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Selected AbstractsThe upper continental crust, an aquifer and its fluid: hydaulic and chemical data from 4 km depth in fractured crystalline basement rocks at the KTB test siteGEOFLUIDS (ELECTRONIC), Issue 1 2005I. STOBER Abstract Detailed information on the hydrogeologic and hydraulic properties of the deeper parts of the upper continental crust is scarce. The pilot hole of the deep research drillhole (KTB) in crystalline basement of central Germany provided access to the crust for an exceptional pumping experiment of 1-year duration. The hydraulic properties of fractured crystalline rocks at 4 km depth were derived from the well test and a total of 23100 m3 of saline fluid was pumped from the crustal reservoir. The experiment shows that the water-saturated fracture pore space of the brittle upper crust is highly connected, hence, the continental upper crust is an aquifer. The pressure,time data from the well tests showed three distinct flow periods: the first period relates to wellbore storage and skin effects, the second flow period shows the typical characteristics of the homogeneous isotropic basement rock aquifer and the third flow period relates to the influence of a distant hydraulic border, probably an effect of the Franconian lineament, a steep dipping major thrust fault known from surface geology. The data analysis provided a transmissivity of the pumped aquifer T = 6.1 × 10,6 m2 sec,1, the corresponding hydraulic conductivity (permeability) is K = 4.07 × 10,8 m sec,1 and the computed storage coefficient (storativity) of the aquifer of about S = 5 × 10,6. This unexpected high permeability of the continental upper crust is well within the conditions of possible advective flow. The average flow porosity of the fractured basement aquifer is 0.6,0.7% and this range can be taken as a representative and characteristic values for the continental upper crust in general. The chemical composition of the pumped fluid was nearly constant during the 1-year test. The total of dissolved solids amounts to 62 g l,1 and comprise mainly a mixture of CaCl2 and NaCl; all other dissolved components amount to about 2 g l,1. The cation proportions of the fluid (XCa approximately 0.6) reflects the mineralogical composition of the reservoir rock and the high salinity results from desiccation (H2O-loss) due to the formation of abundant hydrate minerals during water,rock interaction. The constant fluid composition suggests that the fluid has been pumped from a rather homogeneous reservoir lithology dominated by metagabbros and amphibolites containing abundant Ca-rich plagioclase. [source] English Diarists: Gender, Geography and Occupation, 1500,1700HISTORY, Issue 298 2005ELAINE MCKAY While historians have made use of early modern English diaries as a source for information on a variety of subjects there has been little corresponding research beyond a few select biographies into those people who actually wrote the diaries of this period. From the first English diaries of the fifteenth century to the end of the seventeenth a picture can be pieced together of the growing number of diarists, their status, economic backgrounds, and where they wrote these highly personal documents. In terms of gender it is clear that although female diarists were in a minority, their ability to write analytical and intimate accounts of their lives and close environment differed little from that of their male counterparts. In terms of occupation it is evident that great events and dangerous times inspired men to re-create their lives on paper. Consequently, military and naval diaries collectively make up the largest occupation for diarists. However, diarists also earned their livings from trade, the law, as astrologers, farmers and also, in one case, as a theatre-owner. Moreover, the spread of diaries across England during the period shows that this personalized form of writing was not confined to the capital or to England's universities. [source] Effect of self-assemblies of various surfactants in their single and mixed states on the BZ oscillatory reactionINTERNATIONAL JOURNAL OF CHEMICAL KINETICS, Issue 11 2010Muzaffar Hussain Najar Micelles of different surfactants are well known to affect chemical equilibria and reactivities by selectively sequestering the reagent substrates through electrostatic and hydrophobic interactions. In this article, the effects of micelles of various surfactants on different parameters of the Ce(IV)-catalyzed Belousov,Zhabotinsky (BZ) oscillatory reaction at 35°C in nonstirred closed conditions are studied by employing spectrophotometry and tensiometry. Surfactants used in this study are the cationics hexadecyltrimethylammonium bromide (CTAB) and pentamethylene-1,5-bis(N -hexadecyl- N,N -dimethylammonium)bromide gemini (Gemini), anionic sodium dodecylbenzene sulfonate (SDBS), and nonionic Brij58, whereas the binary