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Preferential Flow (preferential + flow)

Distribution by Scientific Domains

Earth and Environmental Science	36%
Chemistry	8%

Terms modified by Preferential Flow

preferential flow paths

Selected Abstracts

Preferential flow and transport in soil: progress and prognosis

EUROPEAN JOURNAL OF SOIL SCIENCE, Issue 1 2008
B. E. Clothier
Summary Soil is the first filter of the world's water; its buffering and filtering determine the quality and quantity of our reserves of subterranean and surface water. Preferential flow can either enhance, or curtail, the capacity of the soil to buffer and filter, and it can compromise, or boost, other ecosystem services. We ask ,when do preferential flow and transport matter?' We identify 12 of 17 ecosystem services that benefit from preferential flow and three that are affected detrimentally. We estimate by simple arithmetic the value of preferential flow to ecosystem services to be globally some US$304 billion (109) per year. We review the 1989 Monte Verità meeting on preferential flow processes and summarize the 2006 presentations, some of which are published in this issue of the Journal. New technologies and innovative experiments have increased our understanding of the conditions that initiate and sustain preferential flows. We identify contemporary exigencies, and suggest avenues for their resolution. We are progressing through observation-led discovery. Our prognosis is that new data will enable us to develop better models, and more aptly to parameterize existing models, and thereby predict the impact, benefits and detriments of preferential flow in soil. [source]

Preferential flow and aging of NAPL in the unsaturated soil zone of a hazardous waste site: implications for contaminant transport

JOURNAL OF PLANT NUTRITION AND SOIL SCIENCE, Issue 1 2003
Kai U. Totsche
Abstract Flow of non-aqueous phase liquids (NAPL) in the unsaturated zone is thought to be driven by gravity with a dominant vertical flow direction, and lateral spreading to be limited to the gradient of the relative permeabilities. The effect of soil profile build-up, preferential flow, aging, and groundwater level fluctuations is mostly neglected. The objective of our study was to check the effects of such processes on the fate of NAPL in the unsaturated soil zone. At a hazardous waste site, we conducted a field survey of the unsaturated soil zone and monitored the groundwater for a two year period. We conducted spatially resolved and depth dependent soil sampling and analysis and the evaluation of former ram and core drilling protocols. The samples were analyzed for the 16 EPA PAH and alkanes with GC-MS and GC-FID. 13C-NMR spectroscopy was used to assess structural changes of the NAPL phase. Flow of bulk NAPL along macropores and along preferential permeability structures, like sedimentation discontinuities, are the dominant transport pathways which cause large lateral spreading beyond those expected by the relative permeability gradient. Accumulation of NAPL was found at locations with abrupt textural changes and within the zone of capillary rise. Aging of NAPL results in the depletion in soluble and volatile compounds but also in oxidation and polymerization. It increases the chemical diversity and decreases the mobility of the NAPL. Thus, NAPL flow ceases much earlier than expected from the capillary forces. As chemical transformation is restricted to the NAPL water/air interface, a skin-like thin film is formed which encapsulates and preserves the bulk NAPL from further hardening, limiting contaminant mass transfer from the NAPL to the aqueous phase. Präferenzieller Fluss und Alterung nichtwässriger flüssiger Phasen (NAPL) in der ungesättigten Bodenzone eines Altlastenstandortes: Bedeutung für den Stofftransport Bei der Abschätzung der Tiefenverlagerung von nichtwässrigen Phasen (NAPL) in der ungesättigten Bodenzone ging man bisher davon aus, dass der Fluss im Boden eine dominante vertikale Fließkomponente besitzt. Die Bedeutung bevorzugter Fließwege, des Bodenprofils und der Alterung für die Ausbreitung der NAPL wurde bisher nicht untersucht. Ziel unserer Arbeiten war es daher, die Gültigkeit der Vorstellungen zum Transport von NAPL in der ungesättigten Bodenzone zu überprüfen. Hierzu wurde die ungesättigte Bodenzone an einem ehemaligen Teerwerkstandort untersucht und ein zweijähriges Grundwassermonitoring durchgeführt. Es wurde eine tiefendifferenzierte und räumlich aufgelöste Probenahme mit Rammkernsondierungen und Linern durchgeführt, sowie Bohrprotokolle vorhandener Gutachten ausgewertet. In den Proben wurden Alkane mittels GC-FID und PAK mittels GC-MS bestimmt. NAPL wurden 13C-NMR-spektroskopisch untersucht. Der Fluss von NAPL entlang präferenzieller Fließpfade ist der dominante Prozess der Tiefenverlagerung. Dabei kommt es zu einer starken lateralen Ausbreitung von NAPL weit über den Bereich hinaus, der aufgrund der heterogenen Verteilung der relativen Permeabilitäten erwartet werden würde. Innerhalb des Bodenprofils reichern sich NAPL oberhalb der Grenzflächen mit abruptem Texturwechsel und innerhalb der kapillaren Aufstiegszone an. Alterung der NAPL führt zu einer Zunahme der chemischen Diversität und zu einer Abnahme der Mobilität. Die Tiefenverlagerung von NAPL kommt viel früher zum Erliegen als durch Viskosität und Kapillarkräfte zu erwarten wäre. Die strukturchemischen Veränderungen beschränken sich jedoch auf die Grenzfläche NAPL/Wasser bzw. NAPL/Bodenluft: Es bildet sich eine dünne, verhärtete Grenzschicht aus, die die NAPL umhüllt, die weitere Alterung verlangsamt und den Stoffaustausch zwischen NAPL und Bodenwasser bzw. der Bodenluft verringert. [source]

