Photoluminescence Emission (photoluminescence + emission)

Distribution by Scientific Domains


Selected Abstracts


The growth of In-rich InGaN/GaN single quantum wells by metalorganic chemical vapor deposition

PHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 7 2003
Hyun Jin Kim
Abstract In-rich InGaN/GaN single quantum wells were grown by metalorganic chemical vapor deposition for the first time to the best of our knowledge. The structures consist of a 2-,m thick GaN buffer layer, a 2-nm thick In-rich InGaN single quantum well, and a 20 nm thick GaN capping layer. Single quantum well structures were examined by transmission electron microscopy. Photoluminescence emissions from the single quantum well samples were observed at wavelengths ranged from 400 nm to 500 nm depending upon the growth conditions of the InN layer. From a simple energy level calculation, we found the possibility of extremely large emission peak shift with well thickness. [source]


Rapid, Low-Temperature Synthesis of ,-SiC Nanowires from Si and Graphite

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 9 2010
Hui-Ling Zhu
,-SiC nanowires were synthesized at a temperature as low as 150°C by the reaction of Si and graphite induced by an additional reaction between Na and S. Characterization by X-ray diffraction, high-resolution transmission electron microscopy, IR spectra, and Raman spectra demonstrates the formation of curly ,-SiC nanowires with several millimeters in length and 50,70 nm in diameter. Also, a prominent peak at 387 nm is observed in the visible photoluminescence emission. Besides the temperature, the molar ratio of S to Si (or graphite) has significant influence on the synthesis of SiC at relatively low temperatures. [source]


The emitting species formed by the oxidation of hydrazides with hypohalites or N-halosuccinimides

LUMINESCENCE: THE JOURNAL OF BIOLOGICAL AND CHEMICAL LUMINESCENCE, Issue 4 2004
Paul S. Francis
Abstract The chemiluminescence accompanying the oxidation of salicylic hydrazide (2-hydroxybenzoic acid hydrazide) with hypochlorite, hypobromite, N-chlorosuccinimide, N-bromosuccinimide or hydrogen peroxide with cobalt(II) matched the photoluminescence emission of salicylic acid. In a related reaction, the oxidation of a mixture of isoniazid and ammonia, a synergistic effect was observed. The chemiluminescence spectrum for this reaction matches that accompanying the oxidation of the hydrazide, rather than the oxidation of ammonia. These results were used to assess mechanisms proposed by previous authors. Copyright © 2004 John Wiley & Sons, Ltd. [source]


Fabrication of dendrite-like Au nanostructures and their enhanced photoluminescence emission

PHYSICA STATUS SOLIDI (A) APPLICATIONS AND MATERIALS SCIENCE, Issue 10 2007
Ying Hu
Abstract Special hierarchical dendrite-like Au (DLAu) nanostructures were fabricated facilely between the gaps of Au electrodes by an electrochemical method. The composition, morphology and crystallinity of the DLAu nanostructures were characterized using energy dispersive spectroscopy, field emission scanning electron microscopy and X-ray diffraction, respectively. The formation of these nanostructures is attributed to the distribution of the local electrical field between the Au electrodes and a diffusion-limited aggregation process. Photoluminescence (PL) having an emission peak near 530 nm is observed from these nanostructures, which is attributed to the recombination of the s,p band electrons near the Fermi energy with the d band holes in the DLAu nanostructures generated by optical excitation. We believe that such PL enhancement compared to a smooth Au film is due to the local-field enhancement from the surface plasmon resonance of the DLAu nanostructures. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


Effects of oxygen ion implantation in spray-pyrolyzed ZnO thin films

PHYSICA STATUS SOLIDI (A) APPLICATIONS AND MATERIALS SCIENCE, Issue 5 2006
K. P. Vijayakumar
Abstract ZnO thin films, prepared using the chemical spray pyrolysis technique, were implanted using 100 keV O+ ions. Both pristine and ion-implanted samples were characterized using X-ray diffraction, optical absorption, electrical resistivity measurements, thermally stimulated current measurements and photoluminescence. Samples retained their crystallinity even after irradiation at a fluence of ,1015 ions/cm2. However, at a still higher fluence of 2 × 1016 ions/cm2, the films became totally amorphous. The optical absorption edge remained unaffected by implantation and optical absorption spectra indicated two levels at 460 and 510 nm. These were attributed to defect levels corresponding to zinc vacancies (VZn) and oxygen antisites (OZn), respectively. Pristine samples had a broad photoluminescence emission centred at 517 nm, which was depleted on implantation. In the case of implanted samples, two additional emissions appeared at 425 and 590 nm. These levels were identified as due to zinc vacancies (VZn) and oxygen vacancies (VO), respectively. The electrical resistivity of implanted samples was much higher than that of pristine, while photosensitivity decreased to a very low value on implantation. This can be utilized in semiconductor device technology for interdevice isolation. Hall measurements showed a marked decrease in mobility due to ion implantation, while carrier concentration slightly increased. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


