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Operation Conditions (operation + condition)
Selected AbstractsSimulation and Analysis of a Single-Effect Thermal Vapor-Compression Desalination System at Variable Operation ConditionsCHEMICAL ENGINEERING & TECHNOLOGY (CET), Issue 12 2007G. Ji Abstract A mathematical model is developed to analyze a single-effect thermal vapor compression (TVC) desalination system. The effects of the variation of operation conditions such as the intake seawater temperature and the mass flow rate of cooling water on the system performance are investigated for a specific desalination unit. The system performance is found to decrease when the intake seawater temperature is different from the design value. By adjusting the mass flow rate of cooling water, a better system performance can be obtained when the intake seawater temperature differs from the design conditions. Decreasing the cooling water flow rate to values lower than the design value can lead to a better performance when the intake seawater temperature is lower than the design value, and the system performance reaches a peak point when the cooling water flow rate decreases to a definite level. A better performance can also be obtained by increasing the cooling water flow rate to values higher than design value, when the intake seawater temperature is higher than the design value and the system performance also reaches a peak point when the cooling water flow rate increases to a definite level. [source] ChemInform Abstract: Reversible Hydrogen Storage in Ti,Zr-Codoped NaAlH4 under Realistic Operation Conditions.CHEMINFORM, Issue 26 2010Thomas Schmidt Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source] Three-dimensional vibration control of high-tech facilities against earthquakes and microvibration using hybrid platformEARTHQUAKE ENGINEERING AND STRUCTURAL DYNAMICS, Issue 6 2010Xiao-Jian Hong Abstract High-tech equipments engaged in the production of ultra-precision products have very stringent vibration criteria for their functionality in normal operation conditions and their safety during an earthquake. Most previous investigations were based on simplified planar models of building structures, despite the fact that real ground motions and structures are always three-dimensional. This paper hence presents a three-dimensional analytical study of a hybrid platform on which high-tech equipments are mounted for their vibration mitigation. The design methodology of the hybrid platform proposed in this study is based on dual-level performance objectives for high-tech equipments: safety against seismic hazard and functionality against traffic-induced microvibration. The passive devices (represented by springs and viscous dampers) and the active actuators are designed, respectively, to meet vibration criteria corresponding to safety level and functionality level. A prototype three-story building with high-tech equipments installed on the second floor is selected in the case study to evaluate the effectiveness of the hybrid platform. The optimal location of the platform on the second building floor is determined during the design procedure in terms of the minimal H2 cost function of absolute velocity response. The simulation of the coupled actuator-platform-building system subjected to three-dimensional ground motions indicates that the optimally designed hybrid platform can well achieve the dual target performance and effectively mitigate vibration at both ground motion levels. Copyright © 2009 John Wiley & Sons, Ltd. [source] Measurement of Charge-Density Dependence of Carrier Mobility in an Organic Semiconductor BlendADVANCED FUNCTIONAL MATERIALS, Issue 5 2010Christopher G. Shuttle Abstract Here, a new methodology for analyzing the charge-density dependence of carrier mobility in organic semiconductors, applicable to the low-charge-density regime (1014,1017,cm,3) corresponding to the operation conditions of many organic optoelectronic devices, is reported. For the P3HT/PCBM blend photovoltaic devices studied herein, the hole mobility µ is found to depend on charge density n according to a power law µ(n) , n,, where ,,=,0.35. This dependence is shown to be consistent with an energetic disorder model based upon an exponential tail of localized intra-band states. [source] Preparation of a Nanoscale/SOFC-Grade Yttria-Stabilized Zirconia Material: A Quasi-Optimization of the Hydrothermal Coprecipitation ProcessINTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, Issue 6 2008Yang-Chuang Chang Yttria-stabilized zirconia (YSZ) is the key material for an electrolyte of a solid oxide fuel cell (SOFC). In order to prepare a nanoscale/SOFC-grade 8YSZ material, the hydrothermal coprecipitation process is intensively investigated for process improvement and product identification. From the characterization results of the 8YSZ product, the operation conditions were selected for process optimization. The criteria used in optimization condition determination were the reproducibility of the 8YSZ product and the particle size, the crystallinity, as well as the operation simplicity. Experimental results showed that a nanoscale/SOFC-grade 8YSZ powder was directly prepared. The quasi-optimum conditions of the process are proposed. [source] Energetic, exergetic and thermoeconomic analysis of Bilkent combined cycle cogeneration plantINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 11 2006C. Ozgur Colpan Abstract This paper is a case study of thermodynamics and economics related analyses applied to an existing gas/steam combined cycle cogeneration plant. Basic thermodynamic