport. Ectoine utilization was only partially repressed by glucose. Betaine, when used as carbon source, suppresses synthesis of ectoines even under high osmolarity conditions. Significance and Impact of the Study:, This study is a previous step to the subsequent isolation and manipulation of the catabolic genes, so as to generate strains with enhanced production of ectoine and hydroxyectoine. [source]


The Quantification of Qualitative Survey Data: A Critical Assessment

JOURNAL OF ECONOMIC SURVEYS, Issue 5 2003
Michela Nardo
Abstract., Data obtained from business and consumer surveys are often used in forecasting models and in testing different expectation formation schemes. Their use, however, requires a previous step of transformation of the qualitative data into quantitative figures. This paper contains a critical review of the different quantification methods, highlighting the limits of their use in macroeconomic modelling. [source]