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Particular Characteristics (particular + characteristic)
Selected AbstractsStepfather involvement in social interventions made by youth protection services in stepfamiliesCHILD & FAMILY SOCIAL WORK, Issue 3 2007Claudine Parent ABSTRACT Despite efforts made by management and caseworkers to promote active parental participation in the protective context, fathers or other male figures are often brushed aside from intervention. This paper presents the results of qualitative research on methods used by youth protection caseworkers (n = 22) working with stepfather families. The main objective is to identify items that encourage or discourage stepfather involvement in psychosocial interventions. Results showed that certain items do not apply solely to stepfathers, but influence youth protection caseworker decision-making from a broader perspective. Particular characteristics associated with being a stepfather significantly influence involvement practices espoused by caseworkers, notably the absence of legal status and biological connection with the mother's children. [source] An ellipticity criterion in magnetotelluric tensor analysisGEOPHYSICAL JOURNAL INTERNATIONAL, Issue 1 2004M. Becken SUMMARY We examine the magnetotelluric (MT) impedance tensor from the viewpoint of polarization states of the electric and magnetic field. In the presence of a regional 2-D conductivity anomaly, a linearly polarized homogeneous external magnetic field will generally produce secondary electromagnetic fields, which are elliptically polarized. If and only if the primary magnetic field vector oscillates parallel or perpendicular to the 2-D structure, will the horizontal components of the secondary fields at any point of the surface also be linearly polarized. When small-scale inhomogeneities galvanically distort the electric field at the surface, only field rotations and amplifications are observed, while the ellipticity remains unchanged. Thus, the regional strike direction can be identified from vanishing ellipticities of electric and magnetic fields even in presence of distortion. In practice, the MT impedance tensor is analysed rather than the fields themselves. It turns out, that a pair of linearly polarized magnetic and electric fields produces linearly polarized columns of the impedance tensor. As the linearly polarized electric field components generally do not constitute an orthogonal basis, the telluric vectors, i.e. the columns of the impedance tensor, will be non-orthogonal. Their linear polarization, however, is manifested in a common phase for the elements of each column of the tensor and is a well-known indication of galvanic distortion. In order to solve the distortion problem, the telluric vectors are fully parametrized in terms of ellipses and subsequently rotated to the coordinate system in which their ellipticities are minimized. If the minimal ellipticities are close to zero, the existence of a (locally distorted) regional 2-D conductivity anomaly may be assumed. Otherwise, the tensor suggests the presence of a strong 3-D conductivity distribution. In the latter case, a coordinate system is often found, in which three elements have a strong amplitude, while the amplitude of the forth, which is one of the main-diagonal elements, is small. In terms of our ellipse parametrization, this means, that one of the ellipticities of the two telluric vectors approximately vanishes, while the other one may not be neglected as a result of the 3-D response. The reason for this particular characteristic is found in an approximate relation between the polarization state of the telluric vector with vanishing ellipticity and the corresponding horizontal electric field vector in the presence of a shallow conductive structure, across which the perpendicular and tangential components of the electric field obey different boundary conditions. [source] The Emergence Of Multi-Inspectorate Inspections: 'Going It Alone Is Not An Option'PUBLIC ADMINISTRATION, Issue 4 2000Enid Mordaunt Drawing on data from HM Inspectorate of Prisons, HM Inspectorate of Probation, the Office for Standards in Education and the Social Services Inspectorate, this paper develops a typology of inspection, classified according to the focus of inspection. Five basic inspection types emerge, namely single institutional, multi-service, the-matic, survey and monitoring review. The typology is further categorized by a range of characteristics, resulting in a series of variants. The paper then focuses on the particular characteristic of the multi-inspectorate approach to inspection, because this is seen to offer a significant development in inspection practice that is set to expand and develop in the future. By examining operational examples of this approach it becomes clear that inspectorates are affecting the working practices of one another as they use the multi-inspectorate approach as an exercise in bench-marking. [source] Comparison between Principal Component Analysis and Independent Component Analysis in Electroencephalograms ModellingBIOMETRICAL JOURNAL, Issue 2 2007C. Bugli Abstract Principal Component Analysis (PCA) is a classical technique in statistical data analysis, feature extraction and data reduction, aiming at explaining observed signals as a linear combination of orthogonal principal components. Independent Component Analysis (ICA) is a technique of array processing and data analysis, aiming at recovering unobserved signals or ,sources' from observed mixtures, exploiting only the assumption of mutual independence between the