properties of the plant are determined by energy analysis utilizing main operation conditions. Exergy destructions within the plant and exergy losses to environment are investigated to determine thermodynamic inefficiencies and to assist for guiding future improvements in the plant. Cost balances and auxiliary equations are applied to several subsystems in the plant, hence, cost formation in the plant is observed. Additionally, cost rate of each product of the plant is calculated. Copyright © 2005 John Wiley & Sons, Ltd. [source] Thermal performance of a packed bed reactor for a high-temperature chemical heat pumpINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 7 2001Yukitaka Kato Abstract The thermal performance of a chemical heat pump that uses the reaction system of calcium oxide/lead oxide/carbon dioxide, which is developed for utilization of high-temperature heat above 800°C, is studied experimentally. The thermal performance of a packed-bed reactor of a calcium oxide/carbon dioxide reaction system, which stores and transforms a high-temperature heat source in the heat pump operation, is examined under various heat pump operation conditions. The energy analysis based on the experiment shows that it is possible to utilize high-temperature heat with this heat pump. This heat pump can store heat above 850°C and then transform it into a heat above 900°C under an approximate atmospheric pressure. An applied system that combines the heat pump and a high-temperature process is proposed for high-efficiency heat utilization. The scale of the heat pump in the combined system is estimated from the experimental results. Copyright © 2001 John Wiley & Sons, Ltd. [source] Reductive decolourization and total organic carbon reduction of the diazo dye CI Acid Black 24 by zero-valent iron powderJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 7 2006Ming-Chin Chang Abstract In this study, wastewater contaminated by colour and total organic carbon from the diazo dye CI Acid Black 24 was successfully removed by reductive decolourization with zero-valent iron powder. The effects on decolourization of experimental variables such as iron dosage, initial dye concentration, pH and dissolved oxygen level were evaluated. The best removal efficiencies for decolourization of 99.7% and total organic carbon of 57.4% were obtained with an initial dye concentration of 25.0 mg L,1 and iron dosage of 200.0 g L,1. Moreover, the decolourization rates followed pseudo-first-order kinetic equations with respect to dye concentration. The colour removal efficiency was simultaneously dependent on iron dosage and various initial dye concentrations, although the colour and total organic carbon removal efficiencies linearly increased with increased iron dosage, reaching a maximum at 100.0 g L,1. A contour plot was developed to illustrate the 3D relation of removal efficiencies with initial dye concentration and iron dosage. For wastewater with a concentration range from 25 to 100 mg L,1 CI Acid Black 24 the suggested ideal operation conditions are 100.0 g L,1 iron dosage, pH 2-4, normal oxygen concentration of 5-7 mg L,1 and reaction time of 30-60 min. Copyright © 2006 Society of Chemical Industry [source] Prediction model for increasing propylene from FCC gasoline secondary reactions based on Levenberg,Marquardt algorithm coupled with support vector machinesJOURNAL OF CHEMOMETRICS, Issue 9 2010Xiaowei Zhou Abstract Levenberg,Marquardt (LM) algorithm was adopted to optimize the multiple parameters of the support vector machines (SVM) model to overcome the difficulty in selecting the parameters of SVM and to fit relational expression of high nonlinearity. Strategy of dividing the training data into working data to train SVM and the testing data so as to avoid over-fitting was performed. Comparison of the proposed LM/SVM method with three reported hybridized SVM approaches (GA/SVM, SM/SVM and SQP/SVM) was also carried out. The new method was applied in modelling for the prediction of propylene by secondary reactions of FCC gasoline. Best performance of LM/SVM employing polynomial kernel was demonstrated. Good agreement between predicted results and experimental data suggests that the LM/SVM method is successfully developed and the SVM model for increasing propylene is well established. Finally, sequential quadratic programming (SQP) algorithm was employed to optimize the operation conditions of FCC gasoline secondary reaction for maximizing the propylene yield. The obtained optimization conditions are consistent with experimental data and reported results, indicating that the optimization results are reliable. Copyright © 2010 John Wiley & Sons, Ltd. [source] OPTIMIZATION OF NATTOKINASE PRODUCTION CONDUCTION USING RESPONSE SURFACE METHODOLOGYJOURNAL OF FOOD PROCESS ENGINEERING, Issue 1 2006DJA-SHIN WANG ABSTRACT Natto has attracted worldwide attention because of its health benefits and long history in Japanese food. It has been found that a potent fibrinolytic enzyme named nattokinase, which is extracted from natto, is able to prevent atherosclerosis. The production of nattokinase may be influenced by various factors such as temperature, shaking speed, volume of medium, fermentation time and so forth. Three-step response surface methodology was applied to obtain the optimal operation conditions of the fermentation process in order to maximize the nattokinase yield. The three major steps are described as follows. First, the important factors for fermentation were identified by L8 orthogonal array experiment. The chosen factors were temperature (37 or 45C), shaking speed (110 or 150 