Home About us Contact
|
Home About us Contact | ||
|
|
||
Metamorphic Fluids (metamorphic + fluid)
Selected AbstractsFluid Evolution and Metallogenic Dynamics during Tectonic Regime Transition: Example from the Jiapigou Gold Belt in Northeast ChinaRESOURCE GEOLOGY, Issue 2 2009Jun Deng Abstract The Jiapigou gold belt, one of the most important gold-producing districts in China, is located in the northern margin of the North China Craton (NCC). The tectonic evolution of the gold belt is closely related to the Siberian Plate (SP) in the north, Yangtze Craton (YC) in the south and Pacific Plate in the east. In order to investigate the nature of the tectono-fluid-metallogenic system, the authors investigated the relationships among the tectonic regimes, fluid evolution and metallogenesis. This paper examined the corresponding spatial,temporal relationship between the ore-controlling tectonic regime and hydrothermal fluid evolution in the Jiapigou gold belt. There are two types of gold mineralization: disseminated ores that are distributed within the NW-trending main ductile shear zone and gold-bearing quartz veins and minor disseminated ores that are distant to the ductile shear zone. The fluid inclusions in quartz contain a large amount of CO2. Metamorphic fluids of middle to high temperatures and pressures and meteoric waters of low temperatures and pressures mixed together during mineralization. A proposed ore-forming model is as follows: in the pre-ore phase, the collision of SP and NCC resulted in the NS-trending compression of the ore belt. This formed the NE-trending and NW-trending shear faults and EW-trending folds. During the ore-forming phase, the collision of YC and NCC resulted in dextral shearing of the NW-trending Jiapigou fault and the NE-trending Green faults. High-pressure fluids caused by the compression flowed into the dilatant zone. This may have caused both phase separation of CO2 -bearing fluids and the mixing of meteoric waters, metamorphic waters and magmatic source fluids and finally resulted in the disequilibrium of the ore fluids and precipitation of ore minerals. [source] Middle Archean ocean ridge hydrothermal metamorphism and alteration recorded in the Cleaverville area, Pilbara Craton, Western AustraliaJOURNAL OF METAMORPHIC GEOLOGY, Issue 7 2007T. SHIBUYA Abstract A hydrothermally metamorphosed greenstone complex, capped by bedded cherts and banded iron formations (BIFs), is exposed in the Cleaverville area, Pilbara Craton, Western Australia. It has been interpreted as an accretionary complex characterized by both a duplex structure and an oceanic plate stratigraphy, and is shown to represent a 3.2 Ga upper oceanic crust. Three metamorphic zones are identified in the basaltic greenstones. The metamorphic grade increases from sub-greenschist facies (zones A and B) to greenschist facies (zone C) under low-pressure conditions. The boundaries between three mineral zones are subparallel to the bedding plane of overlying chert/BIF, and metamorphic temperature increases stratigraphically downward. The zones correspond to the thermal structure of ocean-floor metamorphism, at a mid-ocean ridge. The uppermost greenstone in the study area is more pervasively altered and carbonatized than the modern upper oceanic crust. This indicates the enrichment of CO2 in the metamorphic fluid by which widespread formation of carbonate occurred, compared with a narrow stability region of Ca-Al silicates. It is, therefore, suggested that the Archean hydrothermal alteration played a more important role in fixation of CO2 than present-day ocean-ridge hydrothermal alteration, as an interaction between sea water and oceanic crust. [source] The formation of eclogite facies metatroctolites and a general petrogenetic grid in Na2O,CaO,FeO,MgO,Al2O3,SiO2,H2O (NCFMASH)JOURNAL OF METAMORPHIC GEOLOGY, Issue 9 2002G. Rebay Abstract Eclogite facies metatroctolites from a variety of Western Alps localities (Voltri, Monviso, Lanzo, Allalin, Zermat,Saas, etc.) that preserve textural evidence of their original form as bimineralic olivine-plagioclase rocks are considered in terms of calculated mineral equilibria in the system Na2O-CaO-FeO-MgO-Al2O3 -SiO2 -H2O (NCFMASH). Pseudosections, based on a new petrogenetic grid for NCFMASH presented here, are used to unravel the metamorphic history of the metatroctolites, considering the rocks to consist of different composition microdomains corresponding to the original olivine and plagioclase grains. On the basis that