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PVC/wood-flour Composites (pvc + composite)
Selected AbstractsFriction and wear properties of NBR/PVC compositesJOURNAL OF APPLIED POLYMER SCIENCE, Issue 4 2007Xinwu Huang Abstract Acrylonitrial butadiene rubber (NBR)/Polyvinyl chloride (PVC) composites with different PVC content were prepared. The effect of PVC content on the mechanical strength and tribological properties of the NBR/PVC composites was investigated. The morphologies of the worn traces and debris of NBR/PVC composites and worn traces of mating ball were observed using a scanning electron microscope (SEM). It was found that the friction and wear of NBR/PVC was lower than that of NBR without PVC. The NBR/PVC composite with 30% PVC content showed the best synthetic mechanical and tribological properties. The inferior elastic properties and the lesser deformation under the applied load of composites with PVC resulted in hysteric force and adhesion force decrease, which leading to a lower friction and wear of NBR/PVC composites. The frictional failure unit of NBR70/PVC30 composite being smaller should be an important reason of the wear of the composite being lowest. The lubricating effect of PVC played an important role in decreasing the friction coefficient and wear of NBR/PVC composites. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 [source] Development of novel conducting composites of nanostructured poly(1-naphthylamine) with poly(vinyl chloride)POLYMER COMPOSITES, Issue 5 2009Ufana Riaz Investigations on the synthesis of nanoconducting polymers have gained much popularity during the past few decades. The processibility of the nanostructured conducting polymers is poor, which hinders their commercial application. Considering the drawbacks of nanostructured conducting polymers, this article reports for the first time the synthesis of processible composites of nanostructured poly(1-naphthylamine) (PNA), a polyaniline derivative with poly(vinyl chloride) (PVC). The composites were prepared by loading different weight ratios of PNA (2,10 wt%) in PVC. The composites were characterized by spectral, thermal, morphological, and conductivity studies. The particle size of PNA/PVC composites was confirmed by transmission electron microscopy and was found to be in the range of 5,20 nm. The highest conductivity of 2.5 × 10,2 S/cm was obtained in the composite with 4 wt% loading of PNA. The high conductivity of the composites was correlated to the agglomerate-free uniform dispersion of self-assembled nanofibrillar network of PNA particles in the PVC matrix. The PNA/PVC composites exhibited good mechanical properties, which holds potential for use in semiconductor nanodevices. POLYM. COMPOS., 2009. © 2008 Society of Plastics Engineers [source] Properties of recycled material containing poly(vinyl chloride), polypropylene, and calcium carbonate nanofillerPOLYMER ENGINEERING & SCIENCE, Issue 3 2008Branka Andri Even at low content, polypropylene significantly worsens mechanical properties of the recycled PVC composite, i.e. tensile strength at break and elongation at break. But, if small quantities of surface modified nanofiller calcium carbonate is added, an applicable composite that contains 10,30% of waste material can be made. It was determined that nanosized calcium carbonate lowers melting point of polypropylene, perhaps by changing its crystalline form and has no influence on thermooxidative degradation of poly(vinyl chloride). Addition of nanofiller slightly lowers the surface free energy of the composites what is more prone when the low content of polypropylene is present. The recovery of tensile strength and elongation at break occurs and those properties reach the highest value at about 6% of CaCO3. POLYM. ENG. SCI., 2008. © 2008 Society of Plastics Engineers [source] Comparative study of the effects of chlorinated polyethylene and acrylic impact modifier on the thermal degradation of poly(vinyl chloride) compounds and poly(vinyl chloride)/(oil palm empty fruit bunch) compositesJOURNAL OF VINYL & ADDITIVE