surfactant systems used are cationic,nonionic CTAB+Brij58 and anionic,nonionic SDBS+Brij58. The results revealed that the induction period shows a definite variation with increasing concentration of different surfactants above their critical micelle concentration (cmc). The amplitudes of oscillation and absorbance maxima and minima are enhanced in the presence of micelles of CTAB and Gemini surfactants, whereas micelles of SDBS and Brij58 have almost no effect on the nature of the oscillations. However, mixed micelles of CTAB+Brij58 and SDBS+Brij58 binary mixtures show a quite different effect on the overall behavior of the oscillations. The enhanced effect of CTAB and Gemini surfactants on the overall nature of oscillations has been attributed to the positive charge on the surface of their micelles and to some extent on the presence of nitrogen in their head group. The effect of mixed binary micelles may be attributed to their synergistic nature. © 2010 Wiley Periodicals, Inc. Int J Chem Kinet 42: 659,668, 2010 [source] The Gulf Stream and Atlantic sea-surface temperatures in AD1790,1825INTERNATIONAL JOURNAL OF CLIMATOLOGY, Issue 12 2010G. van der Schrier Abstract We present gridded sea-surface temperatures (SSTs) for the Atlantic basin (45°S,60°N) as averages over the period AD1790,1825, based on early-instrumental SST data. The original measurements were compiled by Major James Rennell and made by numerous British naval vessels on behalf of the British Admiralty. We describe the digitization of this dataset and the reconstruction of spatially coherent, averaged conditions for the boreal cold (November-March) and warm (May,September) season using a reduced space optimal interpolation (RSOI) technique, in which the data is projected on a limited number of empirical orthogonal functions. This approach is validated on modern data that are sampled in a similar way as the early-instrumental data. The reconstruction for the November,March period shows a large area with anomalously high temperatures from the point where the Gulf Stream separates from the coast until ca. 20°W. A tongue of anomalous cool water is found at the eastern side of the North Atlantic basin, along the coast of Europe and northern Africa. In the northeastern South Atlantic, anomalously high temperatures are found, while temperatures in the southwestern South Atlantic are anomalously cool. For the March,September season, anomalous temperatures in the South Atlantic are similar, but stronger, compared with those in the boreal cold season. Over the North Atlantic, there is not much similarity between the current SST reconstructions and those published in the late 1950s. Copyright © 2009 Royal Meteorological Society [source] Short-period near-contact binary systems at the beginning of the overcontact phaseMONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY, Issue 4 2002Shengbang Qian Abstract A detailed analysis of orbital period changes of seven near-contact binary stars (NCBs) (BL And, V473 Cas, XZ CMi, BV Eri, RU Eri, UU Lyn and GR Tau) with period less than 1 d has been performed and their respective O,C diagrams are formed and discussed. It is found that all systems analysed show secular period decreasing. For V473 Cas, the analysis of the period change was performed based on data collected by Moschner, Frank & Bastian. For XZ CMi, its period shows some complex changes, a possible cyclic oscillation is discovered to superpose on the secular decrease that can be explained either by the presence of a third body or by magnetic activity cycles of the components. Since the third-body assumption is consistent with the photometric solution of Rafert, XZ CMi may be a truly triple system. For BV Eri, the period decrease is only supported by weak evidence. All the seven systems are short-period NCBs with AF-type primary components where both components are filling or nearly filling the critical Roche lobe. As the period decreases, the separation between both components will be reducing and thus these systems will evolve into A-type overcontact binaries. The period decrease may be caused by mass transfer or/and by angular momentum loss via magnetic braking. Combined with the published data on the other systems of the same type, a possible statistical connection between orbital period P and its rate of decrease dP/dt is obtained: dP/dt=,5.3 × 10,7×P+ 1.3 × 10,7 d yr,1. This correlation indicates that the smaller the orbital period P is, the smaller its rate of change dP/dt will be. The correlation found in this paper indicates that there may be a smooth transition from A- and F-type NCBs with period decreases to the A- and F-type overcontact binaries that have period increases, and in that sense one may postulate that the NCBs may be the progenitors of the A-type W UMa systems and will be oscillating around a marginal-contact state as predicted by thermal relaxation oscillation (TRO) theory. [source] |