Oxygen Loss (oxygen + loss)

Distribution by Scientific Domains


Selected Abstracts


Is succession in wet calcareous dune slacks affected by free sulfide?

JOURNAL OF VEGETATION SCIENCE, Issue 2 2003
Erwin B. Adema
van der Meijden (1996) for phanerogams; Schaminée et al. (1995) for syntaxa Abstract. Consequences of sulfide toxicity on succession in wet calcareous dune slacks were investigated. Sulfide may exert an inhibitory effect on dune slack plants, but several pioneer species exhibit ROL (Radial Oxygen Loss) and thereby protect themselves against free sulfide. Under oxic conditions free sulfide will be oxiginated to harmless sulfate. However, successive species when not capable of ROL may be sensitive to free sulfide and cannot invade the area. Therefore, the occurrence of free sulfide may have a stabilizing effect on the pioneer vegetation. Data on the vertical distribution of oxygen, redox and sulfide were collected in mesocosms with Littorella uniflora or Carex nigra, with and without microbial mats and compared to control mesocosms. Also, in situ data were collected in a dune slack on the Frisian Island of Texel. In the mesocosms, free sulfide was detected only at nighttime in C. nigra populated mesocosms and in unvegetated units, but not in L. uniflora vegetated mesocosms. In the field, sulfide and redox profiles showed distinct differences between the groundwater exfiltration and infiltration site of the dune slack. At the exfiltration site, sulfide was only occasionally found; in contrast, measurable amounts of free sulfide were regularly found at the infiltration site of the slack. Since Phragmites australis dominates in the infiltration site of the slack, the results suggest that free sulfide accelerate the succession, rather than slowing it down by the exclusion of some plant species. [source]


Floating zone growth of CuO under elevated oxygen pressure and its relevance for the crystal growth of cuprates

CRYSTAL RESEARCH AND TECHNOLOGY, Issue 1-2 2005
G. Behr
Abstract CuO single crystals have been grown from the melt by a floating zone method with optical heating at elevated oxygen pressures 3.5 to 5.5 MPa and growth rates as high as 10 mm/h. Melting experiments and recalculated Cu-O phase diagram data show that CuO melts incongruently. The melting temperature increases and the concentration difference between the melt and the CuO phase decreases for rising oxygen partial pressure. Accordingly, increasing the oxygen partial pressure improves the growth process by reducing both the significant oxygen loss during melting as well as the composition difference at the growth interface. The results on CuO provide important information for the crystal growth of more complex cuprates. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


Different bacterial communities associated with the roots and bulk sediment of the seagrass Zostera marina

FEMS MICROBIOLOGY ECOLOGY, Issue 1 2007
Sheila Ingemann Jensen
Abstract The bacterial community of Zostera marina -inhabited bulk sediment vs. root-associated bacteria was investigated by terminal restriction fragment length polymorphism and sequencing, and the spatial extension of the oxygen loss from roots was determined by oxygen microsensors. Extensive oxygen loss was found in the tip region of the youngest roots, and most of the rhizoplane of Z. marina roots was thus anoxic. A significant difference between the bacterial communities associated with the roots and bulk sediment was found. No significant differences were found between differently aged root-bundles. Terminal restriction fragments (TRFs) assigned to sulfate-reducing Deltaproteobacteria showed a relative mean distribution of 12% and 23% of the PCR-amplified bacterial community in the bulk-sediment at the two sites, but only contributed <2% to the root-associated communities. TRFs assigned to Epsilonproteobacteria showed a relative mean distribution of between 5% and 11% in the root-associated communities of the youngest root bundle, in contrast to the bulk-sediment where this TRF only contributed <1.3%. TRFs assigned to Actinobacteria and Gammaproteobacteria also seemed important first root-colonizers, whereas TRFs assigned to Deltaproteobacteria became increasingly important in the root-associated community of the older root bundles. The presence of the roots thus apparently selects for a distinct bacterial community, stimulating the growth of potential symbiotic Epsilon - and Gammaproteobacteria and/or inhibiting the growth of sulfate-reducing Deltaproteobacteria. [source]


Preparation and conversion electron Mössbauer study of Fe3O4/,-Fe2O3 composite films

PHYSICA STATUS SOLIDI (A) APPLICATIONS AND MATERIALS SCIENCE, Issue 15 2006
Z. P. Niu
Abstract Fe3O4 and Fe3O4/,-Fe2O3 composite films have been prepared from a sintered Fe2O3 target, using an rf magnetron sputtering apparatus with various argon pressures. The phase and magnetic properties of the samples have been characterized by X-ray-diffraction (XRD) measurements, conversion electron Mössbauer spectroscopy (CEMS), and a vibrating sample magnetometer (VSM). With the increasing argon pressure during sputtering, the increase of the average center shift of Mössbauer lines indicates the decreasing valency state of Fe ions induced by the enhancement of presumed oxygen loss. An enhanced magnetoresistance (MR) has been found in the Fe3O4/,-Fe2O3 composite film that was prepared under an Ar pressure of 1.0 Pa. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


Long-distance transport of gases in plants: a perspective on internal aeration and radial oxygen loss from roots

