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Orientation
Kinds of Orientation Terms modified by Orientation Selected AbstractsWAGE PENALTIES AND SEXUAL ORIENTATION: AN UPDATE USING THE GENERAL SOCIAL SURVEYCONTEMPORARY ECONOMIC POLICY, Issue 2 2009BRENDAN CUSHING-DANIELS This study uses data from the 1988 to 2006 General Social Survey (GSS) to examine the effects of sexual orientation on earnings. Previous research using the GSS has found that lesbians earn 18%,23% more than similarly qualified heterosexual women and that wage penalties for gay men are slightly larger than the premia for lesbians. Using behavioral definitions of sexual orientation based on the previous year and the previous 5 yr of sexual activity, we find the familiar wage premia/penalties for lesbian/gay workers in our ordinary least squares estimations, but we find that these wage differences are falling over time. Furthermore, in contrast to the earlier results, for our regressions over the entire sample period, correcting for differential selection into full-time work reduces the estimated penalties for unmarried gay men and eliminates the entire wage premium for all lesbians. There is now a sizeable, though imprecisely measured, penalty for some lesbians. (JEL J1, J3, J7) [source] EFFECT OF ORIENTATION OF SPATIALLY DISTRIBUTED CURVE NUMBERS IN RUNOFF CALCULATIONS,JOURNAL OF THE AMERICAN WATER RESOURCES ASSOCIATION, Issue 6 2000Glenn E. Moglen ABSTRACT: The NRCS curve number approach to runoff estimation has traditionally been to average or "lump" spatial variability into a single number for purposes of expediency and simplicity in calculations. In contrast, the weighted runoff curve number approach, which handles each individual pixel within the watershed separately, tends to result in larger estimates of runoff than the lumped approach. This work proposes further enhancements that consider not only spatial variability, but also the orientation of this variability with respect to the flow aggregation pattern of the drainage network. Results show that the proposed enhancements lead to much reduced estimates of runoff production. A revised model that considers overland flow lengths, consistent with existing NRCS concepts is proposed, which leads to only mildly reduced runoff estimates. Although more physically-based, this revised model, which accounts directly for spatially distributed curve numbers and flow aggregation, leads to essentially the same results as the original, lumped runoff model when applied to three study watersheds. Philosophical issues and implications concerning the appropriateness of attempting to disaggregate lumped models are discussed. [source] INTEGRATING ERRORS INTO THE TRAINING PROCESS: THE FUNCTION OF ERROR MANAGEMENT INSTRUCTIONS AND THE ROLE OF GOAL ORIENTATIONPERSONNEL PSYCHOLOGY, Issue 2 2003DOERTE HEIMBECK Error management training explicitly allows participants to make errors. We examined the effects of error management instructions ("rules of thumb" designed to reduce the negative emotional effects of errors), goal orientation (learning goal, prove goal, and avoidance goal orientations) and attribute x treatment interactions on performance. A randomized experiment with 87 participants consisting of 3 training procedures for learning to work with a computer program was conducted: (a) error training with error management instructions, (b) error training without error management instructions; and (c) a group that was prevented from making errors. Results showed that short-and medium-term performance (near and far transfer) was superior for participants of the error training that included error management instructions, compared with the two other training conditions. Thus, error management instructions were crucial for the high performance effects of error training. Prove and avoidance goal orientation interacted with training conditions. [source] SOLUTIONS FOR EXTERIOR ORIENTATION IN PHOTOGRAMMETRY: A REVIEWTHE PHOTOGRAMMETRIC RECORD, Issue 100 2002Pierre Grussenmeyer Abstract The determination of the attitude, the position and the intrinsic geometric characteristics of the camera is recognised as the fundamental photogrammetric problem. It can be summarised as the determination of camera interior and exterior orientation parameters, as well as the determination of 3D coordinates of object points. The term "exterior orientation" of an image refers to its position and orientation related to an exterior (object space) coordinate system. Several methods can be applied to determine the parameters of the orientation of one, two or more photos. The orientation can be processed in steps (as relative and absolute orientation) but simultaneous methods (such as bundle adjustments) are now available in many software packages. Several methods have also been developed for the orientation of single images. They are based in general on geometric and topological characteristics of imaged objects. This paper presents a survey of classical and modern methods for the determination of the exterior parameters in photogrammetry, some of which are available as software packages (with practical examples) on the Internet. The methods presented