the preservation of the mineral assemblage in each microdomain will tend to be from where on a rock's P,T path the metamorphic fluid phase is used up via rehydration reactions, P,T pseudosections contoured for water content, and P,T path-MH2O (amount of water) pseudosections, are used to examine fluid behaviour in each microdomain. We show that the different microdomains are likely to preserve their mineral assemblages from different places on the P,T path. For the olivine microdomain, the diagnostic mineral assemblage is chloritoid + talc (+ garnet + omphacite). The preservation of this assemblage, in the light of the closed system P,T path-MH2O relationships, implies that the microdomain loses its metamorphic fluid as it starts to decompress, and, in the absence of subsequent hydration, the high pressure mineral assemblage is then preserved. In the plagioclase microdomain, the diagnostic assemblage is epidote (or zoisite) + kyanite + quartz suggesting a lower pressure (of about 2 GPa) than for the olivine microdomain. In the light of P,T path-MH2O relationships, development of this assemblage implies breakdown of lawsonite across the lawsonite breakdown reaction, regardless of the maximum pressure reached. It is likely that the plagioclase microdomain was mainly fluid-absent prior to lawsonite breakdown, only becoming fluid-present across the reaction, then immediately becoming fluid-absent again. [source] Role of fluids in the metamorphism of the Alpine Fault Zone, New ZealandJOURNAL OF METAMORPHIC GEOLOGY, Issue 1 2001J. K. Vry Abstract Models of fluid/rock interaction in and adjacent to the Alpine Fault in the Hokitika area, South Island, New Zealand, were investigated using hydrogen and other stable isotope studies, together with field and petrographic observations. All analysed samples from the study area have similar whole-rock ,D values (,DWR = ,56 to ,30,, average = ,45,, n = 20), irrespective of rock type, degree of chloritization, location along the fault, or across-strike distance from the fault in the garnet zone. The green, chlorite-rich fault rocks, which probably formed from Australian Plate precursors, record nearly isothermal fluid/rock interaction with a schist-derived metamorphic fluid at high temperatures near 450,500°C (,D of water in equilibrium with the green fault rocks (,DH2O, green) ,,,18,; ,D of water in equilibrium with the greyschists and greyschist-derived mylonites (,DH2O, grey) , ,19, at 500°C; ,DH2O, green , ,17,; ,DH2O, grey , ,14, at 450°C). There is no indication of an influx of a meteoric or mantle-derived fluid in the Alpine Fault Zone in the study area. The Alpine Fault Zone at the surface shows little evidence of late-stage retrogression or veining, which might be attributed to down-temperature fluid flow. It is probable that prograde metamorphism in the root zone of the Southern Alps releases metamorphic fluids that at some region rise vertically rather than following the trace of the Alpine Fault up to the surface, owing to the combined effects of the fault, the disturbed isotherms under the Southern Alps, and the brittle,ductile transition. Such fluids could mix with meteoric fluids to deposit quartz-rich, possibly gold-bearing veins in the region c. 5,10 km back from the fault trace. These results and interpretations are consistent with interpretations of magnetotelluric data obtained in the South Island GeopHysical Transects (SIGHT) programme. [source] Fluid flow and Al transport during quartz-kyanite vein formation, Unst, Shetland Islands, ScotlandJOURNAL OF METAMORPHIC GEOLOGY, Issue 1 2010C. E. BUCHOLZ Abstract Quartz-kyanite veins, adjacent alteration selvages and surrounding ,precursor' wall rocks in the Dalradian Saxa Vord Pelite of Unst in the Shetland Islands (Scotland) were investigated to constrain the geochemical alteration and mobility of Al associated with channelized metamorphic fluid infiltration during the Caledonian Orogeny. Thirty-eight samples of veins, selvages and precursors were collected, examined using the petrographic microscope and electron microprobe, and geochemically analysed. With increasing grade, typical precursor mineral assemblages include, but are not limited to, chlorite+chloritoid, chlorite+chloritoid+kyanite, chlorite+chloritoid+staurolite and garnet+staurolite+kyanite+chloritoid. These assemblages coexist with quartz, white mica (muscovite, paragonite, margarite), and Fe-Ti oxides. The mineral assemblage of the selvages does not change noticeably with metamorphic