signals. The separation of the sources by ICA has great potential in applications such as the separation of sound signals (like voices mixed in simultaneous multiple records, for example), in telecommunication or in the treatment of medical signals. However, ICA is not yet often used by statisticians. In this paper, we shall present ICA in a statistical framework and compare this method with PCA for electroencephalograms (EEG) analysis. We shall see that ICA provides a more useful data representation than PCA, for instance, for the representation of a particular characteristic of the EEG named event-related potential (ERP). (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Implementation, performance, and science results from a 30.7 TFLOPS IBM BladeCenter clusterCONCURRENCY AND COMPUTATION: PRACTICE & EXPERIENCE, Issue 2 2010Craig A. Stewart Abstract This paper describes Indiana University's implementation, performance testing, and use of a large high performance computing system. IU's Big Red, a 20.48 TFLOPS IBM e1350 BladeCenter cluster, appeared in the 27th Top500 list as the 23rd fastest supercomputer in the world in June 2006. In spring 2007, this computer was upgraded to 30.72 TFLOPS. The e1350 BladeCenter architecture, including two internal networks accessible to users and user applications and two networks used exclusively for system management, has enabled the system to provide good scalability on many important applications while being well manageable. Implementing a system based on the JS21 Blade and PowerPC 970MP processor within the US TeraGrid presented certain challenges, given that Intel-compatible processors dominate the TeraGrid. However, the particular characteristics of the PowerPC have enabled it to be highly popular among certain application communities, particularly users of molecular dynamics and weather forecasting codes. A critical aspect of Big Red's implementation has been a focus on Science Gateways, which provide graphical interfaces to systems supporting end-to-end scientific workflows. Several Science Gateways have been implemented that access Big Red as a computational resource,some via the TeraGrid, some not affiliated with the TeraGrid. In summary, Big Red has been successfully integrated with the TeraGrid, and is used by many researchers locally at IU via grids and Science Gateways. It has been a success in terms of enabling scientific discoveries at IU and, via the TeraGrid, across the US. Copyright © 2009 John Wiley & Sons, Ltd. [source] Seismic collapse risk of precast industrial buildings with strong connectionsEARTHQUAKE ENGINEERING AND STRUCTURAL DYNAMICS, Issue 8 2010Miha Kramar Abstract A systematic seismic risk study has been performed on some typical precast industrial buildings that consists of assemblages of cantilever columns with high shear-span ratios connected to an essentially rigid roof system with strong pinned connections. These buildings were designed according to the requirements of Eurocode 8. The numerical models and procedures were modified in order to address the particular characteristics of the analyzed system. They were also verified by pseudo-dynamic and cyclic tests of full-scale large buildings. The intensity measure (IM)-based solution strategy described in the PEER methodology was used to estimate the seismic collapse risk in terms of peak ground acceleration capacity and the probability of exceeding the global collapse limit state. The effect of the uncertainty in the model parameters on the dispersion of collapse capacity was investigated in depth. Reasonable seismic safety (as proposed by the Joint Committee on Structural Safety) was demonstrated for all the regular single-storey precast industrial buildings addressed in this study. However, if the flexural strength required by EC8 was exactly matched, and the additional strength, which results from minimum longitudinal reinforcement, was disregarded as well as large dispersion in records was considered, the seismic risk might in some cases exceed the acceptable limits. Copyright © 2009 John Wiley & Sons, Ltd. [source] Illusory and spurious correlations: distinct phenomena or joint outcomes of exemplar-based category learning?EUROPEAN JOURNAL OF SOCIAL PSYCHOLOGY, Issue 3 2006Thorsten Meiser Stereotype formation about novel groups was analyzed with trivariate stimulus distributions that were generated by group membership, valence of behavior, and a context variable. Within this stimulus setting, we manipulated the confounding role of the context variable and the distinctiveness of events in terms of their relative infrequency. The experimental procedure allowed us to analyze illusory and spurious correlations in a joint framework, to conduct focused tests for memory effects of relative infrequency and to investigate the detection of covariations with the context variable. The results revealed that illusory and spurious correlations were formed without enhanced memory for infrequent events and with existing covariations of the confounding context factor being well extracted. These observations suggest that illusory and spurious correlations can be understood without assuming specific cognitive processes that are tied to the particular characteristics of a given stimulus distribution, such as enhanced memory in the case of relative infrequency and neglect of a context variable in the case of a confounding factor. Instead, computer simulations with an exemplar-based learning model demonstrated that exemplar-based category learning may provide a coherent and integrative theoretical framework for illusory