are classified in three principal groups. In the first. a selection of approximate methods for applications that do not require great accuracy is presented. Such methods are also used to calculate values required for iterative processes. In the second group, standard point-bused methods derived from collinearity, coplanarity or coangularity conditions are briefly reviewed, followed by line-based approaches. The third group represents orientation methods based on constraints and on concepts of projective geometry, which are becoming of increasing interest for photogrammetrists. In the last section, the paper gives a summary of existing strategies for automatic exterior orientation in aerial photogrammetry. Résumé La détermination de l'attitude, de la position et des caractéristiques intrinsèques de la chambre photographique constitue un problème fondamental en photogrammétrie. Il se résume à la détermination des paramètres de l'orientation de la chambre de prise de vue (paramètres des orientations externe et interne), ainsi qu'à la détermination des coordonnées 30 des points de l'objet. L'orientation externe se rapporte à la détermination de la position et de l'orientation d'une chambre par rapport à un système externe de coordonnées. Différentes méthodes peuvent être utilisées pour calculer les éléments dorientation externe d'une photo, d'un couple ou de plusieurs photos. Le calcul de l'orientation peut être réalisé par étapes (par exemple les orientations relative et absolue) mais les méthodes simultanées (la compensation par faisceaux par exemple) sont actuellement proposées dans la plupart des logiciels. Plusieurs méthodes ont aussi été développées pour l'orientation d'images isolées. Ells sont basées en général sur les caactéristiques géométriques et topologiques des objets photographiés. Dans cet article on présente un ensemble de méthodes classiques et modernes pour la détermination des paramètres de l'orientation externe, certaines d'entre elles étant téléchargeables sous la forme d'applications sur Internet. Les méthodes présentées sont classées en trois groupes principaux. Le premier groupe contient une sélection de méthodes approximatives utilisées d'habitude quand une grande précision n'est pas exigée, ou encore pour calculer des vuleurs approchées des paramètres extrinsèques requises pour les méthodes itératives rigoureuses. Dans le deuxième groupe, on rappelle brièvement les jondements des méthodes basées sur les conditions photogrammétriques fondamentales (la colinéarité, la coplanéité et la coangularité). Dans ce groupe, les méthodes basées sur l'extraction des points ou des lignes sont également abordées. Le troisième groupe traite des méthodes d'orientation basées sur les contraintes et les concepts de la géométrie projective, de plus en plus utilisées par les photogrammètres. Le dernier paragraphe se rapporte aux méthodes destinées à automatiser le calcul de l'orientation externe en photogrammétrie aérienne. Zusummenfussung Die Bestimmung der Neigung, der Position und den geometrischen parametern der Kamera wird als das fundamentale Problem der Photogrammetrie angesehen. Es kann zusammenfassend sowohl als die Bestimmung der Parameter der inneren und äusseren Orientierung der Kamera angesehen werden, als auch als die Bestimmung von 3D Koordinaten von Objektpunkten. Der Ausdruck "äussere Orientierung" eines Bildes bezieht sich auf die Lage und Orientierung bezogen auf ein äusseres (Objektraum-) Koordinatensystem. Es können verschiedene Methoden angewandt werden, um die Parameter von einem, zwei oder mehreren Bildern zu bestimmen. Die orientierung kann in Schritten erfolgen, was als Relative und Absolute Orientierung bezeichnet wird, aber auch simultane Methoden, wie die Bündelausgleichung, sind in vielen Softwarepaketen implementiert. Es wurden auch Methoden für die Orientierung von Einzelbildern entwickelt, die geometrische und topologische Eigenschaften der abgebildeten Objekte nutzen. In diesem Beitrag wird Beitrag wird eine Studie klassischer und moderner Methoden der Photogrammetrie zur Bestimmung der Parameter der äßeren Orientierung vorgestellt, wovon einige in Softwarepaketen zur Verfügung stehen, die von praktischen Beispielen im Internet ergänzt werden. Die untersuchten Methoden werden in drei Hauptgruppen eingeteilt. In einer ersten Gruppe werden Näherungslösungen vorgestellt, die für Anwendungen mit geringen Genauigkeitsanforderungen geeignet sind. Diese Methoden werden ansonsten für die Näherngswertberechunggen für iterative Prozesse verwendet. IN der zweiten Gruppe werden zuerst die punktbasierten Standardmethoden vorgestellt, die von Bedingungen zur Kollinearität. Koplanarität und Kowinkligkeit abgeletet sind. Danach folgen linienbasierte Ansätze. Die dritte Gruppe umfasst Orientierungsmethoden, die auf Zwangsbedingungen und auf Konzepte der projektiven Geometrie aufbauen, die für Photogrammeter von zunehmendem Interesse sind, Im letzten Abschnitt wird eine Zusammenfassung existierender Strategien für eine automatische äussere orientierung in der Luftbildphotogrammetrie gegeben. [source] IN SEARCH OF COMMON GROUND: THE IMPORTANCE OF THEORETICAL ORIENTATIONS IN CRIMINOLOGY AND CRIMINAL