rpm), volume of medium (80 or 120 mL), Brix of wheat bran extract (1.5 or 3°), Brix of soy meal extract (1 or 2°), glucose concentration (0.6 or 1.2%) and fermentation time (24 or 36 h). Second, a regression equation was established between the response (i.e., the enzyme activity) and the two statistically significant factors (i.e., the volume of medium and fermentation time). Third, the optimal solutions for the volume of medium and fermentation time were obtained based on the response surface of the regression equation. According to the response surface analysis, the optimal operation conditions for the fermentation process should be 80 mL and 37.0817 h for the volume of medium and the fermentation time, respectively, which resulted in 459.11 FU/mL as the predicted enzyme activity. [source] A new recovery process of carbon dioxide from alkaline carbonate solution via electrodialysisAICHE JOURNAL, Issue 12 2009Hiroki Nagasawa Abstract Bipolar membrane electrodialysis is applied to CO2 recovery from alkaline carbonate solution. CO2 in flue gas is captured by an alkaline hydroxide absorbing solution to form an alkaline carbonate solution. The captured CO2 is recovered from the alkaline carbonate solution via bipolar membrane electrodialysis, and the alkaline solution is regenerated simultaneously. To reduce the power requirement for CO2 recovery, this study considers optimal design and operation. Three membrane arrangements were compared, and the results indicate the membrane arrangement comprising a bipolar membrane and cation exchange membrane is the most energy saving. With further optimization of operation conditions, the minimum power requirement for CO2 recovery was reduced to 2.1 MJ/kg-CO2 (or 2.1 GJ/t-CO2). © 2009 American Institute of Chemical Engineers AIChE J, 2009 [source] Predictive membrane transport model for nanofiltration processes in water treatmentAICHE JOURNAL, Issue 6 2001Shih-Chieh Tu A membrane transport model was developed for prediction and simulation of membrane filtration (nanofiltration) dynamics with reference to permeate flux. It incorporates important phenomenological aspects of membrane transport, such as concentration polarization and gel layer formation, and illustrates the concentration of solutes as foulants in the mass-transfer boundary layer on the membrane surface. Membrane filtration tests using tannic acid as a model organic compound were designed for investigating permeate fluxes, as well as solute concentration profiles for permeates and concentrates. Membrane performance experiments were conducted under various operation conditions by varying several parameters including solute concentrations, transmembrane pressures, and reject flow rates. The tests showed that the NF-45 membrane composed of polypiperazine amide was more susceptible to organic fouling by tannic acid than the NF-70 membrane made of cross-linked aromatic polyamide. These observations were supported by surface-potential measurements that demonstrated higher negative surface charges and greater hydrophilicity for the NF-70 membrane in the presence of tannic acid. The predictive capability of the membrane transport model was evaluated using the results from membrane filtration tests. Model sensitivity studies were conducted to obtain information on effects of various input parameters pertaining to operating conditions and fluid-dynamic regimes. [source] The effect of water to ethanol feed ratio on physical properties and aerosolization behavior of spray dried cromolyn sodium particlesJOURNAL OF PHARMACEUTICAL SCIENCES, Issue 5 2005Kambiz Gilani Abstract Cromolyn sodium (CS) was spray dried under constant operation conditions from different water to ethanol feed ratios (50:50,0:100). The spray dried CS samples were characterized for their physicochemical properties including crystallinity, particle size distribution, morphology, density, and water/ethanol content. To determine quantitatively the crystallinity of the powders, an X-ray diffraction (XRD) method was developed using samples with different crystallinity prepared by physical mixing of 100% amorphous and 100% crystalline CS materials. The aerodynamic behavior of the CS samples was determined using an Andersen Cascade Impactor (ACI) with a Spinhaler® at an air flow of 60 L/min. Binary mixtures of each spray dried CS powder and Pharmatose® 325, a commercial ,-lactose monohydrate available for DPI formulations, were prepared and in vitro aerosol deposition of the drug from the mixtures was analyzed using ACI to evaluate the effect of carrier on deposition profiles of the spray dried samples. CS spray dried from absolute ethanol exhibited XRD pattern characteristic for crystalline materials and different from patterns of the other samples. The crystallinity of spray dried CS obtained in the presence of water varied from 0% to 28.37%, depending on the ratio of water to ethanol in the feed suspensions. All samples presented different particle size, water/ethanol content, and bulk density values. CS particles spray dried from absolute ethanol presented uniform elongated shape whereas the other samples consisted mainly of particles with irregular shape. Overall, fine particle fraction increased significantly (p,<,0.01) with decreasing d50% and water and ethanol content of spray dried CS samples. Significant difference (p,<,0.01) in deposition profiles of the drug were observed between corresponding carrier free and carrier blended formulations. The difference in deposition profiles of CS aerosolized from various spray dried samples were described according to the particle size, shape, and water/ethanol