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Metamorphic Conditions (metamorphic + condition)
Selected AbstractsOrthopyroxene,sillimanite,quartz assemblages: distribution, petrology, quantitative P,T,X constraints and P,T pathsJOURNAL OF METAMORPHIC GEOLOGY, Issue 5 2003D. E. Kelsey Abstract Granulite facies magnesian metapelites commonly preserve a wide array of mineral assemblages and reaction textures that are useful for deciphering the metamorphic evolution of a terrane. Quantitative pressure, temperature and bulk composition constraints on the development and preservation of characteristic peak granulite facies mineral assemblages such as orthopyroxene + sillimanite + quartz are assessed with reference to calculated phase diagrams. In NCKFMASH and its chemical subsystems, peak assemblages form mainly in high-variance fields, and most mineral assemblage changes reflect multivariant equilibria. The rarity of orthopyroxene,sillimanite,quartz-bearing assemblages in granulite facies rocks reflects the need for bulk rock XMg of greater than approximately 0.60,0.65, with pressures and temperatures exceeding c. 8 kbar and 850 °C, respectively. Cordierite coronas mantling peak minerals such as orthopyroxene, sillimanite and quartz have historically been used to infer isothermal decompression P,T paths in ultrahigh-temperature granulite facies terranes. However, a potentially wide range of P,T paths from a given peak metamorphic condition facilitate retrograde cordierite growth after orthopyroxene + sillimanite + quartz, indicating that an individual mineral reaction texture is unable to uniquely define a P,T vector. Therefore, the interpretation of P,T paths in high-grade rocks as isothermal decompression or isobaric cooling may be overly simplistic. Integration of quantitative data from different mineral reaction textures in rocks with varying bulk composition will provide the strongest constraints on a P,T path, and in turn on tectonic models derived from these paths. [source] Aqueous fluids at elevated pressure and temperatureGEOFLUIDS (ELECTRONIC), Issue 1-2 2010A. LIEBSCHER Abstract The general major component composition of aqueous fluids at elevated pressure and temperature conditions can be represented by H2O, different non-polar gases like CO2 and different dissolved metal halides like NaCl or CaCl2. At high pressure, the mutual solubility of H2O and silicate melts increases and also silicates may form essential components of aqueous fluids. Given the huge range of P,T,x regimes in crust and mantle, aqueous fluids at elevated pressure and temperature are highly variable in composition and exhibit specific physicochemical properties. This paper reviews principal phase relations in one- and two-component fluid systems, phase relations and properties of binary and ternary fluid systems, properties of pure H2O at elevated P,T conditions, and aqueous fluids in H2O,silicate systems at high pressure and temperature. At metamorphic conditions, even the physicochemical properties of pure water substantially differ from those at ambient conditions. Under typical mid- to lower-crustal metamorphic conditions, the density of pure H2O is , the ion product Kw = 10,7.5 to approximately 10,12.5, the dielectric constant , = 8,25, and the viscosity , = 0.0001,0.0002 Pa sec compared to , Kw = 10,14, , = 78 and , = 0.001 Pa sec at ambient conditions. Adding dissolved metal halides and non-polar gases to H2O significantly enlarges the pressure,temperature range, where different aqueous fluids may co-exist and leads to potential two-phase fluid conditions under must mid- to lower-crustal P,T conditions. As a result of the increased mutual solubility between aqueous fluids and silicate melts at high pressure, the differences between fluid and melt vanishes and the distinction between fluid and melt becomes obsolete. Both are completely miscible at pressures above the respective critical curve giving rise to so-called supercritical fluids. These supercritical fluids combine comparably low viscosity with high solute contents and are very effective metasomatising agents within the mantle wedge above subduction zones. [source] The mechanism of fluid infiltration in peridotites at Almklovdalen, western NorwayGEOFLUIDS (ELECTRONIC), Issue 3 2002O. Kostenko Abstract A major Alpine-type peridotite located at Almklovdalen in the Western Gneiss Region of Norway was infiltrated by aqueous fluids at several stages during late Caledonian uplift and retrogressive metamorphism. Following peak metamorphic conditions in the garnet,peridotite stability field, the peridotite experienced pervasive fluid infiltration and retrogression in the chlorite,peridotite stability field. Subsequently, the peridotite was infiltrated locally by nonreactive fluids along fracture networks forming pipe-like structures, typically on the order of 10 m wide. Fluid migration away from the fractures into the initially impermeable peridotite matrix was facilitated by pervasive dilation of grain