JUSTICECRIMINOLOGY AND PUBLIC POLICY, Issue 2 2005M. KAY HARRIS [source] HERMENEUTICS: PHILOSOPHICAL UNDERSTANDING AND BASIC ORIENTATIONSJOURNAL OF CHINESE PHILOSOPHY, Issue 2006LAUREN F. PFISTER [source] An Experimental Investigation of Landscape Resistance of Forest versus Old-Field Habitats to Emigrating Juvenile AmphibiansCONSERVATION BIOLOGY, Issue 5 2002Betsie B. Rothermel Larval amphibians,spotted salamander (Ambystoma maculatum), small-mouthed salamander (A. texanum), and American toad ( Bufo americanus ),were added to artificial pools in four dispersal arrays on forest edges. Each array consisted of a pool surrounded by a circular drift fence with pitfall traps and two 2.5 × 50 m enclosures (runs) extending into forest and old-field habitat. Juveniles captured at the circular fences were individually marked and released into either field or forest runs. We determined initial distance, initial rate, total distance, and net distance moved by juveniles in the field versus forest from recaptures in the runs. We also conducted 24-hour dehydration trials to compare the rates of evaporative water loss by spotted and small-mouthed salamanders in field and forest. Initial orientation of spotted salamanders and toads was significantly biased toward forest. Orientation of small-mouthed salamanders did not differ significantly from random expectations. The avoidance of open-canopy habitat by juvenile American toads in particular indicates that predictions of dispersal behavior based on adult habitat use may be misleading. Spotted salamanders moved almost four times farther and toads more than three times farther into the forest than into the field, and recapture rates of both species were much lower in the field. We attribute the lower recapture rates and shorter distances moved in the field to higher mortality due to desiccation or an abundance of predators. Juvenile spotted and small-mouthed salamanders experienced greater evaporative water loss in the field. Our data on movement behavior and dehydration rates suggest that old-field habitats offer greater landscape resistance to dispersing juveniles of some species. Thus, forest fragmentation is likely to reduce dispersal rates between local populations of these three species, with potentially negative consequences for population persistence in altered landscapes. Resumen: Utilizamos un enfoque experimental para investigar los efectos de la composición del paisaje sobre el éxito inicial de dispersión de anfibios juveniles. Colcamos larvas de anfibios (salamandras manchadas [Ambystoma maculatum] y A. texanum y sapo americano [Bufo americanus] ) en estanques artificiales en cuatro secuencias de dispersión en bordes de bosque. Cada secuencia consistió de un estanque rodeado por un cerco circular con trampas de fosa y dos encierros (corridas) de 2.5 × 50 m que se extendían hacia el hábitat de bosque y de campo viejo. Los juveniles capturados en los cercos circulares fueron marcados individualmente y liberados en las corridas de bosque o de campo. A partir de recapturas en las corridas, determinamos la distancia inicial, la tasa inicial, las distancia total y la distancia neta recorrida por juveniles en el campo versus el bosque. También realizamos pruebas de deshidratación de 24 horas para comparar las tasas de pérdida de agua por evaporación en salamandras en el campo y el bosque. La orientación inicial de Ambystoma maculatum y Bufo americanus estuvo significativamente sesgada hacia el bosque. La orientación inicial de A. texanum no fue significativamente diferente de las expectativas aleatorias. La evasión del hábitat abierto en particular por juveniles de sapo americano indica que las predicciones del comportamiento de dispersión basadas en el uso del hábitat por adultos pueden llevar a conclusiones erróneas. Las salamandras manchadas se movieron cuatro veces mas lejos y los sapos más de tres veces más lejos dentro del bosque que dentro del campo, y las tasas de recaptura de ambas especies fueron mucho menores en el campo. Atribuimos las bajas tasas de recaptura y las distancias menores a la mayor mortalidad debido a la desecación o a la abundancia de depredadores. Los juveniles de las dos especies de salamandras experimentaron mayor pérdida de agua por evaporación en los campos. Nuestros datos del comportamiento de movimiento y las tasas de deshidratación sugieren que los hábitats de campo viejo ofrecen mayor resistencia de paisaje para los juveniles dispersantes de algunas especies. Por tanto, es probable que la fragmentación de bosques reduce las tasas de dispersión entre poblaciones locales de estas tres especies, con consecuencias potencialmente negativas para la persistencia de la población en paisajes alterados. [source] A visit from the Candy Witch: factors influencing young children's belief in a novel fantastical beingDEVELOPMENTAL SCIENCE, Issue 4 2004Jacqueline D. Woolley Factors hypothesized to affect beliefs in fantastical beings were examined by introducing children to a novel fantastical entity, the Candy Witch. Results revealed that among older preschoolers, children who were visited by the Candy Witch exhibited stronger beliefs in the Candy Witch than did those who