contents of the powders. The results of this study indicate that enhanced aerosol performance of CS can be obtained by spray drying of the drug from suspensions containing ,87.5% v/v ethanol. © 2005 Wiley-Liss, Inc. and the American Pharmacists Association J Pharm Sci 94:1048,1059, 2005 [source] Molecular thermodynamics of asphaltene precipitation in reservoir fluidsAICHE JOURNAL, Issue 1 2000Jianzhong Wu A previously described molecular-thermodynamic framework, based on colloid theory, is used to correlate experimental asphaltene-precipitation data at high-temperature and pressure conditions. In this framework, asphaltenes and resins are represented by pseudopure components, and all other components in a crude oil are presented by a continuous medium that affects van der Waals attractions among asphaltene and resin molecules. Model parameters are evaluated systematically from average properties of asphaltenes and resins in crude oils, and from dispersion-force properties of the oil medium. Given the composition of the medium, and asphaltene and resin concentrations, the molecular-thermodynamic model described here can be used to identify the onset of asphaltene precipitation, and the total amount of precipitation at the given operation conditions. Calculated results for the effects of oil composition and pressure on asphaltene precipitation are in good agreement with at least some experimental measurements for four reservoir fluids, including Texaco, Shell, Weyburn, and North-Sea crude oils. [source] Performance of a cryogenic silicon monochromator under extreme heat loadJOURNAL OF SYNCHROTRON RADIATION, Issue 2 2004Aleksandr Chumakov The performance of an indirectly cooled cryogenic silicon monochromator under heat loads up to 870,W has been studied. The investigation was performed over numerous parameters and included measurements of total flux, spectral density, rocking curves, angular beam profiles and crystal slope errors. An almost ideal monochromator performance was observed in the 270,570,W range of the heating power. At a heat load of ,400,W and under standard operation conditions, the crystal distortions did not exceed 1,µrad. At the highest available heat load of 870,W, the crystal distortions were about 7,µrad. [source] Simultaneous Data Reconciliation and Parameter Estimation in Bulk Polypropylene Polymerizations in Real TimeMACROMOLECULAR SYMPOSIA, Issue 1 2006Diego Martinez Prata Abstract This work presents the implementation of a methodology for dynamic data reconciliation and simultaneous estimation of quality and productivity parameters in real time, using data from an industrial bulk Ziegler-Natta propylene polymerization process. A phenomenological model of the real process, based on mass and energy balances, was developed and implemented for interpretation of actual plant data. The resulting nonlinear dynamic optimization problem was solved using a sequential approach on a time window specifically tuned for the studied process. Despite the essentially isothermal operation conditions, obtained results show that inclusion of energy balance constraints allows for increase of information redundancy and, as a consequence, for computation of better parameter estimates than the ones obtained when the energy balance constraints are not considered (Prata et al., 2005). Examples indicate that the proposed technique can be used very effectively for monitoring of polymer quality and identification of process malfunctions in real time even when laboratory analyses are scarce. [source] Optimisation of in-service performance of boiler steels by modelling high-temperature corrosionMATERIALS AND CORROSION/WERKSTOFFE UND KORROSION, Issue 3 2006L. Heikinheimo Abstract The main objective of the EU OPTICORR project is the optimisation of in-service performance of boiler steels by modelling high-temperature corrosion, the development of a life-cycle approach (LCA) for the materials in energy production, particularly for the steels used in waste incinerators and co-fired boiler plants. The expected benefits of this approach for safe and cost effective energy production are: - control and optimisation of in-service performance of boiler materials, - understanding of high-temperature corrosion and oxidation mechanisms under service conditions, - improvement of reliability to prevent the failure of components and plant accidents and - expanding the limits of boiler plant materials by corrosion simulations for flexible plant operation conditions (steel, fuel, temperature etc.). The technical aim of the EU OPTICORR project is the development of modelling tools for high-temperature oxidation and corrosion specifically in boiler conditions with HCl- and SO2 -containing combustion gases and Cl-containing salts. The work necessitates thermodynamic data collection and processing. For development and modelling, knowledge about the corrosion mechanisms and exact data are needed. The kinetics of high-temperature oxidation and corrosion are determined from laboratory thermo-gravimetric tests (TG) and multi-sample exposure tests. The materials studied are typical boiler tubes and fin-steels: ferritic alloys, the austenitic steel T347 and the Ni-based alloy Inconel 625. The exposure gases are dry air, air with 15 vol-% H2O, and with 2000 ppm HCl and 200 ppm SO2. The salt deposits used are based on KCl-ZnCl2 and Ca, Na, K, Pb, Zn-sulfates. The test temperatures for exposures with deposits are 320 and 420°C and, for gas exposures, 500 to 600°C. At present the tools being developed are ChemSheet based programmes with a kinetic module and easy-to-use interface and a more