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Operating Parameters (operating + parameter)
Kinds of Operating Parameters Selected AbstractsEnzymatic Hydrolysis of Waste Office Paper Using Viscosity as Operating ParameterBIOTECHNOLOGY PROGRESS, Issue 2 2001Enoch Y. Park Enzymatic hydrolysis of waste office (WO) paper with feeding WO paper in a reactor was investigated using apparent viscosity as operating parameter. Since the apparent viscosity was correlated with the concentration of pulping WO paper, the amount of hydrolyzed WO paper was assumed by measuring the decrease in the apparent viscosity. Then the amount of hydrolysis WO paper and the amount of enzyme corresponding to the desired ratio were fed into the reactor. When the WO paper and 1% (to the amount of WO paper) enzyme were fed to the hydrolytic reaction, 87 g/L of reducing sugar (RS) with a hydrolytic yield of 42.2% was obtained for a 24-h hydrolysis. However, when nonpulping WO paper and 5% (to the amount of WO paper) enzyme were fed to the hydrolytic reaction, 120 g/L of RS with a hydrolytic yield of 40% was obtained for a 24-h hydrolysis. Therefore, the RS concentration from this hydrolysis process feeding WO paper using apparent viscosity as operating parameter may be of sufficient concentration to serve as a carbon source in microorganism culture or chemical feedstock. [source] Effects of Operating Parameters on the Cinnamaldehyde Content of Extracted Essential Oil Using Various MethodsCHEMICAL ENGINEERING & TECHNOLOGY (CET), Issue 2 2010H. Baseri Abstract Supercritical fluid extraction (SFE) of essential oils from commercial cinnamon bark was compared with essential oils that were obtained by hydrodistillation. Effects of operating parameters (pressure, temperature and extraction time of SFE) on the extraction yield and the composition of the extracted volatile oil were studied. Moreover, in the hydrodistillation process, the effect of the pH of the solvent on the concentration of cinnamaldehyde in the extracted volatile oil was studied. The maximum yield of extract in the SFE process is about 7.8,% at 70,°C and 240,bar. The maximum concentration of cinnamaldehyde in the SFE process was obtained at 70,°C and 160,bar, and the maximum concentration of this component in hydrodistillation was achieved at pH,=,4.1. [source] Effect of Operating Parameters on the Condensation of Ammonium Sulfate by ElectrodialysisCHEMICAL ENGINEERING & TECHNOLOGY (CET), Issue 9 2008H. Yang Abstract The separation of ammonium sulfate from dilute solution by electrodialysis was investigated. From the results obtained, it is suggested that it is feasible to separate ammonium sulfate from aqueous solution by electrodialysis. The removal performance of ammonium sulfate obtained was very satisfactory. The optimal cation and anion membranes were found. The removal efficiencies were influenced by voltage, initial concentration, flow rate and temperature. High voltage and high temperature are beneficial to this separation process, but high fluid flow rate and concentrated initial concentration prolong the operation time required to achieve the target value. It was found that the optimal outlet concentration is 1,g/L, since the operation time is prolonged almost two-fold if the outlet concentration is decreased from 1,g/L to 0.5,g/L. [source] Treatment of textile dye wastewater by using an electrochemical bipolar disc stack reactorJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 10 2004Karuppan Muthukumar Abstract Textile dye house wastewater from a reactive dye processing unit was treated by using an electrochemical oxidation technique. The experiments were carried out in an electrochemical bipolar disc reactor using RuO2 coated on titanium as anode and titanium as cathode. The sodium chloride present in the effluent was used as supporting electrolyte. Operating parameters such as current density, reservoir hold-up and electrolysis time were studied for maximum Chemical Oxygen Demand (COD) reduction and other relevant parameters such as current efficiency and power consumption per kg of COD removal were calculated. The higher flow rate and lower reservoir hold-up resulted in improved COD removal. The applied current density was also found to significantly influence the reduction of COD. A suitable mathematical model is also proposed to illustrate the relationship between the basic parameters. Pseudo mass transfer coefficients were also evaluated for different experimental conditions. Copyright © 2004 Society of Chemical Industry [source] Optimization of extraction process for phenolic acids from black cohosh (Cimicifuga racemosa) by pressurized liquid extraction,JOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE, Issue 1 2006Sudarsan Mukhopadhyay Abstract An investigation to optimize the extraction of phenolic acids from black cohosh using a pressurized liquid extractor system was studied with the aim of developing a generalized approach for sample preparation of phenolic compounds from plant matrices. Operating parameters such as solvent composition, solid-to-solvent ratio, temperature, particle size distribution, and number of extraction cycles were identified as main variables that influence extraction efficiency. A mixture of methanol and water (60:40 v/v) was found to be the best solvent for total phenolics (TP) and individual phenolic acids. The four phenolic acids extracted from black cohosh were identified by HPLC and LC-MS as caffeic acid, ferulic acid, sinapic acid and isoferulic acid. Over 96% of the measured phenolics were extracted