correlations, spurious correlations and true contingency learning in social cognition. Copyright © 2006 John Wiley & Sons, Ltd. [source] Solid-State Lasers: (Materials for a Reliable Solid-State Dye Laser at the Red Spectral Edge) Adv.ADVANCED FUNCTIONAL MATERIALS, Issue 16 2009Funct. New photosensitive materials based on dye-doped polymeric matrices as active media in solid-state dye lasers allow highly efficient, stable, laser action, with fine tuning of the emitting wavelength from visible to NIR spectral region (575,750 nm) possible. These particular characteristics impelled the building of a prototype SSDL, which was compact, hazardless, versatile, and easy to handle. [source] Materials for a Reliable Solid-State Dye Laser at the Red Spectral EdgeADVANCED FUNCTIONAL MATERIALS, Issue 16 2009Inmaculada Garcia-Moreno Abstract In the search to extend the tuning range of solid-state dye lasers (SSDLs) to the red-edge spectral region, new photosensitive materials have been designed and synthesized based on six commercial dyes (sulforhodamine B, perylene red, rhodamine 640, LDS698, LDS722, and LDS730) incorporated into different linear, crosslinked, fluorinated, and sililated polymeric matrices. Under transversal pumping at 532,nm, these materials exhibit highly efficient, stable, as well as wavelength-tunable laser action from the visible-to-NIR spectral region (575,750,nm). The lasing performance of the materials doped with perylene and xanthene dyes is, to the best of our knowledge, the highest achieved to date for these chromophores when incorporated into organic, inorganic, or hybrid matrices. Regarding the LDS derivatives, this is the first time that laser action from these dyes in solid-state media is reported. These particular characteristics have impelled the building of the first prototype SSDL that is compact, versatile, and easy to handle. [source] The EFQM Excellence Model®: Higher Education's Latest Management Fad?HIGHER EDUCATION QUARTERLY, Issue 4 2005Paul Temple Robert Birnbaum argues that higher education tends to adopt management fads , newly conceived techniques enjoying brief popularity but which fail to live up to their promoters' claims , at the point when the corporate sector and government are discarding them. Although fads may have failed in these sectors because of various reasons, their failure usually to engage with the complexity of higher education's structures and processes makes their failure here virtually inevitable. The European Foundation for Quality Management Excellence Model, it is argued here, is a classical fad in Birnbaum's sense, showing conceptual weaknesses and being unlikely to engage with the particular characteristics of higher education. The introduction of the Excellence Model into UK higher education is shown to have followed closely the path that Birnbaum has identified; there are also preliminary signs suggesting that it will decline along the predicted trajectory. [source] Advanced and intelligent technologies for reliable operation of power systems and electricity marketsIEEJ TRANSACTIONS ON ELECTRICAL AND ELECTRONIC ENGINEERING, Issue 5 2008Ryuichi Yokoyama Senior Member Abstract Deregulation of power industries is still progressing in many countries, aiming at reduction of the electricity price, diversity of customer diverse choices, services and promotion of new business and keeping supply reliability. Many countries are testing this notion in anticipation of lower power prices through open competition. In such a competitive situation, it is necessary for suppliers to take on the responsibility of keeping supply reliability at the load end in order to prevent outages, for instance, independent power producers (IPP) placing distributed generations (DGs) close to the load or conventional utilities utilizing advanced and intelligent system operation/control technologies that are costly. Usually, customers pay one price for power that is good enough for ordinary use, therefore not necessarily highly consistent in quality of voltage, current, frequency or reliability. However, if customers desire better quality power, additional fees are added according to the particular characteristics desired, thus customers are supplied with this type of better power that they choose. Under such a worldwide new trend in power systems and markets, this article is edited for the purpose of introducing the most advanced technologies and the newest issues related to reliable and stable operations of power markets and systems in the competitive environment. © 2008 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc. [source] Gene signatures of pulmonary metastases of renal cell carcinoma reflect the disease-free interval and the number of metastases per patientINTERNATIONAL JOURNAL OF CANCER, Issue 2 2009Daniela Wuttig Abstract Our understanding of metastatic spread is limited and molecular mechanisms causing particular characteristics of metastasis are largely unknown. Herein, transcriptome-wide expression profiles of a unique cohort of 20 laser-resected pulmonary metastases (Mets) of 18 patients with clear-cell renal cell carcinoma (RCC) were analyzed to identify expression patterns associated with two important prognostic factors in RCC: the disease-free interval (DFI) after nephrectomy and the number of Mets per patient. Differentially expressed genes were identified by comparing early (DFI , 9 months) and late (DFI , 5 years) Mets, and Mets derived from patients with few (,8) and multiple (,16) Mets. Early and late Mets could be separated by the expression of genes involved in metastasis-associated