boundaries and the formation of intragranular hydrofractures. Microstructural observations of serpentine occupying the originally fluid-filled inclusion space indicate that the pervasively infiltrating fluid was characterized by a high dihedral angle (, > 60°) and ,curled up' into discontinuous channels and fluid inclusion arrays following the infiltration event. Re-equilibration of the fluid phase topology took place by growth and dissolution processes driven by the excess surface energy represented by the ,forcefully' introduced external fluid. Pervasive fluid introduction into the peridotite reduced local effective stresses, increased the effective grain boundary diffusion rates and caused extensive recrystallization and some grain coarsening of the infiltrated volumes. Grain boundary migration associated with this recrystallization swept off abundant intragranular fluid inclusions in the original chlorite peridotite, leading to a significant colour change of the rock. This colour change defines a relatively sharp front typically located 1,20 cm away from the fractures where the nonreactive fluids originally entered the peridotite. Our observations demonstrate how crustal rocks may be pervasively infiltrated by fluids with high dihedral angles (, > 60°) and emphasize the coupling between hydrofracturing and textural equilibration of the grain boundary networks and the fluid phase topology. [source] Subdivision of the Sanbagawa pumpellyite,actinolite facies region in central Shikoku, southwest JapanISLAND ARC, Issue 3 2008Masumi Sakaguchi Abstract The mineral assemblages of the pumpellyite,actinolite facies such as pumpellyite + actinolite + epidote + chlorite or actinolite + epidote + hematite + chlorite occur in the Sanbagawa low-grade metamorphic region, central Shikoku, southwest Japan. Chemical compositions of these minerals from the eight newly studied areas were analyzed in order to evaluate the areal extent and thermal structure of the region. In the buffered assemblage of pumpellyite + actinolite + epidote + chlorite, the Fe3+/(Fe3+ + Al) values of epidote decrease slightly with decreasing Fe2+/(Fe2+ + Mg) values for chlorite. The changes in these values show a general correlation with temperature. The presence of this relationship implies that the Fe3+/(Fe3+ + Al) values of epidote can be used to divide the Sanbagawa low-grade metamorphic region into low-, medium- and high-grade subzones. The areal distribution of these subzones indicates that: (i) the temperature seems to decrease in the same sense as envisaged by the zonal mapping of the higher-grade pelitic schists; and (ii) there is no significant gap of metamorphic conditions through the boundary between the two structural units (Besshi and Oboke units). It follows that the Sanbagawa low-grade metamorphic region decreases in temperature going up the structural section, and tectonic discontinuities have not affected the thermal structure. [source] Transpressional tectonics of the Mineoka Ophiolite Belt in a trench,trench,trench-type triple junction, Boso Peninsula, JapanISLAND ARC, Issue 4 2005Ryota Mori Abstract Structures developed in metamorphic and plutonic blocks that occur as knockers in the Mineoka Ophiolite Belt in the Boso Peninsula, central Japan, were analyzed. The aim was to understand the incorporation processes of blocks of metamorphic and plutonic rocks with an arc signature into the serpentinite mélange of the Mineoka Ophiolite Belt in relation to changes in metamorphic conditions during emplacement. Several stages of deformation during retrogressive metamorphism were identified: the first faulting stage had two substage shearing events (mylonitization) under ductile conditions inside the crystalline blocks in relatively deeper levels; and the second stage had brittle faulting and brecciation along the boundaries between the host serpentinite bodies in relatively shallower levels (zeolite facies). The first deformation occurred during uplift before emplacement. The blocks were intensively sheared by the first deformation event, and developed numerous shear planes with spacing of a few centimeters. The displacement and width of each shear plane were a few centimeters and a few millimeters, respectively, at most. In contrast, the fault zone of the second shearing stage reached a few meters in width and developed during emplacement of the Mineoka Ophiolite. Both stages occurred under a right-lateral transpressional regime, in which thrust-faulting was associated with strike-slip faulting. Such displacement on an outcrop scale is consistent with the present tectonics of the Mineoka Belt. This implies that the same tectonic stress has been operating in the Boso trench,trench,trench-type triple junction area in the northwest corner of the Pacific since the emplacement of the Mineoka Ophiolite. The Mineoka Ophiolite Belt must have worked as a forearc sliver fault during the formation of a Neogene accretionary prism further south. [source] Fluid flow and Al transport during