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Melt Temperature (melt + temperature)
Selected AbstractsSystematic optimization for the evaluation of the microinjection molding parameters of light guide plate with TOPSIS-based Taguchi methodADVANCES IN POLYMER TECHNOLOGY, Issue 1 2010Te-Li Su Abstract A back light module is a key product for providing sufficient light source for a liquid crystal display (LCD). The light guide plate (LGP), used to increase the light usage rate, is a key component in the back light module. This study researches the microinjection molding process parameters and the quality performance of the LGP. Its purpose was to develop a combining Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) with the Taguchi method. This is to optimize the multiquality performance of the LGP for the injection molding manufacturing process, in which both the LCD and the LGP spontaneously produce the best quality performance for V-cut depth and angle. First, an L18 orthogonal array was planned for the manufacturing parameters that affect the microinjection molding process. These included cooling time, mold temperature, melt temperature, injection speed, injection pressure, packing pressure, packing switching, and packing time. The TOPSIS was used to deal with the single-quality optimization disadvantage of the Taguchi method. Then, the TOPSIS response table was used to obtain the optimized manufacturing parameters combination for a multiresponse process optimization. From the analysis of variance, the significant factors for the quality performance of the LGP could be obtained. In other words, by controlling these factors, it was possible to efficiently control the quality performance of the LGP. Finally, with the five verified experiments, the optimized processing parameters came within a 95% confidence interval. © 2010 Wiley Periodicals, Inc. Adv Polym Techn 29:54,63, 2010; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/adv.20181 [source] Influence of processing conditions on the weld line in doubly injection-molded glassy polycarbonate and polystyrene: Microindentation hardness studyADVANCES IN POLYMER TECHNOLOGY, Issue 1 2005M. Boyanova Abstract The microhardness (H) technique has been used to characterize the quality of the weld line in injection-molded tensile bars from a two-component machine in which both melt streams from the same material can be independently controlled. More specific, the influence of melt temperature and indentation location (closer or further from the sample edge parallel to the injection direction and across the weld line) has been followed on polycarbonate (PC) and polystyrene (PS) glassy samples. For both polymers at lower melt temperatures, a strong H decrease (between 15 and 50%) followed by a sharp increase in a narrow distance (around 0.10 mm), is observed. When the melt temperature increases up to 300°C (for PC) and 270°C (for PS), a much smaller H decrease is observed in the central part of the samples. However, closer to the tensile bar edges (2 mm) the weld line remains undetectable by microhardness measurements. The present results reveal that the processing temperature affects the broadening of the weld line through the conditions for effective mutual interdiffusion of chains from the two fronts coming from opposite sides. © 2005 Wiley Periodicals, Inc. Adv Polym Techn 24:14,20, 2005; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/adv.20028 [source] Physical characterization of starch extrudates as a function of melting transitions and extrusion conditionsADVANCES IN POLYMER TECHNOLOGY, Issue 4 2004Stéphanie Blanche Abstract The objective of this study was to investigate the relationships between starch melt transition characteristics, extrusion conditions, and final product properties. Cornstarch was extruded using a corotating twin-screw extruder at varying moisture content, medium/high screw configuration, and 300/400-rpm screw speeds. Extrudates were evaluated for bulk density, expansion ratio, cell structure, bending strength, thermal and pasting properties. Temperature change (,T) was defined as the temperature difference between the native starch melting temperature and its melt temperature just behind the die during extrusion at a given moisture content. ,T was significantly affected by starch moisture content and mechanical shearing, which controlled the melting behavior of the starch in the barrel. Amylose,lipid complex formation during extrusion increased as ,T increased and leveled off at ,T of about 20°C. Pasting peak viscosity of the starch extrudates decreased as ,T increased and leveled off at ,T of about 15°C. Within the same range of mechanical shearing intensity, extrudate bulk density and bending strength decreased linearly as ,T increased. Extrudate expansion was negatively correlated to bulk density. © 2004 Wiley Periodicals, Inc. Adv Polym Techn 23: 277,290, 2004; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/adv.20017 [source] Prediction of cooling time in injection molding by means of a simplified semianalytical equationADVANCES IN POLYMER TECHNOLOGY, Issue 3 2003D. M. Zarkadas Abstract A simplified semianalytical equation, used successfully in food freezing/chilling time prediction, is proposed as a potential simple alternative for cooling time prediction in injection molding of polymer parts, amorphous or semicrystalline. This