processes, such as angiogenesis, cell migration and adhesion (e.g., PECAM1, KDR). Samples from patients with multiple Mets showed an elevated expression of genes associated with cell division and cell cycle (e.g., PBK, BIRC5, PTTG1) which indicates that a high number of Mets might result from an increased growth potential. Minimal sets of genes for the prediction of the DFI and the number of Mets per patient were identified. Microarray results were confirmed by quantitative PCR by including nine further pulmonary Mets of RCC. In summary, we showed that subgroups of Mets are distinguishable based on their expression profiles, which reflect the DFI and the number of Mets of a patient. To what extent the identified molecular factors contribute to the development of these characteristics of metastatic spread needs to be analyzed in further studies. © 2009 UICC [source] Characteristics of adolescent depressionINTERNATIONAL JOURNAL OF MENTAL HEALTH NURSING, Issue 1 2006Marie Crowe ABSTRACT:, Depression is a common psychiatric disorder that is acknowledged to be increasing in disease burden. The rates of adolescent depression is particularly concerning as they continue to increase. The seriousness and pervasive effects of depression on young people's lives supports the view that research that extends the knowledge in this area is vital. This is a descriptive study of the characteristics of depression in a sample of 121 adolescents attending an outpatient specialist adolescent mental health service in New Zealand. The adolescents were required to complete two self-report measures to assess presence of depressive symptoms, severity of depression, and particular characteristics of the depression. The findings revealed that irritability was the most common characteristic along with other interpersonal and thought processing symptoms. It is important that mental health nurses are able to identify the specific characteristics of adolescent depression that may differ from adult depression in order to manage this patient population effectively. [source] A heterogeneous-network aided public-key management scheme for mobile ad hoc networksINTERNATIONAL JOURNAL OF NETWORK MANAGEMENT, Issue 1 2007Yuh-Min Tseng A mobile ad hoc network does not require fixed infrastructure to construct connections among nodes. Due to the particular characteristics of mobile ad hoc networks, most existing secure protocols in wired networks do not meet the security requirements for mobile ad hoc networks. Most secure protocols in mobile ad hoc networks, such as secure routing, key agreement and secure group communication protocols, assume that all nodes must have pre-shared a secret, or pre-obtained public-key certificates before joining the network. However, this assumption has a practical weakness for some emergency applications, because some nodes without pre-obtained certificates will be unable to join the network. In this paper, a heterogeneous-network aided public-key management scheme for mobile ad hoc networks is proposed to remedy this weakness. Several heterogeneous networks (such as satellite, unmanned aerial vehicle, or cellular networks) provide wider service areas and ubiquitous connectivity. We adopt these wide-covered heterogeneous networks to design a secure certificate distribution scheme that allows a mobile node without a pre-obtained certificate to instantly get a certificate using the communication channel constructed by these wide-covered heterogeneous networks. Therefore, this scheme enhances the security infrastructure of public key management for mobile ad hoc networks. Copyright © 2006 John Wiley & Sons, Ltd. [source] Barriers to brand building in UK universities?INTERNATIONAL JOURNAL OF NONPROFIT & VOLUNTARY SECTOR MARKETING, Issue 1 2007Chris Chapleo Branding in universities has become an increasingly topical issue with practitioners, with some institutions committing substantial financial resources to branding activities. It has, however, received only limited academic investigation, and as the particular characteristics of the sector present challenges for those seeking to build brands, it seems to be timely and appropriate to investigate potential barriers to branding. This exploratory study investigates the opinions of the ,brand guardians' of UK universities,Vice Chancellors, Principals and Rectors,on the barriers to successfully building brands and draws conclusions on their views of the key challenges facing successful branding activity in the sector. Implications for practitioners are also explored. Copyright © 2006 John Wiley & Sons, Ltd. [source] The nonconserved N-terminus of protein phosphatase 2B confers its properties to protein phosphatase 1IUBMB LIFE, Issue 2 2009Xiu-Jie Xie Abstract The protein phosphatase 1 catalytic subunit (PP1c) and the protein phosphatase 2B (PP2B or calcineurin) catalytic subunit (CNA) contain nonconserved N-terminal regions followed by conserved phosphatase cores. To examine the role of the N-termini of these two phosphatases, we substituted the residues 1,8 of PP1c with residues 1,42 of CNA, which is designated CNA(1-42)-PP1(9-330). The activities of CNA(1-42)-PP1(9-330) were similar to those of PP2B and different from those of PP1. The chimera was at least fourfold less sensitive to inhibition by okadaic acid, but was stimulated by nickel ions and chlorogenic acid, characteristics of PP2B not of PP1. These observations suggest that the N-terminus of CNA shifts the properties of PP1 toward those of PP2B. Our findings provide evidence that the nonconserved N-terminus of PP2B not only functions as important