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Natural Materials (natural + material)
Selected AbstractsDip-coating of Fibrous Natural Materials for Alumina Tube Manufacturing,ADVANCED ENGINEERING MATERIALS, Issue 3 2008S. Gaydardzhiev Hollow ceramic microtubes have been prepared by dip-coating of fibrous plants with water based alumina gel-casting slurries using hemp and coconut fibres as templates. Good correlation between the diameters of the template fibres and the resulting channels have been found. Hemp fibres used as bundles have lead to the formation of multi channel patterns (see figure) and the coconut fibres-templated process resulted in uniform monochannel materials. The micro tubes show good mechanical handling. [source] The Use of Natural Materials in Nanocarbon SynthesisCHEMSUSCHEM CHEMISTRY AND SUSTAINABILITY, ENERGY & MATERIALS, Issue 11 2009Dang Sheng Su Dr. Abstract Nanomaterials are shifting from laboratory-scale preparation to industrial production. The energy costs and starting materials (feedstock, catalyst, and support) consumed or used in the mass production of nanomaterials are issues that limit their broad application. Natural materials, such as sand, rock, and lava, contain small or trace amounts of metals or metal oxides of nanometer-scale sizes and have been recently used as catalysts for the production of carbon nanotubes (CNTs), providing an interesting way to lower the production cost of CNTs. However, the sustainability of the whole production process still needs to be explored. Layered minerals (e.g., clays) are used to produce CNT,clay hybrids, which can be further used to synthesize polymer,CNT,clay nanocomposites. Natural materials and some byproducts of industrial production processes have been explored as carbon sources for nanocarbon synthesis. This Minireview highlights some recent promising work and prospects for the use of natural materials in the synthesis of CNTs, carbon nanofibers (CNFs), and nanocomposites, and their applications in catalysis and in materials science. [source] Revealing the Design Principles of High-Performance Biological Composites Using Ab initio and Multiscale Simulations: The Example of Lobster CuticleADVANCED MATERIALS, Issue 4 2010Svetoslav Nikolov Natural materials are hierarchically structured nanocomposites. A bottom-up multiscale approach to model the mechanical response of the chitin-based mineralized cuticle material of Homarus americanus is presented, by combining quantum-mechanical ab initio calculations with hierarchical homogenization. The simulations show how the mechanical properties are transferred from the atomic scale through a sequence of specifically designed microstructures to realize optimal stiffness. [source] The Use of Natural Materials in Nanocarbon SynthesisCHEMSUSCHEM CHEMISTRY AND SUSTAINABILITY, ENERGY & MATERIALS, Issue 11 2009Dang Sheng Su Dr. Abstract Nanomaterials are shifting from laboratory-scale preparation to industrial production. The energy costs and starting materials (feedstock, catalyst, and support) consumed or used in the mass production of nanomaterials are issues that limit their broad application. Natural materials, such as sand, rock, and lava, contain small or trace amounts of metals or metal oxides of nanometer-scale sizes and have been recently used as catalysts for the production of carbon nanotubes (CNTs), providing an interesting way to lower the production cost of CNTs. However, the sustainability of the whole production process still needs to be explored. Layered minerals (e.g., clays) are used to produce CNT,clay hybrids, which can be further used to synthesize polymer,CNT,clay nanocomposites. Natural materials and some byproducts of industrial production processes have been explored as carbon sources for nanocarbon synthesis. This Minireview highlights some recent promising work and prospects for the use of natural materials in the synthesis of CNTs, carbon nanofibers (CNFs), and nanocomposites, and their applications in catalysis and in materials science. [source] Environmentally friendly mixed tannin/lignin wood resinsJOURNAL OF APPLIED POLYMER SCIENCE, Issue 1 2008Hong Lei Abstract We obtained lignin-based wood adhesives satisfying the requirements of relevant international standards for the manufacture of wood particleboard. These were based on two different low-molecular-mass lignins. These lignin-based wood adhesives did not use any formaldehyde in their formulation; formaldehyde was substituted with a nonvolatile nontoxic aldehyde, namely, glyoxal. The last formaldehyde present, contributed by a fortifying synthetic phenol,formaldehyde resin, was also eliminated by the substitution of the phenol,formaldehyde resin with a natural, vegetable polyflavonoid tannin extract to which no aldehyde was added. This substitution brought the total content of natural material up to 80 wt % of the total adhesive. The adhesives yielded good internal bond strength results of the panels, enough to pass relevant international standard specifications for interior-grade panels. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 [source] Synthesis of ZSM-5 from diatomite: a case of zeolite synthesis from a natural materialJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 7 2004Vilma Sanhueza Abstract A highly crystalline ZSM-5 product was obtained from diatomite, a natural raw material, both with and without the presence of diethanolamine. The synthesis process took 40 h, and was carried out under hydrothermal conditions, at autogenic pressure, and at a temperature of 180 °C. The resulting crystals were identified as ZSM-5 by X-ray diffraction and characterized by scanning electron microscopy, infrared spectroscopy, thermal gravimetry and differential thermal analysis. Copyright © 2004 Society of Chemical Industry [source] Synthesis of mordenite from diatomite: a case of zeolite synthesis from natural materialJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 5 2003Vilma Sanhueza Abstract A high mordenite product was obtained from a natural raw material, diatomite, either with or without the presence of diethanolamine. The synthesis process took 2 days, and was carried out under hydrothermal conditions, at autogenic pressure, and at a temperature of 180 °C. The resulting crystals were identified as mordenite by X-ray diffraction and characterized by scanning electron microscopy, and differential thermal and gravimetric analyses. Copyright © 2003 Society of Chemical Industry [source] Phytochemicals in olive-leaf extracts and their antiproliferative activity against cancer and endothelial cellsMOLECULAR NUTRITION & FOOD RESEARCH (FORMERLY NAHRUNG/FOOD), Issue 5 2009Vlassios Goulas Abstract Olive oil compounds is a dynamic research area because Mediterranean diet has been shown to protect against cardiovascular disease and cancer. Olive leaves, an easily available natural material of low cost, share possibly a similar wealth of health benefiting bioactive phytochemicals. In this work, we investigated the antioxidant potency and antiproliferative activity against cancer and endothelial cells of water and methanol olive leaves extracts and analyzed their content in phytochemicals using LC-MS and LC-UV-SPE-NMR hyphenated techniques. Olive-leaf crude extracts were found to inhibit cell proliferation of human breast adenocarcinoma (MCF-7), human urinary bladder carcinoma (T-24) and bovine brain capillary endothelial (BBCE). The dominant compound of the extracts was oleuropein; phenols and flavonoids were also identified. These phytochemicals demonstrated strong antioxidant potency and inhibited cancer and endothelial cell proliferation at low micromolar concentrations, which is significant considering their high abundance in fruits and vegetables. The antiproliferative activity of crude extracts and phytochemicals against the cell lines used in this study is demonstrated for the first time. [source] Enhanced Chondrogenic Responses of Human Articular Chondrocytes Onto Silk Fibroin/Wool Keratose Scaffolds Treated With Microwave-Induced Argon PlasmaARTIFICIAL ORGANS, Issue 5 2010Young Woo Cheon Abstract Silk fibroin (SF) is a natural, degradable, fibrous protein that is biocompatible, is easily processed, and possesses unique mechanical properties. Another natural material, wool keratose (WK), is a soluble derivative of wool keratin, containing amino acid sequences that induce cell adhesion. Here, we blended SF and WK to improve the poor electrospinability of WK and increase the adhesiveness of SF. We hypothesized that microwave-induced argon plasma treatment would improve chondrogenic cell growth and cartilage-specific extracellular matrix formation on a three-dimensional SF/WK scaffold. After argon plasma treatment, static water contact angle measurement revealed increased hydrophilicity of the SF/WK scaffold, and scanning electron microscopy showed that treated SF/WK scaffolds had deeper and more cylindrical pores than nontreated scaffolds. Attachment and proliferation of neonatal human knee articular chondrocytes on treated SF/WK scaffolds increased significantly, followed by increased glycosaminoglycan synthesis. Our results suggest that microwave-induced, plasma-treated SF/WK scaffolds have potential in cartilage tissue engineering. [source] Perfume Formulation: Words and ChatsCHEMISTRY & BIODIVERSITY, Issue 6 2008Céline Ellena Abstract What does it mean to create fragrances with materials from chemistry and/or from nature? How are they used to display their characteristic differences, their own personality? Is it easier to create with synthetic raw materials or with essential oils? This