quartz-kyanite vein formation, Unst, Shetland Islands, ScotlandJOURNAL OF METAMORPHIC GEOLOGY, Issue 1 2010C. E. BUCHOLZ Abstract Quartz-kyanite veins, adjacent alteration selvages and surrounding ,precursor' wall rocks in the Dalradian Saxa Vord Pelite of Unst in the Shetland Islands (Scotland) were investigated to constrain the geochemical alteration and mobility of Al associated with channelized metamorphic fluid infiltration during the Caledonian Orogeny. Thirty-eight samples of veins, selvages and precursors were collected, examined using the petrographic microscope and electron microprobe, and geochemically analysed. With increasing grade, typical precursor mineral assemblages include, but are not limited to, chlorite+chloritoid, chlorite+chloritoid+kyanite, chlorite+chloritoid+staurolite and garnet+staurolite+kyanite+chloritoid. These assemblages coexist with quartz, white mica (muscovite, paragonite, margarite), and Fe-Ti oxides. The mineral assemblage of the selvages does not change noticeably with metamorphic grade, and consists of chloritoid, kyanite, chlorite, quartz, white mica and Fe-Ti oxides. Pseudosections for selvage and precursor bulk compositions indicate that the observed mineral assemblages were stable at regional metamorphic conditions of 550,600 °C and 0.8,1.1 GPa. A mass balance analysis was performed to assess the nature and magnitude of geochemical alteration that produced the selvages adjacent to the veins. On average, selvages lost about ,26% mass relative to precursors. Mass losses of Na, K, Ca, Rb, Sr, Cs, Ba and volatiles were ,30 to ,60% and resulted from the destruction of white mica. Si was depleted from most selvages and transported locally to adjacent veins; average selvage Si losses were about ,50%. Y and rare earth elements were added due to the growth of monazite in cracks cutting apatite. The mass balance analysis also suggests some addition of Ti occurred, consistent with the presence of rutile and hematite-ilmenite solid solutions in veins. No major losses of Al from selvages were observed, but Al was added in some cases. Consequently, the Al needed to precipitate vein kyanite was not derived locally from the selvages. Veins more than an order of magnitude thicker than those typically observed in the field would be necessary to accommodate the Na and K lost from the selvages during alteration. Therefore, regional transport of Na and K out of the local rock system is inferred. In addition, to account for the observed abundances of kyanite in the veins, large fluid-rock ratios (102,103 m3fluid m,3rock) and time-integrated fluid fluxes in excess of ,104 m3fluid m,2rock are required owing to the small concentrations of Al in aqueous fluids. It is concluded that the quartz-kyanite veins and their selvages were produced by regional-scale advective mass transfer by means of focused fluid flow along a thrust fault zone. The results of this study provide field evidence for considerable Al mass transport at greenschist to amphibolite facies metamorphic conditions, possibly as a result of elevated concentrations of Al in metamorphic fluids due to alkali-Al silicate complexing at high pressures. [source] The P,T path of the ultra-high pressure Lago Di Cignana and adjoining high-pressure meta-ophiolitic units: insights into the evolution of the subducting Tethyan slabJOURNAL OF METAMORPHIC GEOLOGY, Issue 3 2009C. GROPPO Abstract The Lago di Cignana ultra-high-pressure unit (LCU), which consists of coesite,eclogite facies metabasics and metasediments, preserves the most deeply subducted oceanic rocks worldwide. New constraints on the prograde and early retrograde evolution of this ultra-high pressure unit and adjoining units provide important insights into the evolution of the Piemontese,Ligurian palaeo-subduction zone, active in Paleocene,Eocene times. In the LCU, a first prograde metamorphic assemblage, consisting of omphacite + Ca-amphibole + epidote + rare biotite + ilmenite, formed during burial at estimated P < 1.7 GPa and 350 < T < 480 °C. Similar metamorphic conditions of 400 < T < 650 °C and 1.0 < P < 1.7 GPa have been estimated for the meta-ophiolitic rocks juxtaposed to the LCU. The prograde assemblage is partially re-equilibrated into the peak assemblage garnet + omphacite + Na-amphibole + lawsonite + coesite + rutile, whose conditions were estimated at 590 < T < 605 °C and P > 3.2 GPa. The prograde path was characterized by a gradual decrease in the thermal gradient from ,9,10 to ,5,6 °C km,1. This variation is interpreted as the evidence of an increase in the rate of subduction of the Piemonte,Ligurian oceanic slab in the Eocene. Accretion of the Piemontese oceanic rocks to the Alpine orogen and thermal relaxation were probably related to the arrival of more buoyant continental crust at the subduction zone. Subsequent deformation of the orogenic wedge is responsible for the present position of the LCU, sandwiched between two tectonic slices of meta-ophiolites, named the Lower and Upper Units, which