sophisticated numerical finite-difference-based diffusion calculation programme, InCorr, developed for prediction of inward corrosion and internal corrosion. The development of modelling tools for oxidation and high-temperature corrosion was started with thermodynamic data collection for relevant systems and thermodynamic mappings. Further, there are needs to develop the simulation model and tool for salt-induced hot corrosion based on the ChemSheet approach. Also, the work on modelling and simulating with the InCorr kinetic modelling tool will be continued to demonstrate the use of the tool for various steels and alloys in defined combustion environments. [source] Comparative Study of the Carbonisation of CoTMPP by Low Temperature Plasma and Heat TreatmentPLASMA PROCESSES AND POLYMERS, Issue 6 2010Iris Herrmann Abstract Low temperature plasma (LTP) treatment of cobalt-tetramethoxyphenylporphyrin (CoTMPP) has been applied as a promising alternative method to the conventional heat treatment in order to attain highly active catalysts for the electroreduction of oxygen. In this contribution it is shown that CoTMPP can be completely transformed into a carbon matrix by adjusting adequate LTP parameters. The carbonisation process of CoTMPP is investigated at different operation conditions by Raman and IR spectroscopy and compared with the structural features of the heat-treated samples. As a result it appears that the LTP occurs via a different carbonisation process, which yields in a more homogeneously defined molecular carbon structure. [source] Numerical investigation of continuous processes for catalytic hydrogenation of nitrile butadiene rubberPOLYMER ENGINEERING & SCIENCE, Issue 5 2002Qinmin Pan Dynamic behavior of continuous processes was numerically investigated for the catalytic hydrogenation of nitrile butadiene rubber, based on developed models, which took into account the coupling between kinetics and mass transfer. The evolution of hydrogenation reaction trajectories in both cases were analyzed. It is proposed that the coupling behavior between the catalytic hydrogenation and mass transfer was completely determined by the ability of the catalyst in activating hydrogen, carbon-carbon double bond loading level and the relative capacity of reaction to mass transfer as well as the residence time in the reactor. Four dimensionless parameters were derived to characterize these aspects. The effects of operation conditions on the hydrogenation processes were investigated. The application of the ideal flow models to non-ideal flows was in addition discussed. It is suggested that the optimal reactor for such a hydrogenation system would be a plug flow reactor with an instantaneous well-mixing component in the inlet of it, and a reasonable approach to the proposed optimal reactor should be with the flow behavior of at least three continuous stirred tank reactors in series. Further research directions are suggested. [source] Clustering behaviour in gas,liquid,solid circulating fluidized beds with low solid holdups of resin particlesTHE CANADIAN JOURNAL OF CHEMICAL ENGINEERING, Issue 4 2010Jianhua Liu Abstract The flow in a gas,liquid,solid circulating fluidized bed is self-organised and manifests itself with clustering of particles and bubbles. The clustering behaviour in the fluidized bed at low solid holdups of resin particles was experimentally investigated with a high-speed image measurement and treatment technique of complementary metal oxide semiconductor to enhance the fundamental understanding on such a flow. Several new physical quantities were suggested to characterise such ordered flow structures. The main findings are as follows. The clusters of solid particles largely exist as doublets and triplets, the mixed groups of particles and bubbles mostly exist as one bubble carrying two to four particles. Increasing superficial liquid velocity, particle diameter or density weakens the aggregation degrees of both particle and mixed clusters in the riser and downer, except that the increase of superficial liquid velocity enhances the mixed clustering behaviour in the riser. The climbing of the auxiliary liquid velocity or liquid phase viscosity intensifies the aggregation behaviour, except that the increase of liquid phase viscosity reduces the mixed clustering degree in the riser. The influences of superficial gas velocity and surface tension of liquid phase on the clustering behaviour seem to be a little complex and the trends are not simply increasing or decreasing. The life cycle of solid particle clusters in the GLS riser is not sensitive to the operation conditions, being around 0.07,s. The mixed clusters' life cycle is more sensitive to the conditions and physical properties of phases, changing from 0.02 to 0.07,s. L'écoulement dans un lit fluidisé de circulation gaz-liquide-solide s'organise souvent de lui même et se manifeste avec l'agrégation des particules et des bulles. Le comportement de l'agrégation dans le lit fluidisé à faible retenue de particules de résine solide a été étudié expérimentalement en utilisant une technique d'imagerie ultra-rapide de mesure et de traitement à base de semi-conducteur complémentaire à l'oxyde de métal afin d'approfondir la compréhension fondamentale d'un tel écoulement. Plusieurs nouvelles quantités physiques ont été suggérées pour caractériser une telle structure d'écoulement auto-organisé. Les principaux résultats sont comme suit. Les agrégations de particules solides existent principalement en tant que doublets et triplets, les groupes mixtes de particules et de bulles existent pour la plupart sous la forme