in first two cycles. The extraction efficiency for black cohosh with MeOH:H2O (60:40 v/v) was found to be maximum at a solid-to-solvent ratio of 80 mg ml,1. TP content of the extract was found to increase with temperature up to 90 °C. Particle size was found to have a large impact on extraction efficiency of TP. Samples with particle size between 0.25 mm and 0.425 mm provided optimum extraction of phenolics from black cohosh. Published in 2005 for SCI by John Wiley & Sons, Ltd. [source] Enzymatic Hydrolysis of Waste Office Paper Using Viscosity as Operating ParameterBIOTECHNOLOGY PROGRESS, Issue 2 2001Enoch Y. Park Enzymatic hydrolysis of waste office (WO) paper with feeding WO paper in a reactor was investigated using apparent viscosity as operating parameter. Since the apparent viscosity was correlated with the concentration of pulping WO paper, the amount of hydrolyzed WO paper was assumed by measuring the decrease in the apparent viscosity. Then the amount of hydrolysis WO paper and the amount of enzyme corresponding to the desired ratio were fed into the reactor. When the WO paper and 1% (to the amount of WO paper) enzyme were fed to the hydrolytic reaction, 87 g/L of reducing sugar (RS) with a hydrolytic yield of 42.2% was obtained for a 24-h hydrolysis. However, when nonpulping WO paper and 5% (to the amount of WO paper) enzyme were fed to the hydrolytic reaction, 120 g/L of RS with a hydrolytic yield of 40% was obtained for a 24-h hydrolysis. Therefore, the RS concentration from this hydrolysis process feeding WO paper using apparent viscosity as operating parameter may be of sufficient concentration to serve as a carbon source in microorganism culture or chemical feedstock. [source] Optimization of process parameters by Taguchi method in the recovery of lactose from whey using sonocrystallizationCRYSTAL RESEARCH AND TECHNOLOGY, Issue 7 2010S. R. Patel Abstract Anti-solvent crystallization of lactose in the presence of ultrasound will reduce crystal size and the level of agglomeration as compared to the commercial cooling crystallization. It offers a potential route to enhance the physical properties as well as the rapid recovery of lactose. Since lactose recovery itself can reduce biological oxygen demand of whey by more then 80%, recovery of lactose from dairy waste stream (whey) solves the problems of dairy industries by improving economics of whey utilization and pollution reduction. In the present study, recovery of lactose from partially deproteinated whey using an anti-solvent (acetone) by sonocrystallization was optimized for finding the most influencing operating parameters; such as sonication time, anti-solvent concentration, initial lactose concentration in the whey and initial pH of sample mixture at three levels using L9 -orthogonal method. The responses were analyzed for recovery of lactose from whey. The anti-solvent concentration and the sonication time were found to be most influencing parameters for the recovery of lactose and the recovery of lactose was found to be 89.03% at the identified optimized level. The crystal size distribution of recovered lactose was found to be narrower (2.5 , 6.5 ,m) as compared to the commercial lactose crystals (3.5 , 9.5 ,m). (© 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] The Influence of Mass Transfer on a Porous Fuel Cell ElectrodeFUEL CELLS, Issue 1-2 2004Y.-P. Sun Abstract A one-dimensional model for a porous fuel cell electrode using a liquid electrolyte with dissolved reactant is presented. The model consists of a Poisson, second-order ordinary differential equation, describing the effect of the electric field and a one-dimensional; Fickian diffusion, second-order ordinary differential equation describing the concentration variation associated with diffusion. The model accounts for mass transport and heterogeneous electrochemical reaction. The solution of this model is by the approximate Adomian polynomial method and is used to determine lateral distributions of concentration, overpotential and current density and overall cell polarisation. The model is used to simulate the effects of important system and operating parameters, i.e. local diffusion rates, and mass transport coefficients and electrode polarisation behaviour. [source] Prediction of turbulent flow and heat transfer within rotating U-shaped passagesHEAT TRANSFER - ASIAN RESEARCH (FORMERLY HEAT TRANSFER-JAPANESE RESEARCH), Issue 6 2006Liu Chuan Kai Abstract Numerical predictions of three-dimensional flow and heat transfer are presented for rotating serpentine passages with and without rib turbulators. The coolant air is pressurized and its operating conditions are selected closely to match actual turbine operating parameters. Two different arrangements of rib turbulators were studied: (1) transverse ribs on the leading and trailing walls and (2) transverse ribs on all four walls. The rib height-to-hydraulic diameter ratio (e/Dh) is 0.143; the rib pitch-to-height ratio (s/e) is 7. Results for the rib-roughened serpentine passages were compared with those of smooth ones calculated in the literature. It was shown that a significant enhancement is achieved by means of rib turbulators in a serpentine passage at a stationary state as well as in a rotating state. In the radially-outward flow passages, the effect of rotation on heat transfer is relatively prominent. The secondary flows induced by the Coriolis forces are most intensive in the channel with four ribbed surfaces. The heat transfer after a 180° sharp turn in the smooth channel is influenced more by the