experienced peak pressures of 2.7,2.8 and <2.4 GPa respectively. [source] Formation of eclogite, and reaction during exhumation to mid-crustal levels, Snowbird tectonic zone, western Canadian ShieldJOURNAL OF METAMORPHIC GEOLOGY, Issue 9 2007J. A. BALDWIN Abstract A re-evaluation of the P,T history of eclogite within the East Athabasca granulite terrane of the Snowbird tectonic zone, northern Saskatchewan, Canada was undertaken. Using calculated pseudosections in combination with new garnet,clinopyroxene and zircon and rutile trace element thermometry, peak metamorphic conditions are constrained to ,16 kbar and 750 °C, followed by near-isothermal decompression to ,10 kbar. Associated with the eclogite are two types of occurrences of sapphirine-bearing rocks preserving a rich variety of reaction textures that allow examination of the retrograde history below 10 kbar. The first occurs as a 1,2 m zone adjacent to the eclogite body with a peak assemblage of garnet,kyanite,quartz interpreted to have formed during the eclogite facies metamorphism. Rims of orthopyroxene and plagioclase developed around garnet, and sapphirine,plagioclase and spinel,plagioclase symplectites developed around kyanite. The second variety of sapphirine-bearing rocks occurs in kyanite veins within the eclogite. The veins involve orthopyroxene, garnet and plagioclase layers spatially organized around a central kyanite layer that are interpreted to have formed following the eclogite facies metamorphism. The layering has itself been modified, with, in particular, kyanite being replaced by sapphirine,plagioclase, spinel,plagioclase and corundum,plagioclase symplectites, as well as the kyanite being replaced by sillimanite. Petrological modelling in the CFMAS system examining chemical potential gradients between kyanite and surrounding quartz indicates that these vein textures probably formed during further essentially isothermal decompression, ultimately reaching ,7 kbar and 750 °C. These results indicate that the final reaction in these rocks occurred at mid-crustal levels at upper amphibolite facies conditions. Previous geochronological and thermochronological constraints bracket the time interval of decompression to <5,10 Myr, indicating that ,25 km of exhumation took place during this interval. This corresponds to minimum unroofing rates of ,2,5 mm year,1 following eclogite facies metamorphism, after which the rocks resided at mid-crustal levels for 80,100 Myr. [source] LPHT metamorphism in a late orogenic transpressional setting, Albera Massif, NE Iberia: implications for the geodynamic evolution of the Variscan PyreneesJOURNAL OF METAMORPHIC GEOLOGY, Issue 3 2007M. VILÀ Abstract During the Late Palaeozoic Variscan Orogeny, Cambro-Ordovician and/or Neoproterozoic metasedimentary rocks of the Albera Massif (Eastern Pyrenees) were subject to low-pressure/high-temperature (LPHT) regional metamorphism, with the development of a sequence of prograde metamorphic zones (chlorite-muscovite, biotite, andalusite-cordierite, sillimanite and migmatite). LPHT metamorphism and magmatism occurred in a broadly compressional tectonic regime, which started with a phase of southward thrusting (D1) and ended with a wrench-dominated dextral transpressional event (D2). D1 occurred under prograde metamorphic conditions. D2 started before the P,T metamorphic climax and continued during and after the metamorphic peak, and was associated with igneous activity. P,T estimates show that rocks from the biotite-in isograd reached peak-metamorphic conditions of 2.5 kbar, 400 °C; rocks in the low-grade part of the andalusite-cordierite zone reached peak metamorphic conditions of 2.8 kbar, 535 °C; rocks located at the transition between andalusite-cordierite zone and the sillimanite zone reached peak metamorphic conditions of 3.3 kbar, 625 °C; rocks located at the beginning of the anatectic domain reached peak metamorphic conditions of 3.5 kbar, 655 °C; and rocks located at the bottom of the metamorphic series of the massif reached peak metamorphic conditions of 4.5 kbar, 730 °C. A clockwise P,T trajectory is inferred using a combination of reaction microstructures with appropriate P,T pseudosections. It is proposed that heat from asthenospheric material that rose to shallow mantle levels provided the ultimate heat source for the LPHT metamorphism and extensive lower crustal melting, generating various types of granitoid magmas. This thermal pulse occurred during an episode of transpression, and is interpreted to reflect breakoff of the underlying, downwarped mantle lithosphere during the final stages of oblique continental collision. [source] Variation in peak P,T conditions across the upper contact of the UHP terrane, Dabieshan, China: gradational or abrupt?JOURNAL OF METAMORPHIC GEOLOGY, Issue 9 2006Y. SHI Abstract The Southern Dabieshan Terrane (SDT) has previously been divided into high-pressure (HP) and ultrahigh-pressure (UHP) terranes, and its regional extent and the tectonic nature of its boundaries