d'une bulle comportant deux à quatre particules. Une augmentation de la vitesse superficielle du liquide, du diamètre des particules ou de la densité affaiblit à la fois les degrés d'agrégation des particules et des agrégats mixtes dans la colonne montante et dans la colonne descendante, sauf que l'augmentation de la vitesse superficielle du liquide intensifie le comportement d'agrégation mixte dans la colonne montante. L'accroissement de la vitesse auxiliaire du liquide ou de la viscosité de la phase liquide intensifie le comportement d'agrégation, sauf que l'augmentation de la viscosité de la phase liquide réduit le degré d'agrégation mixte dans la colonne montante. Les influences de la vitesse superficielle du gaz et de la tension de surface de la phase liquide sur le comportement de l'agrégation semblent être quelque peu complexes et les tendances ne sont pas simplement croissantes ou décroissantes. Le cycle de vie des agrégats de particules solides dans la colonne gaz-liquide-solide montante n'est pas sensible aux facteurs, tournant autour de 0.07,s. Le cycle de vie des agrégats mixtes est plus sensible aux conditions de fonctionnement et aux caractéristiques physiques des phases, évoluant de 0.02 à 0.07,s. [source] Effect of packed structure on flow behaviour in a trickle bed biofilterTHE CANADIAN JOURNAL OF CHEMICAL ENGINEERING, Issue 4 2001Meisen Li Abstract The effects of operation conditions on the flow behaviour in gas,liquid countercurrent trickle bed biofilter were experimentally examined. In order to prevent gas channelling in the biofilter, packings with a relatively large void fraction, which have a role to maintain a high void fraction in the bed, were added. The gas and liquid velocities of the packed structure and the packings were changed, and the residence time distributions (RTDs) of the gas and liquid were measured. It was found that the addition of void supporters was very effective in the suppression of gas channelling. On a examiné de manière expérimental les effets des conditions opératoires sur les comportements d'écoulement dans un biofiltre à lit ruisselant à contre-courant gaz-liquide. Afin d'emp,cher le renardage dans le biofiltre, des garnissages ayant une fraction de vide relativement grande, qui joue un r,le pour maintenir un haut degré de vide, ont été ajoutés. Les vitesses de gaz et de liquide, la structure garnie et les garnissages ont été modifiés, et les distributions de temps de séjour (RTD) du gaz et du liquide ont été mesurées. On a trouvé que l'ajout de supports de vide était très efficace pour la suppression du renardage. [source] On the costs of parameter uncertainties.THE CANADIAN JOURNAL OF CHEMICAL ENGINEERING, Issue 3 2001Part 2: Impact of EVOP procedures on the optimization, design of experiments Abstract Pinto (1998) showed that an economical value might be assigned to model parameter uncertainties, which could be used for process optimization and for taking decisions during sequential experimental designs. The procedure is extended to take into account the fact that plant operation conditions change with time, leading to improvements of the plant operation and allowing the partial recovering of losses introduced by uncertain parameters during plant design. It is shown that the use of EVOP (Evolutionary Operation Procedures) during plant operation may reduce the cost of parameter uncertainties, exerting a major impact on process optimization and optimal design of experiments. Pinto (1998) a montré qu'une valeur économique peut être assignée aux incertitudes sur les paramétres du modèle. Cette valeur pourrait alors être utilisée dans l'optimisation du processus et dans la prise de décision dans la planification d'une série d'expériences. Cette procédure est maintenant étendue pour prendre en considération le fait qu'habituellement les conditions d'opérations des usines varient avec le temps. Ce qui permet d'améliorer l'opération des usines et de recouvrir les pertes partielles imposées par les incertitudes à propos des paramètres durant l'étape de la planification, il! est aussi montré que l'usage actuel de l'EVOP (Evolutionary Operation Procedure) durant l'opération des usines peut amener à une réduction sigiftcative du coût assigné aux incertitudes des paramétres, avec grand impact tant sur l'optimisation des processus que sur la planification des expériences. [source] Investigation on SO2 emission from 410t/h circulating fluidized bed boiler burning petroleum coke and coalASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, Issue 2 2010Lun-Bo Duan Abstract Effects of operation parameters including bed temperature, Ca/S molar ratio, excess air coefficient, fly ash recirculation rate and limestone microstructure on SO2 emission were investigated on a 410t/h circulating fluidized bed (CFB) boiler burning petroleum coke and coal. Results show that for different fuels, SO2 emission is correspondingly related to the sulfur content in it under the same operation conditions. With increasing bed temperature, SO2 concentration in the flue gas reduces first and then increases. There is an optimal desulfurization temperature. For burning bituminous coal (BC) only or 70% BC + 30% petroleum coke (PC), the optimal desulfurization temperature is about 850 °C, while it is about 850,870 °C for burning 50% anthracite (AN) + 50% PC. SO2 emission decreases with the increase in Ca/S ratio, excess air coefficient and fly ash recirculation rate. Microstructure of limestone has distinct effects on their SO2 retention capacity, and bigger specific surface area and higher specific pore volume lead to stronger SO2 capture activities. The optimal temperature, Ca/S ratio and excess air coefficient for different fuels are recommended for industrial application. Copyright © 2009 Curtin University of Technology and John Wiley & Sons, Ltd. [source] Acoustic comfort in office buildings with double skin glass façadesBAUPHYSIK, Issue 5 2009Volker Huckemann Dipl.