regulatory domain but also confers itself particular characteristics. This region may be targeted for regulation of PP2B activities in vivo. © 2008 IUBMB IUBMB Life, 61(2): 178,183, 2009 [source] Fall risk factors in older people with dementia or cognitive impairment: a systematic reviewJOURNAL OF ADVANCED NURSING, Issue 5 2009Jürgen Härlein Abstract Title.,Fall risk factors in older people with dementia or cognitive impairment: a systematic review. Aim., This paper is a report of a review conducted to identify and summarize specific risk factors for falls in older people with dementia or cognitive impairments as documented by prospective or case,control studies. Background., People with dementia have a doubled to threefold risk for falls, but the reasons for this have not yet been fully explained. Several integrative literature reviews discuss possible specific fall risk factors. However, there is lack of a systematic evaluation of studies. Data sources., The CINAHL, PubMed, EMBASE and PsychInfo databases were searched for the period between 1980 and May 2007. Review methods., A systematic review was conducted. Cohort or case,control studies published in English or German were included if they investigated risk factors for falls or fall-related injuries in a sample consisting of participants with dementia or cognitive impairment. Two reviewers independently assessed study quality. Results., Six prospective studies were included in the review. These differed concerning samples, settings, follow-up periods and examined variables. Therefore, meta-analysis was not possible. Eight categories of risk factors emerged: disease-specific motor impairments, impaired vision, type and severity of dementia, behavioural disturbances, functional impairments, fall history, neuroleptics and low bone mineral density. Conclusion., There is lack of sound studies examining fall risk factors in cognitively impaired elders. Well-known risk factors such as motor impairment show particular characteristics in people with dementia. In addition, behavioural disturbances contribute to their high risk for falls. Further prospective studies are needed. [source] Habitat assessment for a rare, arboreal forest mammal, the tree hyrax Dendrohyrax arboreusAFRICAN JOURNAL OF ECOLOGY, Issue 2 2001A. Gaylard Abstract Recent findings have suggested that there has been a change in the structural nature of forests in the Eastern Cape, South Africa, which explains decreases in forest fauna. One of these (rare) forest species is the tree hyrax Dendrohyrax arboreus, a nocturnal, arboreal folivore, which makes use of cavity-bearing trees as dens. However, a conflict exists between the use of forest resources and in protecting habitats for the tree hyrax. In order to design appropriate management strategies, conservation authorities and forest managers require information regarding the specific habitat requirements of fauna in their forest, particularly those that are already threatened by resource use. The aims of this study were thus: (i) to characterise the den trees of D. arboreus, (ii) to determine whether D. arboreus selects for certain den tree characteristics (i.e. relative to the abundance of that characteristic); and (iii) to develop a habitat assessment model for D. arboreus. The tree hydrax was found to select for den trees with particular characteristics: seven tree species were selected as den trees, which were usually the tallest trees in the canopy (4,8 m). Den trees were usually only partly decayed, with multiple cavity entrances and trunk angles of between 45° and 68°. Cavity entrance and orientation did not appear to play a role in den tree selection by D. arboreus. A function which discriminated between den trees and non-den trees was calculated, and can be used to determine the suitability of a tree as a den for a tree hyrax (and thus to prevent it from being removed during commercial logging operations), or to assess the suitability of an area for habitation by tree hyraxes. This model can therefore help to alleviate the conflict between forest conservation managers and resource users in the Eastern Cape. Résumé Des découvertes récentes laissent entendre qu'il y a eu des changements dans la nature structurelle des forêts du Cap oriental, en Afrique du Sud, qui expliquent le déclin de la faune forestière. Une de ces (rares) espèces forestières est le daman des arbres, Dendrohyrax arboreus, un nocturne arboricole, mangeur de feuilles, qui utilise les cavités dans les arbres comme terriers. Cependant, il existe un conflit entre l'utilisation des ressources forestières et la protection de l'habitat des damans des arbres. Afin de concevoir une stratégie de gestion adéquate, les autorités de la conservation et les gestionnaires forestiers ont besoin d'informations sur les exigences spécifiques en matière d'habitat de la faune de leurs forêts et particulièrement des espèces qui sont déjà menacées par l'utilisation des ressources. Les buts de cette étude étaient donc : (i) de caractériser les arbres qui servent de refuge àD. arboreus, (ii) de déterminer si D .arboreus choisit certaines caractéristiques des arbres qui lui servent d'abris (i.e. en fonction de l'abondance de cette caractéristique) et (iii) de mettre au point un modèle d'évaluation de l'habitat pour D. arboreus. On a découvert que le daman choisissait comme refuge des arbres qui avaient certaines caractéristiques : sept espèces d'arbres étaient choisies comme abris, qui étaient d'habitude les plus hauts arbres de la canopée (4 ,,8 m). Les arbres choisis n'étaient d'habitude que partiellement abîmés, avec des