Mineral Component (mineral + component)

Distribution by Scientific Domains


Selected Abstracts


The role of the mineral component in surface stabilization processes of a disturbed desert sandy surface

LAND DEGRADATION AND DEVELOPMENT, Issue 4 2002
A. Yair
Abstract The stabilization of sandy and loamy surfaces in semiarid and arid areas by topsoil crusts protecting the soil against wind or runoff erosion is well known. Destruction of such crusts, often by overgrazing, can enhance erosion and desertification. Crust recovery does not depend purely on biotic components of the crust and vegetation. Mineral components in the initial surface stabilization process are often overlooked. The present study focuses on the relative importance of the biotic and mineral components in the process of topsoil crust recovery in a sandy desert area located in the northwestern Negev Desert of Israel. Observations of the initial crust and of the disturbed surface, in the field and under the scanning electron microscope, showed that the mineral components of the crust recovered more quickly than its biotic elements. The implications for the rehabilitation of the disturbed ecosystem are discussed. Copyright © 2002 John Wiley & Sons, Ltd. [source]


Mammary Gland Secretory Concretions Contain Non-Collagenous Bone Matrix Proteins

ANATOMIA, HISTOLOGIA, EMBRYOLOGIA, Issue 5 2006
M. Egerbacher
Summary Secretory concretions in mammary gland alveoli are commonly of microscopical size. However, some concretions reach clinically palpable dimensions and may occlude teat canals and obstruct milk flow. We studied secretory concretions in sheep, goat and cow mammary glands, using routine histological staining methods, conventional histochemistry and electron microscopy. As concretions frequently mineralize, immunostaining for keratan sulphate and calcium-binding non-collagenous bone matrix proteins (bone sialoprotein, osteocalcin, osteonectin and osteopontin) was performed. Concretions consisted of organic matrix (condensed secretions) with calcium precipitates. Mineralized deposits mostly show concentric organization, bound haematoxylin, and were readily identified in H&E-stained sections. Mineral components of concretions reacted for calcium carbonate and phosphate, organic matrix was found to contain sialoglycan material. Immunohistochemistry revealed bone sialoprotein, osteonectin and keratan sulphate in cow and goat concretions. Osteocalcin was detected in sheep, cow and goat concretions, whilst osteopontin was not identified in any of the specimens studied. Our results indicate the presence of non-collagenous bone matrix proteins (except osteopontin) in mammary gland concretions. These glycoproteins are commonly thought to govern mineralization of organic matrix and are assumed also to promote mineral deposition in mammary gland secretory concretions. Besides caseins, these particular glycoproteins have to be considered as calcium-binding milk proteins. [source]


Aragonite Formation in the Chiton (Mollusca) Girdle

HELVETICA CHIMICA ACTA, Issue 4 2003
Keren Treves
In the chitons (Polyplacophora, Mollusca), the body is not entirely protected by the shell. Mineralized spicules or scales often, but not always, decorate the exposed part of the girdle. Here, we report a study on the composition and ultrastructural organization of these mineralized skeletal parts in four different chiton species. In all specimens, the mineral component (97,98,wt-%) is aragonite, and the organic matrix (2,3,wt-%) consists of highly glycosylated proteins. X-Ray diffraction and scanning electron microscopy show that the organic matrix fibers are aligned, morphologically and crystallographically, with the prismatic aragonite crystals. Matrix and mineral are thus clearly related. The matrix,mineral composite bundles are, however, assembled in the various skeletal parts examined with widely different degrees of alignment and order. In the same organism, the crystals are aligned within a range of ±15° in one type of spicule, while they are randomly oriented in another type. The wide heterogeneity in shape, density, and ultrastructure suggests that the girdle mineralized tissues do not fulfill a fundamental role necessary for the survival of the organism. This, together with the lack of chitin in the organic matrix, supports the hypothesis that they evolved separately from the other chiton mineralized tissues, namely the shell plates and teeth. [source]


Porous Ti-6Al-4V alloy fabricated by spark plasma sintering for biomimetic surface modification

JOURNAL OF BIOMEDICAL MATERIALS RESEARCH, Issue 1 2004
Masayuki Kon
Abstract Porous compacts with both biological and biomechanical compatibilities and high strength were developed. Spherical powders of Ti-6Al-4V alloy, which were either as received or surface modified with the use of calcium ions by hydrothermal treatment (HTT), were fabricated by a spark plasma sintering process. The porous compacts of pure Ti were used as reference materials. Porosity was approximately 30%, and compressive strengths were 113 and 125 MPa for the as-received Ti alloy powders and those modified by the HTT process, respectively. The bending strength and elastic modulus of as-received Ti alloy powders were 128,178 MPa and 16,18 GPa, respectively. Each of the compacts was immersed in simulated body fluid (SBF). The amount of adsorption/precipitation of calcium phosphate through the compacts was measured by weight change and was observed by SEM. The compacts were covered with calcium phosphate after 2 weeks of immersion in SBF. The compacts of Ti alloy had plenty of precipitated apatite crystals, and modification by HTT accumulated more precipitation. Because calcium phosphate is a mineral component of bone, apatite, which is precipitated on the surface of the compacts, could adsorb proteins and/or drugs such as antibiotics. It is expected that a large amount of proteins and/or drugs could be impregnated when the porous compacts developed are used. © 2003 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater 68B: 88,93, 2004 [source]


