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Petrogenetic Grid (petrogenetic + grid)
Selected AbstractsTalc-phengite-albite assemblage in piemontite-quartz schist of the Sanbagawa metamorphic belt, central Shikoku, JapanISLAND ARC, Issue 1 2000J. Izadyar Abstract The talc (Tlc) + phengite (Phn) + albite (Ab) assemblage is newly confirmed in MnOtotal -rich (1.65 wt% in average) piemontite-quartz schists from the intermediate- and high-grade part of the Sanbagawa belt, central Shikoku, Japan. Talc is in direct contact with Phn, Ab and chlorite (Chl) with sharp boundaries, suggesting that these four phases mutually coexist. Other primary constituents of the Tlc-bearing piemontite-quartz schist are spessartine, braunite, hematite (Ht), crossite/barroisite and dolomite. Phlogopite (Phl) rarely occurs as a later stage mineral developing along the rim of Phn. The studied piemontite-quartz schist has mg# (= Mg/(Mg + Fe2+)) ~ 1.0, because of its high oxidation state. Schreinemakers' analysis in the KNMASH system and the mineral assemblage in the Sanbagawa belt propose a possible petrogenetic grid, in which the Tlc,Phn assemblage is stable in a P-T field surrounded by the following reactions: lower-pressure limit by Chl + Phl + quartz (Qtz) = Phn + Tlc + H2O as proposed by previous workers; higher-pressure limit by glaucophane + Qtz = Tlc + Ab + H2O; and higher-temperature limit by Tlc + Phn + Ab = Phl + paragonite + Qtz + H2O. Thermodynamic calculation based on the database of Holland & Powell (1998), however, suggests that the Tlc,Phn stability field defined by these reactions is unrealistically limited around 580,600 °C at 11.6,12.0 (± 0.7) kbar. Schreinemakers' analysis in the KNMA-Fe3+ -SH system and the observed mineral assemblage predict that Chl + crossite = Tlc + Ab + Ht + H2O is a preferable Tlc-forming reaction in the intermediate-grade part of the Sanbagawa belt and that excess Ab + hematite narrows the stability field of the Tlc,Phn assemblage. [source] Two contrasted P,T,time paths of coronitic metanorites of the French Massif Central: are reaction textures reliable guides to metamorphic histories?JOURNAL OF METAMORPHIC GEOLOGY, Issue 2 2005C. NICOLLET Abstract Metanorites from two eclogitized metagabbros of the Hercynian French Massif Central preserve coronitic textures of hornblende, garnet, quartz and/or kyanite produced at the expense of the primary magmatic assemblage orthopyroxene and plagioclase. Using a petrogenetic grid in the CFMASH system, two possible P,T evolutions for the origin of the coronas are evaluated. The sequence of reactions involving the formation of Hbl (,Ky) ± Grt and Qtz coronitic assemblages is consistent with an isobaric cooling at high pressure (c. 1,2 GPa) under hydrated conditions. However, this P,T path, inferred by using only petrographical observations, is inconsistent with the geochronological constraints: emplacement of the gabbro at 490 Ma and high-pressure metamorphism at 410 Ma. In order to reconcile petrographical observations with geochronological constraints, we propose a discontinuous two-stage evolution involving a change in water activity with time. (1) Emplacement and cooling of the norite at low pressure under anhydrous conditions, at 490 Ma. (2) During the Hercynian orogeny, the norite experienced an increase in pressure and temperature under fluid-present conditions. Adding water to the system implies a dramatic change in the petrogenetic grid topology, restricting the orthopyroxene,plagioclase assemblage only to high temperatures. Therefore, the breakdown of the unstable magmatic assemblage, through apparent retrograde reactions, occurred along the prograde P,T path which never crossed the equilibrium boundaries of these reactions. [source] The formation of eclogite facies metatroctolites and a general petrogenetic grid in Na2O,CaO,FeO,MgO,Al2O3,SiO2,H2O (NCFMASH)JOURNAL OF METAMORPHIC GEOLOGY, Issue 9 2002G. Rebay Abstract Eclogite facies metatroctolites from a variety of Western Alps localities (Voltri, Monviso, Lanzo, Allalin, Zermat,Saas, etc.) that preserve textural evidence of their original form as bimineralic olivine-plagioclase rocks are considered in terms of calculated mineral equilibria in the system Na2O-CaO-FeO-MgO-Al2O3 -SiO2 -H2O (NCFMASH). Pseudosections, based on a new petrogenetic grid for NCFMASH presented here, are used to unravel the metamorphic history of the metatroctolites, considering the rocks to consist of different composition microdomains corresponding to the original olivine and plagioclase grains. On the basis that the preservation of the mineral assemblage in each microdomain will tend to be from where on a rock's P,T path the metamorphic fluid phase is used up via rehydration reactions, P,T pseudosections contoured for water content, and P,T path-MH2O (amount of water) pseudosections, are used to examine fluid behaviour in each microdomain. We show that the different microdomains are likely to preserve their mineral assemblages from different places on the P,T path. For the olivine microdomain, the diagnostic mineral assemblage is chloritoid + talc (+ garnet + omphacite). The preservation of this assemblage, in the light of the closed system P,T path-MH2O relationships, implies that the microdomain loses its metamorphic fluid as it starts to decompress, and, in the absence of subsequent hydration, the high pressure mineral assemblage is then preserved. In the plagioclase microdomain, the diagnostic assemblage is epidote (or zoisite) + kyanite + quartz suggesting a lower pressure (of about 2 GPa) than for the olivine microdomain. In the light of P,T path-MH2O