sharp-turn-induced flow than the rib-roughened ones. © 2006 Wiley Periodicals, Inc. Heat Trans Asian Res, 35(6): 410,420, 2006; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/htj.20125 [source] Prediction of entrance length and mass suction rate for a cylindrical sucking funnelINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS, Issue 6 2010Dipti Prasad Mishra Abstract Conservation equations for mass, momentum and energy have been solved numerically for a cylindrical funnel with louvers (lateral openings on the side wall of the cylindrical funnel through which air can come into it) to compute the suction rate of air into the funnel. The nozzle placed centrally at the bottom of the cylinder ejects high-velocity hot gaseous products so that atmospheric air gets sucked into the funnel. The objective of the work is to compute the ratio of the rate of mass suction to that of the mass ejected by the nozzle for different operating conditions and geometrical size of the funnel. From the computation it has been found that there exists optimum funnel diameter and optimum funnel height for which the mass suction is the highest. The protruding length of the nozzle into the funnel has almost no effect on the mass suction rate after a certain funnel height. The louvers opening area has a very high impact on the mass suction rate. The entrance length for such a sucking funnel is strikingly much lower compared with a simple cylindrical pipe having uniform flow at the inlet at same Reynolds number. A new correlation has been developed to propose the entrance length for a sucking pipe, the rate of mass suction into it and the exhaust plume temperature over a wide range of operating parameters that are normally encountered in a general funnel operations of naval or merchant ship. Copyright © 2009 John Wiley & Sons, Ltd. [source] Performance analysis of a solid oxide fuel cell with reformed natural gas fuelINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 11 2010S. M. Jafarian Abstract In the present study a two-dimensional model of a tubular solid oxide fuel cell operating in a stack is presented. The model analyzes electrochemistry, momentum, heat and mass transfers inside the cell. Internal steam reforming of the reformed natural gas is considered for hydrogen production and Gibbs energy minimization method is used to calculate the fuel equilibrium species concentrations. The conservation equations for energy, mass, momentum and voltage are solved simultaneously using appropriate numerical techniques. The heat radiation between the preheater and cathode surface is incorporated into the model and local heat transfer coefficients are determined throughout the anode and cathode channels. The developed model has been compared with the experimental and numerical data available in literature. The model is used to study the effect of various operating parameters such as excess air, operating pressure and air inlet temperature and the results are discussed in detail. The results show that a more uniform temperature distribution can be achieved along the cell at higher air-flow rates and operating pressures and the cell output voltage is enhanced. It is expected that the proposed model can be used as a design tool for SOFC stack in practical applications. Copyright © 2009 John Wiley & Sons, Ltd. [source] Second law analysis of a natural gas-fired gas turbine cogeneration systemINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 8 2009B. V. Reddy Abstract The influence of operating conditions such as reheat, intercooling, ambient temperature and pressure ratio are analyzed from a second law perspective on the performance of a natural gas-fired gas turbine cogeneration system. The effect of these operating parameters on carbon dioxide emissions is also discussed. The second law efficiency of gas turbine cogeneration system increases markedly with reheat option. Higher pressure ratios lead to decreased second law cogeneration efficiency but this effect can be reduced with a higher level of reheat option. The effect of intercooling on second law efficiency is strongly related to pressure ratio with higher pressure ratios significantly decreasing efficiency. The second law efficiency is not so sensitive to the environment temperature for levels of reheat or intercooling greater than 50%. Copyright © 2009 John Wiley & Sons, Ltd. [source] Cost numerical optimization of the triple-pressure steam-reheat gas-reheat gas-recuperated combined power cycle that uses steam for cooling the first GTINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 15 2008A. M. Bassily Abstract Optimization is an important method for improving the efficiency and power of the combined cycle. In this paper, the triple-pressure steam-reheat gas-reheat gas-recuperated combined cycle that uses steam for cooling the first gas turbine (the regular steam-cooled cycle) was optimized relative to its operating parameters. The optimized cycle generates more power and consumes more fuel than the regular steam-cooled cycle. An objective function of the net additional revenue (the saving of the optimization process) was defined in terms of the revenue of the additional generated power and the costs of replacing the heat recovery steam generator (HRSG) and the costs of the additional operation and maintenance, installation, and fuel. Constraints were set on many operating parameters such as air compression ratio, the minimum temperature difference for pinch points (,Tppm), the dryness fraction at steam turbine outlet, and stack temperature. The