are hotly debated topics. In this study, an eclogite-bearing area of 100 km2 near Taihu is mapped in detail, and divided into Northern, Middle and Southern Zones on the basis of lithological characteristics. The Northern Zone consists of epidote-biotite gneiss and eclogite blocks, the Middle Zone includes granitic gneiss, biotite gneiss, eclogites and amphibolite, and the Southern Zone is composed mainly of garnet-bearing mica schist. The eclogites occur mainly as lens or blocks in the Northern and Middle Zones. The peak P,T conditions for 61 eclogite samples across the area are estimated using the Grt-Cpx Fe2+ -Mg thermometers and the Grt-Cpx-Phe barometers. The results indicate three different P,T regions: 2.82,4.09 GPa/759,942 °C in the Northern Zone, and 2.00,3.54 GPa/641,839 °C in the granitic gneiss and 1.38,2.36 GPa/535,768 °C in the biotite gneiss from the Middle Zone. Combined with the spatial distribution of eclogites across the area, the P,T values for eclogites increase continuously from the south to the north, defining a reference ,geotherm' of 5 °C km,1. However, some unreasonable apparent gradients can be established along two south,north profiles across the area, and display a P,T difference between the Northern and Middle zones. On the basis of the average P,T data for eclogites across the area, a gap of at least 0.3 GPa/20 °C exists between the Northern and Middle zones. By contrast, the P,T values of eclogites from the Middle zone show a coherent pattern with transitional characteristics from HP in the south to UHP in the north. We suggest that the SDT was a coherent slab during subduction, and was broken up by a major fault during exhumation, which was formed under UHP metamorphic conditions. [source] Modelling of mineral equilibria in ultrahigh-temperature metamorphic rocks from the Anápolis,Itauçu Complex, central BrazilJOURNAL OF METAMORPHIC GEOLOGY, Issue 7 2005J. A. BALDWIN Abstract A new quantitative approach to constraining mineral equilibria in sapphirine-bearing ultrahigh-temperature (UHT) granulites through the use of pseudosections and compatibility diagrams is presented, using a recently published thermodynamic model for sapphirine. The approach is illustrated with an example from an UHT locality in the Anápolis,Itauçu Complex, central Brazil, where modelling of mineral equilibria indicates peak metamorphic conditions of about 9 kbar and 1000 °C. The early formed, coarse-grained assemblage is garnet,orthopyroxene,sillimanite,quartz, which was subsequently modified following peak conditions. The retrograde pressure,temperature (P,T) path of this locality involves decompression across the FeO,MgO,Al2O3,SiO2 (FMAS) univariant reaction orthopyroxene + sillimanite = garnet + sapphirine + quartz, resulting in the growth of sapphirine,quartz, followed by cooling and recrossing of this reaction. The resulting microstructures are modelled using compatibility diagrams, and pseudosections calculated for specific grain boundaries considered as chemical domains. The sequence of microstructures preserved in the rocks constrains a two-stage isothermal decompression,isobaric cooling path. The stability of cordierite along the retrograde path is examined using a domainal approach and pseudosections for orthopyroxene,quartz and garnet,quartz grain boundaries. This analysis indicates that the presence or absence of cordierite may be explained by local variation in aH2O. This study has important implications for thermobarometric studies of UHT granulites, mainly through showing that traditional FMAS petrogenetic grids based on experiments alone may overestimate P,T conditions. Such grids are effectively constant aH2O sections in FMAS-H2O (FMASH), for which the corresponding aH2O is commonly higher than that experienced by UHT granulites. A corollary of this dependence of mineral equilibria on aH2O is that local variations in aH2O may explain the formation of cordierite without significant changes in P,T conditions, particularly without marked decompression. [source] Timing and nature of fluid flow and alteration during Mesoproterozoic shear zone formation, Olary Domain, South AustraliaJOURNAL OF METAMORPHIC GEOLOGY, Issue 3 2005C. CLARK Abstract The development of shear zones at mid-crustal levels in the Proterozoic Willyama Supergroup was synchronous with widespread fluid flow resulting in albitization and calcsilicate alteration. Monazite dating of shear zone fabrics reveal that they formed at 1582 ± 22 Ma, at the end of the Olarian D3 deformational event and immediately prior to the emplacement of regional S-type granites. Two stages of fluid flow are identified in the area: first an albitizing event which involved the addition of Na and loss of Si, K and Fe; and a second phase of calcsilicate alteration with additions of Ca, Fe, Mg and Si and removal of Na. Fluid fluxes calculated for albitization and calcsilicate alteration were 5.56 × 109 to 1.02 × 1010 mol m,2 and 2.57 × 108,5.20 × 109 mol m,2 respectively. These fluxes are