Preferential flows and travel time distributions: defining adequate hypothesis tests for hydrological process models

HYDROLOGICAL PROCESSES, Issue 12 2010
Keith J. Beven
Abstract This introduction to the second annual review issue of Hydrological Processes tries to put the collection of papers on preferential flows and travel time distributions into a more general context of testing models as hypotheses about how catchment systems function. It is suggested that, because of the possibilities of non-stationary and epistemic errors in both data and models, such tests could be carried out within a rejectionist limits-of-acceptability framework. The principles and difficulties of hypothesis testing within these particular research areas are discussed. An important point to take from this discussion is that the use of a formal testing framework, and the consequent rejection of models as hypotheses after allowing for uncertainties in the data, is the starting point for developing better theories and data sets. Copyright © 2010 John Wiley & Sons, Ltd. [source]

Preferential flow and transport in soil: progress and prognosis

Percolation characteristics of a water-repellent sandy forest soil

EUROPEAN JOURNAL OF SOIL SCIENCE, Issue 1 2008
G. Wessolek
Summary In a tracer experiment TDR transect measurements were made to study percolation behaviour in a 120-year-old pine stand (Pinus sylvestris) on a water-repellent sandy soil (Haplic Arenosol). The experiment (with potassium iodide) showed an 80% labelling of the total flow in organic layers, whereas the area of transport in the mineral soil was sharply reduced to 12,30%. The average diameters of these preferential flow paths were about 8,15 cm. The TDR measurements indicate a homogeneous flow only for a short period from February until April. At this time of the year preferential flow is insignificant, because the soil is at approximately field capacity and not repellent to water. During summer (May to September) the soil dries out, and most precipitation results in preferential flow during this period. For any daily rainfall exceeding 10 mm, water infiltrates down to 1 m depth in the soil, which nevertheless, is still within the root zone. This kind of deep percolation results in the subsoil's wetting to field capacity (pF 1.8) earlier than the topsoil. A one-dimensional numerical model (SWAP) was used to simulate mean water balance with hydraulic functions with and without a water-repellency term. From the results of our tracer experiment we showed that the de-watering process in spring could be simulated well using the traditional piston flow concept, while the rewetting behaviour could be described more realistically using the mobile,immobile concept for water repellency. [source]

Mass fractal dimension of soil macropores using computed tomography: from the box-counting to the cube-counting algorithm