grade, and consists of chloritoid, kyanite, chlorite, quartz, white mica and Fe-Ti oxides. Pseudosections for selvage and precursor bulk compositions indicate that the observed mineral assemblages were stable at regional metamorphic conditions of 550,600 °C and 0.8,1.1 GPa. A mass balance analysis was performed to assess the nature and magnitude of geochemical alteration that produced the selvages adjacent to the veins. On average, selvages lost about ,26% mass relative to precursors. Mass losses of Na, K, Ca, Rb, Sr, Cs, Ba and volatiles were ,30 to ,60% and resulted from the destruction of white mica. Si was depleted from most selvages and transported locally to adjacent veins; average selvage Si losses were about ,50%. Y and rare earth elements were added due to the growth of monazite in cracks cutting apatite. The mass balance analysis also suggests some addition of Ti occurred, consistent with the presence of rutile and hematite-ilmenite solid solutions in veins. No major losses of Al from selvages were observed, but Al was added in some cases. Consequently, the Al needed to precipitate vein kyanite was not derived locally from the selvages. Veins more than an order of magnitude thicker than those typically observed in the field would be necessary to accommodate the Na and K lost from the selvages during alteration. Therefore, regional transport of Na and K out of the local rock system is inferred. In addition, to account for the observed abundances of kyanite in the veins, large fluid-rock ratios (102,103 m3fluid m,3rock) and time-integrated fluid fluxes in excess of ,104 m3fluid m,2rock are required owing to the small concentrations of Al in aqueous fluids. It is concluded that the quartz-kyanite veins and their selvages were produced by regional-scale advective mass transfer by means of focused fluid flow along a thrust fault zone. The results of this study provide field evidence for considerable Al mass transport at greenschist to amphibolite facies metamorphic conditions, possibly as a result of elevated concentrations of Al in metamorphic fluids due to alkali-Al silicate complexing at high pressures. [source] Synchronous peak Barrovian metamorphism driven by syn-orogenic magmatism and fluid flow in southern Connecticut, USAJOURNAL OF METAMORPHIC GEOLOGY, Issue 5 2008P. J. LANCASTER Abstract Recent work in Barrovian metamorphic terranes has found that rocks experience peak metamorphic temperatures across several grades at similar times. This result is inconsistent with most geodynamic models of crustal over-thickening and conductive heating, wherein rocks which reach different metamorphic grades generally reach peak temperatures at different times. Instead, the presence of additional sources of heat and/or focusing mechanisms for heat transport, such as magmatic intrusions and/or advection by metamorphic fluids, may have contributed to the contemporaneous development of several different metamorphic zones. Here, we test the hypothesis of temporally focussed heating for the Wepawaug Schist, a Barrovian terrane in Connecticut, USA, using Sm,Nd ages of prograde garnet growth and U,Pb zircon crystallization ages of associated igneous rocks. Peak temperature in the biotite,garnet zone was dated (via Sm,Nd on garnet) at 378.9 ± 1.6 Ma (2,), whereas peak temperature in the highest grade staurolite,kyanite zone was dated (via Sm,Nd on garnet rims) at 379.9 ± 6.8 Ma (2,). These garnet ages suggest that peak metamorphism was pene-contemporaneous (within error) across these metamorphic grades. Ion microprobe U,Pb ages for zircon from igneous rocks hosted by the metapelites also indicate a period of syn-metamorphic peak igneous activity at 380.6 ± 4.7 Ma (2,), indistinguishable from the peak ages recorded by garnet. A 388.6 ± 2.1 Ma (2,) garnet core age from the staurolite,kyanite zone indicates an earlier episode of growth (coincident with ages from texturally early zircon and a previously published monazite age) along the prograde regional metamorphic T,t path. The timing of peak metamorphism and igneous activity, as well as the occurrence of extensive syn-metamorphic quartz vein systems and pegmatites, best supports the hypothesis that advective heating driven by magmas and fluids focussed major mineral growth into two distinct episodes: the first at c. 389 Ma, and the second, corresponding to the regionally synchronous peak metamorphism, at c. 380 Ma. [source] Role of fluids in the metamorphism of the Alpine Fault Zone, New ZealandJOURNAL OF