review explains why a perfume formulation corresponds in fact to a conversation, an interplay between synthetic and natural perfumery materials. A synthetic raw material carries a single information, and usually is very linear. Its smell is uniform, clear, and faithful. Natural raw materials, on the contrary, provide a strong, complex and generous image. While a synthetic material can be seen as a single word, a natural one such as rose oil could be compared to chatting: cold, warm, sticky, heavy, transparent, pepper, green, metallic, smooth, watery, fruity, full of information. Yet, if a very small amount of the natural material is used, nothing happens, the fragrance will not change. However, if a large amount is used, the rose oil will swallow up everything else. The fragrance will smell of nothing else except rose! To formulate a perfume is not to create a culinary recipe, with only dosing the ingredients in well-balanced amounts. To formulate rather means to flexibly knit materials together with a lively stitch, meeting or repelling each other, building a pleasant form, which is neither fixed, nor solid, nor rigid. A fragrance has an overall structure, which ranges from a clear sound, made up of stable, unique, and linear items, to a background chat, comfortable and reassuring. But that does, of course, not mean that there is only one way of creating a fragrance! [source] Effectiveness of very thin soil layers in chemical release from bed sedimentENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY, Issue 2 2001Bryan Talbert The chemical containment effectiveness of both the natural recovery and the "particle broadcasting" processes for remediating contaminated bed-sediments depend upon very thin soil and/or sand layers millimeters in depth. Conventional capping for in situ chemical containment of bed-sediment or dredged material typically involves thick layers of 30 to 90 centimeters in depth. Few studies have been conducted with thin layers of candidate natural materials. A steady-state benzoic acid dissolution test apparatus and procedure, devised to realistically simulate bed-sediment chemo-dynamic conditions, was used to measure chemical flux through thin layers (1 to 8 mm) of soil, sand, and ideal porous media. The thin layers were found to be very effective. Flux reductions ranged from 81 to 96%, with fine sand being slightly better than top soil. Design algorithms developed for the thick layers used in conventional capping design will under predict the flux through very thin layers. Advective flow induced by surface roughness is proposed to explain the higher average measure d-to-predicted flux ratio of 1.67. [source] PUEBLO MISSION CHURCHES AS SYMBOLS OF PERMANENCE AND IDENTITY,GEOGRAPHICAL REVIEW, Issue 3 2000KEVIN S. BLAKE ABSTRACT. The three Pueblo mission churches of San Esteban del Rey, Nuestra Señora de Guadalupe, and San José de Laguna are the most visually striking structures in the western New Mexico pueblos of Acoma, Zuni, and Laguna. Prime examples of "structures of permanence" on the landscape, the churches define local cultural identity. Church permanence and Pueblo identity are expressed in a five-part typology of visible characteristics: natural materials and hand labor, massive exterior form, adjoining cemeteries, syncretism of interior decorations, and structural decay and rebirth. Permanence must, however, be understood as an evolving condition, undergoing new representations as multicultural relationships evolve. [source] Mercury removal: a physicochemical study of metal interaction with natural materialsJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 11 2009Leticia Carro Abstract BACKGROUND: Mercury is considered one of the most harmful heavy metals to the environment and human health, so recently remediation processes have been developed to eliminate this metal from wastewaters. Metal retention by natural polymers is a good alternative technique to remove heavy metals from solution. RESULTS: A screening of 25 potential mercury sorbents was carried out at three different pH values in order to find appropriate biomass to remove this metal from polluted waters. High sorption capacities were found for many of the materials studied. Four of these materials were selected for further detailed study. Kinetic studies showed short times to reach equilibrium. For S. muticum, sorption isotherms were obtained at several temperatures and a sorption enthalpy value was obtained. Desorption experiments were performed to determine the possibility for recycling of this brown alga. CONCLUSIONS: Different materials have been found to be potentially good adsorbents of mercury. A detailed study showed that S. muticum is an excellent material with a mercury uptake about 200 mg g,1. This brown alga has a fast kinetic process (80% of metal