consistent with estimates for fluid flow through mid-crustal shear zones in other terranes. The fluids associated with shearing and alteration are calculated to have ,18O and ,D values ranging between +8 and +11,, and ,33 and ,42,, respectively, and ,Nd values between ,2.24 and ,8.11. Our results indicate that fluids were derived from metamorphic dehydration of the Willyama Supergroup metasediments. Fluid generation occurred during prograde metamorphism of deeper crustal rocks at or near peak pressure conditions. Shear zones acted as conduits for major crustal fluid flow to shallow levels where peak metamorphic conditions had been attained earlier leading to the apparent ,retrograde' fluid-flow event. Thus, the peak metamorphism conditions at upper and lower crustal levels were achieved at differing times, prior to regional granite formation, during the same orogenic cycle leading to the formation of retrograde mineral assemblages during shearing. [source] Vertical extrusion and middle crustal spreading of omphacite granulite: a model of syn-convergent exhumation (Bohemian Massif, Czech Republic)JOURNAL OF METAMORPHIC GEOLOGY, Issue 3 2004típská Abstract The exhumation of eclogite facies granulites (Omp,Plg,Grt,Qtz,Rt) in the Rychleby Mts, eastern Czech Republic, was a localised process initiated by buckling of crustal layers in a thickened orogenic root. Folding and post-buckle flattening was followed by the main stage of exhumation that is characterized by vertical ductile extrusion. This process is documented by structural data, and the vertical ascent of rocks from a depth of c. 70 to c. 35 km is documented by metamorphic petrology. SHRIMP 206Pb/238U and 207Pb/206Pb evaporation zircon ages of 342 ± 5 and 341.4 ± 0.7 Ma date peak metamorphic conditions. The next stage of exhumation was associated with sideways flat thrusting associated with lateral viscous spreading of granulites and surrounding rocks over indenting adjacent continental crust at a depth of c. 35,30 km. This stage was associated with syntectonic intrusion of a granodiorite sill at 345,339 Ma, emplaced at a crustal depth of c. 25 km. The time required for cooling of the sill as well as for heating of the country rocks brackets this event to a maximum of 250 000 years. Therefore, similar ages of crystallization for the granodiorite magma and the peak of eclogite facies metamorphism of the granulite suggest a very short period of exhumation, limited by the analytical errors of the dating methods. Our calculations suggest that the initial exhumation rate during vertical extrusion was 3,15 mm yr,1, followed by an exhumation rate of 24,40 mm yr,1 during further uplift along a magma-lubricated shear zone. The extrusion stage of exhumation was associated with a high cooling rate, which decreased during the stage of lateral spreading. [source] Timing of high-grade metamorphism: Early Palaeozoic U,Pb formation ages of titanite indicate long-standing high- T conditions at the western margin of Gondwana (Argentina, 26,29°S)JOURNAL OF METAMORPHIC GEOLOGY, Issue 7 2003F. Lucassen Abstract Concordant U,Pb ages of c. 530,510 Ma and c. 470,420 Ma on titanite from calcsilicate, orthogneiss and amphibolite rocks constrain the age of high- T metamorphism in the Early Palaeozoic mobile belt at the western margin of Proterozoic Gondwana (Argentina, 26,29°S). The U,Pb ages document the time of titanite formation at high- T conditions according to the stable mineral paragenesis and occurrence of titanite in the metamorphic fabric. The presence of migmatite at all sample sites indicates temperatures were > c. 650 °C. Titanite formed at similar metamorphic conditions at different times on the regional and on the outcrop scale. The titanite crystals preserved their U,Pb isotopic signatures and chemical composition under ongoing upper amphibolite to granulite facies temperatures. Different thermal peaks or deformations are only detected by the different U,Pb ages and not by changes in the mineral paragenesis or metamorphic fabric of the samples. The range of U,Pb ages, e.g. in the Ordovician and Silurian (c. 470, 460, 440, 430, 420 Ma), is interpreted as the effect polyphase deformation with deformation-enhanced recrystallization of titanite and/or different thermal peaks during a long-standing, geographically fixed, high- T regime in the mid-crust of a continental magmatic arc. A clear correlation of the different ages with distinct tectonic events, e.g. collision of terranes, is not possible based on the present knowledge of the region. [source] P,T evolution of glaucophane,omphacite bearing HP,LT rocks in the western Tianshan Orogen, NW China:new evidence for ,Alpine-type' tectonicsJOURNAL OF METAMORPHIC GEOLOGY, Issue 2 2002R. Klemd Abstract The late Palaeozoic western Tianshan high-pressure /low-temperature belt extends for about 200 km along the south-central Tianshan suture zone and is composed mainly of blueschist, eclogite and epidote amphibolite/greenschist facies rocks. P,T conditions of mafic