TECHNOLOGY, Issue 2 2010Aznizam Abu Bakar The effects of chlorinated polyethylene (CPE) and acrylic impact modifier (AIM) on the thermal degradation of poly(vinyl chloride) (PVC) compounds and composites were investigated. The amounts of AIM and CPE used were fixed at 9 parts per hundred parts of resin (phr), while oil palm empty fruit bunch (OPEFB) fiber content was increased from 0 to 40 phr. To produce composites, the PVC formulations were dry-blended by using a laboratory blender before being milled into sheets on a two-roll mill at 165°C. The milled sheets were then hot-pressed at 180°C. The thermal degradation of the specimens was evaluated by using thermogravimetry in a nitrogen environment. Thermal stability of the PVC/CPE compounds and PVC/CPE/OPEFB composites was improved by the addition of CPE. The CPE retarded the dehydrochlorination of PVC. However, the stabilization effect was reduced by the incorporation of OPEFB at levels of 30 and 40 phr. The presence of AIM accelerated the dehydrochlorination of PVC/AIM compounds and PVC/AIM/OPEFB composites. J. VINYL ADDIT. TECHNOL., 2010. © 2010 Society of Plastics Engineers [source] Reinforcement of rigid PVC/wood-flour composites with multi-walled carbon nanotubesJOURNAL OF VINYL & ADDITIVE TECHNOLOGY, Issue 2 2008Omar Faruk Multi-walled carbon nanotubes (CNT) were compounded with PVC by a melt blending process based on fusion behaviors of PVC. The effects of CNT content on the flexural and tensile properies of the PVC/CNT composites were evaluated in order to optimize the CNT content. The optimized CNT-reinforced PVC was used as a matrix in the manufacture of wood-plastic composites. Flexural, electrical, and thermal properties of the PVC/wood-flour composites were evaluated as a function of matrix type (nonreinforced vs. CNT-reinforced). The experimental results indicated that rigid PVC/wood-flour composites with properties similar to those of solid wood can be made by using CNT-reinforced PVC as a matrix. The CNT-reinforced PVC did not influence the electrical and thermal conductivity of the PVC/wood-flour composites. J. VINYL ADDIT. TECHNOL., 2008. © 2008 Society of Plastics Engineers. [source] Comparative study of the effects of chlorinated polyethylene and acrylic impact modifier on the thermal degradation of poly(vinyl chloride) compounds and poly(vinyl chloride)/(oil palm empty fruit bunch) compositesJOURNAL OF VINYL & ADDITIVE TECHNOLOGY, Issue 2 2010Aznizam Abu Bakar The effects of chlorinated polyethylene (CPE) and acrylic impact modifier (AIM) on the thermal degradation of poly(vinyl chloride) (PVC) compounds and composites were investigated. The amounts of AIM and CPE used were fixed at 9 parts per hundred parts of resin (phr), while oil palm empty fruit bunch (OPEFB) fiber content was increased from 0 to 40 phr. To produce composites, the PVC formulations were dry-blended by using a laboratory blender before being milled into sheets on a two-roll mill at 165°C. The milled sheets were then hot-pressed at 180°C. The thermal degradation of the specimens was evaluated by using thermogravimetry in a nitrogen environment. Thermal stability of the PVC/CPE compounds and PVC/CPE/OPEFB composites was improved by the addition of CPE. The CPE retarded the dehydrochlorination of PVC. However, the stabilization effect was reduced by the incorporation of OPEFB at levels of 30 and 40 phr. The presence of AIM accelerated the dehydrochlorination of PVC/AIM compounds and PVC/AIM/OPEFB composites. J. VINYL ADDIT. TECHNOL., 2010. © 2010 Society of Plastics Engineers [source] Effect of High-Energy Vibromilling on Interfacial Interaction and Mechanical Properties of PVC/Nano-CaCO3 CompositesMACROMOLECULAR MATERIALS & ENGINEERING, Issue 9 2005Manhong Tian Abstract Summary: The effects of interfacial interaction between nano-CaCO3 and PVC on mechanical properties and morphology of PVC/nano-CaCO3 composites were studied. Nano-CaCO3 was treated with vibromilling in the presence of PVC and coupling agents. The mechanical properties of PVC/treated nano-CaCO3 are remarkably