were not. Among children who were visited, older children had stronger beliefs than did younger children. Among children who were not visited, those with a high Fantasy Orientation believed more strongly than did those with a low Fantasy Orientation. Belief remained high one year later. At both time points, the number of other fantastical beings in which a child believed was significantly related to belief in the Candy Witch. [source] The influence of cultural orientation, alcohol expectancies and self-efficacy on adolescent drinking behavior in BeijingADDICTION, Issue 9 2010Duane F. Shell ABSTRACT Objective We hypothesized that the drinking behavior of adolescents in China is influenced by expectancies and self-efficacy and that adolescents' cultural orientation towards western versus traditional Chinese values influences expectancies, self-efficacy and drinking behavior, with western values leading to more dysfunctional patterns of beliefs and drinking, and that these beliefs are influenced by students' gender and school environment. Methods A total of 1020 high school students from Beijing completed the Chinese Adolescent Alcohol Expectancy, the Chinese Cultural Orientation and the Chinese Self-regulation Self-efficacy questionnaires. Results Results generally confirmed our hypotheses. Higher negative expectancies and higher self-efficacy reduced the likelihood of drinking significantly. Higher positive expectancies increased the likelihood of regular drinking but not occasional drinking. Having western cultural orientation increased the likelihood of drinking. Higher levels of western cultural orientation also increased positive expectancies, lowered negative expectancies and lowered self-efficacy. Having more western (less traditional) views towards traditional Chinese values decreased positive and negative expectancies. Gender influenced beliefs, with males having higher positive and lower negative expectancies, lower self-efficacy and more traditional cultural orientation. Students in key and general schools had less traditional cultural orientation and key school students had higher self-efficacy. Conclusions Results indicate that cultural orientation influences adolescent drinking and this influence is mediated partially through cultural orientation influences on adolescent drinking expectancies and self-efficacy. Having more western and less traditional Chinese cultural orientation leads to more drinking, lower self-efficacy for regulating drinking and more risk-promoting alcohol expectancies. [source] Effects of Ultraviolet Radiation on Locomotion and Orientation in Roughskin Newts (Taricha granulosa)ETHOLOGY, Issue 3 2000Andrew R. Blaustein Environmental changes, including those associated with the atmosphere may significantly affect individual animals and ultimately populations. Ultraviolet (UV) radiation, perhaps increasing due to stratospheric ozone depletion, has been linked to mortality in a number of organisms, including amphibians. The eggs and larvae of certain amphibian species hatch at significantly lower rates when exposed to ambient ultraviolet light. Yet little is known about the sublethal effects of UV radiation. For example, UV radiation may affect specific behaviors of an animal that could alter its ability to survive. To examine if UV radiation affects amphibian behavior, we used roughskin newts (Taricha granulosa) as a model. Newts were exposed to low-level doses of UV in the laboratory and then tested in the field to examine if UV-exposed and control (no UV) newts differed in orientation towards water or in locomotor activity levels. UV-exposed and control newts both exhibited a significant orientation towards water in field tests but there was no significant difference in orientation between treatments. However, UV-exposed newts were significantly more active than control newts. Our results suggest that exposure to short-term low levels of UV radiation alters certain behaviors. Environmentally induced changes in behavior may have significant ecological and evolutionary consequences. [source] Orientation and Arrangement of Octaruthenium Supramolecules with Alkyl Chains on GraphiteEUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 35 2007Dong-Lin Shieh Abstract The self-assemblies of octaruthenium grid-type supramolecules, {[Ru2(CO)4(NH2C16H33)2](,-O2CCO2)}4, on highly oriented pyrolytic graphite (HOPG) in air and in 1-phenyloctane were studied by scanning tunneling microscopy (STM). The surface supramolecules are arranged into rows in which the metal cores are linearly packed and the alkyl chains are parallel to the surface. With the aid of theoretical calculations in the framework of density functional theory, the electronic origin of the tunneling in the measured STM images is discussed. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007) [source] Orientation- and Temperature-Dependent Rotational Behavior of Imidazole Ligands (L) in ,-[Ru(azpy)2(L)2](PF6)2 ComplexesEUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 4 2003Aldrik H. Velders Abstract The synthesis and characterization of the cis bifunctional coordinated ruthenium(II) complexes ,-[Ru(azpy)2(MeIm)2](PF6)2 (,-MeIm) and ,-[Ru(azpy)2(MeBim)2](PF6)2 (,-MeBim) (azpy = 2-phenylazopyridine, MeIm = 1-methylimidazole and MeBim = 1-methylbenzimidazole) is reported. In ,-MeIm the two MeIm ligands can both freely rotate around the Ru,N axes on the NMR timescale. In ,-MeBim the two MeBim ligands appear restricted in their rotation around the Ru,N axes, which becomes slow on the NMR timescale at low temperatures. In contrast to the analogous complexes ,-[Ru(azpy)2(MeBim)2](PF6)2 and cis -[Ru(bpy)2(MeBim)2](PF6)2, only one atropisomer is observed for the two MeBim ligands in ,-MeBim. The orientation of the MeBim ligands appears to correspond to an HT isomer which is similar to the orientation of the MeBim ligands in the most abundant atropisomer found in the related ,-[Ru(azpy)2(MeBim)2](PF6)2. A stacking interaction between the phenyl ring of one azpy and one MeBim ligand is likely to stabilize the observed atropisomer of ,-MeBim, and is such that the rotation of the phenyl ring of one of the two azpy ligands is restricted. At very low temperatures this rotation, or flipping of the phenyl ring between two identical positions, is in the slow-exchange range on the NMR timescale. (© Wiley-VCH Verlag GmbH & Co KGaA, 69451 Weinheim, Germany, 2003) [source] Formation and Topotactical Orientation of Fibrinogen Nanofibrils on Graphite Nanostructures,ADVANCED ENGINEERING MATERIALS, Issue 11 2009Jörg Reichert We studied the adsorption of human plasma fibrinogen and investigated the formation of amyloid-like fibrinogen nanofibrils and fibrinogen networks in the absence of thrombin and Ca·2+ with high resolution atomic force microscopy (AFM). We propose a possible mechanisms for the surface nanostructure mediated self assembly of fibrinogen molecules and the formation of fibrinogen nanofibrils and nanofibril networks in the absence of thrombin. [source] Right-wing authoritarianism and social dominance orientation and the dimensions of generalized prejudice: A longitudinal testEUROPEAN JOURNAL OF PERSONALITY, Issue 4 2010Frank Asbrock Abstract A Dual Process Model (DPM) approach to prejudice proposes that there should be at least two dimensions of generalized prejudice relating to outgroup stratification and social perception, which should be differentially predicted by Right-Wing Authoritarianism (RWA) and Social Dominance Orientation (SDO). The current study assessed the causal effects of SDO and RWA on three dimensions of prejudice using a full cross-lagged longitudinal sample (N,=,127). As expected, RWA, but not SDO, predicted prejudice towards ,dangerous' groups, SDO, but not RWA, predicted prejudice towards ,derogated' groups, and both RWA and SDO predicted prejudice towards ,dissident' groups. Results support previously untested causal predictions derived from the DPM and indicate that different forms of prejudice result from different SDO- and RWA-based motivational processes. Copyright © 2009 John Wiley & Sons, Ltd. [source] Right wing authoritarianism, social dominance orientation and the dimensions of generalized prejudiceEUROPEAN JOURNAL OF PERSONALITY, Issue 2 2007John Duckitt Abstract Prior research suggests that individuals' prejudiced attitudes form a single generalized dimension predicted by Right Wing Authoritarianism (RWA) and Social Dominance Orientation (SDO). A dual process approach, however, expects different domains of generalized prejudice that relate differentially to RWA and SDO. To test this, 212 participants rated attitudes to 24 typically disliked groups. Factor analysis revealed three distinct generalized prejudice dimensions. Hierarchical Linear Modelling indicated that attitudes towards a ,dangerous' groups domain was significantly related only with RWA, attitudes toward a second ,derogated' groups domain was related only to SDO, and attitudes toward a third, ,dissident' groups, domain was significantly related to both, but powerfully with RWA and weakly with SDO. These findings have implications for explaining and reducing prejudice. Copyright © 2006 John Wiley & Sons, Ltd. [source] The intervening role of social worldviews in the relationship between the five-factor model of personality and social attitudesEUROPEAN JOURNAL OF PERSONALITY, Issue 2 2007A. Van Hiel Abstract The present research investigates in a student (N,=,183) and a voter sample (N,=,276) whether the relationships between the Five-Factor Model (FFM) personality dimensions and social attitudes (i.e. Right-Wing Authoritarianism [RWA] and Social Dominance Orientation [SDO]) are mediated by social worldviews (i.e. dangerous and jungle worldviews). Two important results were obtained. First, the perception of the world as inherently dangerous and chaotic partially mediated the relationships of the personality dimensions Openness and Neuroticism and the social attitude RWA. Second, the jungle worldview completely mediated the relationships between Agreeableness and SDO, but considerable item overlap between the jungle worldview and SDO was also noted. It was further revealed that acquiescence response set and item overlap had an impact on social worldviews and attitudes, but that their relationships were hardly affected by these biases. The discussion focuses on the