net additional revenue and cycle efficiency were optimized at 11 different maximum values of turbine inlet temperature (TIT) using two different methods: the direct search and the variable metric. The optima were found at the boundaries of many constraints such as the maximum values of air compression ratio, turbine outlet temperature (TOT), and the minimum value of stack temperature. The performance of the optimized cycles was compared with that for the regular steam-cooled cycle. The results indicate that the optimized cycles are 1.7,1.8 percentage points higher in efficiency and 4.4,7.1% higher in total specific work than the regular steam-cooled cycle when all cycles are compared at the same values of TIT and ,Tppm. Optimizing the net additional revenue could result in an annual saving of 21 million U.S. dollars for a 439,MW power plant. Increasing the maximum TOT to 1000°C and replacing the stainless steel recuperator heat exchanger of the optimized cycle with a super-alloys-recuperated heat exchanger could result in an additional efficiency increase of 1.1 percentage point and a specific work increase of 4.8,7.1%. The optimized cycles were about 3.3 percentage points higher in efficiency than the most efficient commercially available H-system combined cycle when compared at the same value of TIT. Copyright © 2008 John Wiley & Sons, Ltd. [source] Thermodynamic optimization of a solar system for cogeneration of water heating and absorption coolingINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 13 2008R. Hovsapian Abstract This paper presents a contribution to understanding the behavior of solar-powered air conditioning and refrigeration systems with a view to determining the manner in which refrigeration rate, mass flows, heat transfer areas, and internal architecture are related. A cogeneration system consisting of a solar concentrator, a cavity-type receiver, a gas burner, and a thermal storage reservoir is devised to simultaneously produce heat (hot water) and cooling (absorption refrigerator system). A simplified mathematical model, which combines fundamental and empirical correlations, and principles of classical thermodynamics, mass and heat transfer, is developed. The proposed model is then utilized to simulate numerically the system transient and steady-state response under different operating and design conditions. A system global optimization for maximum performance (or minimum exergy destruction) in the search for minimum pull-down and pull-up times, and maximum system second law efficiency is performed with low computational time. Appropriate dimensionless groups are identified and the results are presented in normalized charts for general application. The numerical results show that the three-way maximized system second law efficiency, ,II,max,max,max, occurs when three system characteristic mass flow rates are optimally selected in general terms as dimensionless heat capacity rates, i.e. (,ss, ,wxwx, ,Hs)opt=(0.335, 0.28, 0.2). The minimum pull-down and pull-up times, and maximum second law efficiencies found with respect to the optimized operating parameters are sharp and, therefore, important to be considered in actual design. As a result, the model is expected to be a useful tool for simulation, design, and optimization of solar energy systems in the context of distributed power generation. Copyright © 2008 John Wiley & Sons, Ltd. [source] An examination of exergy destruction in organic Rankine cyclesINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 10 2008P. J. Mago Abstract The exergy topological method is used to present a quantitative estimation of the exergy destroyed in an organic Rankine cycle (ORC) operating on R113. A detailed roadmap of exergy flow is presented using an exergy wheel, and this visual representation clearly depicts the exergy accounting associated with each thermodynamic process. The analysis indicates that the evaporator accounts for maximum exergy destroyed in the ORC and the process responsible for this is the heat transfer across a finite temperature difference. In addition, the results confirm the thermodynamic superiority of the regenerative ORC over the basic ORC since regenerative heating helps offset a significant amount of exergy destroyed in the evaporator, thereby resulting in a thermodynamically more efficient process. Parameters such as thermodynamic influence coefficient and degree of thermodynamic perfection are identified as useful design metrics to assist exergy-based design of devices. This paper also examines the impact of operating parameters such as evaporator pressure and inlet temperature of the hot gases entering the evaporator on ORC performance. It is shown that exergy destruction decreases with increasing evaporator pressure and decreasing turbine inlet temperatures. Finally, the analysis reveals the potential of the exergy topological methodology as a robust technique to identify the magnitude of irreversibilities associated with real thermodynamic processes in practical thermal systems. Copyright © 2008 John Wiley & Sons, Ltd. [source] Analysis and cost optimization of the triple-pressure steam-reheat gas-reheat gas-recuperated combined power cycleINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 2 2008A. M. Bassily Abstract Increasing the inlet temperature of gas turbine (TIT) and optimization are important methods for improving the efficiency and power of the combined cycle. In this paper, the triple-pressure steam-reheat gas-reheat recuperated combined cycle (the Regular Gas-Reheat cycle) was optimized