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Oxide Nanorods (oxide + nanorod)

Distribution by Scientific Domains
Chemistry75%

Selected Abstracts

Crystalline bismuth oxide nanorods fabricated on Pt-coated substrates using a trimethylbismuth and oxygen mixture

CRYSTAL RESEARCH AND TECHNOLOGY, Issue 7 2008
Hyoun Woo Kim
Abstract The current work reports the fabrication of crystalline Bi2O3 nanorods on Pt-coated Si substrates using trimethylbismuth and O2 as the bismuth and the oxygen sources, respectively, in the metalorganic chemical vapor deposition process. Their microstructures were characterized by scanning electron microscopy, X-ray diffraction, and transmission electron microscopy. The obtained nanorods were crystalline, with their diameters in the range of 20,200 nm. The absence of tip-nanoparticle and the presence of predeposited Bi2O3 layer indicated that the growth was dominated by a vapor-solid process. The photoluminescence measurements of the Bi2O3 nanorods at room temperature exhibited an emission band peaked at around 422 nm. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]

General Strategy for a Large-Scale Fabric with Branched Nanofiber,Nanorod Hierarchical Heterostructure: Controllable Synthesis and Applications

CHEMISTRY - A EUROPEAN JOURNAL, Issue 37 2010
Meng Shang
Abstract The preparation and characterization of a branched nanofiber,nanorod hierarchical heterostructure fabric (TiO2/NiO, TiO2/ZnO, and TiO2/SnO2) are described. The nanomaterial was synthesized on a large scale by an inexpensive, generalizable, facile, and controllable approach by combining the electrospinning technique with a hydrothermal method. The controllable formation process and factors (assistance by hexamethylenetetramine and metal oxide nuclei) influencing the morphology of the branched hierarchical heterostructure are discussed. In addition, photocurrent and photocatalytic studies suggest that the branched hierarchical heterostructure fabric shows higher mobility of charge carriers and enhanced photocatalytic activity relative to a bare TiO2 nanofibrous mat and other heterostructures under irradiation by light. This work demonstrates the possibility of growing branched heterostructure fabrics of various uniform, one-dimensional, functional metal oxide nanorods on a TiO2 nanofibrous mat, which has a tunable morphology by changing the precursor. The study may open a new channel for building hierarchical heterostructure device fabrics with optical and catalytic properties, and allow the realization of a new class of nano-heterostructure devices. [source]

Rapid synthesis of lead oxide nanorods by one-step solid-state chemical reaction at room temperature

CHINESE JOURNAL OF CHEMISTRY, Issue 11 2004
Ya-Li Cao
Abstract A simple and facile method was reported to synthesize lead oxide nanorods. Nanorods of lead oxide were obtained directly from grinding solid metal salt and sodium hydroxide in agate mortar with the assistance of a suitable nonionic surfactant in only one step, which is different from the result of hydroxide in solution. The product has been characterized by XRD, TEM and SEM. The formation mechanism of rod-like morphology is discussed and the surfactant plays an important soft-template role in modifying the interface of solid-state reaction and according process of rod-formation. [source]