status of social worldviews to explain social attitudes. Copyright © 2006 John Wiley & Sons, Ltd. [source] What matters most to prejudice: Big Five personality, Social Dominance Orientation, or Right-Wing Authoritarianism?EUROPEAN JOURNAL OF PERSONALITY, Issue 6 2004Bo Ekehammar Whereas previous research has studied the relation of either (i) personality with prejudice, (ii) personality with social dominance orientation (SDO) and right-wing authoritarianism (RWA), or (iii) SDO and RWA with prejudice, the present research integrates all approaches within the same model. In our study (N,=,183), various causal models of the relationships among the Big Five, SDO, RWA, and Generalized Prejudice are proposed and tested. Generalized Prejudice scores were obtained from a factor analysis of the scores on various prejudice instruments (racism, sexism, prejudice toward homosexuals, and mentally disabled people), which yielded a one-factor solution. The best-fitting causal model, which was our suggested hypothetical model, showed that Big Five personality had no direct effect on Generalized Prejudice but an indirect effect transmitted through RWA and SDO, where RWA seems to capture personality aspects to a greater extent than SDO. Specifically, Generalized Prejudice was affected indirectly by Extraversion, Openness to Experience, and Conscientiousness through RWA, and by Agreeableness through SDO, whereas Neuroticism had no effect at all. The results are discussed against the background of previous research and the personality and social psychology approaches to the study of prejudice. Copyright © 2004 John Wiley & Sons, Ltd. [source] Poly(3-hexylthiophene) Nanorods with Aligned Chain Orientation for Organic PhotovoltaicsADVANCED FUNCTIONAL MATERIALS, Issue 4 2010Jong Soo Kim Abstract A structured polymer solar cell architecture featuring a large interface between donor and acceptor with connecting paths to the respective electrodes is explored. To this end, poly-(3-hexylthiophene) (P3HT) nanorods oriented perpendicularly to indium tin oxide (ITO) glass are fabricated using an anodic aluminum oxide template. It is found that the P3HT chains in bulk films or nanorods are oriented differently; perpendicular or parallel to the ITO substrate, respectively. Such chain alignment of the P3HT nanorods enhanced the electrical conductivity up to tenfold compared with planar P3HT films. Furthermore, the donor/acceptor contact area could be maximised using P3HT nanorods as donor and C60 as acceptor. In a photovoltaic device employing this structure, remarkable photoluminescence quenching (88%) and a seven-fold efficiency increase (relative to a device with a planar bilayer) are achieved. [source] The Equality Deficit: Protection against Discrimination on the Grounds of Sexual Orientation in EmploymentGENDER, WORK & ORGANISATION, Issue 4 2001Nicole Busby The provisions of UK law offer no specific protection to gay men and lesbians suffering discrimination in the workplace on the grounds of sexual orientation. Such discrimination may take many forms and can result in ,fair' dismissal in certain circumstances. This article considers the degree of legal protection available under current provisions and investigates possible sources for the development of specific anti-discrimination legislation. It is concluded that, despite the application of certain aspects of employment law, the level of protection afforded to this group of workers amounts to an equality deficit in comparison to the legal redress available to those discriminated against on other grounds. Although the development of human rights legislation may have some application in this context, the combination of institutionalized discrimination and wider public policy concerns suggest that the introduction of specific legislation aimed at eliminating such discrimination in the United Kingdom is still some way off. [source] Ideology, Power Orientation and Policy Drag: Explaining the Elite Politics of Britain's Bill of Rights DebateGOVERNMENT AND OPPOSITION, Issue 1 2009David Erdos This article argues that three factors have framed elite political debate and outcomes on a Bill of Rights in Britain , the degree of commitment to an ideology of social liberalism, the executive/non-executive power orientation of key actors and the phenomenon of policy drag. These factors explain not only the overall historical contours of political debate but also (1) Labour's ,aversive' conversion to the Bill of Rights agenda and passage of the Human Rights Act (1998); and (2) the Conservatives' more positive recent attitude to the Bill of Rights agenda. [source] Catalyst-Free Efficient Growth, Orientation and Biosensing Properties of Multilayer Graphene Nanoflake Films with Sharp Edge Planes,ADVANCED FUNCTIONAL MATERIALS, Issue 21 2008Nai Gui Shang Abstract We report a novel microwave plasma enhanced chemical vapor deposition strategy for the efficient synthesis of multilayer graphene nanoflake films (MGNFs) on Si substrates. The constituent graphene nanoflakes have a highly graphitized knife-edge structure with a 2,3,nm thick sharp edge and show a preferred vertical orientation with respect to the Si substrate as