EUROPEAN JOURNAL OF SOIL SCIENCE, Issue 3 2003
J.S. Perret
Summary Transport phenomena in porous media depend strongly on three-dimensional pore structures. Macropore networks enable water and solute to move preferentially through the vadose zone. A complete representation of their geometry is important for understanding soil behaviour such as preferential flow. Once we know the geometrical, topological and scaling attributes of preferential flow paths, we can begin computer simulations of water movement in the soil. The box-counting method is used in three dimensions (i.e. cube-counting algorithm) to characterize the mass fractal dimension of macropore networks using X-ray computed tomography (CT) matrices. We developed an algorithm to investigate the mass fractal dimension in three dimensions and to see how it compares with the co-dimensions obtained using the box-counting technique in two dimensions. For that purpose, macropore networks in four large undisturbed soil columns (850 mm × 77 mm diameter) were quantified and visualized, in both two and three dimensions, using X-ray CT. We observed an increasing trend between the fractal dimension and macroporosity for the four columns. Moreover, similar natural logarithm functions were obtained for the four cores by a least squares fit through plots of mass fractal dimension against macroporosity. [source]

Single- and dual-porosity modelling of multiple tracer transport through soil columns: effects of initial moisture and mode of application

EUROPEAN JOURNAL OF SOIL SCIENCE, Issue 1 2001
T. Kätterer
Summary We investigated the effect of initial moisture contents and mode of application on the displacement of multiple conservative tracers through undisturbed columns of a Humic Gleysol. Bromide was applied at the soil surface and chloride was injected at 5 cm depth. The columns were irrigated with deuterium-enriched water. A dual-porosity model and two single-porosity models were calibrated separately to Br, and Cl, elution curves in the two columns. Elution curves were almost identical for Br, and Cl, under initially wet conditions, whereas the displacement of Br, was faster than that of Cl, in the initially dry column, indicating rapid transport with preferential flow. Only the dual-porosity model described the long-tailing breakthrough of Cl, in the initially dry column adequately. The parameter values giving acceptable fits for ,Br dry' were not compatible with the description of the three other elution curves, which could be adequately modelled with a single set of parameter values. The estimated set of common parameters was validated by comparing with the elution curves of deuterium water, nitrate and sulphate, as well as with resident tracer concentrations at four depths. The results showed that solutes can be displaced much faster when applied at the surface of initially dry soil than when applied to wet soil or when resident in the soil matrix. The simulation results suggest that solute transport under initially dry conditions was governed by preferential flow of infiltration water through macropores by-passing the matrix due to shrinkage cracks and water repellence of matrix surfaces. [source]

Tracing solute infiltration using a combined method of dye tracer test and electrical resistivity tomography in an undisturbed forest soil profile

HYDROLOGICAL PROCESSES, Issue 21 2010
Jae Gon Kim
Abstract An accurate prediction of solute infiltration in a soil profile is important in the area of environmental science, groundwater and civil engineering. We examined the infiltration pattern and monitored the infiltration process using a combined method of dye tracer test and electrical resistivity tomography (ERT) in an undisturbed field soil (1 m × 1 m). A homogeneous matrix flow was observed in the surface soil (A horizon), but a preferential flow along macropores and residual rock structure was the dominant infiltration pattern in the subsurface soil. Saturated interflow along the slopping boundaries of A and C1 horizons and of an upper sandy layer and a lower thin clay layer in the C horizon was also observed. The result of ERT showed that matrix flow started first in A horizon and then the infiltration was followed by the preferential flows along the sloping interfaces and macropores. The ERT did not show as much detail as the dye-stained image for the preferential flow. However, the area with the higher staining density where preferential flow was dominant showed a relatively lower electrical resistivity. The result of this study indicates that ERT can be applied for the monitoring of solute transportation in the vadose zone. Copyright © 2010 John Wiley & Sons, Ltd. [source]

Mechanisms and pathways of lateral flow on aspen-forested, Luvisolic soils, Western Boreal Plains, Alberta, Canada