-Ing. Schall; Sound protection and acoustics Abstract In the Project TwinSkin at the IGS Institut für Gebäude- und Solartechnik (Institute for Building Services and Energy Design) Brunswick/Germany, nine office buildings with double skin glass façades (DSF) were i.a. acoustically evaluated. Double skin façades (DSF), in comparison with other kind of façades, are frequently promoted to provide higher sound insulation from external noise, especially road traffic noise. DSF offer the advantage of operable windows or doors to the cavity, which provide occupant comfort; however, than questions about the impairment of acoustic comfort arise. The objective was to thoroughly analyse the apparent sound insulation properties of DSF in the extended frequency range from 50 to 5000 Hz. Measurements were performed according to the standard EN ISO 140-5 for different operation conditions of the openings and single number quantities were calculated. Additionally their respective spectrum adaptation terms (C and Ctr) were considered. A remarkable influence of DSF design on the sound insulation properties was found. The results show high levels of weighted apparent sound reduction up to 60 dB, but also there were results from only 35 dB to 40 dB. Multi storey façades tend to better sound insulation performance in relation to the other types of DSF, an average of 13 dB higher values were found. Esthetical favourable arrangements of DSF can provide substantial negative influence on sound insulation. Akustischer Komfort in Bürogebäuden mit Doppelglasfassaden. In dem Projekt TwinSkin am IGS Institut für Gebäude- und Solartechnik Braunschweig wurden neun Bürogebäude mit Doppelglasfassaden (DGF) akustisch bewertet. Glasdoppelfassaden bieten gegenüber anderen Fassadenarten einen erhöhten Schutz der hinter der Fassade liegenden Räume vor von außen eindringendem Lärm, insbesondere Straßenverkehrslärm. Zudem können bei DSF Fenster oder Türen in den Fassadenzwischenraum geöffnet werden, was möglicherweise den Nutzerkomfort erhöht, aber Fragen über die Beeinträchtigung des akustischen Komforts entstehen lässt. Das Ziel der vorliegenden Arbeit war es, die vorhandene Schalldämmung von DSF im erweiterten Frequenzbereich von 50 bis 5000 Hz gründlich zu analysieren. Die Messungen wurden nach EN ISO 140-5 für die verschiedenen Betriebsbedingungen der Öffnungen durchgeführt und es wurden Einzahlangaben berechnet. Zusätzlich wurden die jeweiligen Spektrum-Anpassungswerte (C und Ctr) berücksichtigt. Es wurde ein bemerkenswerter Einfluss des DSF-Designs auf die Schalldämmungseigenschaften gefunden. Die Ergebnisse zeigen ein hohes Schalldämm-Maß bis zu 60 dB, aber es wurden auch Ergebnisse von nur 35 dB und 40 dB gemessen. Mehrgeschossige Fassaden weisen im Vergleich zu den anderen Arten von DSF eine bessere Schalldämmung auf, wobei im Durchschnitt 13 dB höhere Werte gefunden wurden. Ästhetisch bevorzugte Gestaltungen der DSF können dagegen einen erheblichen negativen Einfluss auf die Schalldämmung haben. [source] Hydrodynamics and mass transfer coefficient in activated sludge aerated stirred column reactor: experimental analysis and modelingBIOTECHNOLOGY & BIOENGINEERING, Issue 4 2005Bo Jin Abstract The aerated stirred reactor (ASR) has been widely used in biochemical and wastewater treatment processes. The information describing how the activated sludge properties and operation conditions affect the hydrodynamics and mass transfer coefficient is missing in the literature. The aim of this study was to investigate the influence of flow regime, superficial gas velocity (UG), power consumption unit (P/VL), sludge loading, and apparent viscosity (,ap) of activated sludge fluid on the mixing time (tm), gas hold-up (,), and volumetric mass transfer coefficient (kLa) in an activated sludge aerated stirred column reactor (ASCR). The activated sludge fluid performed a non-Newtonian rheological behavior. The sludge loading significantly affected the fluid hydrodynamics and mass transfer. With an increase in the UG and P/VL, the , and kLa increased, and the tm, decreased. The ,, kLa, and tm, were influenced dramatically as the flow regime changed from homogeneous to heterogeneous patterns. The proposed mathematical models predicted the experimental results well under experimental conditions, indicating that the UG, P/VL, and ,ap had significant impact on the tm, ,, and kLa. These models were able to give the tm, ,, and kLa values with an error around ±8%, and always less than ±10%. © 2005 Wiley Periodicals, Inc. [source] Microarray Studies in Bacillus subtilisBIOTECHNOLOGY JOURNAL, Issue 7 2009nar Kocaba Abstract This review focuses on the construction of a global, comprehensive understanding of Bacillus subtilis through microarray studies. The microarray studies in B. subtilis were analysed based on the theme of the work, by mentioning the growth media, bioreactor operation conditions, RNA isolation method, number of data points analysed in exponential or stationary phases, compared genotypes, induction and repression ratios, investigated gene(s) and their positive and/or negative influences. Based on the theme and scope of the studies, the articles were reviewed under seven thematic sections, i.e., effects of gene deletion(s) or overexpression, effects of overexression of