nombreuses entrées vers des creux et des troncs formant un angle compris entre 45° et 68°. L'entrée et l'orientation de la cavité ne semblaient pas jouer un rôle dans le choix de l'arbre par D. arboreus. On a calculé une fonction qui faisait la distinction entre les arbres qui servaient d'abris et les autres et qui peut servir à déterminer si un arbre convient pour servir d'abri à un daman des arbres (et donc à empêcher de le supprimer lors des opérations d'abattage commercial), ou àévaluer si une zone convient comme habitat pour les damans des arbres. Ce modèle peut donc aider à réduire les conflits entre les responsables de la conservation des forêts et ceux qui veulent en utiliser les ressources au Cap oriental. [source] Equity-Liabilities Distinction: The case for Co-operatives,JOURNAL OF INTERNATIONAL FINANCIAL MANAGEMENT & ACCOUNTING, Issue 3 2009Germán López-Espinosa Members' shares in co-operative entities are financial instruments with particular characteristics. In this paper we analyse the relation between firm leverage and systematic risk to provide empirical evidence on the economic substance of the member shares of members of cooperatives. We have studied the characteristics of members' shares in six European countries: France, Germany, Italy, Portugal, Spain and United Kingdom. We have also conducted tests on co-operatives of these countries over the period 1993,2005. The study reports that in global terms the economic substance of the redeemable part of equity in co-operatives is not the same across countries. Therefore if accounting standards setters want to develop a global standard for co-operatives, a recommendation derived from this study would be to follow a probabilistic model to classify the redeemable part of co-operative financial instruments, where the entity does not have the unconditional right to refuse the redemption, or to report this part as an intermediate item with characteristics of debt and equity. [source] Solvent effects on chemical processes: new solvents designed on the basis of the molecular,microscopic properties of (molecular solvent,+,1,3-dialkylimidazolium) binary mixturesJOURNAL OF PHYSICAL ORGANIC CHEMISTRY, Issue 2 2008P. M. Mancini Abstract The purpose of this work was to analyze the microscopic feature of binary solvent systems formed by a molecular solvent (acetonitrile or dimethylformamide or methanol) and an ionic liquid (IL) cosolvent [1-(1-butyl)-3-methylimidazolium tetrafluoroborate or 1-(1-butyl)-3-methylimidazolium hexafluorophosphate]. The empirical solvatochromic solvent parameters ET(30), ,*, ,, and , were determined from the solvatochromic shifts of adequate indicators. The behavior of the solvent systems was analyzed according to their deviation from ideality. The study focused on the identification of solvent mixtures with relevant solvating properties in order to select mixed solvents with particular characteristics. The comparison of the molecular,microscopic solvent parameters corresponding to the selected binary mixtures with both ILs considered at similar mixed-solvent composition revealed that the difference is centered on the basic character of them. A kinetic study of a nucleophilic aromatic substitution reaction between 1-fluoro-2,4-dinitrobenzene (FDNB) and 1-butylamine (BU) developed in (acetonitrile or dimethylformamide,+,IL) solvent mixtures is presented in order to investigate and compare the solvent effects on a chemical process. For the explored reactive systems the solvation behavior is dominated by both the dipolarity/polarizability and the basicity of the media, contributing these solvent properties to accelerating the chemical process. Copyright © 2007 John Wiley & Sons, Ltd. [source] SENSORY CHARACTERIZATION OF VITIS VINIFERA CV. MALBEC WINES FROM SEVEN VITICULTURE REGIONS OF ARGENTINAJOURNAL OF SENSORY STUDIES, Issue 5 2007MARÍA CRISTINA GOLDNER ABSTRACT Fifty-six Malbec wines from seven Argentine viticulture regions (Valles Calchaquíes, Mendoza del Este, Mendoza del Sur, Patagonia, Alto Río Mendoza, Valle de Uco and San Juan), of the 2004 vintage, were evaluated by sensory descriptive analysis using a panel of 10 not-sighted assessors. "Noncommercial" samples were obtained using standardized conditions, not aging and produced with grapes corresponding to each viticulture region. Malbec wines from same regions exhibited particular characteristics. Valles Calchaquíes wines had strong herbal, spicy, sweet pepper aromas and pungency in contrast to San Juan wines that showed fruity, strawberry, honey and citrus aromas. Mendoza del Este and Valle de Uco wines were associated with cooked fruit, raisin, floral and sweetness attributes as opposed to Mendoza del Sur and Patagonia wines which were characterized by sourness, bitterness, persistency and astringency, and not by aroma attributes. Alto Río Mendoza wines were characterized by pungency, sweet pepper and bitterness. PRACTICAL APPLICATIONS Sensory profiling of "non-commercial" Malbec wines developed in this research could be used as a tool to differentiate and classify Argentine Controlled Denominations of Origin (DOC). Wines with DOC have important value in the market and they are original country representative in the world. The results of this study suggest that Malbec wines from some of the regions located in latitudes 31,33° (San Juan, Mendoza del Este and Valle de Uco; Argentina) were associated with the most desired sensory characteristics. Out of these latitudes, wine-making process would have more importance on Malbec wine quality. [source] Case studies in novel narial anatomy: 2.JOURNAL OF