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Phosphorus Sulfide Cages (phosphorus sulfide + cage)

Distribution by Scientific Domains

Chemistry	100%

Selected Abstracts

ChemInform Abstract: Nb and Ta Adducts: Connecting d0 Metal Chlorides and Phosphorus Sulfide Cages

CHEMINFORM, Issue 41 2009
Diana Hoppe
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]

Nb and Ta Adducts: Connecting d0 Metal Chlorides and Phosphorus Sulfide Cages

CHEMISTRY - A EUROPEAN JOURNAL, Issue 29 2009
Diana Hoppe Dr.
Abstract Phosphorus sulfide cages ,-P4S4, ,-P4S5, ,-P4S5, and ,-P4S6 and transition-metal chlorides TaCl5 and NbCl5 form molecular adducts in CS2/n -hexane. The crystal structures of the adducts (TaCl5)(,-P4S4), (TaCl5)(,-P4S5), (TaCl5)(,-P4S5), (NbCl5)(,-P4S5), and (TaCl5)(,-P4S6) are reported and their conformation and energetic stability are discussed on the basis of ab initio electronic structure calculations. Furthermore bond lengths of coordinated and noncoordinated phosphorus sulfide cages obtained from experiment and theory are compared, emphasizing the changes within the cages that emerge upon coordination. [source]