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Monolayer Coverage (monolayer + coverage)

Distribution by Scientific Domains

Polymers and Materials Science	33%

Selected Abstracts

Determination of surface area of soil by adsorption methods

EUROPEAN JOURNAL OF SOIL SCIENCE, Issue 3 2002
E. A. Ferreiro
Summary How significant are estimates of surface areas of soils obtained by adsorption methods? To answer this we tested the applicability of an equation that relates monolayer coverage (N) of an adsorbent with the area (A) of adsorbate, NAz = k, for six soil samples using six adsorbates of different sizes. The data obtained confirm the validity of the equation with the z parameter ranging between 1.25 and 1.41. Hence each soil sample showed preferences towards small-sized adsorbates for which the product NA (calculated surface area) is inversely related to the size of adsorbate. We also demonstrated that the equation has roots in the Langmuir adsorption equation. [source]

Influence of Dielectric Surface Chemistry on the Microstructure and Carrier Mobility of an n-Type Organic Semiconductor

ADVANCED FUNCTIONAL MATERIALS, Issue 15 2009
Parul Dhagat
Abstract This paper examines the microstructure evolution of 3,4,9,10-perylene-tetracarboxylic bis-benzimidazole (PTCBI) thin films resulting from conditions imposed during film deposition. Modification of the silicon dioxide interface with a hydrophobic monolayer (octadecyltrichlorosilane (OTS-18)) alters the PTCBI growth habit by changing the unit cell contact plane. PTCBI films deposited on oxide surface have an orientation of (011), while films atop OTS-treated oxide surface have a preferred orientation of (001). The quality of the self assembled monolayer does not appear to influence the PTCBI growth preference significantly yet it enhances the carrier mobility, suggesting that charge traps are adequately passivated due to uniform monolayer coverage. High-quality monolayers result in n-type carrier mobility values of 0.05,cm2V,1s,1 Increasing the substrate temperature during PTCBI film deposition correlates with an increase in mobility that is most significant for films deposited on OTS-treated surface. [source]

Adsorption of Cd(II), Pb(II), and Ag(I) in aqueous solution on hollow chitosan microspheres

JOURNAL OF APPLIED POLYMER SCIENCE, Issue 2 2010
Shan Wang
Abstract Cross-linked chitosans synthesized by the inverse emulsion cross-link method were used to investigate adsorption of three metal ions [Cd(II), Pb(II), and Ag(I)] in an aqueous solution. The chitosan microsphere, was characterized by FTIR and SEM, and adsorption of Cd(II), Pb(II), and Ag(I) ions onto a cross-linked chitosan was examined through analysis of pH, agitation time, temperature, and initial concentration of the metal. The order of adsorption capacity for the three metal ions was Cd2+ > Pb2+ > Ag+. This method showed that adsorption of the three metal ions in an aqueous solution followed the monolayer coverage of the adsorbents through physical adsorption phenomena and coordination because the amino (NH2) and/or hydroxy (OH) groups on chitosan chains serve as coordination sites. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 [source]

Low frequency noise in Co/Al2O3,Si,/Py magnetic tunnel junctions

PHYSICA STATUS SOLIDI (A) APPLICATIONS AND MATERIALS SCIENCE, Issue 5 2008
R. Guerrero
Abstract Low frequency noise and dynamic tunneling resistance have been studied in Co(80 Å)/Al2O3(12 Å)/Py(100 Å) magnetic tunnel junctions (MTJs) with and without asymmetric Si doping of the insulating barrier (Si , 1.8 Å). Variation of the dynamic resistance and tunneling resistance with Si doping and applied bias in these MTJs indicate a transition from the Si-doped regime to Si cluster formation above a , -layer thickness of about 1.2 Å, close to 1 monolayer coverage. The measurements show anomalously strong enhancements of the low frequency noise for Si thickness above 1.2 Å, mainly due to the appearance of random telegraph noise. A simple model, which considers suppression of Coulomb blockade in the array of Si dots, opening two-step tunnel channels, qualitatively explains the variation of both conductivity and noise with Si content. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]

Enzyme-Carrying Polymeric Nanofibers Prepared via Electrospinning for Use as Unique Biocatalysts

BIOTECHNOLOGY PROGRESS, Issue 5 2002
Hongfei Jia
Improvement of catalytic efficiency of immobilized enzymes via materials engineering was demonstrated through the preparation of bioactive nanofibers. Bioactive polystyrene (PS) nanofibers with a typical diameter of 120 nm were prepared and examined for catalytic efficiency for biotransformations. The nanofibers were produced by electrospinning functionalized PS, followed by the chemical attachment of a model enzyme, ,-chymotrypsin. The observed enzyme loading as determined by active site titration was up to 1.4% (wt/wt), corresponding to over 27.4% monolayer coverage of the external surface of nanofibers. The apparent hydrolytic activity of the nanofibrous enzyme in aqueous solutions was over 65% of that of the native enzyme, indicating a high catalytic efficiency as compared to other forms of immobilized enzymes. Furthermore, nanofibrous ,-chymotrypsin exhibited a much-improved nonaqueous activity that was over 3 orders of magnitude higher than that of its native counterpart suspended in organic solvents including hexane and isooctane. It appeared that the covalent binding also improved the enzyme's stability against structural denaturation, such that the half-life of the nanofibrous enzyme in methanol was 18-fold longer than that of the native enzyme. [source]

Adsorption of 1,3-Benzenedithiol and 1,3-Benzenedimethanethiol on Gold Surfaces,

CHEMPHYSCHEM, Issue 12 2008
Jong Kuk Lim Dr.
Abstract The adsorption characteristics of 1,3-benzenedithiol (1,3-BDT) and 1,3-benzenedimethanethiol (1,3-BDMT) on Au surfaces are investigated by means of surface-enhanced Raman scattering, UV/Vis absorption spectroscopy, and cyclic voltammetry (CV). 1,3-BDMT is found to adsorb via two S,Au linkages at concentrations below monolayer coverage, but to have an upright geometry as the concentration increases on Au nanoparticles. On the other hand, 1,3-BDT is found to adsorb by forming two S,Au linkages, regardless of concentration, based on the disappearance of the ,(SH)free stretching band. Because of the absence of the methylene unit, 1,3-BDT appeares not to self-assemble efficiently on Au surfaces. The UV/Vis absorption spectroscopy and CV techniques are also applied to check the formation of self-assembled monolayers of 1,3-BDT and 1,3-BDMT on Au. Density functional theory calculations based on a simple adsorption model using an Au8 cluster are performed to better understand the nature of the adsorption characteristics of 1,3-BDT and 1,3-BDMT on Au surfaces. [source]