ZOOLOGY, Issue 4 2004The enigmatic nose of moose (Artiodactyla: Cervidae: Alces alces) Abstract The facial region of moose Alces alces is highly divergent relative to other cervids and other ruminants. In particular, the narial region forms an expanded muzzle or proboscis that overhangs the mouth. The nose of moose provides a case study in the evolution of narial novelty within a phylogenetically well-resolved group (Cervidae). The function of the nasal apparatus of moose remains enigmatic, and new hypotheses are proposed based on our anatomical findings. Head specimens of moose and outgroup taxa were subjected to medical imaging (CT scanning), vascular injection, gross anatomical dissection, gross sectioning, and skeletonization. Moose noses are characterized by highly enlarged nostrils accompanied by specialized musculature, expanded nasal cartilages, and an increase in the connective-tissue pad serving as the termination of the alar fold. The nostrils are widely separated, and the rhinarium that encircles both nostrils in outgroups is reduced to a tiny central patch in moose. The dorsal lateral nasal cartilage is modified to form a pulley mechanism associated with the levator muscle of the upper lip. The lateral accessory nasal cartilage is enlarged and serves as an attachment site for musculature controlling the aperture of the nostril, particularly the lateralis nasi, the apical dilatators, and the rectus nasi. Bony support for narial structures is reduced. Moose show greatly enlarged nasal cartilages, and the entire osseocartilaginous apparatus is relatively much larger than in outgroups. The nasal vestibule of moose is very large and houses a system of three recesses: one rostral and one caudal to the nostrils, and one associated with the enlarged fibrofatty alar fold. As a result of the expanded nasal vestibule, osseous support for the nasal conchae (i.e. turbinates) has retracted caudally along with the bony nasal aperture. The nasoturbinate and its mucosal counterparts (dorsal nasal concha and rectal fold) are reduced. The upturned maxilloturbinate, however, is associated with an enlarged ventral nasal concha and alar fold. Moose are the only species of cervid with these particular characteristics, indicating that this anatomical configuration is indeed novel. Although functional hypotheses await testing, our anatomical findings and published behavioural observations suggest that the novel narial apparatus of moose probably has less to do with respiratory physiology than with functions pertaining specifically to the nostrils. The widely separated and laterally facing nostrils may enhance stereolfaction (i.e. extracting directional cues from gradients of odorant molecules in the environment), but other attributes of narial architecture (enlarged cartilages, specialized musculature, recesses, fibrofatty pads) suggest that this function may not have been the evolutionary driving force. Rather, these attributes suggest a mechanical function, namely, an elaborated nostril-closing system. [source] The (dis)appearance of the dying patient in generalist hospital and care home nurses' talk about the patientNURSING PHILOSOPHY, Issue 4 2008Kirsten Schou PhD Abstract, This article explores interview data from a study of 50 Norwegian generalist nurses' focus group accounts of caring for dying patients in the hospital and care home. An eclectic discourse analytic approach was applied to nurses' accounts of the patient and three discursive contexts of reference to the patient were identified: the ,taken as read' patient, the patient paired with particular characteristics and the patient as psychologically present. Talk about the patient falls mainly into the first two contexts, which position the patient in relation to three closely related discursive processes: individualization, anonymization and objectification. The third context presents the patient as a person with a particular identity. The analysis is discussed in a broader philosophical and sociological context in which we return to some of the theoretical work on death and dying of the 1990s and the topic of sequestration. We suggest that nurses' talk about the patient can be heard to participate in a continuing sequestration of the dying patient in healthcare institutions focused on ,result-oriented' care. [source] The Importance of Deviance in Intellectual DevelopmentAMERICAN JOURNAL OF ECONOMICS AND SOCIOLOGY, Issue 1 2004Especially at Virginia Tech in the 1970s This paper seeks to explain the success of public choice at Virginia Tech in the 1970s in two ways. First, I reflect on my graduate school experience at Virginia Tech, with the intent of identifying particular characteristics of the people and location of Virginia Tech, including its remoteness, that facilitated the development of the paradigm shift that public choice, in the late 1960s and early 1970s, represented. Second, I argue that the success of public choice at Virginia Tech depended critically upon the willingness of the people here to disconnect from professional constraints and to think outside the conventional economics box. I make this point with the aid of a computer simulation of the evolutionary development of "people" (or "trials") as they attempt to scale the highest "mountain" within a "mountain range," the exact features of which (including the heights of the various "mountains") are not known before the climb is started. In such an environment, finding the highest peak, the assumed goal, is critically dependent on a measure of "deviance," or the willingness to shun short-run opportunities of exploiting