established by near-edge X-ray absorption fine structure spectroscopy. The growth rate is approximately 1.6,µm min,1, which is 10 times faster than the previously reported best value. The MGNFs are shown to demonstrate fast electron-transfer (ET) kinetics for the Fe(CN)63,/4, redox system and excellent electrocatalytic activity for simultaneously determining dopamine (DA), ascorbic acid (AA) and uric acid (UA). Their biosensing DA performance in the presence of common interfering agents AA and UA is superior to other bare solid-state electrodes and is comparable only to that of edge plane pyrolytic graphite. Our work here, establishes that the abundance of graphitic edge planes/defects are essentially responsible for the fast ET kinetics, active electrocatalytic and biosensing properties. This novel edge-plane-based electrochemical platform with the high surface area and electrocatalytic activity offers great promise for creating a revolutionary new class of nanostructured electrodes for biosensing, biofuel cells and energy-conversion applications. [source] A Self-Report Measure of Clinicians' Orientation toward Integrative MedicineHEALTH SERVICES RESEARCH, Issue 5p1 2005An-Fu Hsiao Objective. Patients in the U.S. often turn to complementary and alternative medicine (CAM) and may use it concurrently with conventional medicine to treat illness and promote wellness. However, clinicians vary in their openness to the merging of treatment paradigms. Because integration of CAM with conventional medicine can have important implications for health care, we developed a survey instrument to assess clinicians' orientation toward integrative medicine. Study Setting. A convenience sample of 294 acupuncturists, chiropractors, primary care physicians, and physician acupuncturists in academic and community settings in California. Data Collection Methods. We used a qualitative analysis of structured interviews to develop a conceptual model of integrative medicine at the provider level. Based on this conceptual model, we developed a 30-item survey (IM-30) to assess five domains of clinicians' orientation toward integrative medicine: openness, readiness to refer, learning from alternate paradigms, patient-centered care, and safety of integration. Principal Findings. Two hundred and two clinicians (69 percent response rate) returned the survey. The internal consistency reliability for the 30-item total scale and the five subscales ranged from 0.71 to 0.90. Item-scale correlations for the five subscales were higher for the hypothesized subscale than other subscales 75 percent or more of the time. Construct validity was supported by the association of the IM-30 total scale score (0,100 possible range, with a higher score indicative of greater orientation toward integrative medicine) with hypothesized constructs: physician acupuncturists scored higher than physicians (71 versus 50, p<.001), dual-trained practitioners scored higher than single-trained practitioners (71 versus 62, p<.001), and practitioners' self-perceived "integrativeness" was significantly correlated (r=0.60, p<.001) with the IM-30 total score. Conclusion. This study provides support for the reliability and validity of the IM-30 as a measure of clinicians' orientation toward integrative medicine. The IM-30 survey, which we estimate as requiring 5 minutes to complete, can be administered to both conventional and CAM clinicians. [source] Influence of , -Alanine on Hairpin Polyamide Orientation in the DNA Minor GrooveHELVETICA CHIMICA ACTA, Issue 6 2003Victor Antiparallel polyamides containing 1H -pyrrole, 1H -imidazole, and 3-hydroxy-1H -pyrrole amino acids display a preference for minor-groove binding oriented NC with respect to the 5,-3, direction of the DNA helix. We find that replacement of a central Py/Py pair with a ,/, pair within a ten-ring hairpin relaxes the orientation preference and, for some DNA sequences, causes the polyamide to prefer the opposite CN orientation. Substitution of the achiral , -aminobutanoic acid (,) with either (R)(or S)-2-(acetylamino)-4-aminobutanoic acid moderates the orientation preference of the 2- , -2-hairpin. [source] Controlled Deposition of Highly Ordered Soluble Acene Thin Films: Effect of Morphology and Crystal Orientation on Transistor PerformanceADVANCED MATERIALS, Issue 48 2009Christoph W. Sele Controlling the morphology of soluble small molecule organic semiconductors is crucial for the application of such materials in electronic devices. Using a simple dip-coating process we systematically vary the film drying speed to produce a range of morphologies, including oriented needle-like crystals. Structural characterization as well as electrical transistor measurements show that intermediate drying velocities produce the most uniformly aligned films. [source] Conversation Orientation and Cognitive Processes: A Comparison of U.S. Students in Initial Interaction With Native- Versus Nonnative-Speaking PartnersHUMAN COMMUNICATION RESEARCH, Issue 2 2003Ling Chen The present study compares thought patterns, perceptions of interaction (perceived interaction smoothness and interaction involvement), and conversation orientation of U.S. students (N = 