relative to its operating parameters, including the temperature differences for pinch points (,TPP). The optimized triple-pressure steam-reheat gas-reheat recuperated combined cycle (the Optimized cycle) had much lower ,TPP than that for the Regular Gas-Reheat cycle so that the area of heat transfer of the heat recovery steam generator (HRSG) of the Optimized cycle had to be increased to keep the same rate of heat transfer. For the same mass flow rate of air, the Optimized cycle generates more power and consumes more fuel than the Regular Gas-Reheat cycle. An objective function of the net additional revenue (the saving of the optimization process) was defined in terms of the revenue of the additional generated power and the costs of replacing the HRSG and the additional fuel. Constraints were set on many operating parameters such as the minimum temperature difference for pinch points (,TPPm), the steam turbines inlet temperatures and pressures, and the dryness fraction at steam turbine outlet. The net additional revenue was optimized at 11 different maximum values of TIT using two different methods: the direct search and variable metric. The performance of the Optimized cycle was compared with that for the Regular Gas-Reheat cycle and the triple-pressure steam-reheat gas-reheat recuperated reduced-irreversibility combined cycle (the Reduced-Irreversibility cycle). The results indicate that the Optimized cycle is 0.17,0.35 percentage point higher in efficiency and 5.3,6.8% higher in specific work than the Reduced-Irreversibility cycle, which is 2.84,2.91 percentage points higher in efficiency and 4.7% higher in specific work than the Regular Gas-Reheat cycle when all cycles are compared at the same values of TIT and ,TPPm. Optimizing the net additional revenue could result in an annual saving of 33.7 million US dollars for a 481 MW power plant. The Optimized cycle was 3.62 percentage points higher in efficiency than the most efficient commercially available H-system combined cycle when compared at the same value of TIT. Copyright © 2007 John Wiley & Sons, Ltd. [source] Modelling and experimental studies on heat transfer in the convection section of a biomass boilerINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 12 2006Jukka Yrjölä Abstract This paper describes a model of heat transfer for the convection section of a biomass boiler. The predictions obtained with the model are compared to the measurement results from two boilers, a 50 kWth pellet boiler and a 4000 kWth wood chips boiler. An adequate accuracy was achieved on the wood chips boiler. As for the pellet boiler, the calculated and measured heat transfer rates differed more than expected on the basis of the inaccuracies in correlation reported in the literature. The most uncertain aspect of the model was assumed to be the correlation equation of the entrance region. Hence, the model was adjusted to improve the correlation. As a result of this, a high degree of accuracy was also obtained with the pellet boiler. The next step was to analyse the effect of design and the operating parameters on the pellet boiler. Firstly, the portion of radiation was established at 3,13 per cent, and the portion of entrance region at 39,52 per cent of the entire heat transfer rate under typical operating conditions. The effect of natural convection was small. Secondly, the heat transfer rate seemed to increase when dividing the convection section into more passes, even when the heat transfer surface area remained constant. This is because the effect of the entrance region is recurrent. Thirdly, when using smaller tube diameters the heat transfer area is more energy-efficient, even when the bulk velocity of the flow remains constant. Copyright © 2006 John Wiley & Sons, Ltd. [source] Influence of the heat recovery steam generator design parameters on the thermoeconomic performances of combined cycle gas turbine power plantsINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 14 2004Manuel Valdés Abstract This paper proposes a methodology to identify the most relevant design parameters that impact on the thermal efficiency and the economic results of combined cycle gas turbine power plants. The analysis focuses on the heat recovery steam generator (HRSG) design and more specifically on those operating parameters that have a direct influence on the economic results of the power plant. These results are obtained both at full and part load conditions using a dedicated code capable of simulating a wide number of different plant configurations. Two different thermoeconomic models aimed to select the best design point are proposed and compared: the first one analyzes the generating cost of the energy while the second one analyzes the annual cash flow of the plant. Their objective is to determine whether an increase in the investment in order to improve the thermal efficiency is worth from an economic point of view. Both models and the different HRSG configurations analysed are compared in the results section. Some parametric analysis show how the design parameters might be varied in order to improve the power plant efficiency or the economic results. Copyright © 2004 John Wiley & Sons, Ltd. [source] Thermodynamic optimization of internal structure in a fuel cellINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 4 2004Jose V. C. Vargas Abstract This paper shows that the internal structure (relative sizes, spacings) of a fuel cell can be optimized so that performance is maximized at the global level. The optimization of flow geometry begins at the smallest (elemental) level, where the fuel cell is modelled as a unidirectional flow system. The polarization curve, power and efficiency are obtained as functions of temperature, pressure, geometry and operating parameters. Although the model is illustrated for an alkaline fuel cell, it may be applied to other fuel cell types by changing the reaction equations and accounting for the appropriate energy interactions. The optimization of the internal structure is subjected to fixed total volume. There are four degrees of freedom in the optimization, which account for the relative thicknesses of the two (anode and cathode) diffusion layers, two reaction layers and the space occupied by the electrolyte solution. The available volume is distributed optimally through the system so that the total power is maximized. Numerical results show that the optima are sharp, and must be identified accurately. Temperature and pressure gradients play important roles, especially as the fuel and oxidant flow paths increase. The optimized internal structure is reported in dimensionless form. Directions for future improvements in flow architecture (constructal design) are discussed. Copyright © 2004 John Wiley & Sons, Ltd. [source] Fundamental heat transfer mechanism between bed-to-membrane water-walls in circulating fluidized bed combustorsINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 9 2003B.V. Reddy Abstract In the present work, the fundamental mechanism between bed-to-membrane water-walls in the riser column of a circulating fluidized bed (CFB) combustor is presented. The bed-to-membrane water-wall heat transfer depends on the contributions of particle heat transfer, dispersed phase heat transfer and radiation heat transfer. The fundamental mechanism of particle heat transfer and the effect of fraction of wall exposed to clusters and gas gap thickness between cluster and wall on particle heat transfer coefficient and bed-to-wall heat transfer coefficient are investigated. The influence of operating parameters like cross-sectional average volumetric solids concentration and bed temperature on particle and bed-to-wall heat transfer are also reported. The present work contributes some fundamental information on particle heat transfer mechanism, which is responsible for increasing the bed-to-wall heat transfer coefficient (apart from dispersed phase convection and radiation heat transfer). The details on particle heat transfer mechanism will enable to understand the basic heat transfer phenomena between bed-to-membrane water-walls in circulating fluidized bed combustors in a detailed way, which in turn will aid for better design of CFB combustor units. The particle heat transfer mechanism is significantly influenced by the fraction of wall exposed to clusters and gas gap thickness between clusters and wall. Copyright © 2003 John Wiley & Sons, Ltd. [source] Performance study of a partial gasification pressurized combustion topping gas cycle and split rankine combined cycle: Part II,Exergy analysisINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 6 2003S. De Abstract In addition to the energy analysis in part I of this paper, an exergy analysis of an advanced combined cycle is presented in this part of the paper to identify the major causes of thermodynamic imperfections. The exergy loss and exergetical efficiency of each of the components of the plant are investigated for variations of design and operating parameters. This is done to explore the possible improvements in the second law performance of this plant. Copyright © 2003 John Wiley & Sons, Ltd. [source] Preparation of a heterogeneous hollow-fiber affinity membrane having a mercapto chelating resin and its recovery of Hg2+ cationsJOURNAL OF APPLIED POLYMER SCIENCE, Issue 1 2008Bing Wang Abstract A kind of heterogeneous hollow-fiber affinity filter membrane with a high chelating capacity for Hg2+ was prepared by phase separation with blends of a mercapto chelating resin and polysulfone as the membrane materials, N,N -dimethylacetamide as the solvent, and water as the extraction solvent. The adsorption isotherms of the hollow-fiber affinity filter membrane for Hg2+ were determined. The heterogeneous hollow-fiber affinity filter membrane was used for the adsorption of Hg2+ cations through the coordination of the mercapto group and Hg2+ cations, and the effects of the morphology and structure of the affinity membrane on the chelating properties were investigated. The chelating conditions, including the chelating resin grain size, pH value, concentration of the metallic ion solution, mobile phase conditions, and operating parameters, had significant effects on the chelating capacity of the hollow-fiber affinity filter membrane. The results revealed that the greatest chelating capacity of the hollow-fiber affinity filter membrane for Hg2+ was 1090 ,g/cm2 of membrane under appropriate conditions, and the adsorption isotherms of Hg2+ could be described by the Langmuir isotherm. The dynamic chelating experiments indicated that the hollow-fiber affinity membrane could be operated at a high feed flow rate and that large-scale removal of Hg2+ could be realized. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 [source] Application of Cavitational reactors for cell disruption for recovery of intracellular enzymesJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 8 2008Parag R. Gogate Abstract Cavitational reactors are a novel and promising form of multiphase reactors, based on the principle of release of a large amount of energy owing to the violent collapse of cavities. This paper presents an overview of cavitational reactors in the specific area of cell disruption for the recovery of intracellular enzymes, in terms of the basic aspects, different reactor configurations including recommendations for optimum operating parameters and review of earlier literature reports. It has been observed that under optimized conditions, cavitational reactors can reduce the energy requirement for the release of intracellular enzymes by an order of magnitude compared with conventional cell disruption techniques used on an industrial scale. However, problems associated with efficient scale-up and operation at conditions required for industrial scale, hamper the successful utilization of cavitational reactors at this time. Some recommendations have been made for the future work required to realize the dream of harnessing the spectacular effects of cavitation phenomena. Copyright © 2008 Society of Chemical Industry [source] Palm oil mill effluent pretreatment using Moringa oleifera seeds as an environmentally friendly coagulant: laboratory and pilot plant studiesJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 12 2006Subhash Bhatia Abstract This research paper covers the suitability of the coagulation,flocculation process using Moringa oleifera seeds after oil extraction as a natural and environmentally friendly coagulant for palm oil mill effluent treatment. The performance of M. oleifera coagulant was studied along with the flocculant KP 9650 in removal of suspended solids, organic components and in increasing the floc size. The optimum values of the operating parameters obtained from the laboratory jar test were applied in a pilot-scale treatment plant comprised of coagulation,flocculation and filtration processes. Pilot-scale pretreatment resulted in 99.7% suspended solids removal, 71.5% COD reduction, 68.2% BOD reduction, 100% oil and grease removal and 91% TKN removal. In pilot plant pretreatment, the percentage recovery of water was 83.3%, and 99.7% sludge was recovered after dewatering in a filter press. Copyright © 2006 Society of Chemical Industry [source] Supercritical water oxidation of quinoline in a continuous plug flow reactor,part 2: kineticsJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 6 2006Lisete DS Pinto Abstract The results of a detailed investigation into the kinetics of quinoline oxidation in supercritical water are presented. The novel kinetic data presented were obtained in a continuously operated, plug flow reactor where parameters such as temperature, pressure, residence time and stoichiometric ratio of oxidant to quinoline were investigated and detailed in the companion paper (Pinto LDS, Freitas dos Santos LMF, Al-Duri B and Santos RCD, Supercritical water oxidation of quinoline in a continuous plug flow reactor,part 1: effect of key operating parameters. J Chem Technol Biotechnol). An induction time was experimentally observed, ranging from 1.5 to 3.5 s, with longer times observed in experiments carried out at lower temperatures. A pseudo-first-order rate expression with respect to quinoline concentration (with oxygen excess) was first adopted and the activation energy of 234 kJ mol,1 and a pre-exponential factor of 2.1 × 1014 s,1 were estimated. Furthermore, an integral power rate model expression was established, attributing a reaction order for quinoline as 1 and for oxygen as 0.36. An activation energy and pre-exponential factor for this model were determined as 224 kJ mol,1 and 3.68 × 1014 M,0.36 s,1, respectively. A global rate expression was then regressed for the quinoline reaction rate from the complete set of data. The resulting activation energy was 226 ± 19 kJ mol,1 and the pre-exponential factor was 2.7 × 1013 ± 2 M,0.1 s,1. The reaction orders for quinoline and oxygen were 0.8 ± 0.1 and 0.3 ± 0.1, respectively. It was shown that the least-squares regression method provided the best-fit model for experimental results investigated in this study. Copyright © 2006 Society of Chemical Industry [source] Pervaporation of tertiary butanol/water mixtures through chitosan membranes cross-linked with toluylene diisocyanate,JOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 12 2005Smitha Biduru Abstract Membranes made from 84% deacetylated chitosan biopolymer were cross-linked by a novel method using 2,4-toluylene diisocyanate (TDI) and tested for the separation of t -butanol/water mixtures by pervaporation. The unmodified and cross-linked membranes were characterized by Fourier transform infra red (FTIR) spectroscopy, X-ray diffraction (XRD) studies and sorption studies in order to understand the polymer,liquid interactions and separation mechanisms. Thermal stability was analyzed by differential scanning calorimetry (DSC) and thermo gravimetric analysis (TGA) while tensile strength measurement was carried out to assess mechanical strength. The membrane appears to have good potential for breaking the aqueous azeotrope of 88.2 wt% t -butanol by giving a high selectivity of 620 and substantial water flux (0.38 kg m,2 hr,1). The effects of operating parameters such as feed composition, membrane thickness and permeate pressure on membrane performance were evaluated. Copyright © 2005 Society of Chemical Industry [source] Test of flow field on the annular meridian plane in a tubular membrane separator with rotary tangential flowJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 9 2004Cheng Duan Wang Abstract Enhancement of membrane microfiltration by rotary tangential flow is a new technique, which is based on the