equation is based on a convective boundary condition for the mold-part interface and requires information on the thermal contact resistance (TCR) or thermal contact conductance (TCC) at this interface, as well as information on the initial and final product temperatures, the mold surface temperature, and the thermal properties of the part. Eighty-five data points for four polymers, Polystyrene (PS), Polycarbonate (PC), Polypropylene (PP), and Polyethylene (PE) were generated with C-MOLDÔ, a commercial injection molding design software, and the performance of the proposed equation was tested. The % mean error and its standard deviation (SD) in cooling time prediction were, respectively, ,11.61 and 2.27 for PS, ,6.04 and 2.13 for PC, ,7.27 and 6.55 for PP, and ,8.88 and 2.93 for PE. It was also shown that the accuracy of the proposed equation is not affected significantly by the exact knowledge of the TCC, provided that the latter is not smaller than 1000,2000 W m,2 K,1. Since in this comparison all necessary temperatures were obtained from C-MOLDÔ, methods of using the proposed equation independently were tested. The use of the inlet melt temperature as the initial product temperature increased the % mean error by mostly 1.5% while its SD remained practically the same. By incorporating a literature based heat balance method in the proposed equation, it was possible to use it as a stand-alone predictor of polymer cooling time. The % mean error and its SD calculated this way were, respectively, ,9.44 and 0.97 for PS, ,9.44 and 0.83 for PC, ,14.22 and 5 for PP, and ,20.12 and 1.38 for PE. The proposed equation, at least in a preliminary stage, can be used successfully to predict the cooling time of the selected semicrystalline or amorphous polymers with the accuracy being higher for amorphous polymers. © 2003 Wiley Periodicals, Inc. Adv Polym Techn 22: 188,208, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/adv.10048 [source] Influence of processing conditions and part design on the gas-assisted injection molding processADVANCES IN POLYMER TECHNOLOGY, Issue 4 2001Nan-Shing Ong Gas-assisted injection molding has been developed to solve the problems that the conventional injection molding process is not able to. It is believed that the new process is able to produce final parts with higher quality at a more effective cost. Warpage and sink marks are reduced and there is material-savings to be reaped. This research aims to investigate some of the processing parameters that come with this new process. They include shot size, gas delay time, gas pressure, and melt temperature. The influence of part design is also looked into. Five designs were used in the research and compared. The responses evaluated include gas bubble length, residual wall thickness, bending strength, warpage, and fingering. © 2001 John Wiley & Sons, Inc. Adv Polym Techn 20: 270,280, 2001 [source] Crystal form and orientation of isotactic polypropylene samples prepared by vibration-injection moldingJOURNAL OF APPLIED POLYMER SCIENCE, Issue 3 2007Jie Zhang Abstract A vibration,injection molding equipment was developed to prepare isotactic polypropylene injection samples to investigate their crystal form and orientation. Wide-angle X-ray scattering experiments (WAXD) were conducted in two modes: theta,theta mode and tube-fixed mode. Through vibration,injection molding, in additional to , form, , form, or , form can be obtained under different conditions. At high melt temperature (230), ,-PP can be induced and the core of the sample contains more ,-PP than the surface. At low melt temperature (190), ,-PP can be induced and the core and the surface of the sample contain approximate same proportion of ,-PP. Pole figures show that ,-PP of a static sample just orientates slightly along M direction, while that of vibration samples orientate much stronger. The orientation of the normal of (040), plane of the sample obtained at T = 230°C, f = 0.5 Hz, and Pv = 75MPa is preferred in M direction, and the orientation of the normal of (040), plane of the sample obtained at T = 190°C, f = 1.5 Hz, and Pv= 35 MPa is preferred in N direction. ,-PP and ,-PP do not show obvious orientation. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 [source] Separation of fatty acids from binary melts using physical vapour deposition (PVD)JOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 3 2009Young Han Kim Abstract BACKGROUND: The use of fatty acid mixtures, natural biochemical compounds, will be extended to various chemical industries for the production of a wide variety of products, and various mixtures of fatty acids are necessary for production. Separation of a binary fatty acid mixture of lauric acid and myristic acid using physical vapour deposition (PVD) on a cold quartz crystal resonator is examined. The extremely small amount of deposits can be measured with the quartz crystal resonator. The vapour phase is prepared by vaporizing a calculated composition of melt according to the vapour-liquid equilibrium (VLE). RESULTS: The composition of lauric acid in the melt and the melt temperature were utilized as operating variables in the PVD. The growth rate of deposit increases when melt temperature and the composition of lauric acid in the melt are increased. The composition of lauric acid in the deposit is significantly lower than that of the melt of 19% lauric acid, but the