relationships, development of this assemblage implies breakdown of lawsonite across the lawsonite breakdown reaction, regardless of the maximum pressure reached. It is likely that the plagioclase microdomain was mainly fluid-absent prior to lawsonite breakdown, only becoming fluid-present across the reaction, then immediately becoming fluid-absent again. [source] Melt-producing and melt-consuming reactions in the Achankovil cordierite gneisses, South IndiaJOURNAL OF METAMORPHIC GEOLOGY, Issue 6 2002B. Cenki Abstract Migmatitic cordierite gneisses within the Achankovil Zone (AZ) of southern Pan-African India record melt-producing and subsequent melt-consuming mineral reactions. Early mineral assemblages Bt-Sil-Qtz and Bt-Sil-Spl, deduced from inclusion textures in garnet prophyroblasts, break down via successive dehydration melting reactions to high- T phase assemblages (e.g. Grt-Crd-Liq, Opx-Liq, Spl-Crd-Liq). Later back reactions between the restite and the in situ crystallizing melt resulted in thin cordierite coronas separating garnet from the leucosome, and partial resorption of garnet to Opx-Crd or Crd-Bt-Qtz symplectites. Leucosomes generally display a moderate (low-strain gneisses) to strong (high-strain gneisses) depletion of alkali feldspar attributed to mineral-melt back reactions partly controlled by the degree of melt segregation. Using a KFMASH partial petrogenetic grid that includes a melt phase, and qualitative pseudosections for microdomains of high and low Al/Si ratios, the successive phase assemblages and reaction textures are interpreted in terms of a clockwise P,T path culminating at about 6,7 kbar and 900,950 °C. This P,T path is consistent with, but more detailed than published results, which suggests that taking a melt phase into account is not only a valid, but also a useful approach. Comparing P,T data and lithological and isotopic data for the AZ with adjacent East Gondwana fragments, suggests the presence of a coherent metasedimentary unit exposed from southern Madagascar via South India (AZ) and Sri Lanka (Wanni Complex) to the Lützow,Holm Bay in Eastern Antarctica. [source] Modelling of mineral equilibria in ultrahigh-temperature metamorphic rocks from the Anápolis,Itauçu Complex, central BrazilJOURNAL OF METAMORPHIC GEOLOGY, Issue 7 2005J. A. BALDWIN Abstract A new quantitative approach to constraining mineral equilibria in sapphirine-bearing ultrahigh-temperature (UHT) granulites through the use of pseudosections and compatibility diagrams is presented, using a recently published thermodynamic model for sapphirine. The approach is illustrated with an example from an UHT locality in the Anápolis,Itauçu Complex, central Brazil, where modelling of mineral equilibria indicates peak metamorphic conditions of about 9 kbar and 1000 °C. The early formed, coarse-grained assemblage is garnet,orthopyroxene,sillimanite,quartz, which was subsequently modified following peak conditions. The retrograde pressure,temperature (P,T) path of this locality involves decompression across the FeO,MgO,Al2O3,SiO2 (FMAS) univariant reaction orthopyroxene + sillimanite = garnet + sapphirine + quartz, resulting in the growth of sapphirine,quartz, followed by cooling and recrossing of this reaction. The resulting microstructures are modelled using compatibility diagrams, and pseudosections calculated for specific grain boundaries considered as chemical domains. The sequence of microstructures preserved in the rocks constrains a two-stage isothermal decompression,isobaric cooling path. The stability of cordierite along the retrograde path is examined using a domainal approach and pseudosections for orthopyroxene,quartz and garnet,quartz grain boundaries. This analysis indicates that the presence or absence of cordierite may be explained by local variation in aH2O. This study has important implications for thermobarometric studies of UHT granulites, mainly through showing that traditional FMAS petrogenetic grids based on experiments alone may overestimate P,T conditions. Such grids are effectively constant aH2O sections in FMAS-H2O (FMASH), for which the corresponding aH2O is commonly higher than that experienced by UHT granulites. A corollary of this dependence of mineral equilibria on aH2O is that local variations in aH2O may explain the formation of cordierite without significant changes in P,T conditions, particularly without marked decompression. [source] Metamorphism and microstructures along a high-temperature metamorphic field gradient: the north,eastern boundary of the Královský hvozd unit (Bohemian Massif, Czech Republic)JOURNAL OF METAMORPHIC GEOLOGY, Issue 4 2002D. Scheuvens Abstract A metamorphic field gradient has been investigated in the Moldanubian zone of the central European Variscides encompassing, from base to the top, a staurolite,kyanite zone, a muscovite,sillimanite zone, a K-feldspar,sillimanite zone, and a K-feldspar,cordierite zone, respectively. The observed reaction textures in the anatectic metapsammopelites of the higher grade zones are fully compatible with experimental data and petrogenetic grids that are based on fluid-absent melting reactions. From structural and microstructural observations it can be concluded that the boundary between the kyanite,staurolite zone and the muscovite- and K-feldspar,sillimanite zones coincides with an important switch in deformation mechanism(s). Besides minor syn-anatectic shearing (melt-enhanced deformation), microstructural criteria point (a) to a switch in deformation mechanism from rotation recrystallization (climb-accommodated dislocation creep) to prism
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