garnet omphacite and garnet,omphacite blueschist, which are interlayered with eclogite, were investigated in order to establish an exhumation path for these high-pressure rocks. Maximum pressure conditions are represented by the assemblage garnet,omphacite,paragonite,phengite,glaucophane,quartz,rutile. Estimated maximum pressures range between 18 and 21 kbar at temperatures between 490 and 570 °C. Decompression caused the destabilization of omphacite, garnet and glaucophane to albite, Ca-amphibole and chlorite. The post-eclogite facies metamorphic conditions between 9 and 14 kbar at 480,570 °C suggest an almost isothermal decompression from eclogite to epidote,amphibolite facies conditions. Prograde growth zoning and mineral inclusions in garnet as well as post-eclogite facies conditions are evidence for a clockwise P,T path. Analysis of phase diagrams constrains the P,T path to more or less isothermal cooling which is well corroborated by the results of geothermobarometry and mineral textures. This implies that the high-pressure rocks from the western Tianshan Orogen formed in a tectonic regime similar to ,Alpine-type' tectonics. This contradicts previous models which favour ,Franciscan-type' tectonics for the southern Tianshan high-pressure rocks. [source] Contact metamorphic P,T,t paths from Sm,Nd garnet ages, phase equilibria modelling and thermobarometry: Garnet Ledge, south-eastern Alaska, USAJOURNAL OF METAMORPHIC GEOLOGY, Issue 6 2001H. H. Stowell Abstract Sm,Nd garnet-whole rock geochronology, phase equilibria, and thermobarometry results from Garnet Ledge, south-eastern Alaska, provide the first precisely constrained P,T,t path for garnet zone contact metamorphism. Garnet cores from two crystals and associated whole rocks yield a four point isochron age for initial garnet growth of 89.9 ± 3.6 Ma. Garnet rims and matrix minerals from the same samples yield a five point isochron age for final garnet growth of 89 ± 1 Ma. Six size fractions of zircon from the adjacent pluton yield a concordant U,Pb age of 91.6 ± 0.5 Ma. The garnet core and rim, and zircon ages are compatible with single-stage garnet growth during and/or after pluton emplacement. All garnet core,whole rock and garnet rim-matrix data from the two samples constrain garnet growth duration to ,5.5 my. A garnet mid-point and the associated matrix from one of the two garnet crystals yield an age of 90.0 ± 1.0 Ma. This mid-point result is logically younger than the 90.7 ± 5.6 Ma core,whole rock age and older than the 88.4 ± 2.5 Ma rim-matrix age for this sample. A MnNaCaKFMASH phase diagram (P,T pseudosection) and the garnet core composition are used to predict that cores of garnet crystals grew at 610 ± 20 °C and 5 ± 1 kbar. This exceeds the temperature of the garnet-in reaction by c. 50 °C and is compatible with overstepping of the garnet growth reaction during contact metamorphism. Intersection of three reactions involving garnet-biotite-sillimanite-plagioclase-quartz calculated by THERMOCALC in average P,T mode, and exchange thermobarometry were used to estimate peak metamorphic conditions of 678 ± 58 °C at 6.1 ± 0.9 kbar and 685 ± 50 °C at 6.3 ± 1 kbar, respectively. Integration of pressure, temperature, and age estimates yields a pressure-temperature-time path compatible with near isobaric garnet growth over an interval of c. 70 °C and c. 2.3 my. [source] One-dimensional thermal modelling of Acadian metamorphism in southern Vermont, USAJOURNAL OF METAMORPHIC GEOLOGY, Issue 6 2000T. R. Armstrong One-dimensional thermal (1DT) modelling of an Acadian (Devonian) tectonothermal regime in southern Vermont, USA, used measured metamorphic pressures and temperatures and estimated metamorphic cooling ages based on published thermobarometric and geochronological studies to constrain thermal and tectonic input parameters. The area modelled lies within the Vermont Sequence of the Acadian orogen and includes: (i) a western domain containing garnet-grade pre-Silurian metasedimentary and metavolcanic rocks from the eastern flank of an Acadian composite dome structure (Rayponda,Sadawga Dome); and (ii) an eastern domain containing similar, but staurolite- or kyanite-grade, rocks from the western flank of a second dome structure (Athens Dome), approximately 10 km farther east. Using reasonable input parameters based on regional geological, petrological and geochronological constraints, the thermal modelling produced plausible P,T paths, and temperature,time (T ,t) and pressure,time (P,t) curves. Information extracted from P,T ,t modelling includes values of maximum temperature and pressure on the P,T paths, pressure at maximum temperature, predicted Ar closure ages for hornblende, muscovite and K-feldspar, and integrated exhumation and cooling rates for segments of the cooling history. The results from thermal modelling are consistent with independently obtained pressure, temperature and Ar cooling age data on regional metamorphism in southern Vermont. Modelling results provide some important