HYDROLOGICAL PROCESSES, Issue 21 2010
Todd Redding
Abstract Rainfall simulation experiments by Redding and Devito (2008, Hydrological Processes 23: 4287,4300) on two adjacent plots of contrasting antecedent soil moisture storage on an aspen-forested hillslope on the Boreal Plain showed that lateral flow generation occurred only once large soil storage capacity was saturated combined with a minimum event precipitation of 15,20 mm. This paper extends the results of Redding and Devito (2008, Hydrological Processes 23: 4287,4300) with detailed analysis of pore pressure, soil moisture and tracer data from the rainfall simulation experiments, which is used to identify lateral flow generation mechanisms and flow pathways. Lateral flow was not generated until soils were wet into the fine textured C horizon. Lateral flow occurred dominantly through the clay-rich Bt horizon by way of root channels. Lateral flow during the largest event was dominated by event water, and precipitation intensity was critical in lateral flow generation. Lateral flow was initiated as preferential flow near the soil surface into root channels, followed by development of a perched water table at depth, which also interacted with preferential flow pathways to move water laterally by the transmissivity feedback mechanism. The results indicate that lateral flow generated by rainfall on these hillslopes is uncommon because of the generally high available soil moisture storage capacity and the low probability of rainfall events of sufficient magnitude and intensity. Copyright © 2010 John Wiley & Sons, Ltd. [source]

Modified passive capillary samplers for collecting samples of snowmelt infiltration for stable isotope analysis in remote, seasonally inaccessible watersheds 2: field evaluation

HYDROLOGICAL PROCESSES, Issue 7 2010
Marty D. Frisbee
Abstract Twelve modified passive capillary samplers (M-PCAPS) were installed in remote locations within a large, alpine watershed located in the southern Rocky Mountains of Colorado to collect samples of infiltration during the snowmelt and summer rainfall seasons. These samples were collected in order to provide better constraints on the isotopic composition of soil-water endmembers in the watershed. The seasonally integrated stable isotope composition (,18O and ,2H) of soil-meltwater collected with M-PCAPS installed at shallow soil depths < 10 cm was similar to the seasonally integrated isotopic composition of bulk snow taken at the soil surface. However, meltwater which infiltrated to depths > 20 cm evolved along an isotopic enrichment line similar to the trendline described by the evolution of fresh snow to surface runoff from snowmelt in the watershed. Coincident changes in geochemistry were also observed at depth suggesting that the isotopic and geochemical composition of deep infiltration may be very different from that obtained by surface and/or shallow-subsurface measurements. The M-PCAPS design was also used to estimate downward fluxes of meltwater during the snowmelt season. Shallow and deep infiltration averaged 8·4 and 4·7 cm of event water or 54 and 33% of the measured snow water equivalent (SWE), respectively. Finally, dominant shallow-subsurface runoff processes occurring during snowmelt could be identified using geochemical data obtained with the M-PCAPS design. One soil regime was dominated by a combination of slow matrix flow in the shallow soil profile and fast preferential flow at depth through a layer of platy, volcanic rocks. The other soil regime lacked the rock layer and was dominated by slow matrix flow. Based on these results, the M-PCAPS design appears to be a useful, robust methodology to quantify soil-water fluxes during the snowmelt season and to sample the stable isotopic and geochemical composition of soil-meltwater endmembers in remote watersheds. Copyright © 2009 John Wiley & Sons, Ltd. [source]

Soil water repellency in a Japanese cypress plantation restricts increases in soil water storage during rainfall events

HYDROLOGICAL PROCESSES, Issue 17 2007
Masahiro Kobayashi
Abstract Forest soils in Japan are often water repellent. Substantial water repellency frequently occurs and impedes water infiltration into the soil matrix, but continuous overland flow is not necessarily observed because forest soils usually have macropores through which the water can enter the subsoil. Although this flow pattern may influence the manner of water storage in forest soils at the solum scale, field evidence has not yet indicated this process. We monitored soil water storage during natural rainfall events in a 60-cm deep solum using time domain reflectometry (TDR) moisture sensors, and observed stained flow patterns in the soil following simulated rainfall containing a colour dye, on a slope planted with Japanese cypress (Chamaecyparis obtusa). The surface soil at the research plot exhibited strong water repellency at water contents lower than the threshold critical water content of 0·29 m3 m,3. Under dry antecedent moisture conditions, increases in soil water storage were small compared to the cumulative rainfall, despite the low wetness of the soil matrix. In contrast, under moderate moisture conditions, increases in the water content corresponded to the cumulative rainfall. Under dry conditions, rainwater may have entered the subsoil at a few limited locations connected with continuous vertical macropores, such as decayed root channels or interstructural voids. Therefore, the water seemed to bypass a large part of the soil matrix away from the macropores. Such preferential water flow was confirmed by the stained flow patterns after the rainfall simulation. The flow patterns visualized by the dye were discontinuous and scattered under dry conditions and diffuse under moderate moisture conditions. Repellency induced preferential flow led to restricted increases in solum scale water storage during rainfall events, reflecting a physical nonequilibrium in soil water storage. Copyright © 2007 John Wiley & Sons, Ltd. [source]

