Pressure Solution (pressure + solution)

Distribution by Scientific Domains


Selected Abstracts


Bulk growth of gallium nitride: challenges and difficulties

CRYSTAL RESEARCH AND TECHNOLOGY, Issue 12 2007
M. Bockowski
Abstract The present status of the GaN bulk growth by High Pressure Solution (HPS) method and combination of HPS and Hydride Vapor Phase Epitaxy (HVPE) methods is reviewed. Up to now the spontaneous high pressure solution growth of GaN results in crystals having habit of hexagonal platelets of surface area of 3 cm2 or needles with length up to 1 cm. Recently, the platelets and needles have been used as seeds for the HVPE growth. On the other hand, the LPE technique under pressure with pressure-grown GaN (hp-GaN), GaN/sapphire template, patterned GaN/sapphire template and free standing HVPE GaN as seeds has been examined and developed. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


Numerical simulation of viscous flow interaction with an elastic membrane

INTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS, Issue 11 2008
Lisa A. Matthews
Abstract A numerical fluid,structure interaction model is developed for the analysis of viscous flow over elastic membrane structures. The Navier,Stokes equations are discretized on a moving body-fitted unstructured triangular grid using the finite volume method, taking into account grid non-orthogonality, and implementing the SIMPLE algorithm for pressure solution, power law implicit differencing and Rhie,Chow explicit mass flux interpolations. The membrane is discretized as a set of links that coincide with a subset of the fluid mesh edges. A new model is introduced to distribute local and global elastic effects to aid stability of the structure model and damping effects are also included. A pseudo-structural approach using a balance of mesh edge spring tensions and cell internal pressures controls the motion of fluid mesh nodes based on the displacements of the membrane. Following initial validation, the model is applied to the case of a two-dimensional membrane pinned at both ends at an angle of attack of 4° to the oncoming flow, at a Reynolds number based on the chord length of 4 × 103. A series of tests on membranes of different elastic stiffness investigates their unsteady movements over time. The membranes of higher elastic stiffness adopt a stable equilibrium shape, while the membrane of lowest elastic stiffness demonstrates unstable interactions between its inflated shape and the resulting unsteady wake. These unstable effects are shown to be significantly magnified by the flexible nature of the membrane compared with a rigid surface of the same average shape. Copyright © 2007 John Wiley & Sons, Ltd. [source]


Chemical and physical responses to deformation in micaceous quartzites from the Tauern Window, Eastern Alps

JOURNAL OF METAMORPHIC GEOLOGY, Issue 4 2003
J. Selverstone
Abstract Micaceous quartzites from a subvertical shear zone in the Tauern Window contain abundant quartz clasts derived from dismembered quartz-tourmaline veins. Bulk plane strain deformation affected these rocks at amphibolite facies conditions. Shape changes suggest net shortening of the clasts by 11,64%, with a mean value of 35%. Quartz within the clasts accommodated this strain largely via dislocation creep processes. On the high-stress flanks of the clasts, however, quartz was removed via solution mass transfer (pressure solution) processes; the resulting change in bulk composition allowed growth of porphyroblastic staurolite + chlorite ± kyanite on the clast flanks. Matrix SiO2 contents decrease from c. 83 wt% away from the clasts to 49,58% in the selvages on the clast flanks. The chemical changes are consistent with c. 70% volume loss in the high-stress zones. Calculated shortening values within the clast flanks are similar to the volume-loss estimates, and are greatly in excess of the shortening values calculated from the clasts themselves. Flow laws for dislocation creep versus pressure solution imply large strain-rate gradients and/or differential stress gradients between the matrix and the clast selvages. In a rock containing a large proportion of semirigid clasts, weakening within the clast flanks could dominate rock rheology. In our samples, however, weakening within the selvages was self limiting: (1) growth of strong staurolite porphyroblasts in the selvages protected remaining quartz from dissolution; and (2) overall flattening of the quartz clasts probably decreased the resolved shear stress on the flanks to values near those of the matrix, which would have reduced the driving force for solution-transfer creep. Extreme chemical changes nonetheless occurred over short distances. The necessity of maintaining strain compatibility may lead to significant localized dissolution in rocks containing rheologic heterogeneities, and overall weakening of the rocks may result. Solution-transfer creep may be a major process whereby weakening and strain localization occur during deep-crustal metamorphism of polymineralic rocks. [source]


Characterisation of the electrical properties of solution-grown GaN crystals by reflectivity and Hall measurements

PHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 3 2006
B. Birkmann
Abstract By using reflectivity and temperature resolved Hall measurements the electrical properties of low pressure solution grown (LPSG) GaN are determined. Hall measurements show that the material is degenerate. The reflectivity spectra are governed by the free electron gas in accordance with this finding. The charge carrier concentration is about 4 × 1019 cm,3 and the mobility 70 , 80 cm2/V s. These results are compared to gallium nitride synthesized by other solution or vapour phase growth techniques. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


Eclogites of the Dabie Region: Retrograde Metamorphism and Fluid Evolution

ACTA GEOLOGICA SINICA (ENGLISH EDITION), Issue 2 2002
GU Lianxing
Abstract, Based upon fluid effects, retrograde metamorphism of eclogites in the Dabie region can be divided into the fluid-poor, fluid-bearing and fluid-rich stages. The fluid-poor stage is marked by polymorphic inversion, recrystallization and exsolution of solid solutions, and is thought to represent eclogite-facies retrograde environments. The fluid-bearing stage is likely to have occurred at the late stage of ecologite-facies diaphthorosis and is represented by kyanite porphyroblasts, rutile, and sodic pyroxene in association with high-pressure hydrous minerals such as phengite and zoisite (clinozoisite) without significant amount of hydrous minerals such as amphibole, epidote and biotite. The fluid-rich stage might have commenced concomitantly with lower amphibolite-facies diaphthoresis and persisted all the way towards the near-surface environment. The product of this stage is characterized by plentiful hydrous and volatile-bearing phases. The dissemination-type rutile mineralizations in eclogites might have formed by preferential shearing-induced pressure solution of gangue minerals at the fluid-bearing stage. The accompanying vein rutile was precipitated from fluids of this stage after local transport and concentration, and may hence represent proximal mobilization of titanium from the eclogite. Therefore, rutile veins can be used as an exploration indicator for dissemination-type rutile deposits. [source]