is removed from solution in 30 min), and very high metal uptake over a wide pH range, up to 92% elimination for pH values above 3,4. Copyright © 2009 Society of Chemical Industry [source] GLYCOSIDASE INHIBITORY ACTIVITY AND ANTIOXIDANT PROPERTIES OF A POLYSACCHARIDE FROM THE MUSHROOM INONOTUS OBLIQUUSJOURNAL OF FOOD BIOCHEMISTRY, Issue 2010HAIXIA CHEN ABSTRACT A water-soluble polysaccharide from Inonotus obliquus (IOPS) was isolated from the mushroom Inonotus obliquus (Fr.) Pilat. The chemical compositions, molecular weight and inhibitory activities on glycosidase and antioxidant properties of IOPS were investigated. The results indicated that IOPS was an acid protein-bound polysaccharide, with a molecular weight of 1.7 × 104 Da and the contents of neutral sugar, protein and uronic acids being 42.5, 18.5 and 6.1%, respectively. IOPS exhibited an inhibitory activity against ,-glucosidase with the IC50 value of 93.3 µg/mL, whereas it had no effective inhibition on ,-amylase. Results of antioxidant activity assays revealed that IOPS had inhibitory activity on the concentration-dependent quenching of 1,1-Diphenyl-2-picrylhydrazyl and hydroxyl radicals. Furthermore, IOPS inhibited the formation of thiobarbituric acid-reactive substances in Fe2+/ascorbate-induced lipid peroxidation in rat liver tissue. These results clearly demonstrated that IOPS was one of the main bioactive components of I. obliquus that contributed to hypoglycemic activity and antioxidant activity. PRACTICAL APPLICATIONS Diabetes mellitus is one of the primary threats to human health because of its increasing prevalence, chronic course and disabling complications. Postprandial hyperglycemia plays an important role in the development of type 2 diabetes mellitus and complications associated with the disease. One therapeutic approach to decrease postprandial hyperglycemia is to retard the absorption of glucose through inhibition of carbohydrate-hydrolyzing enzymes in the digestive organs. In this study, a polysaccharide isolated from the mushroom Inonotus obliquus (IOPS) was shown to have notable glycosidase inhibitory effects and antioxidant activities. This research will benefit for the investigation of effective and safe ,-glucosidase inhibitors from natural materials. IOPS could be a good candidate for application in food and medicinal fields. It might be developed for functional food or lead compounds for use in antidiabetes. [source] Calcite,graphite isotope thermometry in amphibolite facies marble, Bancroft, OntarioJOURNAL OF METAMORPHIC GEOLOGY, Issue 9 2005S. R. DUNN Abstract This study presents calcite,graphite carbon isotope fractionations for 32 samples from marble in the northern Elzevir terrane of the Central Metasedimentary Belt, Grenville Province, southern Ontario, Canada. These results are compared with temperatures calculated by calcite,dolomite thermometry (15 samples), garnet,biotite thermometry (four samples) and garnet,hornblende thermometry (three samples). ,cal-gr values vary regularly across the area from >6.5, in the south to 4.0, in the north, which corresponds to temperatures of 525 °C in the south to 650 °C in the north. Previous empirical calibration of the calcite,graphite thermometer agrees very well with calcite,dolomite, garnet,biotite and garnet,hornblende thermometry, whereas, theoretical calibrations compare less well with the independent thermometry. Isograds in marble based on the reactions rutile + calcite + quartz =titanite and tremolite + calcite + quartz = diopside, span temperatures of 525,600 °C and are consistent with calculated temperature,X(CO2) relations. Results of this study compare favourably with large-scale regional isotherms, however, local variation is greater than that revealed by large-scale sampling strategies. It remains unclear whether the temperature,,cal-gr relationship observed in natural materials below 650 °C represents equilibrium fractionations or not, but the regularity and consistency apparent in this study demonstrate its utility for thermometry in amphibolite facies marble. [source] Characterisation of proteinaceous binders in artistic paintings by chromatographic techniquesJOURNAL OF SEPARATION SCIENCE, JSS, Issue 3 2004Maria Perla Colombini Abstract This review discusses the application of chromatographic techniques (GC, HPLC and Py-GC) for the characterisation of proteinaceous materials in artistic paintings. The focus is on the various analytical steps that are needed to determine these natural materials in paint samples, from sampling and sample pre-treatment, including various methods of hydrolysis and derivatisation for GC and HPLC, to approaches for data evaluation. [source] Development of Low-Firing B-Fluxed Stoneware TilesJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 11 2009Alessandro F. Gualtieri In a global