bounding limits on the physical conditions during regional metamorphism, and indicate that the pressure contemporaneous with the attainment of peak temperature was probably as much as 2.5 kbar lower than the actual maximum pressure experienced by rocks along various particle paths. In addition, differences in peak metamorphic grade (garnet-grade versus staurolite-grade or kyanite-grade) and peak temperature for rocks initially loaded to similar crustal depths, differences in calculated exhumation rates, and differences in 40Ar/39Ar closure ages are likely to have been consequences of variations in the duration of isobaric heating (or ,crustal residence periods') and tectonic unroofing rates. Modelling results are consistent with a regional structural model that suggests west to east younging of specific Acadian deformational events, and therefore diachroneity of attainment of peak metamorphic conditions and subsequent 40Ar/39Ar closure during cooling. Modelling is consistent with the proposition that regional variations in timing and peak conditions of metamorphism are the result of the variable depths to which rocks were loaded by an eastward-thickening thrust-nappe pile rooted to the east (New Hampshire Sequence), as well as by diachronous structural processes within the lower plate rocks of the Vermont Sequence. [source] Primary carbonate/CO2 inclusions in sapphirine-bearing granulites from central Sri LankaJOURNAL OF METAMORPHIC GEOLOGY, Issue 3 2000Bolder-Schrijver High-density CO2 -rich fluid inclusions from a sapphirine-bearing granulite (Hakurutale, Sri Lanka) have been studied by microthermometry, Raman spectrometry and SEM analysis. Based on textural evidence, two groups of inclusions can be identified: primary, negative crystal shaped inclusions (group I) and pseudo-secondary inclusions, which experienced a local, limited post-trapping modification (group II). Both groups contain magnesite as a daughter mineral, occurring in a relatively constant fluid/solid inclusion volume ratio (volsolid =0.15 total volume). CO2 densities for group I and II differ only slightly. Both groups contain a fluid, which was initially trapped at peak metamorphic conditions as a homogeneous (CO2+MgCO3) mixture. Thermodynamic calculations suggest that such a fluid (CO2+15 vol% MgCO3) is stable under granulite facies conditions. After trapping, magnesite separated upon cooling, while the remaining CO2 density suffered minor re-adjustments. A model isochore based on the integration of the magnesite molar volume in the CO2 fluid passes about 1.5,2 kbar below peak metamorphic conditions. This remaining discrepancy can be explained by the possible role of a small quantity of additional water. [source] First discovery of stishovite in an iron meteoriteMETEORITICS & PLANETARY SCIENCE, Issue 11 2003Dan Holtstam The mineral occurs intimately mixed with amorphous silica, forming tabular grains up to ,3 mm wide, with a hexagonal outline. It was identified using X-ray diffraction and Raman microspectroscopy. The unit-cell parameters of stishovite are a = 4.165(3) Å and c = 2.661(6) Å, and its chemical composition is nearly pure SiO2. Raman spectra show relatively sharp bands at 231 and 754 cm,1 and a broad band with an asymmetric shape and a maximum around 500 cm,1. The rare grains are found within troilite nodules together with chromite, daubreelite, and schreibersite. From their composition and morphology, and by comparisons with silica inclusions in, e.g., the Gibeon IVA iron, we conclude that these rare grains represent pseudomorphs after tridymite. The presence of stishovite in Muonionalusta is suggested to reflect shock metamorphic conditions in the IVA parent asteroid during a cosmic impact event. [source] THE PIEDMONT WHITE MARBLES USED IN ANTIQUITY: AN ARCHAEOMETRIC DISTINCTION INFERRED BY A MINERO-PETROGRAPHIC AND C,O STABLE ISOTOPE STUDY*ARCHAEOMETRY, Issue 6 2009A. BORGHI The metamorphic rocks outcropping in the Western Alps are characterized by a great variety of white marbles, which have been poorly studied in the archaeometric field even though they have been used since antiquity. Typical examples are the Arc of August of Roman times in Susa (Piedmont, Italy) and lots of monuments and historical buildings of Turin (Italy). A multi-analytical approach based on petrographic (optical and scanning electron microscopy), electron microprobe and stable isotope analysis of Piedmont white marbles has been performed in order to carry out a detailed description, summarizing their main microtextural, mineralogical and isotopic features. Eight historical Piedmont marbles have been sampled from well-known quarry sites belonging to different metamorphic geological units of the Western Alps (Ornavasso, Crevola, Pont Canavese, Foresto, Chianocco, Prali, Brossasco and Garessio marbles). Their different metamorphic conditions, ages and structural evolution allowed us to draw a discriminative flowchart based on microscopic and minero-chemical data. [source] | |||||||||||||