Highly Ordered Interstitial Water Observed in Bone by Nuclear Magnetic Resonance,

JOURNAL OF BONE AND MINERAL RESEARCH, Issue 4 2005
Erin E Wilson
Abstract NMR was used to study the nanostructure of bone tissue. Distance measurements show that the first water layer at the surface of the mineral in cortical bone is structured. This water may serve to couple the mineral to the organic matrix and may play a role in deformation. Introduction: The unique mechanical characteristics of bone tissue have not yet been satisfactorily connected to the exact molecular architecture of this complex composite material. Recently developed solid-state nuclear magnetic resonance (NMR) techniques are applied here to the mineral component to provide new structural distance constraints at the subnanometer scale. Materials and Methods: NMR dipolar couplings between structural protons (OH, and H2O) and phosphorus (PO4) or carbon (CO3) were measured using the 2D Lee-Goldburg Cross-Polarization under Magic-Angle Spinning (2D LG-CPMAS) pulse sequence, which simultaneously suppresses the much stronger proton-proton dipolar interactions. The NMR dipolar couplings measured provide accurate distances between atoms, e.g., OH and PO4 in apatites. Excised and powdered femoral cortical bone was used for these experiments. Synthetic carbonate (,2-4 wt%)-substituted hydroxyapatite was also studied for structural comparison. Results: In synthetic apatite, the hydroxide ions are strongly hydrogen bonded to adjacent carbonate or phosphate ions, with hydrogen bond (O-H) distances of ,1.96 Å observed. The bone tissue sample, in contrast, shows little evidence of ordered hydroxide. Instead, a very ordered (structural) layer of water molecules is identified, which hydrates the small bioapatite crystallites through very close arrangements. Water protons are ,2.3-2.55 Å from surface phosphorus atoms. Conclusions: In synthetic carbonated apatite, strong hydrogen bonds were observed between the hydroxide ions and structural phosphate and carbonate units in the apatite crystal lattice. These hydrogen bonding interactions may contribute to the long-range stability of this mineral structure. The biological apatite in cortical bone tissue shows evidence of hydrogen bonding with an ordered surface water layer at the faces of the mineral particles. This structural water layer has been inferred, but direct spectroscopic evidence of this interstitial water is given here. An ordered structural water layer sandwiched between the mineral and the organic collagen fibers may affect the biomechanical properties of this complex composite material. [source]


The role of the mineral component in surface stabilization processes of a disturbed desert sandy surface

LAND DEGRADATION AND DEVELOPMENT, Issue 4 2002
A. Yair
Abstract The stabilization of sandy and loamy surfaces in semiarid and arid areas by topsoil crusts protecting the soil against wind or runoff erosion is well known. Destruction of such crusts, often by overgrazing, can enhance erosion and desertification. Crust recovery does not depend purely on biotic components of the crust and vegetation. Mineral components in the initial surface stabilization process are often overlooked. The present study focuses on the relative importance of the biotic and mineral components in the process of topsoil crust recovery in a sandy desert area located in the northwestern Negev Desert of Israel. Observations of the initial crust and of the disturbed surface, in the field and under the scanning electron microscope, showed that the mineral components of the crust recovered more quickly than its biotic elements. The implications for the rehabilitation of the disturbed ecosystem are discussed. Copyright © 2002 John Wiley & Sons, Ltd. [source]


Principal features of impact-generated hydrothermal circulation systems: mineralogical and geochemical evidence

