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Natural Clay (natural + clay)

Distribution by Scientific Domains

Engineering	41%
Chemistry	25%
Polymers and Materials Science	16%

Selected Abstracts

Electrogenerated Chemiluminescence Sensor Based on Tris(2,2,-bipyridine)ruthenium(II)-Immobilized Natural Clay and Ionic Liquid

ELECTROANALYSIS, Issue 2 2010
Ping Jiang
Abstract A novel electrogenerated chemiluminescence (ECL) sensor based on natural clay and ionic liquid was fabricated. Tris(2,2,-bipyridine)ruthenium(II) (Ru(bpy)32+) was immobilized on natural clay surface through simple adsorption. An ECL sensor was prepared by mixing Ru(bpy)32+ -incorporated clay, graphite powder and an ionic liquid (1-butyl-3-methylimidazolium hexafluorophosphate) as the binder. The electrochemical behavior and ECL of the immobilized Ru(bpy)32+ was investigated. It was observed that the ECL of immobilized Ru(bpy)32+ was activated by the ionic liquid. The proposed ECL sensor showed high sensitivity to tri- n -propylamine (TPrA) and the detection limit was found to be 20,pM. In addition, the ECL sensor displayed good stability for TPrA detection and long-term storage stability. [source]

Thermal stability and ablation properties of silicone rubber composites

JOURNAL OF APPLIED POLYMER SCIENCE, Issue 2 2008
Eung Soo Kim
Abstract Effects of incorporation of clay and carbon fiber (CF) into a high temperature vulcanized (HTV) silicone rubber, i.e., poly(dimethylsiloxane) (PDMS) containing vinyl groups, on its thermal stability and ablation properties were explored through thermogravimetric analyses (TGA) and oxy-acetylene torch tests. Natural clay, sodium montmorillonite (MMT), was modified with a silane compound bearing tetra sulfide (TS) groups to prepare MMTS4: the TS groups may react with the vinyl groups of HTV and enhance the interfacial interaction between the clay and HTV. MMTS4 layers were better dispersed than MMT layers in the respective composites with exfoliated/intercalated coexisting morphology. According to TGA results and to the insulation index, the HTV/MMTS4 composite was more thermally stable than HTV/MMT. However, addition of CF to the composites lowered their thermal stability, because of the high thermal conductivity of CF. The time elapsed for the composite specimen, loaded with a constant weight, to break off after the oxy-acetylene flame bursts onto the surface of the specimen was employed as an index for an integrated assessment of the ablation properties, simultaneously taking into consideration the mechanical strength of the char and the rate of decomposition. The elapsed time increased in the order of: HTV < HTV/CF , HTV/MMTS4 < HTV/CF/MMTS4 , HTV/MMT < HTV/CF/MMT. This order was different from the increasing order of the thermal stability determined by TGA results and the insulation index. The decreased degree of crosslinking of the composites with MMTS4 compared with that of the composite with MMT may be unfavorable for the formation of a mechanically strong char and could lead to early rupture of the HTV/MMTS4 specimen. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 [source]

Electrogenerated Chemiluminescence Sensor Based on Tris(2,2,-bipyridine)ruthenium(II)-Immobilized Natural Clay and Ionic Liquid

The effects of continuous and pulsed exposures of suspended clay on the survival, growth, and reproduction of Daphnia magna

ENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 1 2010
Sarah E. Robinson
Abstract Suspended sediments are a natural component of aquatic ecosystems, but anthropogenic activity such as land development can result in significant increases, especially after rain events. Continuous exposures of suspended clay and silt have been shown to affect growth and reproduction of Cladocera, leading to a decrease in population growth rate. The mechanism of clay toxicity in these filter-feeding organisms is clogging of the gut tract, resulting in decreased food uptake and assimilation. When placed in clean water, daphnids can purge clay from their gut and recover. In many surface waters, aquatic organisms experience episodic exposures of high concentrations of suspended solids driven by rain events. However, little is known about the consequences of pulsed exposures on individuals and populations. The objective of the present study was to characterize the effects of continuous and pulsed exposures of natural and defined clays on survival, growth, and reproduction of Daphnia magna. Two defined clays, montmorillonite and kaolinite, as well as clay isolated from the Piedmont region of South Carolina, USA, were used. Continuous exposures of clays elicited a dose dependent decrease in survival. Toxicity varied depending on clay source with montmorillonite,>,natural clay,>,kaolinite. Pulsed exposures caused a decrease in survival in a 24 h exposure of 734 mg/L kaolinite. Exposure to 73.9 mg/L also caused an increase in the time to gravidity, although there was not a corresponding decrease in neonate production over 21 d. No significant effects resulted from 12 h exposures even at 730 mg/L, almost 10 times the 24-h reproductive effects concentration. This suggests that exposure duration impacted toxicity more than exposure concentration in these pulsed exposures. Environ. Toxicol. Chem. 2010;29:168,175. © 2009 SETAC [source]