Directions of preferential flow in a hillslope soil, 1.

HYDROLOGICAL PROCESSES, Issue 4 2005
Quasi-steady flow
Abstract Preferred infiltration is mainly perceived as vertically down whereas subsurface storm flow is thought to occur parallel to slopes. The transition from vertical to lateral flow in a layered hillslope soil is the focus of the contribution. Transient flow is assumed to move as a wetting front. Three time-domain reflectometry (TDR) wave-guides, each 0·15 m long, were mounted in the shape of a truncated tetrahedron with its peak pointing down. Each wave-guide focuses the front velocity along its axis. The three front-velocity vectors are decomposed into their x, y and z components, which are then assembled to the resultant velocity vector. The volume density flux of preferred flow is the product of the front velocity and the mobile water content. The latter is the amplitude of transient soil moisture measured with each wave-guide. The resultant vector of the volume flux density is computed similarly to the velocity vector. The experimental approach allows for the rapid assessment of transient flows without relying on the variation of water potentials. The experiments indicate that the directions of the resultant vectors of velocity and volume flux density can be estimated if the moisture variations of the three TDR wave-guides are strongly correlated during the passing of the wetting front. Copyright © 2004 John Wiley & Sons, Ltd. [source]

Factors governing the formation and persistence of layers in a subalpine snowpack

HYDROLOGICAL PROCESSES, Issue 7 2004
David Gustafsson
Abstract The layered structure of a snowpack has a great effect on several important physical processes, such as water movement, reflection of solar radiation or avalanche release. Our aim was to investigate what factors are most important with respect to the formation and persistence of distinct layers in a subalpine environment. We used a physically based numerical one-dimensional model to simulate the development of a snowpack on a subalpine meadow in central Switzerland during one winter season (1998,99). A thorough model validation was based on extensive measurement data including meteorological and snow physical parameters. The model simulated the snow water equivalent and the depth of the snowpack as well as the energy balance accurately. The observed strong layering of the snowpack, however, was not reproduced satisfactorily. In a sensitivity analysis, we tested different model options and parameter settings significant for the formation of snow layers. The neglection of effects of snow microstructure on the compaction rate, and the current description of the water redistribution inside the snowpack, which disregard capillary barrier effects, preferential flow and lateral water flow, were the major limitations for a more realistic simulation of the snowpack layering. Copyright © 2004 John Wiley & Sons, Ltd. [source]

Using time-domain reflectometry to characterize shallow solute transport in an oak woodland hillslope in northern California, USA

HYDROLOGICAL PROCESSES, Issue 15 2002
Chris G. Campbell
Abstract The natural heterogeneity of water and solute movement in hillslope soils makes it difficult to accurately characterize the transport of surface-applied pollutants without first gathering spatially distributed hydrological data. This study examined the application of time-domain reflectometry (TDR) to measure solute transport in hillslopes. Three different plot designs were used to examine the transport of a conservative tracer in the first 50 cm of a moderately sloping soil. In the first plot, which was designed to examine spatial variability in vertical transport in a 1·2 m2 plot, a single probe per meter was found to adequately characterize vertical solute travel times. In addition, a dye and excavation study in this plot revealed lateral preferential flow in small macropores and a transport pattern where solute is focused vertically into preferential flow pathways. The bypass flow delivers solute deeper in the soil, where lateral flow occurs. The second plot, designed to capture both vertical and lateral flow, provided additional evidence confirming the flow patterns identified in the excavation of the first plot. The third plot was designed to examine lateral flow and once again preferential flow of the tracer was observed. In one instance rapid solute transport in this plot was estimated to occur in as little as 3% of the available pore space. Finally, it was demonstrated that the soil anisotropy, although partially responsible for lateral subsurface transport, may also homogenize the transport response across the hillslope by decreasing vertical solute spreading. Copyright © 2002 John Wiley & Sons, Ltd. [source]