period of economic recession, innovation is a key requisite to get over this critical phase and prompt an upturn in the economy. Even the market of traditional ceramics is in a stalemate and producers desperately seek for new ideas which may supersede the long-used stoneware tiles. This paper presents the full characterization of a new potential class of ceramics named low-temperature stoneware tiles, highlighting their advantages and disadvantages. The body formulation and the firing process are both covered by an Italian Patent. This innovative product exhibits technological and esthetical features analogous to those of the traditional stoneware tile bodies but is fired at a maximum temperature of 950°C, about 250°C lower than the firing temperature of stoneware tiles. This is possible thanks to the addition of a B-rich frit to the mixture composed of quartz, feldspars, and clays. The frit acts as a low-temperature flux and promotes the melting of the feldspars. Within the fired body, the residual phases are quartz and feldspars. The newly formed phases can be ,-spodumene if Li is present in the frit or spinel if Mg is present in the natural materials. The best body formulations have been characterized with mineralogical, microscopic, and technological methods. The major weakness of these ceramic bodies is their unresistance to acids. The chemical nature of the sintered matrix, with a high content of alkalies and B, triggers off the tendency of the ceramic body to react in contact with acidic solutions. Another penalty factor is the cost of the B-rich frit used in the formulation of the ceramic mixture which increases the overall cost of the ceramic body. [source] Places Of Transformation: Building Monuments From Water And Stone In The Neolithic Of The Irish SeaTHE JOURNAL OF THE ROYAL ANTHROPOLOGICAL INSTITUTE, Issue 1 2003CHRIS FOWLER Using the Irish Sea area as a case-study, we argue that both sites and landscapes can be understood as containing a series of components procured from the landscape and from human, animal, and object bodies. These components were organized in a way that commented on and related to specific cultural relationships between these different locations and through the substances found within them. This idea is explored by examining Neolithic monuments, material culture, and natural materials in southwest Wales, northwest Wales, the Isle of Man, and southwest Scotland. We trace some metaphorical schemes which were integral to Neolithic activity in this part of the Irish Sea. In particular, we highlight the metaphorical connections between water and stone in places associated with transformation, particularly the repeated transformation of human bodies. We suggest that the series of associations present in the Neolithic were not invested with a uniform meaning but, instead, were polyvalent, subject to conflicting interpretations, contextually specific and variable through both space and time. The relationship between these elements was therefore dependent on the contexts of their association. Nevertheless, the association of water and stone can be found repeatedly throughout the Neolithic world and may have been the medium of a powerful trope within broader conceptions of the world. This article is intended as a preliminary consideration of these issues (particularly the links between stone, mountains, water, quartz, shell, and human remains) and is offered as a thinking-point for ongoing research in this area. [source] The Use of Natural Materials in Nanocarbon SynthesisCHEMSUSCHEM CHEMISTRY AND SUSTAINABILITY, ENERGY & MATERIALS, Issue 11 2009Dang Sheng Su Dr. Abstract Nanomaterials are shifting from laboratory-scale preparation to industrial production. The energy costs and starting materials (feedstock, catalyst, and support) consumed or used in the mass production of nanomaterials are issues that limit their broad application. Natural materials, such as sand, rock, and lava, contain small or trace amounts of metals or metal oxides of nanometer-scale sizes and have been recently used as catalysts for the production of carbon nanotubes (CNTs), providing an interesting way to lower the production cost of CNTs. However, the sustainability of the whole production process still needs to be explored. Layered minerals (e.g., clays) are used to produce CNT,clay hybrids, which can be further used to synthesize polymer,CNT,clay nanocomposites. Natural materials and some byproducts of industrial production processes have been explored as carbon sources for nanocarbon synthesis. This Minireview highlights some recent promising work and prospects for the use of natural materials in the synthesis of CNTs, carbon nanofibers (CNFs), and nanocomposites, and their applications in catalysis and in materials science. [source] | |||||||||||||||||||