Home  About us  Contact
 

Mixture Synthesis (mixture + synthesis)

Distribution by Scientific Domains
Chemistry100%

Kinds of Mixture Synthesis

  • racemic mixture synthesis
    		•

    Selected Abstracts

    Fluorous "Racemic" Mixture Synthesis: Simultaneous Strategy for Demixing and Enantioseparation of Racemic Fluorous-Tagged Products

    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, Issue 11 2007
    Takayuki Tonoi
    Abstract Reported herein is the concept of fluorous "racemic" mixture synthesis (FRMS), which is applied to two types of proof-of-concept experiments. Mixtures of racemic O -benzoylmandelate derivatives and prochiral crotonamide derivatives, respectively, bearing different lengths of fluorous-cleavable tags are taken through a segmented reaction sequence to provide their enantiomers, as well as their individual derivatives, by virtue of chiral ,-cyclodextrin columns. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007) [source]

    Fluorous "racemic" mixture synthesis: Polysaccharide-based chiral columns for simultaneous demix and enantioseparation of racemic fluorous tagged compounds

    CHIRALITY, Issue 3-4 2008
    Takayuki Tonoi
    Abstract The proof of concept experiments of fluorous "racemic" mixture synthesis (FRMS) is shown using polysaccharide-based chiral stationary phases. The mixture of racemic O -benzoylmandelate derivatives bearing different lengths of fluorous cleavable tags undergoes sequential reactions to provide individual derivatives as well as their enantiomers resolved on polysaccharide-based chiral HPLC columns (DAICEL CHIRALCEL® and CHIRALPAK® series). Chirality, 2008. © 2008 Wiley-Liss, Inc. [source]