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Morphology Evolution (morphology + evolution)
Selected AbstractsTime-Dependent Morphology Evolution by Annealing Processes on Polymer:Fullerene Blend Solar CellsADVANCED FUNCTIONAL MATERIALS, Issue 6 2009Jang Jo Abstract Changes in the nanoscale morphologies of the blend films of poly (3-hexylthiophene) (P3HT) and [6,6]-phenyl-C61 -butyric acid methyl ester (PCBM), for high-performance bulk-heterojunction (BHJ) solar cells, are compared and investigated for two annealing treatments with different morphology evolution time scales, having special consideration for the diffusion and aggregation of PCBM molecules. An annealing condition with relatively fast diffusion and aggregation of the PCBM molecules during P3HT crystallization results in poor BHJ morphology because of prevention of the formation of the more elongated P3HT crystals. However, an annealing condition, accelerating PCBM diffusion after the formation of a well-ordered morphology, results in a relatively stable morphology with less destruction of crystalline P3HT. Based on these results, an effective strategy for determining an optimized annealing treatment is suggested that considers the effect of relative kinetics on the crystallization of the components for a blend film with a new BHJ materials pair, upon which BHJ solar cells are based. [source] Predicting the Energetics, Phase Stability, and Morphology Evolution of Faceted and Spherical Anatase NanocrystalsCHEMINFORM, Issue 7 2005A. S. Barnard Abstract For Abstract see ChemInform Abstract in Full Text. [source] Friction and degradation of rock joint surfaces under shear loadsINTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS, Issue 10 2001F. Homand Abstract The morpho-mechanical behaviour of one artificial granite joint with hammered surfaces, one artificial regularly undulated joint and one natural schist joint was studied. The hammered granite joints underwent 5 cycles of direct shear under 3 normal stress levels ranging between 0.3 and 4 MPa. The regularly undulated joint underwent 10 cycles of shear under 6 normal stress levels ranging between 0.5 and 5 MPa and the natural schist replicas underwent a monotonics shear under 5 normal stress levels ranging between 0.4 and 2.4 MPa. These direct shear tests were performed using a new computer-controlled 3D-shear apparatus. To characterize the morphology evolution of the sheared joints, a laser sensor profilometer was used to perform surface data measurements prior to and after each shear test. Based on a new characterization of joint surface roughness viewed as a combination of primary and secondary roughness and termed by the joint surface roughness, SRs, one parameter termed ,joint surface degradation', Dw, has been defined to quantify the degradation of the sheared joints. Examinations of SRs and Dw prior to and after shearing indicate that the hammered surfaces are more damaged than the two other surfaces. The peak strength of hammered joint with zero-dilatancy, therefore, significantly differs from the classical formulation of dilatant joint strength. An attempt has been made to model the peak strength of hammered joint surfaces and dilatant joints with regard to their surface degradation in the course of shearing and two peak strength criteria are proposed. Input parameters are initial morphology and initial surface roughness. For the hammered surfaces, the degradation mechanism is dominant over the phenomenon of dilatancy, whereas for a dilatant joint both mechanisms are present. A comparison between the proposed models and the experimental results indicates a relatively good agreement. In particular, compared to the well-known shear strength criteria of Ladanyi and Archambault or Saeb, these classical criteria significantly underestimate and overestimate the observed peak strength, respectively, under low and high normal stress levels. In addition and based on our experimental investigations, we put forward a model to predict the evolution of joint morphology and the degree of degradation during the course of shearing. Degradations of the artificial undulated joint and the natural schist joint enable us to verify the proposed model with a relatively good agreement. Finally, the model of Ladanyi and Archambault dealing with the proportion of total joint area sheared through asperities, as, once again, tends to underestimate the observed degradation. Copyright © 2001 John Wiley & Sons, Ltd. [source] A reactive polymer for toughening epoxy resinJOURNAL OF APPLIED POLYMER SCIENCE, Issue 6 2010Hsu-Chiang Kuan Abstract Epoxy resins are hardly toughened by low weight content of tougheners. In this study, 5 wt % polyurea was adopted to significantly toughen piperidine-cured epoxy, as fracture toughness improved from 0.78 to 1.98 MPa m1/2. We focused on the reactions and morphology evolution of epoxy/polyurea mixture. The polyurea molecular weight was reduced by the exchange reactions of polyurea with epoxy during mixing, as evidenced by gel permeation chromatograph and Fourier transform infrared spectroscopy. As a result, epoxy molecules were chemically bonded with polyurea, improving particle content and interface thickness. Transmission electron microscope observation shows that (a) polyurea in situ formed nanoparticles in matrix which subsequently aggregate into micron-sized particles of thick interface with matrix; and (b) the particles became less stainable with increasing the mixing time, because the reactions promoted high levels of crosslink density of the particles which were thus more resistant to the diffusion of staining chemicals. Longer mixing time improved, obviously, the fracture toughness of epoxy/polyurea composite. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 [source] Shear-induced migration of nanoclay during morphology evolution of PBT/PS blendJOURNAL OF APPLIED POLYMER SCIENCE, Issue 1 2008Joung Sook Hong Abstract In this study, we investigated clay migration and its localization in multiphase blend nanocomposite systems during the evolution of blend morphology to elucidate how a hydrodynamic stress and chemical affinity between the polymer and clay induce them. To observe the morphology evolution, a multilayered blend, alternatively superposed poly(butylenes terephthalate) (PBT) and polystyrene (PS)/clay films or PBT/clay and PS films, was subjected to homogeneous shear flow, 1 s,1. Furthermore, the morphology was observed at different shear rates 1 s,1. When the PBT/(PS/clay) multilayered blend is subjected to flow, the clay dispersed in the PS layer first migrates to the interface depending on the amount of applied strain. The clay at the interface causes the average drop size of blend morphology to become smaller and the blend morphology becomes more stable because of the coalescence suppression effect. As more shear is applied, the clay at the interface moves further into more compatible phase, PBT, although the viscosity of PBT is higher than PS. On the contrary, the clay in the PBT layer does not migrate to the PS phase at any shear rate, which means that its chemical affinity is strong enough to prevent shear-induced migration. The clay increases the viscosity of the PBT phase and results in a different morphology with a droplet, cocontinuous structure. As a result, when the clay is induced to migrate by hydrodynamic stress, it migrates into thermodynamically more stable positions at the interface or in the chemically more compatible phase, depending on the applied strain. Once it is located at a thermodynamically more stable position, it is difficult to push it out only by hydrodynamic stress. The location of clay is significantly affected by the morphology during evolution, which means that the blend morphology can control the droplet form and cocontinuous structure by control of the clay migration kinetics. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 [source] Developments in Oxide Fiber CompositesJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 11 2006Frank W. Zok Prospects for revolutionary design of future power generation systems are contingent on the development of durable high-performance ceramic composites. With recent discoveries in materials and manufacturing concepts, composites with all-oxide constituents have emerged as leading candidates, especially for components requiring a long service life in oxidizing environments. Their insertion into engineering systems is imminent. The intent of this article is to present a synopsis of the current understanding of oxide composites as well as to identify outstanding issues that require resolution for successful implementation. Emphasis is directed toward material systems and microstructural concepts that lead to high toughness and long-term durability. These include: the emergence of La monazite and related compounds as fiber-coating materials, the introduction of the porous-matrix concept as an alternative to fiber coatings, and novel strategies for enabling damage tolerance while retaining long-term morphological stability. Additionally, materials and mechanics models that provide insights into material design, morphology evolution, and composite properties are reviewed. [source] Is AGN feedback necessary to form red elliptical galaxies?MONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY, Issue 1 2008A. Khalatyan ABSTRACT We have used the smoothed particle hydrodynamics (SPH) code gadget-2 to simulate the formation of an elliptical galaxy in a group-size cosmological dark matter halo with mass Mhalo, 3 × 1012 h,1 M, at z= 0. The use of a stellar population synthesis model has allowed us to compute magnitudes, colours and surface brightness profiles. We have included a model to follow the growth of a central black hole and we have compared the results of simulations with and without feedback from active galactic nuclei (AGN). We have studied the interplay between cold gas accretion and merging in the development of galactic morphologies, the link between colour and morphology evolution, the effect of AGN feedback on the photometry of early-type galaxies, the redshift evolution in the properties of quasar hosts, and the impact of AGN winds on the chemical enrichment of the intergalactic medium (IGM). We have found that the early phases of galaxy formation are driven by the accretion of cold filamentary flows, which form a disc galaxy at the centre of the dark matter halo. Disc star formation rates in this mode of galaxy growth are about as high as the peak star formation rates attained at a later epoch in galaxy mergers. When the dark matter halo is sufficiently massive to support the propagation of a stable shock, the gas in the filaments is heated to the virial temperature, cold accretion is shut down, and the star formation rate begins to decline. Mergers transform the spiral galaxy into an elliptical one, but they also reactivate star formation by bringing gas into the galaxy. Without a mechanism that removes gas from the merger remnants, the galaxy ends up with blue colours, which are atypical for its elliptical morphology. We have demonstrated that AGN feedback can solve this problem even with a fairly low heating efficiency. Our simulations support a picture where AGN feedback is important for quenching star formation in the remnant of wet mergers and for moving them to the red sequence. This picture is consistent with recent observational results, which suggest that AGN hosts are galaxies in migration from the blue cloud to the red sequence on the colour,magnitude diagram. However, we have also seen a transition in the properties of AGN hosts from blue and star forming at z, 2 to mainly red and dead at z, 0. Ongoing merging is the primary but not the only triggering mechanism for luminous AGN activity. Quenching by AGN is only effective after the cold filaments have dried out, since otherwise the galaxy is constantly replenished with gas. AGN feedback also contributes to raising the entropy of the hot IGM by removing low-entropy tails vulnerable to developing cooling flows. We have also demonstrated that AGN winds are potentially important for the metal enrichment of the IGM a high redshift. [source] Morphology development during blending of immiscible polymers in screw extrudersPOLYMER ENGINEERING & SCIENCE, Issue 6 2002Sandeep Tyagi The present work reports evolution of morphology from initial (presence of striation) to final (droplet formation) stages in a single-screw extruder. Morphology development during the blending process controls the final size of the dispersed phase, which in turn significantly affects the properties of the blends. The experiments were carried out using a 70/30 wt% polypropylene/ethylene vinyl acetate (PP/EVA) blend; samples were collected along the length of the screw, by screw pullout experiment, to analyze the size and size distribution of the dispersed phase present both as striated layers and subsequently as droplets. Average size of the dispersed phase and standard deviation were taken into account to monitor the morphology evolution along the length of the screw. Pre-breakup morphology development was studied by analyzing the sample collected from the feed zone of the extruder in terms of upper and lower layers along the cross section of screw channel. Examination of micrographs revealed the existence of pattern of ordered striations along the length of the melting zone containing striations from average size of 1000 ,m down to 50 ,m decreasing rapidly along the length of the screw. The breakup process was captured at the start of compression zone where step-up in the shear as well as elongational flow was applied due to decrease in the channel depth along the compression zone. The observed droplet size formed by the breakup of filaments is found to be in accordance with theory. The final droplet size is found to be governed by the emulsification process occurring as a result of stretching, breakup and coalescence in the metering section of the screw and is in the order of 2 ,m. [source] | ||||||||||