accepted methods. [source] The structure of vocalization of ewes and male lambs at pastureANIMAL SCIENCE JOURNAL, Issue 1 2009Hirofumi NAEKAWA ABSTRACT We performed an analysis of the vocalization of 161 ewes and 50 male lambs that were pastured day and night. The vocalization structures of the phonetic notations of the opened-mouth from closed mouth /,aee/ and /,naeee/ and closed-mouth /,,,,/ of ewes, and the opened-mouth from closed-mouth /,eee/ and /,neeee/ and closed-mouth /,,,,/ of male lambs were studied in terms of their audio characteristics. The items subject to analysis included duration of each vocalization, fundamental frequency, sound pressure and first formant (F1), second formant (F2), and third formant (F3). Among the male lambs, the duration of each call type showed significant differences depending on the behavior types or the target types, and the closed-mouth to open-mouth sounds, /,eee/ and /,neeee/ showed a tendency to be longer than the closed-mouth sound of /,,,,/. A significant correlation (r = 0.9, P < 0.05) was observed between the fundamental frequency and F1 with the /,eee/ type of call of the male lambs when the vocalization was targeted toward the stockperson. When the ewes' behavior pattern was grazing and moving and the calling target was an ewe, the sound pressure significantly differed between /,,,,/ and /,naeee/ (P < 0.05). From the analysis of the call durations, the fundamental frequencies, the sound pressures and formants, and the particular characteristics in sound structure were shown to vary according to the vocalization conditions and the situations, and where the animals were placed, even within the same call types. [source] Ionic Mechanisms and Vectorial Model of Early Repolarization Pattern in the Surface Electrocardiogram of the AthleteANNALS OF NONINVASIVE ELECTROCARDIOLOGY, Issue 3 2008Eduardo C. Barbosa M.D. Background: The electrocardiogram (ECG) of the athlete displays particular characteristics as a consequence of both electrophysiological and autonomic remodeling of the heart that follows continued physical training. However, doubts persist on how these changes directly interact during ventricular activation and repolarization ultimately affecting surface ECG waveforms in athletes. Objective: This article considers an in deep rationale for the electrocardiographic pattern known as early repolarization based on both electrophysiological mechanisms at cellular level and the vectorial theory of the cardiac activation. Methods: The mechanism by which the autonomic remodeling influences the cardiac electrical activation is reviewed and an insight model of the ventricular repolarization based on ionic models and the vectorial theory of the cardiac activation is proposed. Results: Considering the underlying processes related to ventricular electrical remodeling, we propose that, in athletes' heart: 1) vagal modulation increases regional electrophysiological differences in action potential phases 1 and 2 amplitudes, thus enhancing a voltage gradient between epicardial and endocardial fibers; 2) this gradient affects depolarization and repolarization timing sequences; 3) repolarization wave front starts earlier on ventricular wall and partially overcomes the end of depolarization causing an upward displacement of the J-point, ST segment elevation, and inscription of magnified T-waves amplitudes leading to characteristic surface ECG waveform patterns. Conclusions: In athletes, the association between epicardial to endocardial electrophysiological differences and early repolarization ECG pattern can be demonstrated by the vectorial theory of the ventricular activation and repolarization. [source] Fruit Traits in Baboon Diet: A Comparison with Plant Species Characteristics in West AfricaBIOTROPICA, Issue 3 2010Britta K. Kunz ABSTRACT Primate fruit choice among plant species has been attributed to different morphological plant and fruit characteristics. Despite a high abundance of animal-dispersed plant species in the savanna,forest mosaic of West Africa, few data are available on the interplay between morphological fruit traits and primate fruit consumers in this ecosystem. We tested whether olive baboons (Papio anubis) at Comoé National Park, north-eastern Ivory Coast, prefer fruit species with particular characteristics relative to the availability of these traits among the woody plant species at the study site. Specifically we were interested in the suites of traits that best predict fruit choice and seed handling by baboons. The baboons ate fruit/seeds from 74 identified plant species, representing 25 percent of the regional pool of woody plant species. They preferred trees to shrubs and lianas as fruit sources. Otherwise, baboons seemed to consume whatever fruit type, color, and size of fruit and seeds available, though they especially included larger fruit into their diet. Against expectations from the African bird,monkey fruit syndrome of brightly colored drupes and berries, baboons ate mostly species having large, dull-colored fruit. Fruit type and color best described whether baboons included a species into their diet, whereas fruit type and seed size best predicted whether baboons predated upon the seeds of their food plant species. As most plant species at the study site had medium-sized to large fruits and seeds, large frugivores like baboons might be particularly important for plant fitness and plant community dynamics in West African savanna,forest ecosystems. Abstract in French is available at http://www.blackwell-synergy.com/loi/btp [source] | |||||||||||||||||||||||||||||||