A flammability performance comparison between synthetic and natural clays in polystyrene nanocomposites

FIRE AND MATERIALS, Issue 4 2005
Alexander B. Morgan
Abstract Polymer-clay nanocomposites are a newer class of flame retardant materials of interest due to their balance of mechanical, thermal and flammability properties. Much more work has been done with natural clays than with synthetic clays for nanocomposite flammability applications. There are advantages and disadvantages to both natural and synthetic clay use in a nanocomposite, and some of these, both fundamental and practical, will be discussed in this paper. To compare natural and synthetic clays in regards to polymer flammability, two clays were used. The natural clay was a US mined and refined montmorillonite, while the synthetic clay was a fluorinated synthetic mica. These two clays were used as inorganic clays for control experiments in polystyrene, and then converted into an organoclay by ion exchange with an alkyl ammonium salt. The organoclays were used to synthesize polystyrene nanocomposites by melt compounding. Each of the formulations was analysed by X-ray diffraction (XRD), thermogravimetric analysis (TGA) and transmission electron microscopy (TEM). Flammability performance was measured by cone calorimeter. The data from the experiments show that the synthetic clay does slightly better at reducing the heat release rate (HRR) than the natural clay. However, all the samples, including the inorganic clay polystyrene microcomposites, showed a decreased time to ignition, with the actual nanocomposites showing the most marked decrease. The reason for this is postulated to be related to the thermal instability of the organoclay (via the quaternary alkyl ammonium). An additional experiment using a more thermally stable organoclay showed a time to ignition identical to that of the base polymer. Finally, it was shown that while polymer-clay nanocomposites (either synthetic or natural clay based) greatly reduce the HRR of a material, making it more fire safe, they do not provide ignition resistance by themselves, at least, at practical loadings. Specifically, the cone calorimeter HRR curve data appear to support that these nanocomposites continue to burn once ignited, rather than self-extinguish. Copyright © 2004 John Wiley & Sons, Ltd. [source]

Use of a new natural clay to produce poly(methyl methacrylate)-based nanocomposites

POLYMER INTERNATIONAL, Issue 1 2010
Djahida Lerari
Abstract Nanocomposites of poly(methyl methacrylate) (PMMA) filled with 3 wt% of modified natural Algerian clay (AC; montmorillonite type) were prepared by either in situ polymerization of methyl methacrylate initiated by 2,2,-azobisisobutyronitrile or a melt-mixing process with preformed PMMA via twin-screw extrusion. The organo-modification of the AC montmorillonite was achieved by ion exchange of Na+ with octadecyldimethylhydroxyethylammonium bromide. Up to now, this AC montmorillonite has found applications only in the petroleum industry as a rheological additive for drilling muds and in water purification processes; its use as reinforcement in polymer matrices has not been reported yet. The modified clay was characterized using X-ray diffraction (XRD), which showed an important shift of the interlayer spacing after organo-modification. The degree of dispersion of the clay in the polymer matrix and the resulting morphology of nanocomposites were evaluated using XRD and transmission electron microscopy. The resulting intercalated PMMA nanocomposites were analysed using thermogravimetric analysis and differential scanning calorimetry. The glass transition temperature of the nanocomposites was not significantly influenced by the presence of the modified clay while the thermal stability was considerably improved compared to unfilled PMMA. This Algerian natural montmorillonite can serve as reinforcing nanofiller for polymer matrices and is of real interest for the fabrication of nanocomposite materials with improved properties. Copyright © 2009 Society of Chemical Industry [source]

Effect of nanoclay on the microcellular structure and morphology of high internal phase emulsion (HIPE) foams

ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, Issue 2 2009
M. Serry Ahmed
Abstract High internal phase emulsion (HIPE) polymerization foaming process is controlled for the production of novel foams with various microcellular structures and morphologies. In this study, two types of organoclay and one type of natural clay, sodium montmorillonite (NaMMT) were introduced at different concentrations to control the microcellular morphologies, cell sizes and open cell contents. A scanning electron microscopy was used to observe the microcellular morphologies and open cell contents; volume expansion ratio (VER) and cell sizes were evaluated. It was believed that the open cell contents increased as organoclay content increased, due to the lowering of the viscosity ratio of dispersed to continuous phases, as a result of adding nanoclay into the oil phase of emulsion. A correlation between the open cell content and VER that depended on clay content was attempted and the result was quite satisfactory. Copyright © 2008 Curtin University of Technology and John Wiley & Sons, Ltd. [source]

A flammability performance comparison between synthetic and natural clays in polystyrene nanocomposites

A destructuration theory and its application to SANICLAY model

INTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS, Issue 10 2010
Mahdi Taiebat
Abstract Many natural clays have an undisturbed shear strength in excess of the remoulded strength. Destructuration modeling provides a means to account for such sensitivity in a constitutive model. This paper extends the SANICLAY model to include destructuration. Two distinct types of destructuration are considered: isotropic and frictional. The former is a concept already presented in relation to other models and in essence constitutes a mechanism of isotropic softening of the yield surface with destructuration. The latter refers to the reduction of the critical stress ratio reflecting the effect of destructuration on the friction angle, and is believed to be a novel proposition. Both the types depend on a measure of destructuration rate expressed in terms of combined plastic volumetric and deviatoric strain rates. The SANICLAY model itself is generalized from its previous form by additional dependence of the yield surface on the third isotropic stress invariant. Such a generalization allows to obtain as particular cases simplified model versions of lower complexity including one with a single surface and associative flow rule, by simply setting accordingly parameters of the generalized version. A detailed calibration procedure of the relatively few model constants is presented, and the performance of three versions of the model, in descending order of complexity, is validated by comparison of simulations to various data for oedometric consolidation followed by triaxial undrained compression and extension tests on two structured clays. Copyright © 2009 John Wiley & Sons, Ltd. [source]

Implicit integration of a mixed isotropic,kinematic hardening plasticity model for structured clays

INTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS, Issue 10 2008
Angelo Amorosi
Abstract In recent years, a number of constitutive models have been proposed to describe mathematically the mechanical response of natural clays. Some of these models are characterized by complex formulations, often leading to non-trivial problems in their numerical integration in finite elements codes. The paper describes a fully implicit stress-point algorithm for the numerical integration of a single-surface mixed isotropic,kinematic hardening plasticity model for structured clays. The formulation of the model stems from a compromise between its capability of reproducing the larger number of features characterizing the behaviour of structured clays and the possibility of developing a robust integration algorithm for its implementation in a finite elements code. The model is characterized by an ellipsoid-shaped yield function, inside which a stress-dependent reversible stiffness is accounted for by a non-linear hyperelastic formulation. The isotropic part of the hardening law extends the standard Cam-Clay one to include plastic strain-driven softening due to bond degradation, while the kinematic hardening part controls the evolution of the position of the yield surface in the stress space. The proposed algorithm allows the consistent linearization of the constitutive equations guaranteeing the quadratic rate of asymptotic convergence in the global-level Newton,Raphson iterative procedure. The accuracy and the convergence properties of the proposed algorithm are evaluated with reference to the numerical simulations of single element tests and the analysis of a typical geotechnical boundary value problem. Copyright © 2007 John Wiley & Sons, Ltd. [source]

Chemical characterization of ancient pottery from sudan by x-ray fluorescence spectrometry (xrf), electron microprobe analyses (empa) and inductively coupled plasma mass spectrometry (ICP,MS),

ARCHAEOMETRY, Issue 3 2004
M. Klein
Sixty-four sherds and seven natural clays from prehistoric sites in northwestern Sudan have been submitted to petrological and chemical analysis using XRF spectrometry, EMPA and ICP,MS. According to their texture, the sherds form five different groups. The high contents of P2O5 (more than 0.5 wt%) discerned in 19 samples and the variation of the P2O5 content in two samples of the same vessel can be explained by post-depositional processes or by the ancient organic contents (e.g., milk) of the vessel. Chemical classification of the pottery bulk suggests that vessels were made locally, as only sherds from the same area show homogeneity of data. [source]