60) in dyadic interaction with a partner who is either another American or a non-American nonnative speaker of English. As hypothesized, U.S. participants with nonnative-speaking partners perceived interaction as more difficult, or less smooth, than did their counterparts with native-speaking partners. U.S. participants with nonnative-speaking partners also displayed different thought patterns, having more thoughts showing confusion, as well as more thoughts focused on the partner and less on the content of the ongoing conversation, than those with fellow native-speaking partners. U.S. participants with a nonnative-speaking partner also exhibited a different conversation orientation pattern, focusing more on understanding of the other's message, less on clarifying their own message, and less on displaying their own involvement. Specific thought categories and perceived interaction smoothness were correlated with conversation orientation indices for participants in interactions between native and nonnative speakers. Finally, interaction involvement was found to contribute most to variation in perceived interaction smoothness for both U.S. and non-U.S. participants in interactions between native and nonnative speakers. Implications of the findings are discussed. [source] Control of Domain Orientation in Block Copolymer Electrolyte Membranes at the Interface with Humid AirADVANCED MATERIALS, Issue 2 2009Moon Jeong Park Domain orientation in polymer electrolyte membranes is tuned by controlling its sulfonation level and the moisture content of the air. At low sulfonation levels, highly ordered hydrophobic cylinders oriented perpendicular to the film surface are obtained, when the film is in humid air. Increasing the sulfonation level results in a transition from perpendicular to parallel orientation. [source] Hierarchy Selection, Position Control, and Orientation of Growing Mesostructures by Patterned Surfaces,ADVANCED MATERIALS, Issue 8 2006Spontaneous hierarchical organization of silica by means of a patterned surface is described, in which the usual coexistence of energetically similar structures is overcome. A patterned substrate is shown to lead to pixel-like, simultaneous growth of a hierarchal assembly involving four structural levels. The individual pixels belong to a new class of circularly organized solids (see figure and cover). [source] The MMSE orientation for time domain is a strong predictor of subsequent cognitive decline in the elderlyINTERNATIONAL JOURNAL OF GERIATRIC PSYCHIATRY, Issue 12 2009Elizabeth Guerrero-Berroa Abstract Background The mini-mental state exam (MMSE) has been used to address questions such as determination of appropriate cutoff scores for differentiation of individuals with intact cognitive function from patients with dementia and rate of cognitive decline. However, little is known about the relationship of performance in specific cognitive domains to subsequent overall decline. Objective To examine the specific and/or combined contribution of four MMSE domains (orientation for time, orientation for place, delayed recall, and attention) to prediction of overall cognitive decline on the MMSE. Methods Linear mixed models were applied to 505 elderly nursing home residents (mean age,=,85,,>,12 years education,=,27%; 79% F, mean follow-up,=,3.20 years) to examine the relationship between baseline scores of these domains and total MMSE scores over time. Results Orientation for time was the only domain significantly associated with MMSE decline over time. Combination of poor delayed recall with either attention or orientation for place was associated with significantly increased decline on the MMSE. Conclusions The MMSE orientation for time predicts overall decline on MMSE scores over time. A good functioning domain added to good functioning delayed recall was associated with slower rate of decline. Copyright © 2009 John Wiley & Sons, Ltd. [source] Photo-Induced Orientation of a Film of Ladderlike Polysiloxane Bearing Dual Photoreactive Side Groups,ADVANCED MATERIALS, Issue 16 2003H.W. Gu A newly designed ladder-like polysiloxane (LPS) containing dual photoreactive side groups has been synthesized for the purpose of generating high-quality photo-alignment layers with controllable pretilt angle (,,1,7°, see Figure and cover). Integrated spectroscopic methods of UV dichroism, surface-enhanced Raman scattering (SERS), and FT-IR are used together for the first time to elucidate the photo-alignment mechanism and the real cause of the high pretilt angle. [source] Effect of Molecular Orientation of Epitaxially Grown Platinum(II) Octaethyl Porphyrin Films on the Performance of Field-Effect Transistors,ADVANCED MATERIALS, Issue 9 2003Y.-Y. Noh The molecular alignment of platinum(II) octaethyl porphyrin (PtOEP) crystals evaporated on KBr (see atomic force microscopy image, Figure) can be readily changed from perpendicular to parallel by changing the substrate temperature. The field-effect mobility of transisitors prepared using epitaxially grown PtOEP films aligned perpendicularly to a substrate is 100 times higher than that of those of parallel alignment. [source] | ||||||||||||||||||||||||||||||||||||||||