heterologous genes, comparison of global gene expression between aerobic and anaerobic respiration, effects of temperature change, effects of transported molecules, effects of limitations and stress conditions, and other microarray studies in B. subtilis. [source] Operational concept for the improved synthesis of (R)-3,3'-furoin and related hydrophobic compounds with benzaldehyde lyaseBIOTECHNOLOGY JOURNAL, Issue 5 2006Marion B. Ansorge-Schumacher Dr. Abstract Biphasic reaction systems for enzyme catalysis are an elegant way to overcome limited solubility and stability of reactants and facilitate continuous processes. However, many synthetically useful enzymes are not stable in biphasic systems of water and organic solvent. The entrapment in polymer beads of polyvinyl alcohol has been shown to enable the stable operation of enzymes unstable in conventional biphasic reaction systems. We report the extension of this concept to continuous operation in a fluidised bed reactor. The enzyme benzaldehyde lyase was used for the continuous synthesis of enantiopure (R)-3,3'-furoin. The results show enhanced stability with half-life times under operation conditions of more than 100 h, as well as superior enzyme utilisation in terms of productivity. Furthermore, racemisation and oxidation of the product could be successfully prevented under the non-aqueous and inert reaction conditions. [source] Mimic of a large-scale diafiltration process by using ultra scale-down rotating disc filterBIOTECHNOLOGY PROGRESS, Issue 2 2010Guijun Ma Abstract Ultra scale-down (USD) approach is a powerful tool to predict large-scale process performance by using very small amounts of material. In this article, we present a method to mimic flux and transmission performance in a labscale crossflow operation by an USD rotating disc filter (RDF). The Pellicon 2 labscale system used for evaluation of the mimic can readily be related to small pilot and industrial scale. Adopted from the pulsed sample injection technique by Ghosh and Cui (J Membr Sci. 2000;175:5-84), the RDF has been modified by building in inserts to allow the flexibility of the chamber volume, so that only 1.5 mL of processing material is required for each diafiltration experiment. The reported method enjoys the simplicity of dead-end mode operation with accurate control of operation conditions that can mimic well the crossflow operation in large scale. Wall shear rate correlations have been established for both the labscale cassette and the USD device, and a mimic has been developed by operating both scales under conditions with equivalent averaged shear rates. The studies using E. coli lysate show that the flux vs. transmembrane pressure profile follows a first-order model, and the transmission of antibody fragment (Fab,) is independent of transmembrane pressure. Predicted flux and transmission data agreed well with the experimental results of a labscale diafiltration where the cassette resistance was considered. © 2009 American Institute of Chemical Engineers Biotechnol. Prog., 2010 [source] Simulation and Analysis of a Single-Effect Thermal Vapor-Compression Desalination System at Variable Operation ConditionsCHEMICAL ENGINEERING & TECHNOLOGY (CET), Issue 12 2007G. Ji Abstract A mathematical model is developed to analyze a single-effect thermal vapor compression (TVC) desalination system. The effects of the variation of operation conditions such as the intake seawater temperature and the mass flow rate of cooling water on the system performance are investigated for a specific desalination unit. The system performance is found to decrease when the intake seawater temperature is different from the design value. By adjusting the mass flow rate of cooling water, a better system performance can be obtained when the intake seawater temperature differs from the design conditions. Decreasing the cooling water flow rate to values lower than the design value can lead to a better performance when the intake seawater temperature is lower than the design value, and the system performance reaches a peak point when the cooling water flow rate decreases to a definite level. A better performance can also be obtained by increasing the cooling water flow rate to values higher than design value, when the intake seawater temperature is higher than the design value and the system performance also reaches a peak point when the cooling water flow rate increases to a definite level. [source] Photocatalytic Oxidation for Determination of Chemical Oxygen Demand Using Nano-TiO2 FilmCHINESE JOURNAL OF CHEMISTRY, Issue 10 2005Hong-Chun Ding Abstract A photocatalytic oxidation method for determination of chemical oxygen demand (COD) using nano-TiO2 film, based on the use of a nano-TiO2 -Ce(SO4)2 system and electrochemical detection, was proposed. The technique was originated from the direct determination of the Ce(III) concentration change resulting from photocatalytic oxidation of organic compounds. Ce(III), which was produced by photocatalytic reduction of Ce(SO4)2, could be measured at a multi-walled carbon nanotubes (MWNT) chemically modified electrode (CME). The COD values by this method were calculated from the differential pulse voltammetry (DPV) current of Ce(III) at the CME. Under the optimal operation conditions, the detection limit of 0.5 mg·L,1 COD with the linear range of 1,600 mg·L,1 was achieved. This method was also applied to determination of various COD of ground water and wastewater samples. The results were in good agreement with those from the conventional COD methods, i.e., permanganate and dichromate ones. [source] | |||||||||||||||||||