Physical and optical properties of size-selective CdTe nanocrystals

PHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 6 2010
Alice Fok
Abstract Physical and optical properties of colloidal cadmium telluride nanocrystals (CdTe NCs) were investigated. The CdTe NCs were synthesized by reacting elemental tellurium dissolved in tributylphosphine with a mixture of cadmium oxide, octadecene, and oleic acid. These NCs, which were characterized by transmission electron microscopy (TEM) are spherical and ranged from 5 to 7 nm in diameter. The identity of the compound post-synthesis was confirmed by X-Ray diffraction (XRD) patterns. UV-Vis and photoluminescence (PL) properties as grown and pure CdTe samples were investigated. Bright excitonic photoluminescence emission was observed (© 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


Deterministic self-organization: Ordered positioning of InAs quantum dots by self-organized anisotropic strain engineering on patterned GaAs (311)B

PHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 6 2009
E. Selçuk
Abstract Laterally ordered InGaAs quantum dot (QD) arrays, InAs QD molecules, and single InAs QDs in a spot-like periodic arrangement are created by self-organized anisotropic strain engineering of InGaAs/GaAs superlattice (SL) templates on planar GaAs (311)B substrates in molecular beam epitaxy. On shallow- and deep-patterned substrates the respectively generated steps and facets guide the self-organization process during SL template formation to create more complex ordering such as periodic stripes, depending on pattern design. Here we demonstrate for patterns such as shallow- and deepetched round holes and deep-etched zigzag mesas that the self-organized periodic arrangement of QD molecules and single QDs is spatially locked to the pattern sidewalls and corners. This extends the concept of guided self-organization to deterministic self-organization. Absolute position control of the QDs is achieved without one-to-one pattern definition. This guarantees the excellent arrangement control of the ordered QD molecules and single QDs with strong photoluminescence emission up to room temperature, which is required for future quantum functional devices. (© 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


Temperature dependence of the photoluminescence of single GaAs/AlGaAs concentric quantum ring structure

PHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 11 2006
M. Bonfanti
Abstract We present the temperature dependence of the photoluminescence emission of single concentric quantum rings. The two rings which form the nanostructure show a decoupled recombination kinetics in the whole temperature range. The emission is characterized by a doublet. The emission linewidth, which is already larger than 1 meV at low temperatures and increases as the temperature raises, is dominated by the thermal activation of carriers to higher excited states. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


Polycrystalline GaN: Analysis of the Defects

PHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 1 2003
G. Nouet
Abstract GaN polycrystalline layers were grown by ECR molecular beam epitaxy on quartz glass substrate. Strong photoluminescence emission was observed. Analysis of these layers was carried out by high resolution transmission electron microscopy. It is shown that the microstructure is characterised by a columnar growth with the ,0001, direction parallel to the growth direction. The mean size of the grains is in the range 30,50 nm. Sphalerite, cubic, and wurtzite, hexagonal, phases are observed, thus some defects such as basal stacking faults are present. Inversion domain boundaries are also formed. However, no threading dislocations within the grains are visible. [source]


A New Donor,Acceptor,Donor Polyfluorene Copolymer with Balanced Electron and Hole Mobility,

ADVANCED FUNCTIONAL MATERIALS, Issue 18 2007
A. Gadisa
Abstract A new alternating polyfluorene copolymer poly[2,7-(9,9-dioctylfluoren)- alt -5,5-(5,,8,-di-2-thienyl-(2,,3,-bis-(3,,-octyloxyphenyl)-quinoxaline))] (APFO-15), which has electron donor,acceptor,donor units in between the fluorene units, is synthesized and characterized. This polymer has a strong absorption and emission in the visible range of the solar spectrum. Its electroluminescence and photoluminescence emissions extend from about 560 to 900 nm. Moreover, solar cells with efficiencies in excess of 3.5,% have been realized from blends of APFO-15 and an electron acceptor molecule, a methanofullerene [6,6]-phenyl-C61 -butyric acid methyl ester (PCBM). It has also been observed that electron and hole transport is balanced both in the pure polymer phase and in polymer/PCBM bulk heterojunction films, which makes this material quite attractive for applications in opto-electronic devices. [source]