improved. Transmission electron microscopy results revealed that vibromilled nano-CaCO3 particles are well dispersed in PVC matrix with good homogeneity and well adhered to PVC matrix. Molau test indicated that chemical reaction between newly formed surface of nano-CaCO3 and PVC or coupling agent took place. Theoretical calculation results show that the interfacial interaction between PVC and nano-CaCO3 are substantially improved through vibromilling treatment of nano-CaCO3 in the presence of PVC and coupling agent. Molau test results of the samples in THF. [source] Reinforcement of rigid PVC/wood-flour composites with multi-walled carbon nanotubesJOURNAL OF VINYL & ADDITIVE TECHNOLOGY, Issue 2 2008Omar Faruk Multi-walled carbon nanotubes (CNT) were compounded with PVC by a melt blending process based on fusion behaviors of PVC. The effects of CNT content on the flexural and tensile properies of the PVC/CNT composites were evaluated in order to optimize the CNT content. The optimized CNT-reinforced PVC was used as a matrix in the manufacture of wood-plastic composites. Flexural, electrical, and thermal properties of the PVC/wood-flour composites were evaluated as a function of matrix type (nonreinforced vs. CNT-reinforced). The experimental results indicated that rigid PVC/wood-flour composites with properties similar to those of solid wood can be made by using CNT-reinforced PVC as a matrix. The CNT-reinforced PVC did not influence the electrical and thermal conductivity of the PVC/wood-flour composites. J. VINYL ADDIT. TECHNOL., 2008. © 2008 Society of Plastics Engineers. [source] Fusion characteristics of rigid PVC/wood-flour composites by torque rheometryJOURNAL OF VINYL & ADDITIVE TECHNOLOGY, Issue 1 2007Laurent M. Matuana This study was aimed at examining the effects of wood flour contents, wood species (softwood vs. hardwood), and particle size on the fusion characteristics (fusion time, fusion temperature, fusion torque, and fusion energy) of rigid PVC/wood-flour composites in a torque rheometer. Neat rigid PVC exhibited one fusion peak, whereas the addition of wood flour into the PVC matrix led to two fusion peaks. Increased wood flour content caused a significant increase in the time, temperature, and energy at which fusion between the primary particles started, thereby leading to increased fusion torque, irrespective of the wood flour species. These results implied that rigid PVC filled with wood flour must be processed at higher temperatures than neat resin. Although fusion characteristics of the composites were influenced by the wood species, a clear trend between softwood and hardwood species could not be established. However, finer particles fused more quickly and needed less energy than coarse ones. J. VINYL ADDIT. TECHNOL., 13:7,13, 2007. © 2007 Society of Plastics Engineers. [source] Effects of copper amine treatment on mechanical properties of PVC/wood-flour compositesJOURNAL OF VINYL & ADDITIVE TECHNOLOGY, Issue 2 2004Haihong Jiang Copper amine,treated wood flour was added to PVC [poly(vinyl chloride)] matrix in order to manufacture PVC/wood-flour composites. Effects of copper treatments on the mechanical properties of PVC-wood composites were evaluated. Unnotched impact strength, flexural strength, and flexural toughness of the composites were significantly improved by the wood-flour copper treatment. The optimum copper concentration range was 0.2 to 0.6 wt% of wood flour. Fractured surfaces were examined by using scanning electron microscopy (SEM) combined with energy-dispersive spectroscopy (EDS). PVC/wood interfacial debonding was the main fracture mode of untreated wood-flour composites, whereas wood-particle pullout and breakage dominating the fractured surfaces of copper-treated wood-flour composites. On the fractured surfaces, more PVC could be found on the exposed copper-treated wood particles than on untreated wood, a result suggesting improved PVC-wood interfacial adhesion after copper treatments. J. Vinyl Addit. Technol. 10:70,78, 2004. © 2004 Society of Plastics Engineers. [source] | ||||||||||