hydrocyclone mechanism. It improved the structure of the general membrane separator and the form of the liquid suspension flowing into the separator, so as to increase membrane fluxes and decrease membrane fouling. In our research, a tubular membrane separator with rotary tangential flow was designed for the first time. The flow field characteristics of polypropylene tubular membrane microfiltration in this tubular separator were studied systematically by means of the Particle Image Velocimetry (PIV) test. Streamlines and velocity distributions of the meridian plane of the separator under different operating parameters were obtained. The velocity distribution characteristics of rotary circular tangential flow were analyzed quantitatively with the following conclusions being obtained: (1)In the non-vortex area, no matter how the operating parameters (flux, entry pressure) change, the velocity near the rotary tangential flow entrance is higher than the velocity far from the entrance at the same radial coordinates. In the vortex area, generally the flow velocity of the inner vortex is lower than that of the outer vortex. At the vortex center, the velocity is the lowest, the radial velocity being generally equal to zero. In the vortex zone, the radial velocity is less than the axial velocity. (2)Under test conditions, the radial velocity and the axial velocity of the vortexes' borders are 1,2 times the average axial velocity in the annular gap of the membrane module. The maximum radial velocity and axial velocity of Taylor vortexes are 2,5 times the average axial velocity in the annular gap of the membrane module. (3)In the vortexes that formed on the meridian plane, it was found that mass transfer occurred between the inner and outer parts of the fluid. Much fluid moved from the outer vortexes into the inner ones, which was able to prevent particles blocking the membrane tube. Copyright © 2004 Society of Chemical Industry [source] Multi-objective optimization of venturi scrubbers using a three-dimensional model for collection efficiency,JOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 2-3 2003Gopalan Ravi Abstract Multi-objective optimization of a venturi scrubber was carried out using a three-dimensional model for collection efficiency and non-dominated sorting genetic algorithm (NSGA). Two objective functions, namely (a) maximization of the overall collection efficiency, and (b) minimization of the pressure drop were used in this study. Three decision variables including two operating parameters, viz liquid,gas ratio and gas velocity in the throat, and the nozzle configuration, which takes into account the three-dimensional nature of the problem, were used in the optimization. Optimal design curves (non-dominated Pareto sets) and the values of the decision variables corresponding to optimum conditions on the Pareto set for a pilot-scale scrubber were obtained. The liquid to gas (L/G) ratio, which is a key decision variable that determines the uniformity of liquid distribution, and a staggered nozzle configuration can produce uniform liquid distribution in the scrubber. Multiple penetration using nozzles of two different sizes in a triangular staggered arrangement can reduce liquid loading by as much as 50%, consequently reducing the pressure drop in the scrubber. © 2003 Society of Chemical Industry [source] Concentration and separation of glycyrrhizic acid by foam separationJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 6 2002Jun-Gang Ma Abstract By the aid of the surface activities of glycyrrhizic acid, foam separation can be used to extract and concentrate it. The effects of operating parameters such as flow rate of air, initial feed concentration, pH and ionic strength on the enrichment ratio and recovery yield of glycyrrhizic acid are investigated in detail. In addition, the influences of other surface-active substances in solution, such as proteins, on the separation of glycyrrhizic acid are also discussed. The experimental results show that foam separation is a simple and effective method to separate and concentrate glycyrrhizic acid. © 2002 Society of Chemical Industry [source] Sensitivity analysis in oxidation ditch modelling: the effect of variations in stoichiometric, kinetic and operating parameters on the performance indicesJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 4 2001A Abusam Abstract This paper demonstrates the application of the factorial sensitivity analysis methodology in studying the influence of variations in stoichiometric, kinetic and operating parameters on the performance indices of an oxidation ditch simulation model (benchmark). Factorial sensitivity analysis investigates the sensitivities in a region rather than in a point. Hence, it has the advantage of giving more information about parameter interactions (non-linearity). Short-term results obtained have shown the following. The index AE is not significantly affected by variations in the value of parameters of the activated sludge model (ASM) No 1. The index TSP is greatly influence by heterotrophic yield (YH), heterotrophic decay (bH) and specific hydrolysis (kh) and the index EQ is dominated by YH, Monod coefficient (KS), bH, kh, anoxic condition correction factors (,g, ,h), hydrolysis half-saturation coefficient (KX), autotrophs maximum specific growth rate (µA) and ammonia half-saturation coefficient (KNH). Furthermore, the index EQ has been shown to be very sensitive to parameter interactions, at certain regions. © 2001 Society of Chemical Industry [source] | |||||||||||||||||||||||||||||||