METAMORPHIC GEOLOGY, Issue 1 2001J. K. Vry Abstract Models of fluid/rock interaction in and adjacent to the Alpine Fault in the Hokitika area, South Island, New Zealand, were investigated using hydrogen and other stable isotope studies, together with field and petrographic observations. All analysed samples from the study area have similar whole-rock ,D values (,DWR = ,56 to ,30,, average = ,45,, n = 20), irrespective of rock type, degree of chloritization, location along the fault, or across-strike distance from the fault in the garnet zone. The green, chlorite-rich fault rocks, which probably formed from Australian Plate precursors, record nearly isothermal fluid/rock interaction with a schist-derived metamorphic fluid at high temperatures near 450,500°C (,D of water in equilibrium with the green fault rocks (,DH2O, green) ,,,18,; ,D of water in equilibrium with the greyschists and greyschist-derived mylonites (,DH2O, grey) , ,19, at 500°C; ,DH2O, green , ,17,; ,DH2O, grey , ,14, at 450°C). There is no indication of an influx of a meteoric or mantle-derived fluid in the Alpine Fault Zone in the study area. The Alpine Fault Zone at the surface shows little evidence of late-stage retrogression or veining, which might be attributed to down-temperature fluid flow. It is probable that prograde metamorphism in the root zone of the Southern Alps releases metamorphic fluids that at some region rise vertically rather than following the trace of the Alpine Fault up to the surface, owing to the combined effects of the fault, the disturbed isotherms under the Southern Alps, and the brittle,ductile transition. Such fluids could mix with meteoric fluids to deposit quartz-rich, possibly gold-bearing veins in the region c. 5,10 km back from the fault trace. These results and interpretations are consistent with interpretations of magnetotelluric data obtained in the South Island GeopHysical Transects (SIGHT) programme. [source] Alteration Patterns Related to Hydrothermal Gold Mineralizaition in Meta-andesites at Dungash Area, Eastern Desert, EgyptRESOURCE GEOLOGY, Issue 1 2001Hossam A. Helba Abstract: The hydrothermal alteration patterns associating with the gold prospect hosted by metavolcanics in the Dungash area, Eastern Desert of Egypt, were investigated in order to assign their relationship to mineralization. The metavolcanics of andesitic composition are generated by regional metamorphism of greenschist facies superimposed by hydrothermal activity. Epidote and chlorite are metamorphic minerals, whereas sericite, carbonates, and chlorite are hydrothermal alteration minerals. The auriferous quartz vein is of NEE-SWW trend and cuts mainly the andesitic metavolcanics, but sometimes extends to the neighbouring metapyroclastics and metasediments. Quartz-sericite, sericite, carbonate-sericite, and chlorite-sericite constitute four distinctive alteration zones which extend outwards from the mineralized quartz vein. The quartz-sericite and sericite zones are characterized by high contents of SiO2, K2O, Rb, and As, the carbonate-sericite zone is by high contents of CaO, Au, Cu, Cr, Ni, and Y, and the chlorite-sericite zone is by high contents of MgO, Na2O, Zn, Ba, and Co. Gold and sulphide minerals are relatively more abundant in the carbonate-sericite zone followed by the sericite one. The geochemistry of the alteration system was investigated using volume-composition and mass balance calculations. The volume factors obtained for the different alteration zones, mentioned above (being 1.64, 1.19, 1.17, and 1.07, respectively), indicate that replacement had taken place with a volume gain. The mass balance calculations revealed addition of SiO2, K2O, As, Cu, Rb, Ba, Ni, and Y to the system as a whole and subtraction of Fe2O3 from the system. Initial high aK+ and aH+ for the invading fluids is suggested. As the fluids migrated into wallrocks, they became more concentrated in Mg, Ca, and Na with increasing activities of CO2 and S. The calculated loss-gain data are in agreement with the microscopic observations. Breakdown of ferromagnesian minerals and feldspars in the quartz-sericite, sericite, and chlorite-sericite zones accompanied by loss in Mg, Fe, Ca, and Na under acidic conditions and low CO2/H2O ratio may obstruct the formation of carbonates and sulphides, and the precipitation of gold in these zones. The role of metamorphic fluids in the area is expected to be restricted to the liberation of Au and some associated elements from their hosts. [source] | ||||||||||