composition of lauric acid in the deposit is much higher than that of the melts of 50% and 75% lauric acid. CONCLUSION: The distribution coefficient of lauric acid between solid and vapour phases can be correlated as a function of the growth rate of deposit. The possibility of separation of fatty acid mixtures by PVD is suggested experimentally and theoretically. Copyright © 2008 Society of Chemical Industry [source] DGEBA monomer as a solvent for syndiotactic polystyreneMACROMOLECULAR SYMPOSIA, Issue 1 2003Jaap Schut Abstract Syndiotactic polystyrene (sPS) has to be processed at high temperatures (i.e. >290°C due to its melting point of 270°C), which approaches its degradation temperature. We aim to facilitate the processing of sPS by lowering its melt temperature and viscosity with a curable epoxy/amine model system as reactive solvent, which will result in a thermoplastic-thermoset polymer blend. As a first step we therefore investigated the melting behaviour of sPS in epoxy monomer, established its phase diagram, and investigated the crystalline form of sPS in these mixtures. DGEBA epoxy monomer is found to be a solvent for syndiotactic polystyrene at temperatures above 220°C. The DGEBA-sPS phase diagram was established by means of DSC, on the basis of crystallization and melting peaks. The form of the curve in the phase diagram indicates that DGEBA is a poor solvent for sPS. In WAXS studies of blends only the , crystalline form was detected, not the , form, thus no sPS-DGEBA polymer-solvent compounds (clathrates) were detected. However, DGEBA can still serve as a monomer for improved processing as it depresses the crystallization temperature by 20 to 60 K upon addition of 20 to 90 wt% DGEBA respectively, while a 16 to 45 K melting peak depression can be observed by adding 20 to 90 wt% DGEBA. [source] The occurrence of surface roughness in gas assist injection molded nylon compositesPOLYMER COMPOSITES, Issue 2 2000Shih-Jung Liu Gas assist injection molding has increasingly become an important industrial process because of its tremendous flexibility in the design and manufacture of plastic parts. However, there are some unsolved problems that limit the overall success of this technique. The purpose of this report was to study the surface roughness phenomenon occurring in gas assist injection molded thermoplastic composities. The materials used were 15 % and 35% glass-fiber filled nylon-6 composites. Experiments were carried out on an 80-ton injection molding machine equipped with a high-pressure nitrogen-gas injection unit. Two "float-shape" axisymmetric cavities were used. After molding, the surface quality of molded parts was measured by a roughness meter. Various processing variables were studied in terms of their influence on formation of surface roughness: melt temperature, mold temperature, melt filling speed, short-shot size, gas pressure, and gas injection delay time. Scanning electronic microscopy was also employed to characterize the composites. It was found that the surface roughness results mainly from the exposure of glass fiber in the matrix. The jetting and irregular flows of the polymer melt during the filling process might be factors causing the fiber exposure. [source] Theoretical and experimental studies of anisotropic shrinkage in injection moldings of semicrystalline polymersPOLYMER ENGINEERING & SCIENCE, Issue 6 2006Keehae Kwon A novel approach to predict anisotropic shrinkage of semicrystalline polymers in injection moldings was proposed using flow-induced crystallization, frozen-in molecular orientation, elastic recovery, and PVT equation of state. The anisotropic thermal expansion and compressibility affected by the frozen-in orientation function and the elastic recovery that was not frozen during moldings were introduced to obtain the in-plane anisotropic shrinkages. The frozen-in orientation function was calculated from amorphous and crystalline contributions. The amorphous contribution was based on the frozen-in and intrinsic amorphous birefringence, whereas the crystalline contribution was based on the crystalline orientation function, which was determined from the elastic recovery and intrinsic crystalline birefringence. To model the elastic recovery and frozen-in stresses related to birefringence during molding process, a nonlinear viscoelastic constitutive equation was used with temperature- and crystallinity-dependent viscosity and relaxation time. Occurrence of the flow-induced crystallization was introduced through the elevation of melting temperature affected by entropy production during flow of the viscoelastic melt. Kinetics of the crystallization was modeled using Nakamura and Hoffman-Lauritzen equations with the rate constant affected by the elevated melting temperature. Numerous injection molding runs on polypropylene of various molecular weights were carried out by varying the packing time, flow rate, melt temperature, and mold temperature. The anisotropic shrinkage of the moldings was measured. Comparison of the experimental and simulated results indicated a good predictive capability of the proposed approach. POLYM. ENG. SCI., 46:712,728, 2006. © 2006 Society of Plastics Engineers [source] The Effect of Orientation on Extrusion Cast Metallocene Polyethylenes and the Role of Processing Conditions in the Die Swell of Metallocene and Conventional PolyethylenesASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, Issue 1-2 2004B.G. Millar Cast films were prepared from a range of metallocene polyethylenes (mPEs) of varied co-monomer types (hexene, octene) using a Killion single-screw extruder, using different haul off speeds (8,4 m/min) and die gaps (700,250 m,m). Samples with greater orientation in one direction had increased tensile strength and shrinkage in that direction. DSC analysis showed crystallinity to decrease with decreasing haul of speed. Extrusion of mPEs and conventional linear low density polyethylenes (LLDPEs) by single capillary rheology showed that die swell increased with increasing extrusion rate and decreasing melt temperature. Increased die swell was found for the broader molecular weight distribution (M.W.D.) LLDPEs and in the higher molecular weight resins. Furthermore, long chain branching was found to increase die swell. [source] Effect of the age of a spin pack on the dyeing properties of poly(ethylene terephthalate) fibresCOLORATION TECHNOLOGY, Issue 2 2005Sule Altun The spin pack is an essential component of melt spinning processes. However, the age of the spin pack can affect the physical properties of polymers. The dyeing properties of poly(ethylene terephthalate) fibres over time in relation to spin pack age were investigated in the present study. With an increase in the age of the spin pack, an increase in colour strength and a decrease in fibre crystallinity were observed. The crystallinity decrease of the fibres through spin pack age was explained by the increase in polymer melt temperature due to increase in spin pack pressure. [source] Online control of the injection molding process based on process variablesADVANCES IN POLYMER TECHNOLOGY, Issue 2 2009Walter Michaeli Abstract The conventional control of the injection molding process is based on machine variables, which cannot sufficiently characterize the course of the process. Hence, a system that controls the injection molding process based on process variables has been developed at the Institute of Plastics Processing at RWTH Aachen University during the last years. It controls the quality determining process variable cavity pressure directly and realizes a desired course of cavity pressure in the injection and holding pressure phases. The cavity pressure course in the holding pressure phase is controlled online on the basis of pvT behavior of the processed plastic material. Thus, an optimal course of the process in the pvT diagram can be guaranteed and the quality constancy of the molded parts can be clearly increased. Using the pvT-based process control, the effect of varying mold and melt temperatures on the molded part weight can be decreased by about 90% compared with the conventional process control. © 2009 Wiley Periodicals, Inc. Adv Polym Techn 28:65,76, 2009; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/adv.20153 [source] Influence of processing conditions on the weld line in doubly injection-molded glassy polycarbonate and polystyrene: Microindentation hardness studyADVANCES IN POLYMER TECHNOLOGY, Issue 1 2005M. Boyanova Abstract The microhardness (H) technique has been used to characterize the quality of the weld line in injection-molded tensile bars from a two-component machine in which both melt streams from the same material can be independently controlled. More specific, the influence of melt temperature and indentation location (closer or further from the sample edge parallel to the injection direction and across the weld line) has been followed on polycarbonate (PC) and polystyrene (PS) glassy samples. For both polymers at lower melt temperatures, a strong H decrease (between 15 and 50%) followed by a sharp increase in a narrow distance (around 0.10 mm), is observed. When the melt temperature increases up to 300°C (for PC) and 270°C (for PS), a much smaller H decrease is observed in the central part of the samples. However, closer to the tensile bar edges (2 mm) the weld line remains undetectable by microhardness measurements. The present results reveal that the processing temperature affects the broadening of the weld line through the conditions for effective mutual interdiffusion of chains from the two fronts coming from opposite sides. © 2005 Wiley Periodicals, Inc. Adv Polym Techn 24:14,20, 2005; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/adv.20028 [source] Lubrication mechanism of poly(vinyl chloride) compounds: Changes upon PVC fusion (gelation)JOURNAL OF VINYL & ADDITIVE TECHNOLOGY, Issue 2 2005James W. Summers Poly(vinyl chloride) (PVC) compounds perform best with adequate metal lubrication and polymer-to-polymer lubrication of PVC primary particle flow units. Much of the mechanism for the lubrication of PVC has been elucidated over the years. One point has not been completely understood, which is the "lubricant failure" at higher processing temperatures where the compound is known to become less ductile. This result is contrary to what might be expected with better PVC fusion (gelation). This article discusses the mechanism involved, which is lubricant inversion, where the lubricant goes from the continuous phase, as a surfactant coating all the PVC primary particle flow units at lower melt temperatures, to become the discontinuous phase at higher melt temperatures. J. VINYL. ADDIT. TECHNOL., 11:57,62, 2005. © 2005 Society of Plastics Engineers [source] | |||||||||||||