GEOFLUIDS (ELECTRONIC), Issue 3 2005
MIKHAIL V. NAUMOVArticle first published online: 14 JUL 200
Abstract Any hypervelocity impact generates a hydrothermal circulation system in resulting craters. Common characteristics of hydrothermal fluids mobilized within impact structures are considered, based on mineralogical and geochemical investigations, to date. There is similarity between the hydrothermal mineral associations in the majority of terrestrial craters; an assemblage of clay minerals,zeolites,calcite,pyrite is predominant. Combining mineralogical, geochemical, fluid inclusion, and stable isotope data, the distinctive characteristics of impact-generated hydrothermal fluids can be distinguished as follows: (i) superficial, meteoric and ground water and, possibly, products of dehydration and degassing of minerals under shock are the sources of hot water solutions; (ii) shocked target rocks are sources of the mineral components of the solutions; (iii) flow of fluids occurs mainly in the liquid state; (iv) high rates of flow are likely (10,4 to 10,3 m s,1); (v) fluids are predominantly aqueous and of low salinity; (vi) fluids are weakly alkaline to near-neutral (pH 6,8) and are supersaturated in silica during the entire hydrothermal process because of the strong predominance of shock-disordered aluminosilicates and fusion glasses in the host rocks; and (vii) variations in the properties of the circulating solutions, as well as the spatial distribution of secondary mineral assemblages are controlled by tempera ure gradients within the circulation cell and by a progressive cooling of the impact crater. Products of impact-generated hydrothermal processes are similar to the hydrothermal mineralization in volcanic areas, as well as in modern geothermal systems, but impacts are always characterized by a retrograde sequence of alteration minerals. [source]


The role of the mineral component in surface stabilization processes of a disturbed desert sandy surface

LAND DEGRADATION AND DEVELOPMENT, Issue 4 2002
A. Yair
Abstract The stabilization of sandy and loamy surfaces in semiarid and arid areas by topsoil crusts protecting the soil against wind or runoff erosion is well known. Destruction of such crusts, often by overgrazing, can enhance erosion and desertification. Crust recovery does not depend purely on biotic components of the crust and vegetation. Mineral components in the initial surface stabilization process are often overlooked. The present study focuses on the relative importance of the biotic and mineral components in the process of topsoil crust recovery in a sandy desert area located in the northwestern Negev Desert of Israel. Observations of the initial crust and of the disturbed surface, in the field and under the scanning electron microscope, showed that the mineral components of the crust recovered more quickly than its biotic elements. The implications for the rehabilitation of the disturbed ecosystem are discussed. Copyright © 2002 John Wiley & Sons, Ltd. [source]


Formation of zinc protoporphyrin IX in Parma-like ham without nitrate or nitrite

ANIMAL SCIENCE JOURNAL, Issue 2 2009
Jun-ichi WAKAMATSU
ABSTRACT Zinc protoporphyrin IX (ZPP) is a characteristic red pigment in meat products that are manufactured without the addition of a curing agent such as nitrate or nitrite. To examine the effects of impurities such as mineral components in sea salt on the formation of ZPP, we manufactured Parmatype dry-cured hams that were salted with refined salt or sea salt and examined the involvement of oxidation-reduction potential (ORP) in the formation of ZPP. The content of ZPP was increased drastically after 40 weeks. Microscopic observation showed strong fluorescence caused by ZPP muscle fiber after 40 weeks. Conversely, heme content varied considerably during processing. ORP increased during processing. However, there was no obvious difference between ham salted with refined salt and that salted with sea salt. Therefore, it was concluded that impurities in sea salt were not involved in the formation of ZPP. [source]


High-Resolution Records of the Holocene Paleoenvironmental Variation Reflected by Carbonate and Its Isotopic Compositions in Bosten Lake and Response to Glacial Activities

ACTA GEOLOGICA SINICA (ENGLISH EDITION), Issue 6 2009
ZHANG Chengjun
Abstract: The Early Holocene paleoclimate in Bosten Lake on the northern margin of the Tarim Basin, southern Xinjiang, is reconstructed through an analysis of a 953 cm long core (BSTC2000) taken from Bosten Lake. Multiple proxies of this core, including the mineral components of carbonate, carbonate content, stable isotopic compositions of carbonate, Ca/Sr, TOC and C/N and C/S of organic matter, are used to reconstruct the climatic change since 8500 a B.P. The chronology model is made by nine AMS 14C ages of leaves, seeds and organic matter contained in two parallel cores. The climate was cold and wet during 8500 to 8100 a B.P. Temperature increased from 8100 to 6400 a B.P., the climate was warm and humid, and the lake expanded. The lake level was highest during this stage. Then from 6400 to 5100 a B.P., the climate became cold and the lake level decreased slightly. During the late mid-Holocene, the climate was hot and dry from 5100 to 3100 a B.P., but there was a short cold period during 4400 to 3800 a B.P. At this temporal interval, a mass of ice and snow melting water supplied the lake at the early time and made the lake level rise. The second highest lake level stage occurred during 5200 to 3800 a B.P. The climate was cool and wet during 3100 to 2200 a B.P., when the lake expanded with decreasing evaporation. The lake had the last short-term high level during 3100 to 2800 a B.P. After this short high lake level period, the lake shrank because of the long-term lower temperature and reduced water supply. From 2200 to 1200 a B.P., the climate was hot and dry, and the lake shrank greatly. Although the temperature decreased somewhat from 1200 a B.P. to the present, the climate was warm and dry. The lake level began to rise a little again, but it did not reach the river bed altitude of the Konqi River, an outflow river of the Bosten Lake. [source]