PLANT CELL & ENVIRONMENT, Issue 1 2003
T. D. COLMER
ABSTRACT Internal transport of gases is crucial for vascular plants inhabiting aquatic, wetland or flood-prone environments. Diffusivity of gases in water is approximately 10 000 times slower than in air; thus direct exchange of gases between submerged tissues and the environment is strongly impeded. Aerenchyma provides a low-resistance internal pathway for gas transport between shoot and root extremities. By this pathway, O2 is supplied to the roots and rhizosphere, while CO2, ethylene, and methane move from the soil to the shoots and atmosphere. Diffusion is the mechanism by which gases move within roots of all plant species, but significant pressurized through-flow occurs in stems and rhizomes of several emergent and floating-leaved wetland plants. Through-flows can raise O2 concentrations in the rhizomes close to ambient levels. In general, rates of flow are determined by plant characteristics such as capacity to generate positive pressures in shoot tissues, and resistance to flow in the aerenchyma, as well as environmental conditions affecting leaf-to-air gradients in humidity and temperature. O2 diffusion in roots is influenced by anatomical, morphological and physiological characteristics, and environmental conditions. Roots of many (but not all) wetland species contain large volumes of aerenchyma (e.g. root porosity can reach 55%), while a barrier impermeable to radial O2 loss (ROL) often occurs in basal zones. These traits act synergistically to enhance the amount of O2 diffusing to the root apex and enable the development of an aerobic rhizosphere around the root tip, which enhances root penetration into anaerobic substrates. The barrier to ROL in roots of some species is induced by growth in stagnant conditions, whereas it is constitutive in others. An inducible change in the resistance to O2 across the hypodermis/exodermis is hypothesized to be of adaptive significance to plants inhabiting transiently waterlogged soils. Knowledge on the anatomical basis of the barrier to ROL in various species is scant. Nevertheless, it has been suggested that the barrier may also impede influx of: (i) soil-derived gases, such as CO2, methane, and ethylene; (ii) potentially toxic substances (e.g. reduced metal ions) often present in waterlogged soils; and (iii) nutrients and water. Lateral roots, that remain permeable to O2, may be the main surface for exchange of substances between the roots and rhizosphere in wetland species. Further work is required to determine whether diversity in structure and function in roots of wetland species can be related to various niche habitats. [source]


Waterlogging tolerance in the tribe Triticeae: the adventitious roots of Critesion marinum have a relatively high porosity and a barrier to radial oxygen loss

PLANT CELL & ENVIRONMENT, Issue 6 2001
M. P. Mcdonald
Abstract Nine species from the tribe Triticeae , three crop, three pasture and three ,wild' wetland species , were evaluated for tolerance to growth in stagnant deoxygenated nutrient solution and also for traits that enhance longitudinal O2 movement within the roots. Critesion marinum (syn. Hordeum marinum) was the only species evaluated that had a strong barrier to radial O2 loss (ROL) in the basal regions of its adventitious roots. Barriers to ROL have previously been documented in roots of several wetland species, although not in any close relatives of dryland crop species. Moreover, the porosity in adventitious roots of C. marinum was relatively high: 14% and 25% in plants grown in aerated and stagnant solutions, respectively. The porosity of C. marinum roots in the aerated solution was 1·8,5·4-fold greater, and in the stagnant solution 1·2,2·8-fold greater, than in the eight other species when grown under the same conditions. These traits presumably contributed to C. marinum having a 1·4,3 times greater adventitious root length than the other species when grown in deoxygenated stagnant nutrient solution or in waterlogged soil. The length of the adventitious roots and ROL profiles of C. marinum grown in waterlogged soil were comparable to those of the extremely waterlogging-tolerant species Echinochloa crus-galli L. (P. Beauv.). The superior tolerance of C. marinum, as compared to Hordeum vulgare (the closest cultivated relative), was confirmed in pots of soil waterlogged for 21 d; H. vulgare suffered severe reductions in shoot and adventitious root dry mass (81% and 67%, respectively), whereas C. marinum shoot mass was only reduced by 38% and adventitious root mass was not affected. [source]


Fabrication of multilayer ceramic membranes

ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, Issue 3 2009
V.V. Zyryanov
Abstract The development of multilayer mixed conducting oxide membranes on macroporous dead-end tubular composite glass/ceramic substrates is presented. Sol modification of glass/ceramic substrate enhances the performance of catalytic membrane reactor (CMR) with reduced thickness of ceramic layers. The shrinkage misfit between support and ceramic layers can be regulated by different processing steps including sol modification of substrate and preliminary annealing of ceramic powders. Nanopowders of compatible complex perovskites as membrane materials were obtained by mechanochemical synthesis. Porous and dense ceramic layers were supported onto the internal wall of substrate by slip casting of slurries comprised of the narrow fractions of agglomerated powders dispersed in organic media with addition of surfactants. For SrFeO3 -based dense perovskite ceramics, both dynamics of oxygen loss at high temperatures and mechanical properties were found to be affected by the presence of SrSO4 surface inclusions formed due to sulfur admixture in starting reactants. Copyright © 2009 Curtin University of Technology and John Wiley & Sons, Ltd. [source]


Photostimulated Reduction Processes in a Titania Hybrid Metal,Organic Framework

CHEMPHYSCHEM, Issue 11 2010
Aron Walsh Dr.
Lights, camera, action! A hybrid material derived from TiO2 is found to have remarkable defect chemistry: optical excitations larger than the band gap have sufficient energy to reduce titanium, accompanied by oxygen loss (see figure). New states introduced in the electronic gap are responsible for the material,s photochromicity. The future looks bright for photoactive metal,organic frameworks. [source]