Characteristics of preferential flow and groundwater discharge to Shingobee Lake, Minnesota, USA

HYDROLOGICAL PROCESSES, Issue 10 2002
Hans F. Kishel
Abstract Small-scale heterogeneities and large changes in hydraulic gradient over short distances can create preferential groundwater flow paths that discharge to lakes. A 170 m2 grid within an area of springs and seeps along the shore of Shingobee Lake, Minnesota, was intensively instrumented to characterize groundwater-lake interaction within underlying organic-rich soil and sandy glacial sediments. Seepage meters in the lake and piezometer nests, installed at depths of 0·5 and 1·0 m below the ground surface and lakebed, were used to estimate groundwater flow. Statistical analysis of hydraulic conductivity estimated from slug tests indicated a range from 21 to 4·8 × 10,3 m day,1 and small spatial correlation. Although hydraulic gradients are overall upward and toward the lake, surface water that flows onto an area about 2 m onshore results in downward flow and localized recharge. Most flow occurred within 3 m of the shore through more permeable pathways. Seepage meter and Darcy law estimates of groundwater discharge agreed well within error limits. In the small area examined, discharge decreases irregularly with distance into the lake, indicating that sediment heterogeneity plays an important role in the distribution of groundwater discharge. Temperature gradients showed some relationship to discharge, but neither temperature profiles nor specific electrical conductance could provide a more convenient method to map groundwater,lake interaction. These results suggest that site-specific data may be needed to evaluate local water budget and to protect the water quality and quantity of discharge-dominated lakes. Copyright © 2002 John Wiley & Sons, Ltd. [source]

A conceptual model of preferential flow systems in forested hillslopes: evidence of self-organization

HYDROLOGICAL PROCESSES, Issue 10 2001
Roy C. Sidle
Abstract Preferential flow paths are known to be important conduits of subsurface stormflow in forest hillslopes. Earlier research on preferential flow paths focused on vertical transport; however, lateral transport is also evident in steep forested slopes underlain by bedrock or till. Macropores consisting of decayed and live roots, subsurface erosion, surface bedrock fractures, and animal burrows form the basis of a ,backbone' for lateral preferential flow in such sites. Evidence from field studies in Japan indicates that although individual macropore segments are generally <0·5 m in length, they have a tendency to self-organize into larger preferential flow systems as sites become wetter. Staining tests show clear evidence of interconnected macropore flow segments, including: flow within decayed root channels and subsurface erosion cavities; flow in small depressions of the bedrock substrate; fracture flow in weathered bedrock; exchange between macropores and mesopores; and flow at the organic horizon,mineral soil interface and in buried pockets of organic material and loose soil. Here we develop a three-dimensional model for preferential flow systems based on distributed attributes of macropores and potential connecting nodes (e.g. zones of loose soil and buried organic matter). We postulate that the spatially variable and non-linear preferential flow response observed at our Japan field site, as well as at other sites, is attributed to discrete segments of macropores connecting at various nodes within the regolith. Each node is activated by local soil water conditions and is influenced strongly by soil depth, permeability, pore size, organic matter distribution, surface and substrate topography, and possibly momentum dissipation. This study represents the first attempt to characterize the spatially distributed nature of preferential flow paths at the hillslope scale and presents strong evidence that these networks exhibit complex system behaviour. Copyright © 2001 John Wiley & Sons, Ltd. [source]

Catalytic wet air oxidation of phenol using active carbon: performance of discontinuous and continuous reactors

JOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 7 2001
Frank Stüber
Abstract Catalytic wet air oxidation (CWAO) of an aqueous phenol solution using active carbon (AC) as catalytic material was compared for a slurry and trickle bed reactor. Semi-batchwise experiments were carried out in a slurry reactor in the absence of external and internal mass transfer. Trickle-bed runs were conducted under the same conditions of temperature and pressure. Experimental results from the slurry reactor study showed that the phenol removal rate significantly increased with temperature and phenol concentration, whereas partial oxygen pressure had little effect. Thus, at conditions of 160,°C and 0.71,MPa of oxygen partial pressure, almost complete phenol elimination was achieved within 2,h for an initial phenol concentration of 2.5,g,dm,3. Under the same conditions of temperature and pressure, the slurry reactor performed at much higher initial rates with respect to phenol removal than the trickle bed reactor, both for a fresh active carbon and an aged active carbon, previously used for 50,h in the trickle bed reactor, but mineralisation was found to be much lower in the slurry reactor. Mass transfer limitations, ineffective catalyst wetting or preferential flow in the trickle bed alone cannot explain the drastic difference in the phenol removal rate. It is likely that the slurry system also greatly favours the formation of condensation polymers followed by their irreversible adsorption onto the AC surface, thereby progressively preventing the phenol molecules to be oxidised. Thus, the application of this type of reactor in CWAO has to be seriously questioned when aiming at complete mineralisation of phenol. Furthermore, any kinetic study of phenol oxidation conducted in a batch slurry reactor may not be useful for the design and scale-up of a continuous trickle bed reactor. © 2001 Society of Chemical Industry [source]

Simulation of pesticide leaching in a cracking clay soil with the PEARL model

PEST MANAGEMENT SCIENCE (FORMERLY: PESTICIDE SCIENCE), Issue 5 2005
Rômulo P Scorza Júnior
Abstract Testing of pesticide leaching models is important to increase confidence in their use in pesticide registration procedures world-wide. The chromatographic PEARL model was tested against the results of a field leaching study on a cracking clay soil with a tracer (bromide), a mobile pesticide (bentazone) and a moderately sorbing, persistent pesticide (imidacloprid). Input parameters for water flow and solute transport were obtained from site-specific measurements and from literature. The model was tested using a stepwise approach in which each sub-model was sequentially and separately tested. Uncalibrated simulations for the water flow resulted in moisture profiles that were too wet. Calibration of the hydraulic relationships resulted in a good description of the moisture profiles. Calibration of the dispersion length was necessary to obtain a good description of bromide leaching. The calibrated dispersion length was 61 cm, which is very long and indicates a large non-uniformity of solute transport. The half-life of bentazone had to be calibrated to obtain a good description of its field persistence. The calibrated half-life was 2.5 times shorter than the half-life derived from the laboratory studies. Concentrations of bentazone in drain water and groundwater were described reasonably well by PEARL. Although measured and simulated persistence of imidacloprid in soil corresponded well, the bulk of the imidacloprid movement was overestimated by PEARL. However, imidacloprid concentrations in drain water were underestimated. In spite of the extensive calibration of water flow and tracer movement, the behaviour of the moderately sorbing pesticide imidacloprid could not be simulated. This indicates that the convection,dispersion equation cannot be used for accurate simulation of pesticide transport in cracking clay soils (even if extremely long dispersion length is used). Comparison of the model results from a poorly sorbed chemical (bentazone) and a moderately sorbed chemical (imidacloprid) were useful in defining the limitations of using a chromatographic flow model to simulate the effects of preferential flow. Copyright © 2005 Society of Chemical Industry [source]

A nonoccluding bag and closed scavenging system for the Jackson Rees modified T-piece breathing system

ANAESTHESIA, Issue 5 2000
S. S. Dhara
We used the inner tube and its 22-mm connector from the patient end of a Bain breathing system to splint the double-ended bag of the Jackson Rees modification of the Ayre's T-piece breathing system. A paediatric airway pressure-limiting valve was connected to the distal end of the tube for closed scavenging. The resistance of the modified bags was similar to that of unmodified bags at gas flows below 11 l.min,1. The valve offered no resistance to gas flows below 5 l.min,1. During its use in 30 paediatric patients, analysis of carbon dioxide from inside the bag and from the expiratory port confirmed no loss of deadspace gas by preferential flow bypassing the bag into the scavenging system. [source]